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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-tert.-Butylthio-1-pentanol 1962-39-6 C9H20OS
    5-tert.-Butylthio-1-pentanol
    —— tert.-Butyl-hydroxypentylsulfoxid 62295-82-3 C9H20O2S
    tert.-Butyl-hydroxypentylsulfoxid
    —— n-Butyl-5-hydroxypentyl-sulfon 14633-45-5 C9H20O3S
    n-Butyl-5-hydroxypentyl-sulfon
    —— 1,1'-carbonylbis(3-ethylthio-1,2,4-triazole) 71704-97-7 C9H12N6OS2
    1,1'-carbonylbis(3-ethylthio-1,2,4-triazole)
    —— 3-ethylsulfanyl-[1,2,4]triazole-1-carboxylic acid dipropylamide 34945-18-1 C11H20N4OS
    3-ethylsulfanyl-[1,2,4]triazole-1-carboxylic acid dipropylamide
    —— bis<ethyl(thiocarbonyl)> sulfide 83078-33-5 C6H10S3
    bis<ethyl(thiocarbonyl)> sulfide
    —— 3-(6-ethylthio-3-pyridyl)acrylic acid 118420-06-7 C10H11NO2S
    3-(6-ethylthio-3-pyridyl)acrylic acid
    —— Morpholine-4-carboxylic acid 2-phenylsulfanyl-imidazol-1-yl ester 548767-55-1 C14H15N3O3S
    Morpholine-4-carboxylic acid 2-phenylsulfanyl-imidazol-1-yl ester
    —— 1-(3-(trifluoromethyl)phenyl)-3-(4-(2-oxo-2,3-dihydro-1H-imidazo[4,5-b]pyridin-7-ylthio)phenyl)urea 1147504-54-8 C20H14F3N5O2S
    1-(3-(trifluoromethyl)phenyl)-3-(4-(2-oxo-2,3-dihydro-1H-imidazo[4,5-b]pyridin-7-ylthio)phenyl)urea
    —— 1-(4-chloro-3-(trifluoromethyl)phenyl)-3-(4-(2-oxo-2,3-dihydro-1H-imidazo[4,5-b]pyridin-7-ylthio)phenyl)urea 1147504-56-0 C20H13ClF3N5O2S
    1-(4-chloro-3-(trifluoromethyl)phenyl)-3-(4-(2-oxo-2,3-dihydro-1H-imidazo[4,5-b]pyridin-7-ylthio)phenyl)urea
    —— N1,N1-dimethyl-N2-(4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)pyrimidin-2-yl)ethane-1,2-diamine 1228759-34-9 C19H22N8S
    N1,N1-dimethyl-N2-(4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)pyrimidin-2-yl)ethane-1,2-diamine
    —— 3-chloro-N,N-diethyl-2-{[(4-hydroxy-6-methylpyrimidin-2-yl)sulfanyl]methyl}benzene-1-carboximidamide 1256558-05-0 C17H21ClN4OS
    3-chloro-N,N-diethyl-2-{[(4-hydroxy-6-methylpyrimidin-2-yl)sulfanyl]methyl}benzene-1-carboximidamide
    —— N-butyl-4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)pyrimidin-2-amine 1228759-28-1 C19H21N7S
    N-butyl-4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)pyrimidin-2-amine
    —— 1H-Benzimidazole, 5-chloro-2-[(3,5-dinitrophenyl)thio]- 848725-97-3 C13H7ClN4O4S
    1H-Benzimidazole, 5-chloro-2-[(3,5-dinitrophenyl)thio]-
    —— S-butyl N,N-dimethylthiocarbamate 7322-52-3 C7H15NOS
    S-butyl N,N-dimethylthiocarbamate
    —— 6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-N2,N4-bis(2-morpholinoethyl)-1,3,5-triazine-2,4-diamine 1228759-20-3 C25H33N11O2S
    6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-N2,N4-bis(2-morpholinoethyl)-1,3,5-triazine-2,4-diamine
    —— methyl-thiocarbamic acid <i>S</i>-butyl ester 39076-39-6 C6H13NOS
    methyl-thiocarbamic acid <i>S</i>-butyl ester
    —— 2,6-bis(4,5-dithiobutyl-1,3-dithiol-2-ylidene)benzo[1,2-d:4,5-d']bis[1,3]dithiole 908033-01-2 C30H38S12
    2,6-bis(4,5-dithiobutyl-1,3-dithiol-2-ylidene)benzo[1,2-d:4,5-d']bis[1,3]dithiole
    —— 2,6-bis(4,5-dithiohexyl-1,3-dithiol-2-ylidene)benzo[1,2-d:4,5-d']bis[1,3]dithiole 908033-03-4 C38H54S12
    2,6-bis(4,5-dithiohexyl-1,3-dithiol-2-ylidene)benzo[1,2-d:4,5-d']bis[1,3]dithiole
    —— 4,5-bis-(2-ethylbutylsulfanyl)[1,3]dithiole-2-thione 600717-88-2 C15H26S5
    4,5-bis-(2-ethylbutylsulfanyl)[1,3]dithiole-2-thione
    —— 2,6-bis(4,5-dithiooctyl-1,3-dithiol-2-ylidene)benzo[1,2-d:4,5-d']bis[1,3]dithiole 908033-05-6 C46H70S12
    2,6-bis(4,5-dithiooctyl-1,3-dithiol-2-ylidene)benzo[1,2-d:4,5-d']bis[1,3]dithiole
    —— 4,4'-(6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-1,3,5-triazine-2,4-diyl)dimorpholine 1228759-14-5 C21H23N9O2S
    4,4'-(6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-1,3,5-triazine-2,4-diyl)dimorpholine
    —— N2,N4-dibutyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-1,3,5-triazine-2,4-diamine 1228759-17-8 C21H27N9S
    N2,N4-dibutyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-1,3,5-triazine-2,4-diamine
    —— 3-(4,6-di(piperidin-1-yl)-1,3,5-triazin-2-ylthio)-5-methyl-5H-[1,2,4]triazino[5,6-b]indole 1228759-13-4 C23H27N9S
    3-(4,6-di(piperidin-1-yl)-1,3,5-triazin-2-ylthio)-5-methyl-5H-[1,2,4]triazino[5,6-b]indole
    —— 6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-N2,N4-bis(3-morpholinopropyl)-1,3,5-triazine-2,4-diamine 1228759-21-4 C27H37N11O2S
    6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-N2,N4-bis(3-morpholinopropyl)-1,3,5-triazine-2,4-diamine
    —— N1,N1'-(6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-1,3,5-triazine-2,4-diyl)bis(N2,N2-diethylethane-1,2-diamine) 1228759-23-6 C25H37N11S
    N1,N1'-(6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-1,3,5-triazine-2,4-diyl)bis(N2,N2-diethylethane-1,2-diamine)
    —— N2,N4-diisopropyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-1,3,5-triazine-2,4-diamine 1228759-19-0 C19H23N9S
    N2,N4-diisopropyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-1,3,5-triazine-2,4-diamine
    —— 5-methyl-3-(6-methyl-2-(piperidin-1-yl)pyrimidin-4-ylthio)-5H-[1,2,4]triazino[5,6-b]indole 1228759-24-7 C20H21N7S
    5-methyl-3-(6-methyl-2-(piperidin-1-yl)pyrimidin-4-ylthio)-5H-[1,2,4]triazino[5,6-b]indole
    —— N2,N4-di-tert-butyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-1,3,5-triazine-2,4-diamine 1228759-18-9 C21H27N9S
    N2,N4-di-tert-butyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-1,3,5-triazine-2,4-diamine
    —— N1,N1'-(6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-1,3,5-triazine-2,4-diyl)bis(N2,N2-dimethylethane-1,2-diamine) 1228759-22-5 C21H29N11S
    N1,N1'-(6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-1,3,5-triazine-2,4-diyl)bis(N2,N2-dimethylethane-1,2-diamine)
    —— N-isopropyl-4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)pyrimidin-2-amine 1228759-30-5 C18H19N7S
    N-isopropyl-4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)pyrimidin-2-amine
    —— 3-(4,6-dichloro-1,3,5-triazin-2-ylthio)-5-methyl-5H-[1,2,4]triazino[5,6-b]indole 1228759-11-2 C13H7Cl2N7S
    3-(4,6-dichloro-1,3,5-triazin-2-ylthio)-5-methyl-5H-[1,2,4]triazino[5,6-b]indole
    —— 4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-N-(2-morpholinoethyl)pyrimidin-2-amine 1228759-31-6 C21H24N8OS
    4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-N-(2-morpholinoethyl)pyrimidin-2-amine
    —— 4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-N-(3-morpholinopropyl)pyrimidin-2-amine 1228759-32-7 C22H26N8OS
    4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)-N-(3-morpholinopropyl)pyrimidin-2-amine
    —— N-tert-butyl-4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)pyrimidin-2-amine 1228759-29-2 C19H21N7S
    N-tert-butyl-4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)pyrimidin-2-amine
    —— N1,N1-diethyl-N2-(4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)pyrimidin-2-yl)ethane-1,2-diamine 1228759-35-0 C21H26N8S
    N1,N1-diethyl-N2-(4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)pyrimidin-2-yl)ethane-1,2-diamine
    —— 4-(4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)pyrimidin-2-yl)morpholine 1228759-25-8 C19H19N7OS
    4-(4-methyl-6-(5-methyl-5H-[1,2,4]triazino[5,6-b]indol-3-ylthio)pyrimidin-2-yl)morpholine
    —— 2,3-dihydrobenzo[b]thiophene-7-sulfonylisocyanate-1,1-dioxide 100594-14-7 C9H7NO5S2
    2,3-dihydrobenzo[b]thiophene-7-sulfonylisocyanate-1,1-dioxide
    —— 1,6-dihydro-3-(phenylthio)-7H-pyrrolo[2,3-c]pyridin-7-one 259684-39-4 C13H10N2OS
    1,6-dihydro-3-(phenylthio)-7H-pyrrolo[2,3-c]pyridin-7-one
    —— 2-(3-amino-2-methoxypyridin-4-yl)-2-(phenylthio)acetaldehyde dimethylacetal 259684-48-5 C16H20N2O3S
    2-(3-amino-2-methoxypyridin-4-yl)-2-(phenylthio)acetaldehyde dimethylacetal
    —— 1-Isopropyl-3-hydroxy-5-aethylthio-1,2,4-triazol 55375-82-1 C7H13N3OS
    1-Isopropyl-3-hydroxy-5-aethylthio-1,2,4-triazol
    —— O,O-dimethyl 2-chloro-1-phenylthioisopropylphosphonate 88691-18-3 C11H16ClO3PS
    O,O-dimethyl 2-chloro-1-phenylthioisopropylphosphonate
    —— 4-methoxy-6-methyl-2-(methylthio)-3-nitropyridine 179056-95-2 C8H10N2O3S
    4-methoxy-6-methyl-2-(methylthio)-3-nitropyridine
    —— 6-methyl-2-(methylthio)-3-nitro-1H-pyridin-4-one 179056-96-3 C7H8N2O3S
    6-methyl-2-(methylthio)-3-nitro-1H-pyridin-4-one
    —— 4-chloro-6-methyl-2-(methylthio)-3-nitropyridine 179056-97-4 C7H7ClN2O2S
    4-chloro-6-methyl-2-(methylthio)-3-nitropyridine
    —— 3-amino-4-chloro-6-methyl-2-(methylthio)pyridine 179055-85-7 C7H9ClN2S
    3-amino-4-chloro-6-methyl-2-(methylthio)pyridine
    —— dichloroanhydride of 2-chloro-1-phenylthioisopropylphosphonic acid 88691-20-7 C9H10Cl3OPS
    dichloroanhydride of 2-chloro-1-phenylthioisopropylphosphonic acid
    —— 2-[(5,6,7,8-Tetrahydro-2-methyl[1,2,4]triazolo[5,1-b]quinazolin-9-yl)thio]benzenamine 1211496-18-2 C16H17N5S
    2-[(5,6,7,8-Tetrahydro-2-methyl[1,2,4]triazolo[5,1-b]quinazolin-9-yl)thio]benzenamine
    —— 5-amino-2-methylthiopyrimidine-4,6-diol 884861-16-9 C5H7N3O2S
    5-amino-2-methylthiopyrimidine-4,6-diol
    —— N-Methylthiopropionimidsaeure-methylester 117966-03-7 C5H11NS
    N-Methylthiopropionimidsaeure-methylester