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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— methyl (3R)-4-tert-butyldiphenylsiloxy-3-(5-phenylthio-2-furoyloxy)-2-oxobutanoate 215173-30-1 C32H32O7SSi
    methyl (3R)-4-tert-butyldiphenylsiloxy-3-(5-phenylthio-2-furoyloxy)-2-oxobutanoate
    —— 4,4,6-Trimethyl-2-methylamino-4H-1,3-thiazin 27848-23-3 C8H14N2S
    4,4,6-Trimethyl-2-methylamino-4H-1,3-thiazin
    —— methyl (2R,3R)-4-tert-butyldiphenylsiloxy-3-(5-phenylthio-2-furoyloxy)-2-(4'-methoxybenzyloxy)butanoate 440640-95-9 C40H42O8SSi
    methyl (2R,3R)-4-tert-butyldiphenylsiloxy-3-(5-phenylthio-2-furoyloxy)-2-(4'-methoxybenzyloxy)butanoate
    —— methyl (2S,3R)-4-tert-butyldiphenylsiloxy-3-(5-phenylthio-2-furoyloxy)-2-(tetrahydro-2H-pyran-2-yloxy)butanoate 215173-29-8 C37H42O8SSi
    methyl (2S,3R)-4-tert-butyldiphenylsiloxy-3-(5-phenylthio-2-furoyloxy)-2-(tetrahydro-2H-pyran-2-yloxy)butanoate
    —— 3-phenyl-3-phenylsulfanylmethyl-1,2,5-trioxaspiro[5.5]undecane 869661-00-7 C21H24O3S
    3-phenyl-3-phenylsulfanylmethyl-1,2,5-trioxaspiro[5.5]undecane
    —— N-Cyclopropyl-2-phenylsulfanyl-propanamide 6415-28-7 C12H15NOS
    N-Cyclopropyl-2-phenylsulfanyl-propanamide
    —— 1-Butyl-3-(pyridin-2-ylsulfanyl)-azepane 129885-62-7 C15H24N2S
    1-Butyl-3-(pyridin-2-ylsulfanyl)-azepane
    —— 2(S)-3-cyclohexyl-1-phenylthio-2-propylamine 253449-42-2 C15H23NS
    2(S)-3-cyclohexyl-1-phenylthio-2-propylamine
    —— 3-[(4-Chlorophenyl)sulfanylmethyl]-3-phenyl-1,2,5-trioxaspiro[5.5]undecane 1227098-76-1 C21H23ClO3S
    3-[(4-Chlorophenyl)sulfanylmethyl]-3-phenyl-1,2,5-trioxaspiro[5.5]undecane
    —— 2(S)-3-cyclohexyl-1-tert-butylthio-2-propylamine 253449-41-1 C13H27NS
    2(S)-3-cyclohexyl-1-tert-butylthio-2-propylamine
    —— 4-(6-chloro-2-quinoxalylthio)-aniline 83183-54-4 C14H10ClN3S
    4-(6-chloro-2-quinoxalylthio)-aniline
    —— 2(S)-3-cyclohexyl-1-ethylthio-2-propylamine 216316-93-7 C11H23NS
    2(S)-3-cyclohexyl-1-ethylthio-2-propylamine
    —— 2(S)-3-cyclohexyl-1-cyclolhexylthio-2-propylamine 253449-44-4 C15H29NS
    2(S)-3-cyclohexyl-1-cyclolhexylthio-2-propylamine
    —— 2(S)-3-cyclohexyl-1-(2-methylphenyl)thio-2-propylamine 253449-43-3 C16H25NS
    2(S)-3-cyclohexyl-1-(2-methylphenyl)thio-2-propylamine
    —— tert-butyl N-[(2S)-1-cyclohexyl-3-(2-methylphenyl)sulfanylpropan-2-yl]carbamate 1025928-09-9 C21H33NO2S
    tert-butyl N-[(2S)-1-cyclohexyl-3-(2-methylphenyl)sulfanylpropan-2-yl]carbamate
    —— 4-(benzyloxy)-6-chloro-2-(methylthio)pyrimidin-5-amine 1196886-06-2 C12H12ClN3OS
    4-(benzyloxy)-6-chloro-2-(methylthio)pyrimidin-5-amine
    —— ethyl 2-cyclopropyl-4,6,7-tri(4-methoxyphenylthio)quinoline-3-carboxylate 1263064-68-1 C36H33NO5S3
    ethyl 2-cyclopropyl-4,6,7-tri(4-methoxyphenylthio)quinoline-3-carboxylate
    —— 4,4-Dimercaptoheptan 14272-19-6 C7H16S2
    4,4-Dimercaptoheptan
    —— ethyl 2-cyclopropyl-4,6,7-tri(4-fluorophenylthio)quinoline-3-carboxylate 1263064-67-0 C33H24F3NO2S3
    ethyl 2-cyclopropyl-4,6,7-tri(4-fluorophenylthio)quinoline-3-carboxylate
    —— 4-Phenylmercapto-thieno<2,3-d>pyrimidin 18740-24-4 C12H8N2S2
    4-Phenylmercapto-thieno<2,3-d>pyrimidin
    —— [(2S)-4-[azidosulfonyl(methyl)amino]butan-2-yl]benzene 1263429-80-6 C11H16N4O2S
    [(2S)-4-[azidosulfonyl(methyl)amino]butan-2-yl]benzene
    —— 3-(thieno[2,3-d]pyrimidin-4-ylthio)thieno[3,2-e][1,2,4]triazolo[4,3-c]pyrimidine 1262236-29-2 C13H6N6S3
    3-(thieno[2,3-d]pyrimidin-4-ylthio)thieno[3,2-e][1,2,4]triazolo[4,3-c]pyrimidine
    —— 3-(thieno[2,3-d]pyrimidin-4-ylthio)thieno[2,3-e][1,2,4]triazolo[4,3-c]pyrimidine 1262236-34-9 C13H6N6S3
    3-(thieno[2,3-d]pyrimidin-4-ylthio)thieno[2,3-e][1,2,4]triazolo[4,3-c]pyrimidine
    —— 4-([1,2,4]triazolo[4,3-a]pyridin-3-ylthio)thieno[2,3-d]pyrimidine 897295-28-2 C12H7N5S2
    4-([1,2,4]triazolo[4,3-a]pyridin-3-ylthio)thieno[2,3-d]pyrimidine
    —— 1-Methyl-sulfinyl-buten-(2) 13159-41-6 C5H10OS
    1-Methyl-sulfinyl-buten-(2)
    —— 2-Butenyl 5-Chloro-2-Thienyl Sulfide 84716-63-2 C8H9ClS2
    2-Butenyl 5-Chloro-2-Thienyl Sulfide
    —— 2-chloro-5-(2-chloroethylthio)thiophene 333782-98-2 C6H6Cl2S2
    2-chloro-5-(2-chloroethylthio)thiophene
    —— 2-chloro-5-[[(5-(p-aminophenyl)-1,3,4-oxadiazol-2-yl)thio]methyl]pyridine 1257842-95-7 C14H11ClN4OS
    2-chloro-5-[[(5-(p-aminophenyl)-1,3,4-oxadiazol-2-yl)thio]methyl]pyridine
    —— 2-chloro-5-[[(5-(p-fluorophenyl)-1,3,4-oxadiazol-2-yl)thio]methyl]pyridine 1257842-84-4 C14H9ClFN3OS
    2-chloro-5-[[(5-(p-fluorophenyl)-1,3,4-oxadiazol-2-yl)thio]methyl]pyridine
    —— 5-<(2H)formyl>-3-methyl-6-phenylthiouracil 344251-03-2 C12H10N2O3S
    5-<(2H)formyl>-3-methyl-6-phenylthiouracil
    —— 2-chloro-5-[[(5-(thiophen-2-yl)-1,3,4-oxadiazol-2-yl)thio]methyl]pyridine 1257843-04-1 C12H8ClN3OS2
    2-chloro-5-[[(5-(thiophen-2-yl)-1,3,4-oxadiazol-2-yl)thio]methyl]pyridine
    —— 2-chloro-5-[[(5-(p-(dimethylamino)phenyl)-1,3,4-oxadiazol-2-yl)thio]methyl]pyridine 1257842-97-9 C16H15ClN4OS
    2-chloro-5-[[(5-(p-(dimethylamino)phenyl)-1,3,4-oxadiazol-2-yl)thio]methyl]pyridine
    —— 2-chloro-5-[[(5-(o-fluorophenyl)-1,3,4-oxadiazol-2-yl)thio]methyl]pyridine 1257842-82-2 C14H9ClFN3OS
    2-chloro-5-[[(5-(o-fluorophenyl)-1,3,4-oxadiazol-2-yl)thio]methyl]pyridine
    —— 2-chloro-5-[[(5-(furan-2-yl)-1,3,4-oxadiazol-2-yl)thio]methyl]pyridine 1257843-02-9 C12H8ClN3O2S
    2-chloro-5-[[(5-(furan-2-yl)-1,3,4-oxadiazol-2-yl)thio]methyl]pyridine
    —— 2-chloro-5-[[(5-(o-chlorophenyl)-1,3,4-oxadiazol-2-yl)thio]methyl]pyridine 1257842-86-6 C14H9Cl2N3OS
    2-chloro-5-[[(5-(o-chlorophenyl)-1,3,4-oxadiazol-2-yl)thio]methyl]pyridine
    —— 2-chloro-5-[[(5-(p-chlorophenyl)-1,3,4-oxadiazol-2-yl)thio]methyl]pyridine 1257842-88-8 C14H9Cl2N3OS
    2-chloro-5-[[(5-(p-chlorophenyl)-1,3,4-oxadiazol-2-yl)thio]methyl]pyridine
    —— 2-chloro-5-[[(5-(p-tolyl)-1,3,4-oxadiazol-2-yl)thio]methyl]pyridine 1257842-76-4 C15H12ClN3OS
    2-chloro-5-[[(5-(p-tolyl)-1,3,4-oxadiazol-2-yl)thio]methyl]pyridine
    —— 2,3-dihydro-3,3-ethylenedioxy-2-(1H-imidazol-1-yl-methyl)-5-methylbenzo<b>thiophene 121899-63-6 C15H16N2O2S
    2,3-dihydro-3,3-ethylenedioxy-2-(1H-imidazol-1-yl-methyl)-5-methylbenzo<b>thiophene
    —— 2-chloro-5-[[(5-(p-hydroxyphenyl)-1,3,4-oxadiazol-2-yl)thio]methyl]pyridine 1257842-90-2 C14H10ClN3O2S
    2-chloro-5-[[(5-(p-hydroxyphenyl)-1,3,4-oxadiazol-2-yl)thio]methyl]pyridine
    —— 2-chloro-5-[[(5-(o-tolyl)-1,3,4-oxadiazol-2-yl)thio]methyl]pyridine 1223721-63-8 C15H12ClN3OS
    2-chloro-5-[[(5-(o-tolyl)-1,3,4-oxadiazol-2-yl)thio]methyl]pyridine
    —— exo-tert-butyl (1S,2R,4R)-2-{[5-(4-chlorophenylsulfanyl)thiophene-2-carbonyl]amino}-7-azabicyclo[2.2.1]heptane-7-carboxylate 500604-93-3 C22H25ClN2O3S2
    exo-tert-butyl (1S,2R,4R)-2-{[5-(4-chlorophenylsulfanyl)thiophene-2-carbonyl]amino}-7-azabicyclo[2.2.1]heptane-7-carboxylate
    —— 2-chloro-5-[4-(methylthio)benzyl]pyridine 1613043-16-5 C13H12ClNS
    2-chloro-5-[4-(methylthio)benzyl]pyridine
    —— (E)-1-(phenylthio)vinylstannane —— C21H36OSSn
    (E)-1-(phenylthio)vinylstannane
    —— ethyl 2-(methylsulfanyl)phenylpropiolate 157889-58-2 C12H12O2S
    ethyl 2-(methylsulfanyl)phenylpropiolate
    —— 3-phenylthiopenta-2,4-dien-1-ol 214466-82-7 C11H12OS
    3-phenylthiopenta-2,4-dien-1-ol
    —— 2-(ortho-chlorobenzylthio)-6-aminouracil 333411-14-6 C11H10ClN3OS
    2-(ortho-chlorobenzylthio)-6-aminouracil
    —— 2-amino-5-[(2-chlorobenzyl)sulfanyl][1,3]thiazolo[4,5-d]pyrimidin-7-ol 259100-95-3 C12H9ClN4OS2
    2-amino-5-[(2-chlorobenzyl)sulfanyl][1,3]thiazolo[4,5-d]pyrimidin-7-ol
    —— bis(5-chloro-2-thienyl) sulfide 53381-41-2 C8H4Cl2S3
    bis(5-chloro-2-thienyl) sulfide
    —— (2R)-1-{2-[(2R)2-hydroxy-3-methoxypropyl]-1,3-dithian-2-yl}-3-methoxypropan-2-ol 404914-41-6 C12H24O4S2
    (2R)-1-{2-[(2R)2-hydroxy-3-methoxypropyl]-1,3-dithian-2-yl}-3-methoxypropan-2-ol
    —— 2-Chlor-1-(4-chlor-2-amino-phenylmercapto)-benzol 3169-65-1 C12H9Cl2NS
    2-Chlor-1-(4-chlor-2-amino-phenylmercapto)-benzol