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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (4-bromonaphthalen-1-yl)(phenyl)sulfide 129278-08-6 C16H11BrS
    (4-bromonaphthalen-1-yl)(phenyl)sulfide
    —— 6-Methyl-5-phenyl-3,4,5,6-tetrahydro-2H-1,6-benzothiazocine 87697-07-2 C17H19NS
    6-Methyl-5-phenyl-3,4,5,6-tetrahydro-2H-1,6-benzothiazocine
    —— 5-butyl-3,4,5,6-tetrahydro-5-phenyl-2H-1,6-benzothiazocine 87697-17-4 C20H25NS
    5-butyl-3,4,5,6-tetrahydro-5-phenyl-2H-1,6-benzothiazocine
    —— 5-Phenyl-3,4,5,6-tetrahydro-2H-1,6-benzothiazocine 87697-02-7 C16H17NS
    5-Phenyl-3,4,5,6-tetrahydro-2H-1,6-benzothiazocine
    —— 2,6-bis((4-(pyridin-2-yl)pyrimidin-2-ylthio)methyl)-4-chlorophenol 944956-82-5 C26H19ClN6OS2
    2,6-bis((4-(pyridin-2-yl)pyrimidin-2-ylthio)methyl)-4-chlorophenol
    —— 1-(5-Phenyl-2,3,4,5-tetrahydro-6H-1,6-benzothiazocin-6-yl)ethan-1-one 87697-11-8 C18H19NOS
    1-(5-Phenyl-2,3,4,5-tetrahydro-6H-1,6-benzothiazocin-6-yl)ethan-1-one
    —— (2R,4R)-2,4-O-Isopropylidene-1-(phenylthio)-6-heptene-2-ol 171523-98-1 C16H22O2S
    (2R,4R)-2,4-O-Isopropylidene-1-(phenylthio)-6-heptene-2-ol
    —— trans-1,4-di(thioethyl)but-2-ene 79029-65-5 C8H16S2
    trans-1,4-di(thioethyl)but-2-ene
    —— (2S)-1-[2-[(2R,4R)-4-[tert-butyl(dimethyl)silyl]oxy-2-triethylsilyloxyhept-6-enyl]-1,3-dithian-2-yl]propan-2-ol 1173020-18-2 C26H54O3S2Si2
    (2S)-1-[2-[(2R,4R)-4-[tert-butyl(dimethyl)silyl]oxy-2-triethylsilyloxyhept-6-enyl]-1,3-dithian-2-yl]propan-2-ol
    —— (2R,4S)-4-<<Dimethyl(2-methyl-2-propyl)silyl>oxy>-1-(phenylthio)-6-hepten-2-ol 171523-99-2 C19H32O2SSi
    (2R,4S)-4-<<Dimethyl(2-methyl-2-propyl)silyl>oxy>-1-(phenylthio)-6-hepten-2-ol
    —— (2R,4R)-4-<<Dimethyl(2-methyl-2-propyl)silyl>oxy>-1-(phenylthio)-6-hepten-2-ol 171523-97-0 C19H32O2SSi
    (2R,4R)-4-<<Dimethyl(2-methyl-2-propyl)silyl>oxy>-1-(phenylthio)-6-hepten-2-ol
    —— (2R,4S)-2,4-O-Isopropylidene-1-(phenylthio)-6-heptene-2-ol 171598-92-8 C16H22O2S
    (2R,4S)-2,4-O-Isopropylidene-1-(phenylthio)-6-heptene-2-ol
    —— 3,4-bis(methylthio)-1,2,5-thiadiazole 1-oxide 79844-65-8 C4H6N2OS3
    3,4-bis(methylthio)-1,2,5-thiadiazole 1-oxide
    —— 13,13-dichloro-1-phenylthio <10.1.0> bicyclotridecane 143741-59-7 C19H26Cl2S
    13,13-dichloro-1-phenylthio <10.1.0> bicyclotridecane
    —— 2-(sec-butyldisulfanyl)pyridine 52197-11-2 C9H13NS
    2-(sec-butyldisulfanyl)pyridine
    —— γ-phenylthiopropyl gem-dichlorocyclopropylmethyl ether 872413-70-2 C13H16Cl2OS
    γ-phenylthiopropyl gem-dichlorocyclopropylmethyl ether
    —— 2-(3-Propoxypropylsulfanyl)phenol 210350-94-0 C12H18O2S
    2-(3-Propoxypropylsulfanyl)phenol
    —— S,S′-[benzene-1,3-diylbis(4H-1,2,4-triazole-5,3-diyl)]bis{[(5-benzene-1,3-diyl-4H-1,2,4-triazol-3-yl)sulfanyl]ethanethioate} 1370035-70-3 C24H16N12O2S4
    S,S′-[benzene-1,3-diylbis(4H-1,2,4-triazole-5,3-diyl)]bis{[(5-benzene-1,3-diyl-4H-1,2,4-triazol-3-yl)sulfanyl]ethanethioate}
    —— 2-hydroxy-(2-(2-phenylthio)phenyl)acetic acid 132121-24-5 C14H12O3S
    2-hydroxy-(2-(2-phenylthio)phenyl)acetic acid
    —— ethanethiosulfonic acid 51554-68-8 C2H6O2S2
    ethanethiosulfonic acid
    —— 4-chloro-2-[[4-(ethylsulfonyl)phenyl]thio]-1-methoxy-benzene 847147-98-2 C15H15ClO3S2
    4-chloro-2-[[4-(ethylsulfonyl)phenyl]thio]-1-methoxy-benzene
    —— {2-[(2,4-dinitrophenyl)thio]phenyl}hydrazine 1309863-58-8 C12H10N4O4S
    {2-[(2,4-dinitrophenyl)thio]phenyl}hydrazine
    —— 1,2-bis(2-ethylthio-3-thienyl)perfluorocyclopentene 223129-11-1 C17H14F6S4
    1,2-bis(2-ethylthio-3-thienyl)perfluorocyclopentene
    —— 1,6-dioxa-2,5-diaza-6aΛ<sup>4</sup>-thiapentalene 57167-49-4 C3H2N2O2S
    1,6-dioxa-2,5-diaza-6aΛ<sup>4</sup>-thiapentalene
    —— ethyl 3-(4-chlorophenylthio)-2,2-difluoro-3-phenylpropanoate 1253930-82-3 C17H15ClF2O2S
    ethyl 3-(4-chlorophenylthio)-2,2-difluoro-3-phenylpropanoate
    —— 1-[2-(1,3-benzodithiol-2-ylidenemethyl)-1,5-dimethylpyrrol-4-yl]-2-(2-formyl-1,5-dimethylpyrrol-4-yl)perfluorocyclopentene 638173-92-9 C26H20F6N2OS2
    1-[2-(1,3-benzodithiol-2-ylidenemethyl)-1,5-dimethylpyrrol-4-yl]-2-(2-formyl-1,5-dimethylpyrrol-4-yl)perfluorocyclopentene
    —— 1,2-bis[2-(1,3-benzodithiol-2-ylidenemethyl)-1,5-dimethylpyrrol-4-yl]perfluorocyclopentene 638173-94-1 C33H24F6N2S4
    1,2-bis[2-(1,3-benzodithiol-2-ylidenemethyl)-1,5-dimethylpyrrol-4-yl]perfluorocyclopentene
    —— O-[methyl (1R,2R,4S,4aR,8aR)-decahydro-2-methylnaphthalene-1-carboxylate-4-yl] S-methyl dithiocarbonate 327162-04-9 C15H24O3S2
    O-[methyl (1R,2R,4S,4aR,8aR)-decahydro-2-methylnaphthalene-1-carboxylate-4-yl] S-methyl dithiocarbonate
    —— 4-methoxy-6-[(1R,2R,4aS,8aR)-1,2,4a,5,6,7,8,8a-octahydro-2-methyl-1-naphthyl]-3-phenylthiomethyl-2H-pyran-2-one 327162-12-9 C24H28O3S
    4-methoxy-6-[(1R,2R,4aS,8aR)-1,2,4a,5,6,7,8,8a-octahydro-2-methyl-1-naphthyl]-3-phenylthiomethyl-2H-pyran-2-one
    —— N-tert-Butyl-2,2-dichloro-3-methylcyclopropanethioamide 155193-22-9 C9H15Cl2NS
    N-tert-Butyl-2,2-dichloro-3-methylcyclopropanethioamide
    —— 1-chlorocyclopropyl methyl sulfide 78708-99-3 C4H7ClS
    1-chlorocyclopropyl methyl sulfide
    —— 1,1-Dichloro-2-(2-methylpropylsulfanyl)cyclopropane 75382-55-7 C7H12Cl2S
    1,1-Dichloro-2-(2-methylpropylsulfanyl)cyclopropane
    —— ethyl 5-ethyl-2-thienyl sulfide 14744-79-7 C8H12S2
    ethyl 5-ethyl-2-thienyl sulfide
    —— 2-Butylsulfanyl-1,1-dichlorocyclopropane 70358-75-7 C7H12Cl2S
    2-Butylsulfanyl-1,1-dichlorocyclopropane
    —— Dimethylmercaptoacetamid 5311-18-2 C4H9NOS2
    Dimethylmercaptoacetamid
    —— isobutylsulfanyl-ethene 24345-81-1 C6H12S
    isobutylsulfanyl-ethene
    —— 1-<5-(phenylselanyl)pentyl>-2-(phenylsulfanyl)-1H-benzimidazole 191542-45-7 C24H24N2SSe
    1-<5-(phenylselanyl)pentyl>-2-(phenylsulfanyl)-1H-benzimidazole
    —— 6-(phenylthio)bicyclo<2.2.1>hept-5-en-2-one ethylene ketal 119595-42-5 C15H16O2S
    6-(phenylthio)bicyclo<2.2.1>hept-5-en-2-one ethylene ketal
    —— (E)-1-methoxy-3-<(phenylthio)methyl>-1,3-butadiene 86531-05-7 C12H14OS
    (E)-1-methoxy-3-<(phenylthio)methyl>-1,3-butadiene
    —— tert-butyl [((S)-1-{(3S,4R,6R)-4-(tert-butyldimethylsilyloxy)-6-[(4S,6S)-2,2-dimethyl-6-(phenylsulfanylmethyl)-1,3-dioxan-4-yl]methyl}-2-methoxy-3,4,5,6-tetrahydro-2H-pyran-3-yl)hexyloxy]dimethylsilane 1643685-85-1 C38H70O6SSi2
    tert-butyl [((S)-1-{(3S,4R,6R)-4-(tert-butyldimethylsilyloxy)-6-[(4S,6S)-2,2-dimethyl-6-(phenylsulfanylmethyl)-1,3-dioxan-4-yl]methyl}-2-methoxy-3,4,5,6-tetrahydro-2H-pyran-3-yl)hexyloxy]dimethylsilane
    —— (4R,6R)-4-(dimethylphenylsilyl)-6-{[(4S,6S)-2,2-dimethyl-6-(phenylsulfanylmethyl)-1,3-dioxan-4-yl]methyl}-3,4,5,6-tetrahydro-2H-pyran-2-one 1643685-79-3 C27H36O4SSi
    (4R,6R)-4-(dimethylphenylsilyl)-6-{[(4S,6S)-2,2-dimethyl-6-(phenylsulfanylmethyl)-1,3-dioxan-4-yl]methyl}-3,4,5,6-tetrahydro-2H-pyran-2-one
    —— 2-(phenylthiomethyl)prop-2-en-1-ol 141502-71-8 C10H12OS
    2-(phenylthiomethyl)prop-2-en-1-ol
    —— 1-[2-Methoxy-4-[(phenylthio)methyl]-1-cyclohex-3-enyl]ethanone 344338-69-8 C16H20O2S
    1-[2-Methoxy-4-[(phenylthio)methyl]-1-cyclohex-3-enyl]ethanone
    —— 1-<4-(phenylselanyl)butyl>-2-(phenylsulfanyl)-1H-benzimidazole 191542-44-6 C23H22N2SSe
    1-<4-(phenylselanyl)butyl>-2-(phenylsulfanyl)-1H-benzimidazole
    —— 1-[4-[(Phenylthio)methyl]-1-cyclohexa-1,3-dienyl]ethanone 86531-30-8 C15H16OS
    1-[4-[(Phenylthio)methyl]-1-cyclohexa-1,3-dienyl]ethanone
    —— 2,3,4,5-Tetrafluorophenylmethylsulfid 27384-37-8 C7H4F4S
    2,3,4,5-Tetrafluorophenylmethylsulfid
    —— tert-Butyl{[9-methoxy-9-(phenylsulfanyl)nonyl]oxy}dimethylsilane 116204-89-8 C22H40O2SSi
    tert-Butyl{[9-methoxy-9-(phenylsulfanyl)nonyl]oxy}dimethylsilane
    —— n-propyl [(3-nitropyridin-2-yl)sulfanyl]acetate 1379575-27-5 C10H12N2O4S
    n-propyl [(3-nitropyridin-2-yl)sulfanyl]acetate
    —— 2-(p-tolyl)-2-(phenylsulfenyl)ethanol 139058-60-9 C15H16OS
    2-(p-tolyl)-2-(phenylsulfenyl)ethanol
    —— methyl 3-methyl-4-phenylthiobut-2-enoate 73311-59-8 C12H14O2S
    methyl 3-methyl-4-phenylthiobut-2-enoate