摩熵化学
数据库官网
小程序
打开微信扫一扫
首页 分子通 化学资讯 化学百科 反应查询 关于我们
请输入关键词
历史搜索
    热门化合物HOT
    • 喹啉
    • 水杨醛
    • 二溴甲烷
    • 谷胱甘肽
    • L-乳酸
    • 苯巴比妥
    • 辣椒碱
    • 非那明
    • 百草枯
    • 联苯烯
    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2,5-hexanedithiol 4038-07-7 C6H14S2
    2,5-hexanedithiol
    —— bis<2-(thiophenoxy)benzyl> oxalate 120454-38-8 C28H22O4S2
    bis<2-(thiophenoxy)benzyl> oxalate
    —— 3-(morpholinomethyl)-2-(methoxycarbonylamino)-6-(phenylthio) imidazo [1,2-a] pyridine 77527-43-6 C20H22N4O3S
    3-(morpholinomethyl)-2-(methoxycarbonylamino)-6-(phenylthio) imidazo [1,2-a] pyridine
    —— (4R,5E,7E,9R)-9-(tert-butyldiphenylsilyloxy)-9-((2R,4R,6R)-4-methoxy-6-(phenylthio)-tetrahydro-2H-pyran-2-yl)-7-methylnona-1,5,7-trien-4-ol 920018-65-1 C38H48O4SSi
    (4R,5E,7E,9R)-9-(tert-butyldiphenylsilyloxy)-9-((2R,4R,6R)-4-methoxy-6-(phenylthio)-tetrahydro-2H-pyran-2-yl)-7-methylnona-1,5,7-trien-4-ol
    —— 1-tert-butyl-1,1-dimethylsilyl ((4R,5R)-5-(2-methyl-1,3-dithian-2-ylmethyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl ether 872831-94-2 C18H36O3S2Si
    1-tert-butyl-1,1-dimethylsilyl ((4R,5R)-5-(2-methyl-1,3-dithian-2-ylmethyl)-2,2-dimethyl-1,3-dioxolan-4-yl)methyl ether
    —— ethyl (2E,4E)-6-(tert-butyldiphenylsilyloxy)-6-((2R,4R,6R)-4-methoxy-6-(phenylthio)-tetrahydro-2H-pyran-2-yl)-4-methylhexa-2,4-dienoate 920018-63-9 C37H46O5SSi
    ethyl (2E,4E)-6-(tert-butyldiphenylsilyloxy)-6-((2R,4R,6R)-4-methoxy-6-(phenylthio)-tetrahydro-2H-pyran-2-yl)-4-methylhexa-2,4-dienoate
    —— 1,1-bis-acetylsulfanyl-propane 729602-98-6 C7H12O2S2
    1,1-bis-acetylsulfanyl-propane
    —— <i>N</i>,<i>N</i>-bis-[(4-chloro-phenylsulfanyl)-methyl]-<i>p</i>-toluidine 6969-13-7 C21H19Cl2NS2
    <i>N</i>,<i>N</i>-bis-[(4-chloro-phenylsulfanyl)-methyl]-<i>p</i>-toluidine
    —— 2,3-epoxypropyl 3-(phenylthio)propionate 77500-64-2 C12H14O3S
    2,3-epoxypropyl 3-(phenylthio)propionate
    —— 3-chloro-<i>N</i>-[(4-chloro-phenylsulfanyl)-methyl]-aniline 956-65-0 C13H11Cl2NS
    3-chloro-<i>N</i>-[(4-chloro-phenylsulfanyl)-methyl]-aniline
    —— ethyl-propyl-thiocarbamic acid <i>S</i>-propyl ester 98956-76-4 C9H19NOS
    ethyl-propyl-thiocarbamic acid <i>S</i>-propyl ester
    —— <i>N</i>-[(4-chloro-phenylsulfanyl)-methyl]-<i>p</i>-toluidine 6632-00-4 C14H14ClNS
    <i>N</i>-[(4-chloro-phenylsulfanyl)-methyl]-<i>p</i>-toluidine
    —— 6-[(4-Chlorophenyl)sulfanyl]-3-pyridinylamine 25935-62-0 C11H9ClN2S
    6-[(4-Chlorophenyl)sulfanyl]-3-pyridinylamine
    —— 4-chloro-<i>N</i>-[(4-chloro-phenylsulfanyl)-methyl]-aniline 107623-18-7 C13H11Cl2NS
    4-chloro-<i>N</i>-[(4-chloro-phenylsulfanyl)-methyl]-aniline
    —— 2-Amino-6-(phenylthio)imidazo<1,2-a>pyridin 64064-29-5 C13H11N3S
    2-Amino-6-(phenylthio)imidazo<1,2-a>pyridin
    —— (N-Methyl-4-amino-benzyl)-(4-chlor-phenyl)-sulfid 7153-31-3 C14H14ClNS
    (N-Methyl-4-amino-benzyl)-(4-chlor-phenyl)-sulfid
    —— 2-(2-aminophenylthio)-2-(2-thienyl)ethyl 2-thienyl cetone 101441-84-3 C17H15NOS3
    2-(2-aminophenylthio)-2-(2-thienyl)ethyl 2-thienyl cetone
    —— (3aS,8aR)-3-[phenylsulfanyl(trimethylsilyl)methyl]-3,3a,4,5,6,7,8,8a-octahydrocyclohepta[b]furan-2-one 118522-18-2 C19H28O2SSi
    (3aS,8aR)-3-[phenylsulfanyl(trimethylsilyl)methyl]-3,3a,4,5,6,7,8,8a-octahydrocyclohepta[b]furan-2-one
    —— 1,12-bis-carbamimidoylmercapto-dodecane 62476-83-9 C14H30N4S2
    1,12-bis-carbamimidoylmercapto-dodecane
    —— tert-Butyl-thiocarbamic acid O-ethyl ester 82360-13-2 C7H15NOS
    tert-Butyl-thiocarbamic acid O-ethyl ester
    —— 4-[2-benzyloxymethyl-4-isopropyl-5-(3-methoxy-phenylsulfanyl)-imidazol-1-ylmethyl]-pyridine 620969-33-7 C27H29N3O2S
    4-[2-benzyloxymethyl-4-isopropyl-5-(3-methoxy-phenylsulfanyl)-imidazol-1-ylmethyl]-pyridine
    —— 8-amino-6-hydroxy-1,4,7,9-tetraazabenzo<b>phenothiazine 77708-96-4 C12H8N6OS
    8-amino-6-hydroxy-1,4,7,9-tetraazabenzo<b>phenothiazine
    —— GK 03192 679391-42-5 C12H9F3N2OS
    GK 03192
    —— 1-methoxy-1-(phenylthio)octane 89423-37-0 C15H24OS
    1-methoxy-1-(phenylthio)octane
    —— 2-(4-Chlorophenyl)sulfanyl-1,3-dinitro-5-(trifluoromethyl)benzene 17811-50-6 C13H6ClF3N2O4S
    2-(4-Chlorophenyl)sulfanyl-1,3-dinitro-5-(trifluoromethyl)benzene
    —— 4-chloro-1-(2,5-dimethoxy-phenylsulfanyl)-2-nitro-benzene 72418-75-8 C14H12ClNO4S
    4-chloro-1-(2,5-dimethoxy-phenylsulfanyl)-2-nitro-benzene
    —— 5-exo-methyl-2-exo-phenylsulfenyl-4,7-dioxatricyclo<3.2.1.0<sup>3,6</sup>>octane 114765-67-2 C13H14O2S
    5-exo-methyl-2-exo-phenylsulfenyl-4,7-dioxatricyclo<3.2.1.0<sup>3,6</sup>>octane
    —— 3,5-Bis-cyanomethylsulfanyl-isothiazole-4-carbonitrile 24134-78-9 C8H4N4S3
    3,5-Bis-cyanomethylsulfanyl-isothiazole-4-carbonitrile
    —— 3,5-Bis(cyanomethylthio)-1,2,4-thiadiazole 332110-36-8 C6H4N4S3
    3,5-Bis(cyanomethylthio)-1,2,4-thiadiazole
    —— 1H-1,2,4-Triazole-1-propanenitrile, 3-amino-5-(methylthio)- 87866-44-2 C6H9N5S
    1H-1,2,4-Triazole-1-propanenitrile, 3-amino-5-(methylthio)-
    —— 4-(4-chlorophenyl)sulfanyl-N-(1-ethynylcyclohexyl)-3-nitrobenzenesulfonamide 675104-57-1 C20H19ClN2O4S2
    4-(4-chlorophenyl)sulfanyl-N-(1-ethynylcyclohexyl)-3-nitrobenzenesulfonamide
    —— 3-allyl-2-(phenylthio)thiophene 790715-17-2 C13H12S2
    3-allyl-2-(phenylthio)thiophene
    —— N-(1-ethynylcyclohexyl)-3-nitro-4-pyridin-2-ylsulfanylbenzenesulfonamide 675104-59-3 C19H19N3O4S2
    N-(1-ethynylcyclohexyl)-3-nitro-4-pyridin-2-ylsulfanylbenzenesulfonamide
    —— morpholin-4-yl-acetic acid [2-oxo-2-(4-phenylsulfanyl-phenyl)-ethylidene]-hydrazide 6592-87-6 C20H21N3O3S
    morpholin-4-yl-acetic acid [2-oxo-2-(4-phenylsulfanyl-phenyl)-ethylidene]-hydrazide
    —— N-(1-ethynylcyclohexyl)-3-nitro-4-phenylsulfanylbenzenesulfonamide 675104-58-2 C20H20N2O4S2
    N-(1-ethynylcyclohexyl)-3-nitro-4-phenylsulfanylbenzenesulfonamide
    —— Benzo[b]thiophen-3(2H)-one, 2-[(2-methylphenyl)methylene]-, (Z)- 97871-91-5 C16H12OS
    Benzo[b]thiophen-3(2H)-one, 2-[(2-methylphenyl)methylene]-, (Z)-
    —— butan-2-one-dimethyldithioacetal 82726-71-4 C6H14S2
    butan-2-one-dimethyldithioacetal
    —— 2-(allylthio)-6,7-dihydro-5H-cyclopenta[b]pyridine-3-carbonitrile 166113-79-7 C12H12N2S
    2-(allylthio)-6,7-dihydro-5H-cyclopenta[b]pyridine-3-carbonitrile
    —— 2-prop-2-enylsulfanyl-6,7,8,9-tetrahydro-5H-cyclohepta[b]pyridine-3-carbonitrile 123413-88-7 C14H16N2S
    2-prop-2-enylsulfanyl-6,7,8,9-tetrahydro-5H-cyclohepta[b]pyridine-3-carbonitrile
    —— 2-(methylsulfanyl)-6,7-dihydro-5H-cyclopenta[b]pyridine-3-carbonitrile 154384-15-3 C10H10N2S
    2-(methylsulfanyl)-6,7-dihydro-5H-cyclopenta[b]pyridine-3-carbonitrile
    —— 2-Methylthio-5,6,7,8,9-pentahydrocyclohepta[2,1-b]pyridine-3-carbonitrile 130506-73-9 C12H14N2S
    2-Methylthio-5,6,7,8,9-pentahydrocyclohepta[2,1-b]pyridine-3-carbonitrile
    —— ethyl 4-[(3-cyano-6,7,8,9-tetrahydro-5H-cyclohepta[b]pyridin-2-yl)sulfanyl]-3-oxobutanoate 290299-63-7 C17H20N2O3S
    ethyl 4-[(3-cyano-6,7,8,9-tetrahydro-5H-cyclohepta[b]pyridin-2-yl)sulfanyl]-3-oxobutanoate
    —— (1Z)-N'-hydroxy-2-(isopropylsulfonyl)ethanimidamide 1923816-08-3 C5H12N2O3S
    (1Z)-N'-hydroxy-2-(isopropylsulfonyl)ethanimidamide
    —— 1-chloro-5-nitro-2,4-bis-phenylsulfanyl-benzene 93819-59-1 C18H12ClNO2S2
    1-chloro-5-nitro-2,4-bis-phenylsulfanyl-benzene
    —— 5-(2-methylsulfanyl-pyrimidin-4-yl)-thiophene-2-sulfonic acid dimethylamide 882278-17-3 C11H13N3O2S3
    5-(2-methylsulfanyl-pyrimidin-4-yl)-thiophene-2-sulfonic acid dimethylamide
    —— 4-[5-(4-Bromo-3,5-dimethylpyrazol-1-yl)sulfonylthiophen-2-yl]-2-methylsulfanylpyrimidine 4762-39-4 C14H13BrN4O2S3
    4-[5-(4-Bromo-3,5-dimethylpyrazol-1-yl)sulfonylthiophen-2-yl]-2-methylsulfanylpyrimidine
    —— 6,6-Dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophen-4-one 172516-40-4 C11H14OS2
    6,6-Dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophen-4-one
    —— (1''RS,1'R,4'R)-[4-(2-bromo-1-ethoxy-ethoxymethyl)cyclopent-2-enyllsulfanyl]-benzene 371783-79-8 C16H21BrO2S
    (1''RS,1'R,4'R)-[4-(2-bromo-1-ethoxy-ethoxymethyl)cyclopent-2-enyllsulfanyl]-benzene
    —— 1-[4-Methyl-2-methylsulfanyl-5-(4-methyl-thiazol-2-yl)-thiophen-3-yl]-ethanone 473530-81-3 C12H13NOS3
    1-[4-Methyl-2-methylsulfanyl-5-(4-methyl-thiazol-2-yl)-thiophen-3-yl]-ethanone
    —— (1'R,4'R)-(+)-(4-phenylsulfanyl-cyclopent-2-enyl)methanol 371783-78-7 C12H14OS
    (1'R,4'R)-(+)-(4-phenylsulfanyl-cyclopent-2-enyl)methanol