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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 12-Azidododecylmethanethiosulfonate 1215670-42-0 C13H27N3O2S2
    12-Azidododecylmethanethiosulfonate
    —— 2-(3-Trifluoromethyl-pyridin-2-ylsulfanyl)-ethylamine; hydrochloride 1208081-53-1 C8H10ClF3N2S
    2-(3-Trifluoromethyl-pyridin-2-ylsulfanyl)-ethylamine; hydrochloride
    —— (6-Methoxy-4-(trifluoromethyl)pyridin-2-ylsulfanyl)acetic acid 1053657-58-1 C9H8F3NO3S
    (6-Methoxy-4-(trifluoromethyl)pyridin-2-ylsulfanyl)acetic acid
    —— (6-Chloro-4-(trifluoromethyl)pyridin-2-ylsulfanyl)acethydrazide 1053657-49-0 C8H7ClF3N3OS
    (6-Chloro-4-(trifluoromethyl)pyridin-2-ylsulfanyl)acethydrazide
    —— 2-[[6-Chloro-4-(trifluoromethyl)-2-pyridyl]sulfanyl]ethanamine hydrochloride 1208081-83-7 C8H9Cl2F3N2S
    2-[[6-Chloro-4-(trifluoromethyl)-2-pyridyl]sulfanyl]ethanamine hydrochloride
    —— 10-(t-Boc-amino)-1-decylmethanethiosulfonate 1216932-86-3 C16H33NO4S2
    10-(t-Boc-amino)-1-decylmethanethiosulfonate
    —— Spiro[bicyclo[3.1.1]heptane-6,2'-[1,3]dithiolane] 18543-35-6 C9H14S2
    Spiro[bicyclo[3.1.1]heptane-6,2'-[1,3]dithiolane]
    —— Copper(1+);thiourea 27316-89-8 C3H12CuN6S3
    Copper(1+);thiourea
    —— (3S)-1-(Methanesulfonyl)-5-methylhex-1-en-3-amine 193482-44-9 C8H17NO2S
    (3S)-1-(Methanesulfonyl)-5-methylhex-1-en-3-amine
    —— O,O-Dimethyl S-[2-(propane-2-sulfinyl)ethyl] phosphorothioate 2635-50-9 C7H17O4PS2
    O,O-Dimethyl S-[2-(propane-2-sulfinyl)ethyl] phosphorothioate
    —— Chionxalin-2,3-sulfid 286-91-9 C8H4N2S
    Chionxalin-2,3-sulfid
    —— 2,3,7,8,12,13,17,18-octakis-(4-fluorobutylthio)porphyrazinatomagnesium(II) 1360897-06-8 C48H64F8MgN8S8
    2,3,7,8,12,13,17,18-octakis-(4-fluorobutylthio)porphyrazinatomagnesium(II)
    —— 2,3,7,8,12,13,17,18-octakis-[2-(2-ethoxyethoxy)ethylthio]porphyrazine 1360897-10-4 C64H106N8O16S8
    2,3,7,8,12,13,17,18-octakis-[2-(2-ethoxyethoxy)ethylthio]porphyrazine
    —— 2(1,3)-benzena-1(4),3(4)-diethyl-4,8-dithia-6-thio-(1,3)(3,5)-1,2,4-triazolacyclooctaphan 1375489-00-1 C17H18N6S3
    2(1,3)-benzena-1(4),3(4)-diethyl-4,8-dithia-6-thio-(1,3)(3,5)-1,2,4-triazolacyclooctaphan
    —— 3-(4-Fluorophenyl)sulfanyl-1-methylquinolin-1-ium;iodide 1383710-37-9 C16H13FNS*I
    3-(4-Fluorophenyl)sulfanyl-1-methylquinolin-1-ium;iodide
    —— 2(1,3)-benzena-1(4),3(4)-diethyl-4,8-dithia-(1,3)(3,5)-1,2,4-triazolacyclooctaphane-6-one 1375488-97-3 C17H18N6OS2
    2(1,3)-benzena-1(4),3(4)-diethyl-4,8-dithia-(1,3)(3,5)-1,2,4-triazolacyclooctaphane-6-one
    —— ACP1a 1371635-84-5 C18H18ClF3N2O3S2
    ACP1a
    —— 2-methyl-N-(3-(phenylthio)propyl)-2-((5-(trifluoromethyl)-pyridin-2-yl)sulfonyl)propanamide 1382488-96-1 C19H21F3N2O3S2
    2-methyl-N-(3-(phenylthio)propyl)-2-((5-(trifluoromethyl)-pyridin-2-yl)sulfonyl)propanamide
    —— 2-[4-(7-Methyl-5,8,10-trithia-3-azatricyclo[7.3.0.02,6]dodeca-1(9),2(6),3,11-tetraen-4-yl)-5-oxo-1,2,4-triazol-1-yl]acetonitrile 1343408-85-4 C13H9N5OS3
    2-[4-(7-Methyl-5,8,10-trithia-3-azatricyclo[7.3.0.02,6]dodeca-1(9),2(6),3,11-tetraen-4-yl)-5-oxo-1,2,4-triazol-1-yl]acetonitrile
    —— 2-(2-Bromophenyl)sulfanyl-1-(6-chloropyridin-3-yl)ethanone 1350522-24-5 C13H9BrClNOS
    2-(2-Bromophenyl)sulfanyl-1-(6-chloropyridin-3-yl)ethanone
    —— amino-4-[5-(2-pyrimidinylsulfanyl)-1,3,4-oxadiazol-2-yl]anilinomethanethione 1350301-83-5 C13H10N6OS2
    amino-4-[5-(2-pyrimidinylsulfanyl)-1,3,4-oxadiazol-2-yl]anilinomethanethione
    —— 2-[[5-(3-Chlorophenyl)-2-methylfuran-3-yl]methylsulfanyl]-3,5,6,7-tetrahydrocyclopenta[d]pyrimidin-4-one 1351525-82-0 C19H17ClN2O2S
    2-[[5-(3-Chlorophenyl)-2-methylfuran-3-yl]methylsulfanyl]-3,5,6,7-tetrahydrocyclopenta[d]pyrimidin-4-one
    —— (E)-4-(dimethylamino)-N-methyl-N-[4-(2-methylphenyl)sulfanylimidazo[1,5-a]quinoxalin-8-yl]but-2-enamide 1345250-86-3 C24H25N5OS
    (E)-4-(dimethylamino)-N-methyl-N-[4-(2-methylphenyl)sulfanylimidazo[1,5-a]quinoxalin-8-yl]but-2-enamide
    —— 2-(1-Methyl-1H-indazol-5-ylsulfanyl)-5-fluorobenzylamine 756839-32-4 C15H14FN3S
    2-(1-Methyl-1H-indazol-5-ylsulfanyl)-5-fluorobenzylamine
    —— 2-(5-bromo-2-(methylthio)pyrimidin-4-yl)thiazolo[5,4-c]pyridine 893441-61-7 C11H7BrN4S2
    2-(5-bromo-2-(methylthio)pyrimidin-4-yl)thiazolo[5,4-c]pyridine
    —— 3-(4-dimethylcarbamoylsulfanyl-2-methyl-phenyl)-propionic acid methyl ester 591775-11-0 C14H19NO3S
    3-(4-dimethylcarbamoylsulfanyl-2-methyl-phenyl)-propionic acid methyl ester
    —— 3-(2-methylsulfanyl-pyrimidin-4-yl)-6,7-dihydro-5H-pyrazolo[1,2-a]pyrazol-1-one 852164-96-6 C11H12N4OS
    3-(2-methylsulfanyl-pyrimidin-4-yl)-6,7-dihydro-5H-pyrazolo[1,2-a]pyrazol-1-one
    —— 5-[3-(4-benzoxyphenylthio)fur-2-yl]imidazoline-2,4-dione 877176-12-0 C20H16N2O4S
    5-[3-(4-benzoxyphenylthio)fur-2-yl]imidazoline-2,4-dione
    —— 2-(2-chloro-benzyl)-3-(2-methylsulfanyl-pyrimidin-4-yl)-6,7-dihydro-5H-pyrazolo[1,2-a]pyrazol-1-one 852165-07-2 C18H17ClN4OS
    2-(2-chloro-benzyl)-3-(2-methylsulfanyl-pyrimidin-4-yl)-6,7-dihydro-5H-pyrazolo[1,2-a]pyrazol-1-one
    —— 1-(4-Methoxybenzyl)-2-(6-methylbenzo[d][1,3]dioxol-5-ylthio)-1H-imidazo[4,5-c]pyridin-4-amine 1061318-23-7 C22H20N4O3S
    1-(4-Methoxybenzyl)-2-(6-methylbenzo[d][1,3]dioxol-5-ylthio)-1H-imidazo[4,5-c]pyridin-4-amine
    —— [(Methanesulfonyl)methyl]cyclopropane 62427-76-3 C5H10O2S
    [(Methanesulfonyl)methyl]cyclopropane
    —— 4-Cyclopentylsulfanylbutan-1-amine 1339531-15-5 C9H19NS
    4-Cyclopentylsulfanylbutan-1-amine
    —— Cycloprop-1-ene-1-thiol 81788-90-1 C3H4S
    Cycloprop-1-ene-1-thiol
    —— [2-(1H-indol-5-ylsulfanyl)-benzyl]-methyl-amine 857499-82-2 C16H16N2S
    [2-(1H-indol-5-ylsulfanyl)-benzyl]-methyl-amine
    —— 2-(phenylthio)-4-(5-(trifluoromethyl)-1H-pyrrolo[2,3-b]pyridin-3-yl)pyrimidine-5-carbonitrile 1036027-21-0 C19H10F3N5S
    2-(phenylthio)-4-(5-(trifluoromethyl)-1H-pyrrolo[2,3-b]pyridin-3-yl)pyrimidine-5-carbonitrile
    —— N,N'-(Ethane-1,2-diyl)bis[3-(ethenesulfonyl)propanamide] 67326-55-0 C12H20N2O6S2
    N,N'-(Ethane-1,2-diyl)bis[3-(ethenesulfonyl)propanamide]
    —— Cyclopentanemethanamine, I+/--[3-(methylsulfonyl)propyl]- 1341975-52-7 C10H21NO2S
    Cyclopentanemethanamine, I+/--[3-(methylsulfonyl)propyl]-
    —— 3-(4-(trifluoromethoxy)phenylthio)pyrazin-2(1H)-one 1099664-67-1 C11H7F3N2O2S
    3-(4-(trifluoromethoxy)phenylthio)pyrazin-2(1H)-one
    —— 1-Pentanamine, 2-(1-methylethyl)-5-(methylsulfonyl)-N-propyl- 1343640-84-5 C12H27NO2S
    1-Pentanamine, 2-(1-methylethyl)-5-(methylsulfonyl)-N-propyl-
    —— 1-[4-(2-hydroxy-2-methylpropoxy)-3-methylphenyl]-3-[4-(trifluoromethoxy)phenylthio]pyrazine-2(1H)-one 1099662-74-4 C22H21F3N2O4S
    1-[4-(2-hydroxy-2-methylpropoxy)-3-methylphenyl]-3-[4-(trifluoromethoxy)phenylthio]pyrazine-2(1H)-one
    —— 2-[3-(4-morpholin-4-ylmethylphenyl)-[1,2,4]triazolo[4,3-a]pyridin-6-ylsulfanyl]-benzylamine 946050-93-7 C24H25N5OS
    2-[3-(4-morpholin-4-ylmethylphenyl)-[1,2,4]triazolo[4,3-a]pyridin-6-ylsulfanyl]-benzylamine
    —— 4-(3-Chloro-2-hydroxypropyl)sulfanylphenol 915155-43-0 C9H11ClO2S
    4-(3-Chloro-2-hydroxypropyl)sulfanylphenol
    —— 3-(2-(pyridin-2-yl)ethylthio)pyrazin-2(1H)-one 1099665-60-7 C11H11N3OS
    3-(2-(pyridin-2-yl)ethylthio)pyrazin-2(1H)-one
    —— Dibenzyl 3,3-difluoro-1-((2-methoxy-4-(2-oxo-3-(4-(trifluoromethoxy)phenylthio)pyrazin-1(2H)-yl)phenoxy)methyl)cyclobutyl phosphate 1099664-77-3 C37H32F5N2O8PS
    Dibenzyl 3,3-difluoro-1-((2-methoxy-4-(2-oxo-3-(4-(trifluoromethoxy)phenylthio)pyrazin-1(2H)-yl)phenoxy)methyl)cyclobutyl phosphate
    —— 3-(phenethylthio)pyrazin-2(1H)-one 942910-23-8 C12H12N2OS
    3-(phenethylthio)pyrazin-2(1H)-one
    —— 5-(tert-butyl-dimethyl-silanyloxymethyl)-4-methyl-2-phenylsulfanyl-oxazole 1030014-61-9 C17H25NO2SSi
    5-(tert-butyl-dimethyl-silanyloxymethyl)-4-methyl-2-phenylsulfanyl-oxazole
    —— 5,5-dimethyl-3-phenyl-sulfanyl-4,5-dihydro-isoxazole 447401-72-1 C11H13NOS
    5,5-dimethyl-3-phenyl-sulfanyl-4,5-dihydro-isoxazole
    —— 4-bromomethyl-5-ethylsulfanyl-1-methyl-3-trifluoromethyl-1H-pyrazole 915137-37-0 C8H10BrF3N2S
    4-bromomethyl-5-ethylsulfanyl-1-methyl-3-trifluoromethyl-1H-pyrazole
    —— 2-chloro-6-(4-fluorophenylthio)pyridine 1112982-60-1 C11H7ClFNS
    2-chloro-6-(4-fluorophenylthio)pyridine
    —— 2-(6-methylsulfanyl-pyrimidin-4-yl)-malonic acid dimethyl ester 946422-09-9 C10H12N2O4S
    2-(6-methylsulfanyl-pyrimidin-4-yl)-malonic acid dimethyl ester