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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (4-methylphenyl)bis[2-(phenylthio)phenyl]stibine 1319746-13-8 C31H25S2Sb
    (4-methylphenyl)bis[2-(phenylthio)phenyl]stibine
    —— 2-ethylmercapto-5,6-dimethyl-3<i>H</i>-pyrimidin-4-one 101251-29-0 C8H12N2OS
    2-ethylmercapto-5,6-dimethyl-3<i>H</i>-pyrimidin-4-one
    —— Phenyl tert-butylcarbonochloridimidothioate 90496-27-8 C11H14ClNS
    Phenyl tert-butylcarbonochloridimidothioate
    —— 5-isopentyl-6-methyl-2-methylsulfanyl-3<i>H</i>-pyrimidin-4-one 100051-32-9 C11H18N2OS
    5-isopentyl-6-methyl-2-methylsulfanyl-3<i>H</i>-pyrimidin-4-one
    —— Distearoyldisulfid 3633-08-7 C36H70O2S2
    Distearoyldisulfid
    —— 2,5-dimethylthioanisole 66623-67-4 C9H12S
    2,5-dimethylthioanisole
    —— 6-Amino-3-(2-phenylethyl)-2-propylsulfanylpyrimidin-4-one 1013029-23-6 C15H19N3OS
    6-Amino-3-(2-phenylethyl)-2-propylsulfanylpyrimidin-4-one
    —— 6-Amino-3-[(3-chlorophenyl)methyl]-2-propylsulfanylpyrimidin-4-one 1013029-19-0 C14H16ClN3OS
    6-Amino-3-[(3-chlorophenyl)methyl]-2-propylsulfanylpyrimidin-4-one
    —— 6-Amino-3-methyl-2-propylsulfanylpyrimidin-4-one 1013029-14-5 C8H13N3OS
    6-Amino-3-methyl-2-propylsulfanylpyrimidin-4-one
    —— 4-benzylamino-2,6-dipropylthiopyrimidine 1314704-91-0 C17H23N3S2
    4-benzylamino-2,6-dipropylthiopyrimidine
    —— 6-Amino-3-benzyl-2-propylsulfanylpyrimidin-4-one 1013029-17-8 C14H17N3OS
    6-Amino-3-benzyl-2-propylsulfanylpyrimidin-4-one
    —— 6-Amino-3-propyl-2-propylsulfanylpyrimidin-4-one 1013029-15-6 C10H17N3OS
    6-Amino-3-propyl-2-propylsulfanylpyrimidin-4-one
    —— 6-(2-Phenylethoxy)-2-propylsulfanylpyrimidin-4-amine 1013029-35-0 C15H19N3OS
    6-(2-Phenylethoxy)-2-propylsulfanylpyrimidin-4-amine
    —— 4-cyclohexylamino-6-phenylthio-2-propylthiopyrimidine 1314704-95-4 C19H25N3S2
    4-cyclohexylamino-6-phenylthio-2-propylthiopyrimidine
    —— 6-(Cyclohexylmethoxy)-2-propylsulfanylpyrimidin-4-amine 1013029-36-1 C14H23N3OS
    6-(Cyclohexylmethoxy)-2-propylsulfanylpyrimidin-4-amine
    —— 6-Propoxy-2-propylsulfanylpyrimidin-4-amine 1013029-27-0 C10H17N3OS
    6-Propoxy-2-propylsulfanylpyrimidin-4-amine
    —— 6-Phenylmethoxy-2-propylsulfanylpyrimidin-4-amine 1013029-29-2 C14H17N3OS
    6-Phenylmethoxy-2-propylsulfanylpyrimidin-4-amine
    —— 6-Amino-3-(cyclohexylmethyl)-2-propylsulfanylpyrimidin-4-one 1013029-24-7 C14H23N3OS
    6-Amino-3-(cyclohexylmethyl)-2-propylsulfanylpyrimidin-4-one
    —— 2-Propylmercapto-4-methoxy-6-amino-pyrimidin 3289-55-2 C8H13N3OS
    2-Propylmercapto-4-methoxy-6-amino-pyrimidin
    —— 6-[(3-Chlorophenyl)methoxy]-2-propylsulfanylpyrimidin-4-amine 1013029-31-6 C14H16ClN3OS
    6-[(3-Chlorophenyl)methoxy]-2-propylsulfanylpyrimidin-4-amine
    —— S-(2-cyclopentylphenyl) N,N-dimethylcarbamothioate 1026842-71-6 C14H19NOS
    S-(2-cyclopentylphenyl) N,N-dimethylcarbamothioate
    —— Ethyl 2-methyl-3-(4-methylphenyl)sulfanylbut-3-enoate 1308656-52-1 C14H18O2S
    Ethyl 2-methyl-3-(4-methylphenyl)sulfanylbut-3-enoate
    —— 2-amino-6-methylsulfanyl-4-thiophen-3-ylpyridine-3,5-dicarbonitrile 391663-86-8 C12H8N4S2
    2-amino-6-methylsulfanyl-4-thiophen-3-ylpyridine-3,5-dicarbonitrile
    —— (2S,6R,7S,9S)-2,9-Bis(phenylthiomethyl)-1,8,13,16-tetraoxadispiro<5.0.5.4>hexadecan-14-one 244155-68-8 C26H30O5S2
    (2S,6R,7S,9S)-2,9-Bis(phenylthiomethyl)-1,8,13,16-tetraoxadispiro<5.0.5.4>hexadecan-14-one
    —— (1RS,2RS,3S)-3,4-O-isopropylidenedioxy-1-methoxy-1-phenylthio-2,3,4-butanetriol 117770-30-6 C14H20O4S
    (1RS,2RS,3S)-3,4-O-isopropylidenedioxy-1-methoxy-1-phenylthio-2,3,4-butanetriol
    —— 2-[[(4R)-2,2-Dimethyl-1,3-dioxolan-4-YL](phenylsulfanyl)methyl]-1,3-cycloheptanedione 836649-42-4 C19H24O4S
    2-[[(4R)-2,2-Dimethyl-1,3-dioxolan-4-YL](phenylsulfanyl)methyl]-1,3-cycloheptanedione
    —— phenyl thiophene-2-carbimidothioate hydrobromide 659743-43-8 BrH*C11H9NS2
    phenyl thiophene-2-carbimidothioate hydrobromide
    —— 9(R)-6,6-ethylenedithio-9-methyl-9-nonanolide 138332-44-2 C12H20O2S2
    9(R)-6,6-ethylenedithio-9-methyl-9-nonanolide
    —— 1-Acetoxy-1-(triphenylsilyloxy)-2-phenylthioethane 123541-68-4 C28H26O3SSi
    1-Acetoxy-1-(triphenylsilyloxy)-2-phenylthioethane
    —— 2-Phenylsulfanyl-1-tri(propan-2-yl)silylethanol 162247-37-2 C17H30OSSi
    2-Phenylsulfanyl-1-tri(propan-2-yl)silylethanol
    —— E-1-(tri-n-butylstannyl)-1-(phenylthio)-2-phenylethene 198219-71-5 C26H38SSn
    E-1-(tri-n-butylstannyl)-1-(phenylthio)-2-phenylethene
    —— (5S,2'R)-3-[2'-(t-butyldimethylsilanyloxy)-hex-6-enyl]-5-methyl-3-phenylsulfanyldihydrofuran-2-one 909270-36-6 C23H36O3SSi
    (5S,2'R)-3-[2'-(t-butyldimethylsilanyloxy)-hex-6-enyl]-5-methyl-3-phenylsulfanyldihydrofuran-2-one
    —— N-(2-Phenylmercapto-1,1-dimethyl-ethyl)-benzamid 1155-29-9 C17H19NOS
    N-(2-Phenylmercapto-1,1-dimethyl-ethyl)-benzamid
    —— tert-butyl 2-[4-(methylsulfanyl)benzyl]acrylate 942298-95-5 C15H20O2S
    tert-butyl 2-[4-(methylsulfanyl)benzyl]acrylate
    —— 2-tributylstannyl-1,3-benzodithiole 155127-03-0 C19H32S2Sn
    2-tributylstannyl-1,3-benzodithiole
    —— 2-(methoxycarbonylamino) 6-(p-hydroxyphenylthio) imidazo [1,2-a] pyridine 76911-42-7 C15H13N3O3S
    2-(methoxycarbonylamino) 6-(p-hydroxyphenylthio) imidazo [1,2-a] pyridine
    —— 2-[(4-trifluoromethyl-2-nitrophenyl)thio]aniline 322-71-4 C13H9F3N2O2S
    2-[(4-trifluoromethyl-2-nitrophenyl)thio]aniline
    —— 2,2-dimethyl-5-(4-(methylthio)benzyl)-1,3-dioxane-4,6-dione 154317-91-6 C14H16O4S
    2,2-dimethyl-5-(4-(methylthio)benzyl)-1,3-dioxane-4,6-dione
    —— 1-Dimethylaminomethyl-4-hydroxy-7-phenylsulfanyl-isoquinoline-3-carboxylic acid butyl ester 808120-25-4 C23H26N2O3S
    1-Dimethylaminomethyl-4-hydroxy-7-phenylsulfanyl-isoquinoline-3-carboxylic acid butyl ester
    —— 4-[4-(4-bromo-2,6-dimethylphenylsulfanyl)pyrimidin-2-ylamino]benzonitrile 374067-83-1 C19H15BrN4S
    4-[4-(4-bromo-2,6-dimethylphenylsulfanyl)pyrimidin-2-ylamino]benzonitrile
    —— 3-(2-trifluoromethylphenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide 1299398-83-6 C27H25F3NS*I
    3-(2-trifluoromethylphenylsulfanyl)-1-(5-phenylpentyl)quinolin-1-ium iodide
    —— (2S)-2-[(2S)-2-(methoxymethoxy)-4-phenylsulfanylbutyl]oxirane 197520-82-4 C14H20O3S
    (2S)-2-[(2S)-2-(methoxymethoxy)-4-phenylsulfanylbutyl]oxirane
    —— 2-phenylthio-1-phenylethylamine 140372-83-4 C14H15NS
    2-phenylthio-1-phenylethylamine
    —— Cyclobutyl-heptyl-sulfid 10394-45-3 C11H22S
    Cyclobutyl-heptyl-sulfid
    —— (E)-3-methyl-1-(methylsulfonyl)-1-butene 286376-75-8 C6H12O2S
    (E)-3-methyl-1-(methylsulfonyl)-1-butene
    —— n-3-thiadecanal 1174747-14-8 C9H18OS
    n-3-thiadecanal
    —— 4-Pyridinecarbothioamide, 2-(heptylthio)- 180791-11-1 C13H20N2S2
    4-Pyridinecarbothioamide, 2-(heptylthio)-
    —— (E)-5-(4-cyanobut-3-enyl)-2,3-dihydro-1,4-benzoxathiin 261633-80-1 C13H13NOS
    (E)-5-(4-cyanobut-3-enyl)-2,3-dihydro-1,4-benzoxathiin
    —— methylheptyl disulfide 70869-29-3 C8H18S2
    methylheptyl disulfide
    —— (5S)-3-[(2R)-2-[tert-butyl(dimethyl)silyl]oxyundec-10-enyl]-5-methyl-3-phenylsulfanyloxolan-2-one 862603-29-0 C28H46O3SSi
    (5S)-3-[(2R)-2-[tert-butyl(dimethyl)silyl]oxyundec-10-enyl]-5-methyl-3-phenylsulfanyloxolan-2-one