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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(6-hydroxyhexylthio)-4-methyl-6-(5-methyl-1H-pyrazol-3-ylamino)nicotinonitrile 1024600-40-5 C17H23N5OS
    2-(6-hydroxyhexylthio)-4-methyl-6-(5-methyl-1H-pyrazol-3-ylamino)nicotinonitrile
    —— Prop-2-enenitrile--(ethenesulfonyl)ethene (1/1) 28931-39-7 C7H9NO2S
    Prop-2-enenitrile--(ethenesulfonyl)ethene (1/1)
    —— Tetracosyl carbamimidothioate--hydrogen bromide (1/1) 7399-05-5 C25H53BrN2S
    Tetracosyl carbamimidothioate--hydrogen bromide (1/1)
    —— (5Z)-6-Oxo-5-{2-[4-({4-[(2E)-2-(2-oxo-6-sulfonaphthalen-1(2H)-ylidene)hydrazinyl]phenyl}sulfanyl)phenyl]hydrazinylidene}-5,6-dihydronaphthalene-2-sulfonic acid 6661-25-2 C32H22N4O8S3
    (5Z)-6-Oxo-5-{2-[4-({4-[(2E)-2-(2-oxo-6-sulfonaphthalen-1(2H)-ylidene)hydrazinyl]phenyl}sulfanyl)phenyl]hydrazinylidene}-5,6-dihydronaphthalene-2-sulfonic acid
    —— 3-Dimethylsulfoniobutan-2-yl(dimethyl)sulfanium;2,4,6-trinitrobenzenesulfonate 2026-33-7 C14H22N3O9S3+
    3-Dimethylsulfoniobutan-2-yl(dimethyl)sulfanium;2,4,6-trinitrobenzenesulfonate
    —— 17-Oxa-8,16-dithia-6,14-diazatetracyclo[7.7.1.02,7.010,15]heptadeca-2(7),3,5,10(15),11,13-hexaene;hydrochloride 62295-88-9 C12H9ClN2OS2
    17-Oxa-8,16-dithia-6,14-diazatetracyclo[7.7.1.02,7.010,15]heptadeca-2(7),3,5,10(15),11,13-hexaene;hydrochloride
    —— 2-(Hexadecylsulfanyl)pyridine--hydrogen bromide (1/1) 6313-83-3 C21H38BrNS
    2-(Hexadecylsulfanyl)pyridine--hydrogen bromide (1/1)
    —— Hexacosyl carbamimidothioate--hydrogen bromide (1/1) 6624-74-4 C27H57BrN2S
    Hexacosyl carbamimidothioate--hydrogen bromide (1/1)
    —— O-Ethyl hydrogen carbonodithioate--lead (1/1) 5439-55-4 C3H6OPbS2
    O-Ethyl hydrogen carbonodithioate--lead (1/1)
    —— 2-(Octylsulfanyl)pyridine--hydrogen bromide (1/1) 6313-79-7 C13H22BrNS
    2-(Octylsulfanyl)pyridine--hydrogen bromide (1/1)
    —— S-[2-(Diethylamino)ethyl] 2-(diethylamino)ethane-1-sulfonothioate--hydrogen chloride (1/1) 88890-27-1 C12H29ClN2O2S2
    S-[2-(Diethylamino)ethyl] 2-(diethylamino)ethane-1-sulfonothioate--hydrogen chloride (1/1)
    —— Diethylcarbamodithioic acid--ethane-1,2-diyl dicarbamimidothioate (1/1) 68059-73-4 C9H21N5S4
    Diethylcarbamodithioic acid--ethane-1,2-diyl dicarbamimidothioate (1/1)
    —— Octacosyl carbamimidothioate--hydrogen bromide (1/1) 7154-96-3 C29H61BrN2S
    Octacosyl carbamimidothioate--hydrogen bromide (1/1)
    —— Nonane-1,9-diyl dicarbamimidothioate--hydrogen bromide (1/1) 5433-13-6 C11H25BrN4S2
    Nonane-1,9-diyl dicarbamimidothioate--hydrogen bromide (1/1)
    —— Ethenyl acetate--(ethenesulfonyl)ethene (1/1) 27358-55-0 C8H12O4S
    Ethenyl acetate--(ethenesulfonyl)ethene (1/1)
    —— Carbamothioic acid, sodium salt 21055-93-6 C5H11NNaOS+
    Carbamothioic acid, sodium salt
    —— 2-(Tridecylsulfanyl)pyridine--hydrogen bromide (1/1) 6313-82-2 C18H32BrNS
    2-(Tridecylsulfanyl)pyridine--hydrogen bromide (1/1)
    —— 2-(Hexylsulfanyl)pyridine--hydrogen bromide (1/1) 6937-14-0 C11H18BrNS
    2-(Hexylsulfanyl)pyridine--hydrogen bromide (1/1)
    —— Hexane-1,6-diyl bis(N'-prop-2-en-1-ylcarbamimidothioate)--hydrogen bromide (1/1) 6323-55-3 C14H27BrN4S2
    Hexane-1,6-diyl bis(N'-prop-2-en-1-ylcarbamimidothioate)--hydrogen bromide (1/1)
    —— Pentane-1,5-diyl bis(N'-prop-2-en-1-ylcarbamimidothioate)--hydrogen bromide (1/1) 6276-61-5 C13H25BrN4S2
    Pentane-1,5-diyl bis(N'-prop-2-en-1-ylcarbamimidothioate)--hydrogen bromide (1/1)
    —— Xanthic acid, lead(II) salt 5439-59-8 C4H8OPbS2
    Xanthic acid, lead(II) salt
    —— 2,4-Dioxo-1,2,3,4-tetrahydropyrimidin-5-yl carbamimidothioate hydrochloride 42074-70-4 C5H7ClN4O2S
    2,4-Dioxo-1,2,3,4-tetrahydropyrimidin-5-yl carbamimidothioate hydrochloride
    —— 2-Oxopropyl carbamimidothioate--hydrogen chloride (1/1) 6333-72-8 C4H9ClN2OS
    2-Oxopropyl carbamimidothioate--hydrogen chloride (1/1)
    —— (2Z)-2-Methylbut-2-ene-1,4-diyl dicarbamimidothioate--hydrogen bromide (1/1) 16464-63-4 C7H15BrN4S2
    (2Z)-2-Methylbut-2-ene-1,4-diyl dicarbamimidothioate--hydrogen bromide (1/1)
    —— 3,3-Dimethylbutyl carbamimidothioate--hydrogen bromide (1/1) 5467-41-4 C7H17BrN2S
    3,3-Dimethylbutyl carbamimidothioate--hydrogen bromide (1/1)
    —— 2-(Butylsulfanyl)-1H-imidazole--hydrogen chloride (1/1) 6946-12-9 C7H13ClN2S
    2-(Butylsulfanyl)-1H-imidazole--hydrogen chloride (1/1)
    —— Bis(2-methylprop-2-en-1-yl)carbamodithioic acid--lead (1/1) 6303-14-6 C9H15NPbS2
    Bis(2-methylprop-2-en-1-yl)carbamodithioic acid--lead (1/1)
    —— 2-(Pentylsulfanyl)pyridine--hydrogen bromide (1/1) 6313-78-6 C10H16BrNS
    2-(Pentylsulfanyl)pyridine--hydrogen bromide (1/1)
    —— Heptane-1,7-diyl dicarbamimidothioate--hydrogen bromide (1/1) 6634-90-8 C9H21BrN4S2
    Heptane-1,7-diyl dicarbamimidothioate--hydrogen bromide (1/1)
    —— 2-[(4-fluorophenyl)methylsulfanyl]-N,N,5-trimethylpyrimidin-4-amine;hydrochloride 893-57-2 C14H17ClFN3S
    2-[(4-fluorophenyl)methylsulfanyl]-N,N,5-trimethylpyrimidin-4-amine;hydrochloride
    —— (3-Amino-2-methyl-3-oxopropyl) carbamimidothioate;hydrochloride 6634-44-2 C5H12ClN3OS
    (3-Amino-2-methyl-3-oxopropyl) carbamimidothioate;hydrochloride
    —— 2-(Heptylsulfanyl)pyridine--hydrogen bromide (1/1) 7248-77-3 C12H20BrNS
    2-(Heptylsulfanyl)pyridine--hydrogen bromide (1/1)
    —— 2-(Tetradecylsulfanyl)-1H-imidazole--hydrogen bromide (1/1) 5512-30-1 C17H33BrN2S
    2-(Tetradecylsulfanyl)-1H-imidazole--hydrogen bromide (1/1)
    —— <i>N</i>,<i>N</i>''-dibutyl-<i>S,S'</i>-butanediyl-bis-isothiourea; dihydrobromide 6276-20-6 2BrH*C14H30N4S2
    <i>N</i>,<i>N</i>''-dibutyl-<i>S,S'</i>-butanediyl-bis-isothiourea; dihydrobromide
    —— 2-[(4-fluorophenyl)methylsulfanyl]-N,N,6-trimethylpyrimidin-4-amine;hydrochloride 893-55-0 C14H17ClFN3S
    2-[(4-fluorophenyl)methylsulfanyl]-N,N,6-trimethylpyrimidin-4-amine;hydrochloride
    —— 2-Azanidylethylazanide;cobalt(3+);2-sulfaniumylethylazanide;thiocyanic acid 41212-25-3 C7H20CoN6S2-
    2-Azanidylethylazanide;cobalt(3+);2-sulfaniumylethylazanide;thiocyanic acid
    —— 4-Methylsulfanylpyridine-2,3,6-triamine 60282-80-6 C6H11ClN4S
    4-Methylsulfanylpyridine-2,3,6-triamine
    —— 2-(Undecylsulfanyl)pyridine--hydrogen bromide (1/1) 6313-81-1 C16H28BrNS
    2-(Undecylsulfanyl)pyridine--hydrogen bromide (1/1)
    —— 2-(Ethylsulfanyl)pyridine--hydrogen bromide (1/1) 6313-76-4 C7H10BrNS
    2-(Ethylsulfanyl)pyridine--hydrogen bromide (1/1)
    —— 2-(Decylsulfanyl)pyridine--hydrogen bromide (1/1) 6313-80-0 C15H26BrNS
    2-(Decylsulfanyl)pyridine--hydrogen bromide (1/1)
    —— Cyclohexylmethyl carbamimidothioate--hydrogen chloride (1/1) 6326-45-0 C8H17ClN2S
    Cyclohexylmethyl carbamimidothioate--hydrogen chloride (1/1)
    —— N'-(1-adamantylmethyl)-2-[[2-(1-adamantylmethylimino)-2-aminoethyl]disulfanyl]ethanimidamide;hydrochloride 37764-44-6 C26H43ClN4S2
    N'-(1-adamantylmethyl)-2-[[2-(1-adamantylmethylimino)-2-aminoethyl]disulfanyl]ethanimidamide;hydrochloride
    —— N-(2-phenylethyl)-N-[(Z)-phenylsulfanylmethyldiazenyl]acetamide 84304-09-6 C17H19N3OS
    N-(2-phenylethyl)-N-[(Z)-phenylsulfanylmethyldiazenyl]acetamide
    —— Octane-1,2-diyl dicarbamimidothioate--hydrogen bromide (1/1) 7355-48-8 C10H23BrN4S2
    Octane-1,2-diyl dicarbamimidothioate--hydrogen bromide (1/1)
    —— Butane-1,4-diyl bis(N'-prop-2-en-1-ylcarbamimidothioate)--hydrogen bromide (1/1) 6271-48-3 C12H23BrN4S2
    Butane-1,4-diyl bis(N'-prop-2-en-1-ylcarbamimidothioate)--hydrogen bromide (1/1)
    —— 1-Butanethiol, mercury(2+) salt 23601-34-5 C4H10HgS
    1-Butanethiol, mercury(2+) salt
    —— 1,8-bis-carbamimidoylmercapto-octane; dihydrobromide 6270-77-5 2BrH*C10H22N4S2
    1,8-bis-carbamimidoylmercapto-octane; dihydrobromide
    —— 53806-40-9 C10H6FeO4S
    —— 2-phenyl-4-methylthio-3-oxo-5-hydroxy-2H-pyridazine 64178-80-9 C11H10N2O2S
    2-phenyl-4-methylthio-3-oxo-5-hydroxy-2H-pyridazine
    —— 3-[4-Hydroxy-5-(2-isopropyl-phenylsulfanyl)-6-oxo-6H-pyran-2-yl]-benzoic acid ethyl ester 178875-59-7 C23H22O5S
    3-[4-Hydroxy-5-(2-isopropyl-phenylsulfanyl)-6-oxo-6H-pyran-2-yl]-benzoic acid ethyl ester