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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-(1-cyclohexyl-1-phenylmethyl)-N-(2-phenylsulfanylethyl)formamide 886759-23-5 C22H27NOS
    N-(1-cyclohexyl-1-phenylmethyl)-N-(2-phenylsulfanylethyl)formamide
    —— 1-phenylmethyl-1-propyl-(2-phenylsulfanyl)ethylamine 886759-14-4 C18H23NS
    1-phenylmethyl-1-propyl-(2-phenylsulfanyl)ethylamine
    —— Methanethiol, N-(2-phenylthioethyl)amidino-, hydrogen thiosulfate 40283-97-4 C10H14N2O3S3
    Methanethiol, N-(2-phenylthioethyl)amidino-, hydrogen thiosulfate
    —— 2-(2-Phenylsulfanylethyl)-4,5-dimethyl-3,6-dihydro-2H-1,2-thiazine 157736-13-5 C14H19NS2
    2-(2-Phenylsulfanylethyl)-4,5-dimethyl-3,6-dihydro-2H-1,2-thiazine
    —— 1-cyclohexyl-1-phenylmethyl-(2-phenylsulfanyl)ethylamine 886759-17-7 C21H27NS
    1-cyclohexyl-1-phenylmethyl-(2-phenylsulfanyl)ethylamine
    —— 1-cyclobutyl-1-phenylmethyl-(2-phenylsulfanyl)ethylamine 886759-16-6 C19H23NS
    1-cyclobutyl-1-phenylmethyl-(2-phenylsulfanyl)ethylamine
    —— N-[1-(4-fluorophenyl)ethyl]-N-(2-phenylsulfanylethyl)formamide 886759-24-6 C17H18FNOS
    N-[1-(4-fluorophenyl)ethyl]-N-(2-phenylsulfanylethyl)formamide
    —— N-(1-cyclobutyl-1-phenylmethyl)-N-(2-phenylsulfanylethyl)formamide 886759-22-4 C20H23NOS
    N-(1-cyclobutyl-1-phenylmethyl)-N-(2-phenylsulfanylethyl)formamide
    —— 1-Chloro-4-(1-phenylprop-2-enylsulfanyl)benzene 1173006-72-8 C15H13ClS
    1-Chloro-4-(1-phenylprop-2-enylsulfanyl)benzene
    —— 2-((2-fluorophenyl)thio)acetonitrile 61081-27-4 C8H6FNS
    2-((2-fluorophenyl)thio)acetonitrile
    —— β-Hydroxyethyl-2-methallylsulfid 60154-79-2 C6H12OS
    β-Hydroxyethyl-2-methallylsulfid
    —— 2,2,2-trifluoro-N-methyl-N-(2-phenylsulfanylethyl)acetamide 173267-12-4 C11H12F3NOS
    2,2,2-trifluoro-N-methyl-N-(2-phenylsulfanylethyl)acetamide
    —— N-acetyl-N-benzyl-2-(phenylthio)ethylamine 191545-71-8 C17H19NOS
    N-acetyl-N-benzyl-2-(phenylthio)ethylamine
    —— 2-(o-tolylthio)acetonitrile 103575-38-8 C9H9NS
    2-(o-tolylthio)acetonitrile
    —— 1-(6-Chloropyridazin-3-yl)oxy-3-(2-phenylsulfanylethylamino)propan-2-ol 138803-32-4 C15H18ClN3O2S
    1-(6-Chloropyridazin-3-yl)oxy-3-(2-phenylsulfanylethylamino)propan-2-ol
    —— 1-(2-methylsulfanylphenyl)-N-(2-phenylsulfanylethyl)methanimine 1258493-81-0 C16H17NS2
    1-(2-methylsulfanylphenyl)-N-(2-phenylsulfanylethyl)methanimine
    —— 2,2,2-trifluoro-N-(2-(phenylthio)ethyl)acetamide 173267-11-3 C10H10F3NOS
    2,2,2-trifluoro-N-(2-(phenylthio)ethyl)acetamide
    —— N-(2-hydroxyethyl)-N'-<2-(phenylthio)ethyl>urea 66923-49-7 C11H16N2O2S
    N-(2-hydroxyethyl)-N'-<2-(phenylthio)ethyl>urea
    —— N-(2-Phenylmercapto-aethyl)-propionamid 2173-29-7 C11H15NOS
    N-(2-Phenylmercapto-aethyl)-propionamid
    —— 2-methyl-7,7-di[(phenylsulfanyl)methyl]bicyclo[3.3.0]oct-1-en-3-one 938436-24-9 C23H24OS2
    2-methyl-7,7-di[(phenylsulfanyl)methyl]bicyclo[3.3.0]oct-1-en-3-one
    —— cis-3-nonen-1-thiol 265655-15-0 C9H18S
    cis-3-nonen-1-thiol
    —— Glutaraldehydbis-(diphenylmercaptal) 53480-96-9 C29H28S4
    Glutaraldehydbis-(diphenylmercaptal)
    —— 2-cyano-3-(2-methyl-2-trifluoroacetamidopropanethio)-pyridine 342816-11-9 C12H12F3N3OS
    2-cyano-3-(2-methyl-2-trifluoroacetamidopropanethio)-pyridine
    —— 3-(2-chloroethylsulfanyl)-2-methylprop-1-ene 60154-80-5 C6H11ClS
    3-(2-chloroethylsulfanyl)-2-methylprop-1-ene
    —— 3-Ethensulfonyl-2-methylpropen 60154-78-1 C6H10O2S
    3-Ethensulfonyl-2-methylpropen
    —— 2,3-bis(2,5-dimethylthiophen-3-yl)-5-(phenylsulfanyl)cyclopent-2-en-1-one 1380607-60-2 C23H22OS3
    2,3-bis(2,5-dimethylthiophen-3-yl)-5-(phenylsulfanyl)cyclopent-2-en-1-one
    —— tert.-Butylhydroxyhexylsulfoxid 62295-83-4 C10H22O2S
    tert.-Butylhydroxyhexylsulfoxid
    —— tert.-Butyl-hydroxypropylsulfoxid 40390-75-8 C7H16O2S
    tert.-Butyl-hydroxypropylsulfoxid
    —— [1-(Phenylsulfanylmethyl)cyclobutyl]methanamine 1387575-94-1 C12H17NS
    [1-(Phenylsulfanylmethyl)cyclobutyl]methanamine
    —— [(2R,4S,5R)-4-[(Z)-3-[(2R)-3,3-bis(ethylsulfanyl)oxan-2-yl]prop-2-enyl]-2-phenyl-1,3-dioxan-5-yl]oxy-tert-butyl-dimethylsilane 193970-57-9 C28H46O4S2Si
    [(2R,4S,5R)-4-[(Z)-3-[(2R)-3,3-bis(ethylsulfanyl)oxan-2-yl]prop-2-enyl]-2-phenyl-1,3-dioxan-5-yl]oxy-tert-butyl-dimethylsilane
    —— 6-(4-ethylphenyl)-3-(4-methylsulfanylphenyl)-4-phenylpyran-2-one 742699-43-0 C26H22O2S
    6-(4-ethylphenyl)-3-(4-methylsulfanylphenyl)-4-phenylpyran-2-one
    —— dimethyl 3-<(1,3-dithian-2-methyl-2-yl)methyl>pentanedioate 911801-86-0 C13H22O4S2
    dimethyl 3-<(1,3-dithian-2-methyl-2-yl)methyl>pentanedioate
    —— Methyl N-(carbamoyloxy)thioacetimidate 16960-39-7 C4H8N2O2S
    Methyl N-(carbamoyloxy)thioacetimidate
    —— [(Z)-(2,4-dimethyl-1,3-dithiolan-2-yl)methylideneamino] N-methylcarbamate —— C8H14N2O2S2
    [(Z)-(2,4-dimethyl-1,3-dithiolan-2-yl)methylideneamino] N-methylcarbamate
    —— Bis-<2-trimethylsilyl-aethyl>-sulfon 18001-74-6 C10H26O2SSi2
    Bis-<2-trimethylsilyl-aethyl>-sulfon
    —— Trimethyl[2-methylidene-4,4-bis(phenylsulfanyl)butyl]silane 215182-46-0 C20H26S2Si
    Trimethyl[2-methylidene-4,4-bis(phenylsulfanyl)butyl]silane
    —— 3,3-dimethyl-1,3-thiasilinane 1-oxide 209158-56-5 C6H14OSSi
    3,3-dimethyl-1,3-thiasilinane 1-oxide
    —— 4-[2-[[2-(Dimethylamino)pyrimido[4,5-d]pyrimidin-5-yl]amino]-4-methyl-phenyl]sulfanylphenol 1365922-64-0 C21H20N6OS
    4-[2-[[2-(Dimethylamino)pyrimido[4,5-d]pyrimidin-5-yl]amino]-4-methyl-phenyl]sulfanylphenol
    —— 4-[4-Methyl-2-[(7-propylpyrido[2,3-d]pyrimidin-4-yl)amino]phenyl]sulfanylphenol 944504-13-6 C23H22N4OS
    4-[4-Methyl-2-[(7-propylpyrido[2,3-d]pyrimidin-4-yl)amino]phenyl]sulfanylphenol
    —— 4-[2-[[2-(Ethylamino)pyrimido[4,5-d]pyrimidin-5-yl]amino]-4-methyl-phenyl]sulfanylphenol 1365922-60-6 C21H20N6OS
    4-[2-[[2-(Ethylamino)pyrimido[4,5-d]pyrimidin-5-yl]amino]-4-methyl-phenyl]sulfanylphenol
    —— 4-[2-[(7-Cyclopropylpyrido[2,3-d]pyrimidin-4-yl)amino]-4-methyl-phenyl]sulfanylphenol 944503-98-4 C23H20N4OS
    4-[2-[(7-Cyclopropylpyrido[2,3-d]pyrimidin-4-yl)amino]-4-methyl-phenyl]sulfanylphenol
    —— 4-(2-amino-4-methyl-phenylsulfanyl)-phenol 943614-81-1 C13H13NOS
    4-(2-amino-4-methyl-phenylsulfanyl)-phenol
    —— (7-cyclopropyl-pyrido[2,3-d]pyrimidin-4-yl)-(5-methyl-2-phenylsulfanyl-phenyl)-amine 944503-96-2 C23H20N4S
    (7-cyclopropyl-pyrido[2,3-d]pyrimidin-4-yl)-(5-methyl-2-phenylsulfanyl-phenyl)-amine
    —— 2-(4-Methoxy-phenylsulfanyl)-5-methyl-phenylamine 1097818-27-3 C14H15NOS
    2-(4-Methoxy-phenylsulfanyl)-5-methyl-phenylamine
    —— 7-isopropyl-N-(5-methyl-2-phenylsulfanyl-phenyl)pyrido[2,3-d]pyrimidin-4-amine 1365921-39-6 C23H22N4S
    7-isopropyl-N-(5-methyl-2-phenylsulfanyl-phenyl)pyrido[2,3-d]pyrimidin-4-amine
    —— N-[2-(4-fluorophenyl)sulfanyl-5-methyl-phenyl]-7-isopropyl-pyrido[2,3-d]pyrimidin-4-amine 1365921-60-3 C23H21FN4S
    N-[2-(4-fluorophenyl)sulfanyl-5-methyl-phenyl]-7-isopropyl-pyrido[2,3-d]pyrimidin-4-amine
    —— 4-[2-[(7-Isopropylpyrido[2,3-d]pyrimidin-4-yl)amino]-4-methyl-phenyl]sulfanylphenol 944503-77-9 C23H22N4OS
    4-[2-[(7-Isopropylpyrido[2,3-d]pyrimidin-4-yl)amino]-4-methyl-phenyl]sulfanylphenol
    —— N-(5-methyl-2-phenylsulfanyl-phenyl)-7-propyl-pyrido[2,3-d]pyrimidin-4-amine 944504-08-9 C23H22N4S
    N-(5-methyl-2-phenylsulfanyl-phenyl)-7-propyl-pyrido[2,3-d]pyrimidin-4-amine
    —— 7-ethyl-N-(5-methyl-2-phenylsulfanyl-phenyl)pyrido[2,3-d]pyrimidin-4-amine 944504-42-1 C22H20N4S
    7-ethyl-N-(5-methyl-2-phenylsulfanyl-phenyl)pyrido[2,3-d]pyrimidin-4-amine
    —— 7-isopropyl-N-[2-(4-methoxyphenyl)sulfanyl-5-methyl-phenyl]pyrido[2,3-d]pyrimidin-4-amine 944503-94-0 C24H24N4OS
    7-isopropyl-N-[2-(4-methoxyphenyl)sulfanyl-5-methyl-phenyl]pyrido[2,3-d]pyrimidin-4-amine