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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Methyl 3-methyl-4-phenylsulfanylbut-2-enoate 73311-58-7 C12H14O2S
    Methyl 3-methyl-4-phenylsulfanylbut-2-enoate
    —— N-(1H-benzimidazol-2-ylmethyl)-2-[1-[2-[2-(1H-benzimidazol-2-ylmethylamino)-2-oxoethoxy]naphthalen-1-yl]sulfanylnaphthalen-2-yl]oxyacetamide 1351952-57-2 C40H32N6O4S
    N-(1H-benzimidazol-2-ylmethyl)-2-[1-[2-[2-(1H-benzimidazol-2-ylmethylamino)-2-oxoethoxy]naphthalen-1-yl]sulfanylnaphthalen-2-yl]oxyacetamide
    —— methyl 3-methyl-4-phenylthiobut-2-enoate 73311-58-7 C12H14O2S
    methyl 3-methyl-4-phenylthiobut-2-enoate
    —— 2,6-C5H3N(CH2OP(OC10H6)(μ-S)(C10H6O))2 934736-94-4 C47H31NO6P2S2
    2,6-C5H3N(CH2OP(OC10H6)(μ-S)(C10H6O))2
    —— 2-Methyl-1,3-dithian-2-essigsaeure 73510-78-8 C7H12O2S2
    2-Methyl-1,3-dithian-2-essigsaeure
    —— 14-[1-[2-(13,15-Dioxa-2-thia-14-phosphapentacyclo[14.8.0.03,12.04,9.019,24]tetracosa-1(16),3(12),4,6,8,10,17,19,21,23-decaen-14-yloxy)naphthalen-1-yl]sulfanylnaphthalen-2-yl]oxy-13,15-dioxa-2-thia-14-phosphapentacyclo[14.8.0.03,12.04,9.019,24]tetracosa-1(16),3(12),4,6,8,10,17,19,21,23-decaene 1034498-37-7 C60H36O6P2S3
    14-[1-[2-(13,15-Dioxa-2-thia-14-phosphapentacyclo[14.8.0.03,12.04,9.019,24]tetracosa-1(16),3(12),4,6,8,10,17,19,21,23-decaen-14-yloxy)naphthalen-1-yl]sulfanylnaphthalen-2-yl]oxy-13,15-dioxa-2-thia-14-phosphapentacyclo[14.8.0.03,12.04,9.019,24]tetracosa-1(16),3(12),4,6,8,10,17,19,21,23-decaene
    —— 3-(hexadecane-1-sulfonyl)-2-(hexadecane-1-sulfonylmethyl)propionic acid 888731-27-9 C36H72O6S2
    3-(hexadecane-1-sulfonyl)-2-(hexadecane-1-sulfonylmethyl)propionic acid
    —— 5-phenyl-[1,3]dithiolo[4,5-b][1,4]dithiin-2-one 337533-79-6 C11H6OS4
    5-phenyl-[1,3]dithiolo[4,5-b][1,4]dithiin-2-one
    —— 6<i>H</i>-benzo[<i>f</i>]pyrido[1,2-<i>c</i>][1,3,5]thiadiazepine 54258-12-7 C12H10N2S
    6<i>H</i>-benzo[<i>f</i>]pyrido[1,2-<i>c</i>][1,3,5]thiadiazepine
    —— 2-amino-1-[[(o-bromophenyl)thio]methyl]pyrimidinium chloride 55695-09-5 C11H11BrN3S*Cl
    2-amino-1-[[(o-bromophenyl)thio]methyl]pyrimidinium chloride
    —— (RS)-1-(2-pyridylthio)propan-2-ol 464934-45-0 C8H11NOS
    (RS)-1-(2-pyridylthio)propan-2-ol
    —— 4-{[dichlorofluoromethyl]thio}-1H-pyrazole-1-ylmethanol 860807-78-9 C5H5Cl2FN2OS
    4-{[dichlorofluoromethyl]thio}-1H-pyrazole-1-ylmethanol
    —— methyl 3-<(phenylthio)methyl>pent-2-enoate 88087-87-0 C13H16O2S
    methyl 3-<(phenylthio)methyl>pent-2-enoate
    —— 4-{[dichlorofluoromethyl]thio}-1H-pyrazole 860807-77-8 C4H3Cl2FN2S
    4-{[dichlorofluoromethyl]thio}-1H-pyrazole
    —— 3-(hexadecane-1-sulfonyl)-2-(hexadecane-1-sulfonylmethyl)-propionic acid 2-{2-[2-(2-{2-[2-(tert-butyl-dimethyl-silanyloxy)ethoxy]-ethoxy}ethoxy)ethoxy]ethoxy}ethyl ester 888731-30-4 C54H110O12S2Si
    3-(hexadecane-1-sulfonyl)-2-(hexadecane-1-sulfonylmethyl)-propionic acid 2-{2-[2-(2-{2-[2-(tert-butyl-dimethyl-silanyloxy)ethoxy]-ethoxy}ethoxy)ethoxy]ethoxy}ethyl ester
    —— 4-ethyl-4-(phenylthio)-4,5-dihydrofuran-2(3H)-one 79749-95-4 C12H14O2S
    4-ethyl-4-(phenylthio)-4,5-dihydrofuran-2(3H)-one
    —— 6-Methyl-6-[(phenylsulfanyl)methyl]decan-5-one 144424-56-6 C18H28OS
    6-Methyl-6-[(phenylsulfanyl)methyl]decan-5-one
    —— 1-chloro-4-[(E)-1-chlorohex-1-en-2-yl]sulfanylbenzene 58866-61-8 C12H14Cl2S
    1-chloro-4-[(E)-1-chlorohex-1-en-2-yl]sulfanylbenzene
    —— methyl 3-[(phenylthio)methyl]pent-3-enoate 108378-59-2 C13H16O2S
    methyl 3-[(phenylthio)methyl]pent-3-enoate
    —— 2-[[5-(3-oxo-3-thiophen-2-ylpropanoyl)-1H-1,2,4-triazol-3-yl]sulfanyl]butanedioic acid 133765-19-2 C13H11N3O6S2
    2-[[5-(3-oxo-3-thiophen-2-ylpropanoyl)-1H-1,2,4-triazol-3-yl]sulfanyl]butanedioic acid
    —— ethyl-5-(2-thenoylacetyl)-1,2,4-triazol-3-yl-thioacetate 133782-36-2 C13H13N3O4S2
    ethyl-5-(2-thenoylacetyl)-1,2,4-triazol-3-yl-thioacetate
    —— 2-Ethylsulfanyl-5-methylsulfonyl-4-phenyl-1,3-thiazine-6-thione 117235-96-8 C13H13NO2S4
    2-Ethylsulfanyl-5-methylsulfonyl-4-phenyl-1,3-thiazine-6-thione
    —— 1,8-bis(methylthio)octane 20295-48-1 C10H22S2
    1,8-bis(methylthio)octane
    —— S-allylisothiosemicarbazone hydrobromide 58255-42-8 BrH*C4H9N3S
    S-allylisothiosemicarbazone hydrobromide
    —— bis(3,5-dimethyl-4-oxo-4H-thiopyran-2-yl)sulfide 61170-12-5 C14H14O2S3
    bis(3,5-dimethyl-4-oxo-4H-thiopyran-2-yl)sulfide
    —— cis-2,6-diethylsulfonyl-1,4-dithiafulvene 74057-73-1 C8H12O4S4
    cis-2,6-diethylsulfonyl-1,4-dithiafulvene
    —— trans-2,6-diethylsulfonyl-1,4-dithiafulvene 74057-74-2 C8H12O4S4
    trans-2,6-diethylsulfonyl-1,4-dithiafulvene
    —— Dimethyl-2,4 methylthio-7 dihydro-1,2 pyrazino<4,3-c>pyridine 97224-48-1 C10H11N3OS
    Dimethyl-2,4 methylthio-7 dihydro-1,2 pyrazino<4,3-c>pyridine
    —— hydroxy-3 trimethyl-1,2,5 methylthio-4(1H)pyrrole 117839-41-5 C8H13NOS
    hydroxy-3 trimethyl-1,2,5 methylthio-4(1H)pyrrole
    —— Dimethyl-2,4 bis(methylthio)-5,7 oxo-1 dihydro-1,2 pyrazino<4,3-c>pyridine 97224-47-0 C11H13N3OS2
    Dimethyl-2,4 bis(methylthio)-5,7 oxo-1 dihydro-1,2 pyrazino<4,3-c>pyridine
    —— 2-phenyl-2-(phenylthio)tetrahydrofuran 1469994-85-1 C16H16OS
    2-phenyl-2-(phenylthio)tetrahydrofuran
    —— methyl β-dichloromethylsulfonylpropionate 119451-34-2 C5H8Cl2O4S
    methyl β-dichloromethylsulfonylpropionate
    —— 1-ethanesulfonyl-propene 161573-87-1 C5H10O2S
    1-ethanesulfonyl-propene
    —— (E)-ethyl 1-propenyl sulfone 65832-95-3 C5H10O2S
    (E)-ethyl 1-propenyl sulfone
    —— 3-chloro-1<i>t</i>-ethylsulfanyl-propene 70967-12-3 C5H9ClS
    3-chloro-1<i>t</i>-ethylsulfanyl-propene
    —— ethyl 2-propenyl sulfoxide 34757-40-9 C5H10OS
    ethyl 2-propenyl sulfoxide
    —— 5-[2-fluoro-6-(ethylthio)phenyl]oxazolidine-2,4-dione 100947-71-5 C11H10FNO3S
    5-[2-fluoro-6-(ethylthio)phenyl]oxazolidine-2,4-dione
    —— 5-(5-Methylsulfanyl-1,3,4-thiadiazol-2-yl)-1,3,4-thiadiazol-2-amine 110713-57-0 C5H5N5S3
    5-(5-Methylsulfanyl-1,3,4-thiadiazol-2-yl)-1,3,4-thiadiazol-2-amine
    —— 2-methylthio-4-(1-phenylethyl)amino-6-propylthiopyrimidine 1314704-90-9 C16H21N3S2
    2-methylthio-4-(1-phenylethyl)amino-6-propylthiopyrimidine
    —— N,N-Dimethyl-5-(methylsulfanyl)-1,3,4-thiadiazole-2-carbothioamide 90298-78-5 C6H9N3S3
    N,N-Dimethyl-5-(methylsulfanyl)-1,3,4-thiadiazole-2-carbothioamide
    —— 7-Methylbenzo<b>thiophen-3(2H)-on 68670-99-5 C9H8OS
    7-Methylbenzo<b>thiophen-3(2H)-on
    —— 2,2-dichlorocyclopropylmethanethiol 873804-88-7 C4H6Cl2S
    2,2-dichlorocyclopropylmethanethiol
    —— 3-(6-chloro-2-(methylthio)pyrimidin-4-yl)-2-(2-chloro-6-fluorophenyl)thiazolidin-4-one 1350308-15-4 C14H10Cl2FN3OS2
    3-(6-chloro-2-(methylthio)pyrimidin-4-yl)-2-(2-chloro-6-fluorophenyl)thiazolidin-4-one
    —— 2-[(4-chlorophenyl)thio]-6-fluorobenzaldehyde 710961-05-0 C13H8ClFOS
    2-[(4-chlorophenyl)thio]-6-fluorobenzaldehyde
    —— (2-nitro-1,3-phenylene)bis(phenylsulfane) 98119-89-2 C18H13NO2S2
    (2-nitro-1,3-phenylene)bis(phenylsulfane)
    —— (3-chloro-2-nitro-phenyl)-<i>p</i>-tolyl sulfide 860240-96-6 C13H10ClNO2S
    (3-chloro-2-nitro-phenyl)-<i>p</i>-tolyl sulfide
    —— 2,2-bis-ethylsulfanyl-3,3-dimethyl-butane 91717-90-7 C10H22S2
    2,2-bis-ethylsulfanyl-3,3-dimethyl-butane
    —— 1-(2,6-dichlorophenyl)-6-(2,4-difluorophenylthio)-3,4-dihydropyrido[3,2-d]pyrimidin-2(1H)-one 547756-17-2 C19H11Cl2F2N3OS
    1-(2,6-dichlorophenyl)-6-(2,4-difluorophenylthio)-3,4-dihydropyrido[3,2-d]pyrimidin-2(1H)-one
    —— N-[[3,5-dibromo-6-(2,4-difluorophenyl)sulfanylpyridin-2-yl]methyl]-1-(4-methoxyphenyl)methanamine 632628-10-5 C20H16Br2F2N2OS
    N-[[3,5-dibromo-6-(2,4-difluorophenyl)sulfanylpyridin-2-yl]methyl]-1-(4-methoxyphenyl)methanamine
    —— 1-[[3,5-Dibromo-6-(2,4-difluorophenyl)sulfanylpyridin-2-yl]methyl]-3-(2,6-dichlorophenyl)-1-[(4-methoxyphenyl)methyl]urea 632628-11-6 C27H19Br2Cl2F2N3O2S
    1-[[3,5-Dibromo-6-(2,4-difluorophenyl)sulfanylpyridin-2-yl]methyl]-3-(2,6-dichlorophenyl)-1-[(4-methoxyphenyl)methyl]urea