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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-Chloro-5-phenylsulfanylthiophene-2,4-dicarbonitrile 119754-42-6 C12H5ClN2S2
    3-Chloro-5-phenylsulfanylthiophene-2,4-dicarbonitrile
    —— 2,4-dicyano-3-amino-5-methylthiothiophene 116255-96-0 C7H5N3S2
    2,4-dicyano-3-amino-5-methylthiothiophene
    —— 3-chloro-2,4-dicyano-5-methylthiothiophene 119754-39-1 C7H3ClN2S2
    3-chloro-2,4-dicyano-5-methylthiothiophene
    —— 4-(3,5-Dimethylpyrazol-1-yl)-2-methylthioimidazo<4,5-d>pyridazine 85732-91-8 C11H12N6S
    4-(3,5-Dimethylpyrazol-1-yl)-2-methylthioimidazo<4,5-d>pyridazine
    —— Ethanol, 2-(octadecylsulfinyl)- 58840-42-9 C20H42O2S
    Ethanol, 2-(octadecylsulfinyl)-
    —— (3S)-3-isothiocyanato-2,2-dimethylbutane 874662-42-7 C7H13NS
    (3S)-3-isothiocyanato-2,2-dimethylbutane
    —— 3,6-bis(ethylthio)-1,2,4,5-tetrazine 136506-23-5 C6H10N4S2
    3,6-bis(ethylthio)-1,2,4,5-tetrazine
    —— (2-azido-1-fluoroethylsulfanyl)benzene 501121-53-5 C8H8FN3S
    (2-azido-1-fluoroethylsulfanyl)benzene
    —— 4-(3,5-Dimethylpyrazol-1-yl)-2-(3-chlorobenzylthio)imidazo<4,5-d>pyridazine 85732-92-9 C17H15ClN6S
    4-(3,5-Dimethylpyrazol-1-yl)-2-(3-chlorobenzylthio)imidazo<4,5-d>pyridazine
    —— 4-(3,5-Dimethylpyrazol-1-yl)-2-(4-chlorobenzylthio)imidazo<4,5-d>pyridazine 85732-94-1 C17H15ClN6S
    4-(3,5-Dimethylpyrazol-1-yl)-2-(4-chlorobenzylthio)imidazo<4,5-d>pyridazine
    —— 2-Amino-6-(5-brom-2-methylmercapto-4-methyl-pyrimidinyl-(6)-mercapto)-purin 91426-84-5 C11H10BrN7S2
    2-Amino-6-(5-brom-2-methylmercapto-4-methyl-pyrimidinyl-(6)-mercapto)-purin
    —— 3-chloro-4-(5-phenylthiazol-2-ylsulfanyl)phenylamine 848133-00-6 C15H11ClN2S2
    3-chloro-4-(5-phenylthiazol-2-ylsulfanyl)phenylamine
    —— 2-(2-chloro-4-nitrophenylsulfanyl)-5-phenyl-1,3-thiazole 848132-99-0 C15H9ClN2O2S2
    2-(2-chloro-4-nitrophenylsulfanyl)-5-phenyl-1,3-thiazole
    —— 4-methylthio-5-(2-hydroxyethylthio)-1,3-dithiole-2-thione 207510-78-9 C6H8OS5
    4-methylthio-5-(2-hydroxyethylthio)-1,3-dithiole-2-thione
    —— 3,4-dihydro-2H-pyrimido[1,2-c]pyrido[3,2-e][1,3]thiazine-6-thione 1202519-02-5 C10H9N3S2
    3,4-dihydro-2H-pyrimido[1,2-c]pyrido[3,2-e][1,3]thiazine-6-thione
    —— di-1-propenyl sulfone 38405-93-5 C6H10O2S
    di-1-propenyl sulfone
    —— 6-chloro-8-methylthio-5H-pyrimido[5,4-e][1,2,4]triazolo[5,1-b][1,3]thiazin-5-ol 321660-52-0 C8H6ClN5OS2
    6-chloro-8-methylthio-5H-pyrimido[5,4-e][1,2,4]triazolo[5,1-b][1,3]thiazin-5-ol
    —— (4S,5S)-4-hydroxymethyl-2-methyl-5-[4-(methylthio)phenyl]-2-oxazoline 203576-39-0 C12H15NO2S
    (4S,5S)-4-hydroxymethyl-2-methyl-5-[4-(methylthio)phenyl]-2-oxazoline
    —— tert-butyl phenylacetyl-[2-(2-phenylsulfanyl-1H-indol-3-yl)ethyl]carbamate 712273-36-4 C29H30N2O3S
    tert-butyl phenylacetyl-[2-(2-phenylsulfanyl-1H-indol-3-yl)ethyl]carbamate
    —— 4-chloro-6-isopropyl-2-(methylthio)pyrimidine 199863-95-1 C8H11ClN2S
    4-chloro-6-isopropyl-2-(methylthio)pyrimidine
    —— (2-Amino-3,5-difluoro-phenylsulfanyl)acetonitrile 293316-30-0 C8H6F2N2S
    (2-Amino-3,5-difluoro-phenylsulfanyl)acetonitrile
    —— 1,3,9,11-tetraaza-6,14,17,22,25-pentaoxabicyclo<9.8.8>heptacosane-2,10-dithione 89863-10-5 C18H34N4O5S2
    1,3,9,11-tetraaza-6,14,17,22,25-pentaoxabicyclo<9.8.8>heptacosane-2,10-dithione
    —— 2-ethylsulfanyl-6-methyl-4H-thiopyran-4-one 935700-38-2 C8H10OS2
    2-ethylsulfanyl-6-methyl-4H-thiopyran-4-one
    —— 1,4,12-Trioxa-7,9,15,17-tetraazacyclononadecane-8,16-dithione 107447-41-6 C12H24N4O3S2
    1,4,12-Trioxa-7,9,15,17-tetraazacyclononadecane-8,16-dithione
    —— 1,3,9,11-tetraaza-6,14,17,22-tetraoxabicyclo<9.8.5>tetracosane-2,10-dithione 110228-75-6 C16H30N4O4S2
    1,3,9,11-tetraaza-6,14,17,22-tetraoxabicyclo<9.8.5>tetracosane-2,10-dithione
    —— 3-phenylsulfanyl-1-(1H-pyrazol-3-yl)-6,7-dihydrothieno[3,4-c]pyridin-4(5H)-one 1374103-04-4 C16H13N3OS2
    3-phenylsulfanyl-1-(1H-pyrazol-3-yl)-6,7-dihydrothieno[3,4-c]pyridin-4(5H)-one
    —— N,N-bis(trimethylsilyl)-3-amino-4-butylthio-1,2,5-thiadiazole 191467-39-7 C12H27N3S2Si2
    N,N-bis(trimethylsilyl)-3-amino-4-butylthio-1,2,5-thiadiazole
    —— bis-(4-amino-3-methyl-phenyl)-sulfide 34237-94-0 C14H16N2S
    bis-(4-amino-3-methyl-phenyl)-sulfide
    —— 1-Hexynyl trifluoromethyl sulfone 119353-19-4 C7H9F3O2S
    1-Hexynyl trifluoromethyl sulfone
    —— 2-chloro-4-diethylamino-8-p-tolylsulfanylpyrido[3,2-d]pyrimidine-6-carboxylic acid methyl ester 1352402-79-9 C20H21ClN4O2S
    2-chloro-4-diethylamino-8-p-tolylsulfanylpyrido[3,2-d]pyrimidine-6-carboxylic acid methyl ester
    —— 8-benzylsulfanyl-4-diethylamino-2-p-tolylsulfanylpyrido[3,2-d]pyrimidine-6-carboxylic acid methyl ester 1352402-84-6 C27H28N4O2S2
    8-benzylsulfanyl-4-diethylamino-2-p-tolylsulfanylpyrido[3,2-d]pyrimidine-6-carboxylic acid methyl ester
    —— 2-p-tolylsulfanyl-8-chloro-4-diethylaminopyrido[3,2-d]pyrimidine-6-carboxylic acid methyl ester 1352402-82-4 C20H21ClN4O2S
    2-p-tolylsulfanyl-8-chloro-4-diethylaminopyrido[3,2-d]pyrimidine-6-carboxylic acid methyl ester
    —— N-benzyl-(Z)-3-phenylthio-2-(benzylthio)propenamide 1294897-83-8 C23H21NOS2
    N-benzyl-(Z)-3-phenylthio-2-(benzylthio)propenamide
    —— 6-Amino-9-benzyl-8-bromo-2-phenylthiopurine 226907-79-5 C18H14BrN5S
    6-Amino-9-benzyl-8-bromo-2-phenylthiopurine
    —— S-prenyl isothiourea hydrobromide 62770-96-1 BrH*C6H12N2S
    S-prenyl isothiourea hydrobromide
    —— 4-ethoxycarbonyl-5-methyl-2-methylthio-1,3-selenazole 647032-82-4 C8H11NO2SSe
    4-ethoxycarbonyl-5-methyl-2-methylthio-1,3-selenazole
    —— 4-butoxycarbonyl-2-butylthio-5-methyl-1,3-selenazole 647032-85-7 C13H21NO2SSe
    4-butoxycarbonyl-2-butylthio-5-methyl-1,3-selenazole
    —— 4-butoxycarbonyl-5-methyl-2-methylthio-1,3-selenazole 647032-84-6 C10H15NO2SSe
    4-butoxycarbonyl-5-methyl-2-methylthio-1,3-selenazole
    —— 2-butylthio-4-ethoxycarbonyl-5-methyl-1,3-selenazole 647032-83-5 C11H17NO2SSe
    2-butylthio-4-ethoxycarbonyl-5-methyl-1,3-selenazole
    —— 3-(dodecane-1-sulfonyl)-propionic acid ethyl ester 101791-28-0 C17H34O4S
    3-(dodecane-1-sulfonyl)-propionic acid ethyl ester
    —— (6-Amino-3,5-dicyano-pyridin-2-ylsulfanyl)-acetic acid 119022-86-5 C9H6N4O2S
    (6-Amino-3,5-dicyano-pyridin-2-ylsulfanyl)-acetic acid
    —— 1-Butylsulfanyl-4-methyl-2-(2-methylprop-2-enyl)pent-4-ene-1-selone 173281-66-8 C14H24SSe
    1-Butylsulfanyl-4-methyl-2-(2-methylprop-2-enyl)pent-4-ene-1-selone
    —— 2-(4-Chloro-phenylsulfanyl)-5-trifluoromethyl-phenylamine 32631-27-9 C13H9ClF3NS
    2-(4-Chloro-phenylsulfanyl)-5-trifluoromethyl-phenylamine
    —— 3-methyl-6,7,8,9,10,10a-hexahydro-cyclohepta[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine 781558-69-8 C10H14N4S
    3-methyl-6,7,8,9,10,10a-hexahydro-cyclohepta[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine
    —— 3-trifluoromethyl-6,7,8,9,10,10a-hexahydro-cyclohepta[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine 66933-19-5 C10H11F3N4S
    3-trifluoromethyl-6,7,8,9,10,10a-hexahydro-cyclohepta[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine
    —— 3-methyl-5,5a,6,7,8,9,10,10a-octahydro-cyclohepta[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine 66933-23-1 C10H16N4S
    3-methyl-5,5a,6,7,8,9,10,10a-octahydro-cyclohepta[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine
    —— 3-ethyl-6,7,8,9,10,10a-hexahydro-cyclohepta[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine 744995-07-1 C11H16N4S
    3-ethyl-6,7,8,9,10,10a-hexahydro-cyclohepta[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine
    —— 3-ethyl-5,5a,6,7,8,9,10,10a-octahydro-cyclohepta[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine 60681-20-1 C11H18N4S
    3-ethyl-5,5a,6,7,8,9,10,10a-octahydro-cyclohepta[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine
    —— 5-acetyl-3-ethyl-5,5a,6,7,8,9,10,10a-octahydro-cyclohepta[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine 60681-27-8 C13H20N4OS
    5-acetyl-3-ethyl-5,5a,6,7,8,9,10,10a-octahydro-cyclohepta[<i>e</i>][1,2,4]triazolo[3,4-<i>b</i>][1,3,4]thiadiazine
    —— <i>S</i>-dimethylaminomethyl-isothiourea 98021-15-9 C4H11N3S
    <i>S</i>-dimethylaminomethyl-isothiourea