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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Benzenemethanol, 2-((2-((4-methyl-1-piperazinyl)methyl)phenyl)thio)-, dihydrochloride 93288-97-2 C19H26Cl2N2OS
    Benzenemethanol, 2-((2-((4-methyl-1-piperazinyl)methyl)phenyl)thio)-, dihydrochloride
    —— 1,4-tert-butyl-2,5,7-trithiabicyclo[2.2.1]heptane 124782-81-6 C12H22S3
    1,4-tert-butyl-2,5,7-trithiabicyclo[2.2.1]heptane
    —— 1-(2-(4-Chloro-2-(1-hydroxyethyl)phenylthio)benzyl)-4-methylpiperazine dihydrochloride 93288-37-0 C20H27Cl3N2OS
    1-(2-(4-Chloro-2-(1-hydroxyethyl)phenylthio)benzyl)-4-methylpiperazine dihydrochloride
    —— 3-(5-chloro-2-methylphenyl)-2-methylthio-4(3H)-pyrimidinone 89069-30-7 C12H11ClN2OS
    3-(5-chloro-2-methylphenyl)-2-methylthio-4(3H)-pyrimidinone
    —— 2,5-Dimethyl-2-phenylthiohexanonitril 66164-80-5 C14H19NS
    2,5-Dimethyl-2-phenylthiohexanonitril
    —— 2,5-Dimethyl-2-(phenylthio)hexan-1-ol 66332-74-9 C14H22OS
    2,5-Dimethyl-2-(phenylthio)hexan-1-ol
    —— 1-Cyclohexyl-3-hexylthiourea 401640-79-7 C13H26N2S
    1-Cyclohexyl-3-hexylthiourea
    —— Piperidine, 1-(3-((2-((p-chlorophenyl)thio)ethyl)amino)propyl)- 93144-71-9 C16H25ClN2S
    Piperidine, 1-(3-((2-((p-chlorophenyl)thio)ethyl)amino)propyl)-
    —— 6,6'-Diethoxy-thioindigo 42917-53-3 C20H16O4S2
    6,6'-Diethoxy-thioindigo
    —— Morpholine, 4-(3-((2-((p-chlorophenyl)thio)ethyl)amino)propyl)- 92724-93-1 C15H23ClN2OS
    Morpholine, 4-(3-((2-((p-chlorophenyl)thio)ethyl)amino)propyl)-
    —— (E)-1-cyclohexyl-2-(phenylthio)-1,3-butadiene 83877-76-3 C16H20S
    (E)-1-cyclohexyl-2-(phenylthio)-1,3-butadiene
    —— 1-methyl-2-phenylsulfanyl-cyclohex-2-enecarboxylic acid ethyl ester 862563-51-7 C16H20O2S
    1-methyl-2-phenylsulfanyl-cyclohex-2-enecarboxylic acid ethyl ester
    —— 1,3-Dimethyl-5-methylmercapto-pyrazol 32323-16-3 C6H10N2S
    1,3-Dimethyl-5-methylmercapto-pyrazol
    —— 1-methyl-2-phenylsulfanyl-cyclohex-2-enecarbaldehyde 862563-52-8 C14H16OS
    1-methyl-2-phenylsulfanyl-cyclohex-2-enecarbaldehyde
    —— 1,4-Dithia-spiro[4.5]decane-6-carboxylic acid 337468-24-3 C9H14O2S2
    1,4-Dithia-spiro[4.5]decane-6-carboxylic acid
    —— 4,6-di-methylthio-2-methyl-5-(2-imidazolin-2-yl)-aminopyrimidine 75438-59-4 C10H15N5S2
    4,6-di-methylthio-2-methyl-5-(2-imidazolin-2-yl)-aminopyrimidine
    —— 1-((methylsulfonyl)methyl)bicycle[3.1.0]hexan-2-one 1549803-77-1 C8H12O3S
    1-((methylsulfonyl)methyl)bicycle[3.1.0]hexan-2-one
    —— chloromethanesulfonyl chloride 112382-26-0 CHClO2S
    chloromethanesulfonyl chloride
    —— 2-tert-butoxycarbonylaminomethyl-3-(2-hydroxy-2-methylpropanethio)pyridine 342816-17-5 C15H24N2O3S
    2-tert-butoxycarbonylaminomethyl-3-(2-hydroxy-2-methylpropanethio)pyridine
    —— (4R)-4-hydroxy-4-(4-methylsulfanylphenyl)-butan-2-one 1147131-67-6 C11H14O2S
    (4R)-4-hydroxy-4-(4-methylsulfanylphenyl)-butan-2-one
    —— formic acid-[2-(2-nitro-5-trifluoromethyl-phenylsulfanyl)-anilide] 7639-63-6 C14H9F3N2O3S
    formic acid-[2-(2-nitro-5-trifluoromethyl-phenylsulfanyl)-anilide]
    —— 2-bromo-4-methyl-5-[(phenylthio)(2,3,6-trifluorophenyl)methyl]pyridine 913091-89-1 C19H13BrF3NS
    2-bromo-4-methyl-5-[(phenylthio)(2,3,6-trifluorophenyl)methyl]pyridine
    —— 3-Methylthio-1-cyclopentene 27557-68-2 C6H10S
    3-Methylthio-1-cyclopentene
    —— 2-bromo-4-methyl-5-[[[6-(trifluoromethyl)pyridin-3-yl]thio](2,3,6-trifluorophenyl)methyl]pyridine 913091-90-4 C19H11BrF6N2S
    2-bromo-4-methyl-5-[[[6-(trifluoromethyl)pyridin-3-yl]thio](2,3,6-trifluorophenyl)methyl]pyridine
    —— 2-Cyclopentenyl-butyl-sulfid 18508-17-3 C9H16S
    2-Cyclopentenyl-butyl-sulfid
    —— 6-(4-bromo-3-methyl-phenylsulfanyl)-3-methoxymethoxymethyl-2-methyl-pyridine 926640-01-9 C16H18BrNO2S
    6-(4-bromo-3-methyl-phenylsulfanyl)-3-methoxymethoxymethyl-2-methyl-pyridine
    —— di(cyclo-2-pentenyl) sulfide 78400-60-9 C10H14S
    di(cyclo-2-pentenyl) sulfide
    —— [6-(4-bromo-3-methyl-phenylsulfanyl)-2-methyl-pyridin-3-yl]-methanol 926304-63-4 C14H14BrNOS
    [6-(4-bromo-3-methyl-phenylsulfanyl)-2-methyl-pyridin-3-yl]-methanol
    —— 4-(N,N'-bis(4-bromophenyl))guanidino-2-methyl-5-methylthio-2H-1,2,4-triazol-3(4H)-one 116088-22-3 C17H16Br2N6OS
    4-(N,N'-bis(4-bromophenyl))guanidino-2-methyl-5-methylthio-2H-1,2,4-triazol-3(4H)-one
    —— N,N’-bis(5-((3-fluorobenzyl)thio)-1,3,4-thiadiazol-2-yl)methane diamine 1516888-52-0 C19H16F2N6S4
    N,N’-bis(5-((3-fluorobenzyl)thio)-1,3,4-thiadiazol-2-yl)methane diamine
    —— 4-(3-Fluoro-benzylsulfanyl)-pyridine-2-carbonitrile 225112-52-7 C13H9FN2S
    4-(3-Fluoro-benzylsulfanyl)-pyridine-2-carbonitrile
    —— 2,6-Bis(2,6-dimethylpyrazolo[1,5-b][1,2,4]triazol-7-ylidene)-[1,3]dithiolo[4,5-f][1,3]benzodithiole-4,8-diol 1116390-80-7 C20H14N8O2S4
    2,6-Bis(2,6-dimethylpyrazolo[1,5-b][1,2,4]triazol-7-ylidene)-[1,3]dithiolo[4,5-f][1,3]benzodithiole-4,8-diol
    —— 3-hydroxy-2-methylsulphinylprop-1-ene 63067-85-6 C4H8O2S
    3-hydroxy-2-methylsulphinylprop-1-ene
    —— trans-3-methylsulfinyl-2-propenol 654670-99-2 C4H8O2S
    trans-3-methylsulfinyl-2-propenol
    —— 3,3-Bis(methylthio)-2-butanone oxime 94291-65-3 C6H13NOS2
    3,3-Bis(methylthio)-2-butanone oxime
    —— Morpholine, 4-(2-(N-(2-((p-chlorophenyl)thio)ethyl)anilino)ethyl)- 96966-63-1 C20H25ClN2OS
    Morpholine, 4-(2-(N-(2-((p-chlorophenyl)thio)ethyl)anilino)ethyl)-
    —— 1-(phenylthio)cyclopropyl-1-(4-methylphenyl)-methanol 144453-16-7 C17H18OS
    1-(phenylthio)cyclopropyl-1-(4-methylphenyl)-methanol
    —— N-Methyl-2-[[N-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)-N-methyl]amino]ethanesulfonamide 203656-97-7 C15H19N5O2S2
    N-Methyl-2-[[N-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)-N-methyl]amino]ethanesulfonamide
    —— 1-(10H-Pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)-1-azoniabicyclo[2.2.2]octane-4-carboxylate 203650-71-9 C19H20N4O2S
    1-(10H-Pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)-1-azoniabicyclo[2.2.2]octane-4-carboxylate
    —— ethyl [1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]oxyacetate 741729-92-0 C20H24N4O3S
    ethyl [1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]oxyacetate
    —— methyl (anti)-[3-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)-3-azabicyclo[3.3.1]non-9-yl]acetate 203646-61-1 C22H26N4O2S
    methyl (anti)-[3-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)-3-azabicyclo[3.3.1]non-9-yl]acetate
    —— 5-Chloro-2-(4-chlorophenyl)sulfanylaniline 15211-90-2 C12H9Cl2NS
    5-Chloro-2-(4-chlorophenyl)sulfanylaniline
    —— 3-methoxy-4-methyl-2-phenyl-4-(phenylthio)-2-cyclobuten-1-one 137395-12-1 C18H16O2S
    3-methoxy-4-methyl-2-phenyl-4-(phenylthio)-2-cyclobuten-1-one
    —— ethyl [3-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)-3-azabicyclo[3.3.1]non-9-ylidene]acetate 203646-60-0 C23H26N4O2S
    ethyl [3-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)-3-azabicyclo[3.3.1]non-9-ylidene]acetate
    —— ethyl [1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]thioacetate 203649-42-7 C20H24N4O2S2
    ethyl [1-(10H-pyrazino[2,3-b][1,4]benzothiazin-8-ylmethyl)piperidin-4-yl]thioacetate
    —— 8-(1,4,5,6-Tetrahydropyrimidin-1-ylmethyl)-10H-pyrazino[2,3-b][1,4]benzothiazine hydrochloride 203659-68-1 C15H15N5S*ClH
    8-(1,4,5,6-Tetrahydropyrimidin-1-ylmethyl)-10H-pyrazino[2,3-b][1,4]benzothiazine hydrochloride
    —— 10H-pyrazino[2,3-b][1,4]benzothiazine-8-acetonitrile 203659-39-6 C12H8N4S
    10H-pyrazino[2,3-b][1,4]benzothiazine-8-acetonitrile
    —— 7-Bromo-1,4-dithia-spiro[4.4]non-6-ene 81770-77-6 C7H9BrS2
    7-Bromo-1,4-dithia-spiro[4.4]non-6-ene
    —— 2-(5,6,7,8-tetrahydro-3,5,5,8,8-pentamethyl-2-naphthylthio)-5-thiazolecarboxylic acid 179762-67-5 C19H23NO2S2
    2-(5,6,7,8-tetrahydro-3,5,5,8,8-pentamethyl-2-naphthylthio)-5-thiazolecarboxylic acid
    —— 2-Nitrophenyl-4-(trifluormethylphenyl)sulfid 61174-10-5 C13H8F3NO2S
    2-Nitrophenyl-4-(trifluormethylphenyl)sulfid