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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-[(2-hydroxyethoxy)methyl]-6-(phenylthio)-5-(2-(Z)-phenylvinyl)uracil 131194-26-8 C21H20N2O4S
    1-[(2-hydroxyethoxy)methyl]-6-(phenylthio)-5-(2-(Z)-phenylvinyl)uracil
    —— S-[3,6-di(propan-2-yl)pyrazin-2-yl] chloromethanethioate 107292-22-8 C11H15ClN2OS
    S-[3,6-di(propan-2-yl)pyrazin-2-yl] chloromethanethioate
    —— 1-<(2-hydroxyethoxy)methyl>-5-(methoxycarbonyl)-6-(phenylthio)uracil 137897-81-5 C15H16N2O6S
    1-<(2-hydroxyethoxy)methyl>-5-(methoxycarbonyl)-6-(phenylthio)uracil
    —— 1-[(2-hydroxyethoxy)methyl]-5-(2-phenylethynyl)-6-phenylthiouracil 125056-93-1 C21H18N2O4S
    1-[(2-hydroxyethoxy)methyl]-5-(2-phenylethynyl)-6-phenylthiouracil
    —— 1-[(2-hydroxyethoxy)methyl]-5,6-diphenylthiouracil 125057-00-3 C19H18N2O4S2
    1-[(2-hydroxyethoxy)methyl]-5,6-diphenylthiouracil
    —— 2-benzylthio-3,6-diisopropylpyrazine 120061-24-7 C17H22N2S
    2-benzylthio-3,6-diisopropylpyrazine
    —— 1-[(2-hydroxyethoxy)methyl]-5-ethynyl-6-phenylthiouracil 125056-95-3 C15H14N2O4S
    1-[(2-hydroxyethoxy)methyl]-5-ethynyl-6-phenylthiouracil
    —— 1-[(2-hydroxyethoxy)methyl]-5-isobutyroyl-6-phenylthiouracil 125057-02-5 C17H20N2O5S
    1-[(2-hydroxyethoxy)methyl]-5-isobutyroyl-6-phenylthiouracil
    —— propyl-thiocarbamic acid <i>S</i>-propyl ester 39078-46-1 C7H15NOS
    propyl-thiocarbamic acid <i>S</i>-propyl ester
    —— 2-(4-methylbenzylthio)-3,6-diisopropylpyrazine 120061-27-0 C18H24N2S
    2-(4-methylbenzylthio)-3,6-diisopropylpyrazine
    —— isobutyl S-3,6-diisopropylpyrazin-2-ylthiolcarbonate 104272-90-4 C15H24N2O2S
    isobutyl S-3,6-diisopropylpyrazin-2-ylthiolcarbonate
    —— 1-<<2-<(tert-butyldimethylsilyl)oxy>ethoxy>methyl>-6-(phenylthio)-5-<2-(trimethylsilyl)ethynyl>uracil 131194-25-7 C24H36N2O4SSi2
    1-<<2-<(tert-butyldimethylsilyl)oxy>ethoxy>methyl>-6-(phenylthio)-5-<2-(trimethylsilyl)ethynyl>uracil
    —— 1-[(2-hydroxyethoxy)methyl]-6-phenylthiocytosine 125057-04-7 C13H15N3O3S
    1-[(2-hydroxyethoxy)methyl]-6-phenylthiocytosine
    —— 2-Methylmercapto-6-methyl-pyrimidin-aldehyd-4 1075-58-7 C7H8N2OS
    2-Methylmercapto-6-methyl-pyrimidin-aldehyd-4
    —— 3-Cyclohexyl-6-methylsulfanyl-1,2,4,5-tetrazine 159801-90-8 C9H14N4S
    3-Cyclohexyl-6-methylsulfanyl-1,2,4,5-tetrazine
    —— Pyrrolo<2,1-e>sym-triazolo<1,2-a><3,1,6>benzothiadiazocine 112798-03-5 C13H10N4S
    Pyrrolo<2,1-e>sym-triazolo<1,2-a><3,1,6>benzothiadiazocine
    —— 3-(4-chloro-phenylsulfanyl)-azetidine 1340259-48-4 C9H10ClNS
    3-(4-chloro-phenylsulfanyl)-azetidine
    —— 3-[(4-chlorophenyl)thio]-1-azetidinecarbonyl chloride 132924-61-9 C10H9Cl2NOS
    3-[(4-chlorophenyl)thio]-1-azetidinecarbonyl chloride
    —— 5,6-Dihydro-6-thioxopyrrolo<1,2-a><3,1,6>benzothiadiazocine 112798-08-0 C12H10N2S2
    5,6-Dihydro-6-thioxopyrrolo<1,2-a><3,1,6>benzothiadiazocine
    —— 3-[(4-{[(3S)-1-methylpyrrolidin-3-yl]methoxy}phenyl)thio]-N-(3-methyl-1,2,4-thiadiazol-5-yl)-6-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]pyridine-2-carboxamide 1018966-17-0 C24H26N8O2S3
    3-[(4-{[(3S)-1-methylpyrrolidin-3-yl]methoxy}phenyl)thio]-N-(3-methyl-1,2,4-thiadiazol-5-yl)-6-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]pyridine-2-carboxamide
    —— 4-{[(2-pyrazinyl)methyl]sulfanyl}aniline 497853-54-0 C11H11N3S
    4-{[(2-pyrazinyl)methyl]sulfanyl}aniline
    —— Diethyl N-<4-(2-Methylthio)thiazolyl>aminomethylenemalonate 94507-75-2 C12H16N2O4S2
    Diethyl N-<4-(2-Methylthio)thiazolyl>aminomethylenemalonate
    —— 2-(4-fluorophenylthio)tetrahydropyran 146328-81-6 C11H13FOS
    2-(4-fluorophenylthio)tetrahydropyran
    —— Methylthioharnstoff —— C2H6N2S*H
    Methylthioharnstoff
    —— <4-Nitro-phenyl>-<m-tolyl>-sulfid 76590-34-6 C13H11NO2S
    <4-Nitro-phenyl>-<m-tolyl>-sulfid
    —— bis(4-methylphenyl) N,N'-dihydroxypentanediimidothioate 1390628-49-5 C19H22N2O2S2
    bis(4-methylphenyl) N,N'-dihydroxypentanediimidothioate
    —— tert-butyl 2,4-bis(methylthio)imidazo[1,2-f][1,2,4]triazin-7-ylcarbamate 1062135-89-0 C12H17N5O2S2
    tert-butyl 2,4-bis(methylthio)imidazo[1,2-f][1,2,4]triazin-7-ylcarbamate
    —— (6R,7R)-7-<(1R)-1-hydroxy-2(phenylthio)ethyl>-2,2-dimethyl-8-oxo-3-oxa-1-azabicyclo<4.2.0>octane 116050-82-9 C16H21NO3S
    (6R,7R)-7-<(1R)-1-hydroxy-2(phenylthio)ethyl>-2,2-dimethyl-8-oxo-3-oxa-1-azabicyclo<4.2.0>octane
    —— (2-cyclopentylsulfanylpyridin-3-yl)methanol 1609289-06-6 C11H15NOS
    (2-cyclopentylsulfanylpyridin-3-yl)methanol
    —— 3-(2-(4-((tert-butyldiphenylsilyl)oxy)butyl)-1,3-dithian-2-yl)propan-1-ol 182008-78-2 C27H40O2S2Si
    3-(2-(4-((tert-butyldiphenylsilyl)oxy)butyl)-1,3-dithian-2-yl)propan-1-ol
    —— 3-[2-(4-oxo-pent-2-enyl)-1,3-dithian-2-yl]-propionaldehyde 871469-01-1 C12H18O2S2
    3-[2-(4-oxo-pent-2-enyl)-1,3-dithian-2-yl]-propionaldehyde
    —— tert-Butyl-[4-(2-but-3-ynyl-[1,3]dithian-2-yl)-butoxy]-diphenyl-silane 208400-08-2 C28H38OS2Si
    tert-Butyl-[4-(2-but-3-ynyl-[1,3]dithian-2-yl)-butoxy]-diphenyl-silane
    —— (2R)-1-[tert-butyl(dimethyl)silyl]oxy-3-[2-(2,2-dimethoxyethyl)-1,3-dithian-2-yl]propan-2-ol 159486-47-2 C17H36O4S2Si
    (2R)-1-[tert-butyl(dimethyl)silyl]oxy-3-[2-(2,2-dimethoxyethyl)-1,3-dithian-2-yl]propan-2-ol
    —— (E)-methyl 2-(4-t-butyldimethylsilyloxy-1-<2-(1,3-dioxan-2-ylmethyl)-1,3-dithian-2-yl>-3-methylpenta-2,4-dienyloxymetyl)prop-2-enoate 121362-87-6 C26H44O6S2Si
    (E)-methyl 2-(4-t-butyldimethylsilyloxy-1-<2-(1,3-dioxan-2-ylmethyl)-1,3-dithian-2-yl>-3-methylpenta-2,4-dienyloxymetyl)prop-2-enoate
    —— (E)-1-<2'-(2'',2''-Dimethoxyethyl)-1',3'-dithian-2'-yl>-4,4-(ethylenedioxy)pent-2-en-1-ol 145746-16-3 C15H26O5S2
    (E)-1-<2'-(2'',2''-Dimethoxyethyl)-1',3'-dithian-2'-yl>-4,4-(ethylenedioxy)pent-2-en-1-ol
    —— (8R)-8-(hydroxymethyl)-9-oxa-1,5-dithiaspiro[5.5]undecan-10-ol 135304-61-9 C9H16O3S2
    (8R)-8-(hydroxymethyl)-9-oxa-1,5-dithiaspiro[5.5]undecan-10-ol
    —— 4-(o-tolylthio)aniline 76590-35-7 C13H13NS
    4-(o-tolylthio)aniline
    —— (E)-Methyl 2-<1'-<2''-(2''',2'''-Dimethoxyethyl)-1'',3''-dithian-2''-yl>-4',4'-(ethylenedioxy)pent-2'-enyloxymethyl>propenoate 145746-17-4 C20H32O7S2
    (E)-Methyl 2-<1'-<2''-(2''',2'''-Dimethoxyethyl)-1'',3''-dithian-2''-yl>-4',4'-(ethylenedioxy)pent-2'-enyloxymethyl>propenoate
    —— 3-(2-(2-(cyclopenta-2,4-dienylidene)ethyl)-1,3-dithian-2-yl)propanal 1351600-40-2 C14H18OS2
    3-(2-(2-(cyclopenta-2,4-dienylidene)ethyl)-1,3-dithian-2-yl)propanal
    —— p'-Brom-p-acetylamino-diphenylsulfid 79995-57-6 C14H12BrNOS
    p'-Brom-p-acetylamino-diphenylsulfid
    —— (E)-Methyl 2-<4'-(tert-Butyldimethylsiloxy)-1'-<2''-(1,3-dioxan-2-ylmethyl)-1'',3''-dithian-2''-yl>penta-2',4'-dienyloxymethyl>propenoate 145746-11-8 C25H42O6S2Si
    (E)-Methyl 2-<4'-(tert-Butyldimethylsiloxy)-1'-<2''-(1,3-dioxan-2-ylmethyl)-1'',3''-dithian-2''-yl>penta-2',4'-dienyloxymethyl>propenoate
    —— (E)-methyl 2-(1-<2-(1,3-dioxan-2-ylmethyl)-1,3-dithian-2-yl>-3-methyl-4-oxopent-2-enyloxymethyl)prop-2-enoate 121362-98-9 C20H30O6S2
    (E)-methyl 2-(1-<2-(1,3-dioxan-2-ylmethyl)-1,3-dithian-2-yl>-3-methyl-4-oxopent-2-enyloxymethyl)prop-2-enoate
    —— (E)-Methyl 2-<1-<2''-(1,3-Dioxan-2-ylmethyl)-1'',3''-dithian-2''-yl>-4'-oxopent-2'-enyloxymethyl>propenoate 145746-19-6 C19H28O6S2
    (E)-Methyl 2-<1-<2''-(1,3-Dioxan-2-ylmethyl)-1'',3''-dithian-2''-yl>-4'-oxopent-2'-enyloxymethyl>propenoate
    —— [5-(3,5-Dichlorophenylthio)-4-isopropyl-1-methyl-1H-imidazol-2-yl]acetic Acid 178979-71-0 C15H16Cl2N2O2S
    [5-(3,5-Dichlorophenylthio)-4-isopropyl-1-methyl-1H-imidazol-2-yl]acetic Acid
    —— 1-Benzyl-3,3-bis(methylsulfanyl)pyrrolidin-2-one 261967-37-7 C13H17NOS2
    1-Benzyl-3,3-bis(methylsulfanyl)pyrrolidin-2-one
    —— 1-bromo-5-chloro-2-isocyanato-4-methylsulfanyl-benzene 1232688-58-2 C8H5BrClNOS
    1-bromo-5-chloro-2-isocyanato-4-methylsulfanyl-benzene
    —— 5-allyloxy-4-phenylthio-1,3-benzodioxole 316800-25-6 C16H14O3S
    5-allyloxy-4-phenylthio-1,3-benzodioxole
    —— 5-hydroxy-4-phenylthio-6-(2-propenyl)-1,3-benzodioxole 316800-31-4 C16H14O3S
    5-hydroxy-4-phenylthio-6-(2-propenyl)-1,3-benzodioxole
    —— bromomethyl ethyl sulfide 36056-14-1 C3H7BrS
    bromomethyl ethyl sulfide
    —— 4-phenylthio-5-methoxymethoxy-1,3-benzodioxole 316800-28-9 C15H14O4S
    4-phenylthio-5-methoxymethoxy-1,3-benzodioxole