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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Ethyl (3Z)-3-ethoxy-3-{[2-(methylsulfanyl)phenyl]imino}propanoate 861397-42-4 C14H19NO3S
    Ethyl (3Z)-3-ethoxy-3-{[2-(methylsulfanyl)phenyl]imino}propanoate
    —— (3-dimethylcarbamoyl-sulfanyl-4-fluorophenyl)-acetic acid methyl ester 915789-08-1 C12H14FNO3S
    (3-dimethylcarbamoyl-sulfanyl-4-fluorophenyl)-acetic acid methyl ester
    —— ethyl (6-methanesulfanylpyridin-3-yl)glyoxylate 745816-49-3 C10H11NO3S
    ethyl (6-methanesulfanylpyridin-3-yl)glyoxylate
    —— 4,4,5,5-Tetramethyl-2-[4-(phenylsulfanylmethyl)phenyl]-1,3,2-dioxaborolane 1029438-27-4 C19H23BO2S
    4,4,5,5-Tetramethyl-2-[4-(phenylsulfanylmethyl)phenyl]-1,3,2-dioxaborolane
    —— 2-Ethoxyethymethylensulfon 28525-27-1 C5H12O3S
    2-Ethoxyethymethylensulfon
    —— 4H-1,2,4-Triazole-3-methanamine, 4-cyclopropyl-5-[(2-methylbutyl)thio]- 1344359-13-2 C11H20N4S
    4H-1,2,4-Triazole-3-methanamine, 4-cyclopropyl-5-[(2-methylbutyl)thio]-
    —— tert-butyl (2S,4S)-4-[[3-[[(3S,5S)-1-[(2-methylpropan-2-yl)oxycarbonyl]-5-[(5-phenylsulfanyltetrazol-1-yl)methyl]pyrrolidin-3-yl]carbamoyl]benzoyl]amino]-2-[(5-phenylsulfanyltetrazol-1-yl)methyl]pyrrolidine-1-carboxylate 1072146-99-6 C42H50N12O6S2
    tert-butyl (2S,4S)-4-[[3-[[(3S,5S)-1-[(2-methylpropan-2-yl)oxycarbonyl]-5-[(5-phenylsulfanyltetrazol-1-yl)methyl]pyrrolidin-3-yl]carbamoyl]benzoyl]amino]-2-[(5-phenylsulfanyltetrazol-1-yl)methyl]pyrrolidine-1-carboxylate
    —— 8-fluoro-3,4-dihydro-2H-1,5-benzoxathiepine 915771-65-2 C9H9FOS
    8-fluoro-3,4-dihydro-2H-1,5-benzoxathiepine
    —— 1H-Pyrazol-3-amine, 1-[2-(2-pyrimidinylthio)ethyl]- 1340433-80-8 C9H11N5S
    1H-Pyrazol-3-amine, 1-[2-(2-pyrimidinylthio)ethyl]-
    —— 2-n-Amylthio-4,5,6-triaminopyrimidin 70805-46-8 C9H17N5S
    2-n-Amylthio-4,5,6-triaminopyrimidin
    —— tert-butyl methyl{[4-phenyl-5-(phenylthio)-1,3-thiazol-2-yl]methyl}carbamate 952191-77-4 C22H24N2O2S2
    tert-butyl methyl{[4-phenyl-5-(phenylthio)-1,3-thiazol-2-yl]methyl}carbamate
    —— 2-n-Amylthio-5-nitroso-4,6-diaminopyrimidin 70805-45-7 C9H15N5OS
    2-n-Amylthio-5-nitroso-4,6-diaminopyrimidin
    —— 1-[4-phenyl-5-(phenylthio)-1,3-thiazol-2-yl]methanamine 952191-75-2 C16H14N2S2
    1-[4-phenyl-5-(phenylthio)-1,3-thiazol-2-yl]methanamine
    —— tert-butyl {[4-phenyl-5-(phenylthio)-1,3-thiazol-2-yl]methyl}carbamate 952191-76-3 C21H22N2O2S2
    tert-butyl {[4-phenyl-5-(phenylthio)-1,3-thiazol-2-yl]methyl}carbamate
    —— 3,4-bis(decylsulfanyl)thiophene 913964-73-5 C24H44S3
    3,4-bis(decylsulfanyl)thiophene
    —— 2-(3-Chlorophenyl)sulfanyl-1-(2,5-dichlorothiophen-3-yl)ethanone 1405282-29-2 C12H7Cl3OS2
    2-(3-Chlorophenyl)sulfanyl-1-(2,5-dichlorothiophen-3-yl)ethanone
    —— 2,4-dichloro-N-{4-formyl-5-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-pyridin-2-yl}-benzenesulfonamide 882500-09-6 C23H21Cl2N3O5S3
    2,4-dichloro-N-{4-formyl-5-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-pyridin-2-yl}-benzenesulfonamide
    —— Benzenemethanamine, 3-bromo-I+/--methyl-4-[(1-methylethyl)thio]-, (I+/-R)- 1344948-05-5 C11H16BrNS
    Benzenemethanamine, 3-bromo-I+/--methyl-4-[(1-methylethyl)thio]-, (I+/-R)-
    —— 2-amino-5-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-isonicotinic acid pentyl ester 882500-06-3 C22H29N3O4S2
    2-amino-5-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-isonicotinic acid pentyl ester
    —— Benzenamine, 2-chloro-5-[(2-pyrazinylthio)methyl]- 1342772-42-2 C11H10ClN3S
    Benzenamine, 2-chloro-5-[(2-pyrazinylthio)methyl]-
    —— Pyrazine, 2-[(2-azidoethyl)thio]- 1343894-51-8 C6H7N5S
    Pyrazine, 2-[(2-azidoethyl)thio]-
    —— Pentanoic acid, 5-(2-pyrazinylthio)- 1344114-54-0 C9H12N2O2S
    Pentanoic acid, 5-(2-pyrazinylthio)-
    —— 3-(Propyldisulfanyl)propanoic acid 112401-23-7 C6H12O2S2
    3-(Propyldisulfanyl)propanoic acid
    —— 2,4-Dichloro-N-{4-hydroxy-5-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-pyrimidin-2-yl}-benzenesulfonamide 882496-56-2 C21H20Cl2N4O5S3
    2,4-Dichloro-N-{4-hydroxy-5-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-pyrimidin-2-yl}-benzenesulfonamide
    —— 2,4-dichloro-N-{4-(cyclopropyl-hydroxy-methyl)-5-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-pyridin-2-yl}-benzenesulfonamide 882500-10-9 C26H27Cl2N3O5S3
    2,4-dichloro-N-{4-(cyclopropyl-hydroxy-methyl)-5-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-pyridin-2-yl}-benzenesulfonamide
    —— 3-phenylsulfanyl-thioxanthen-9-one 875664-53-2 C19H12OS2
    3-phenylsulfanyl-thioxanthen-9-one
    —— 1-(2,5-Dichlorothiophen-3-yl)-2-(2-methylphenyl)sulfanylethanone 1282935-04-9 C13H10Cl2OS2
    1-(2,5-Dichlorothiophen-3-yl)-2-(2-methylphenyl)sulfanylethanone
    —— [3-(3-chloro-4-methanesulfonyl-phenylsulfanyl)-6-fluoro-2-methylindolizin-1-yl]acetic acid 917761-32-1 C18H15ClFNO4S2
    [3-(3-chloro-4-methanesulfonyl-phenylsulfanyl)-6-fluoro-2-methylindolizin-1-yl]acetic acid
    —— [7-chloro-3-(2-chloro-4-methanesulfonylphenylsulfanyl)-6-fluoro-2-methylindolizin-1-yl]acetic acid 917761-28-5 C18H14Cl2FNO4S2
    [7-chloro-3-(2-chloro-4-methanesulfonylphenylsulfanyl)-6-fluoro-2-methylindolizin-1-yl]acetic acid
    —— N-allyloxy-5-benzylthio-1-methylpyrazole-4-carboxylic acid amide 868681-38-3 C15H17N3O2S
    N-allyloxy-5-benzylthio-1-methylpyrazole-4-carboxylic acid amide
    —— [7-chloro-3-(4-methanesulfonylphenylsulfanyl)-2-methylindolizin-1-yl]acetic acid 917760-84-0 C18H16ClNO4S2
    [7-chloro-3-(4-methanesulfonylphenylsulfanyl)-2-methylindolizin-1-yl]acetic acid
    —— [6-cyano-3-(4-methanesulfonylphenylsulfanyl)-2-methylindolizin-1-yl]acetic acid 917761-03-6 C19H16N2O4S2
    [6-cyano-3-(4-methanesulfonylphenylsulfanyl)-2-methylindolizin-1-yl]acetic acid
    —— [7-chloro-3-(4-methanesulfonylphenylsulfanyl)-2-methyl-6-trifluoromethylindolizin-1-yl]acetic acid 917761-09-2 C19H15ClF3NO4S2
    [7-chloro-3-(4-methanesulfonylphenylsulfanyl)-2-methyl-6-trifluoromethylindolizin-1-yl]acetic acid
    —— [3-(4-methanesulfonylphenylsulfanyl)-2-methyl-6-trifluoromethylindolizin-1-yl]acetic acid 917761-08-1 C19H16F3NO4S2
    [3-(4-methanesulfonylphenylsulfanyl)-2-methyl-6-trifluoromethylindolizin-1-yl]acetic acid
    —— [3-(4-methanesulfonylphenylsulfanyl)-2-methyl-7-trifluoromethylindolizin-1-yl]acetic acid 917761-01-4 C19H16F3NO4S2
    [3-(4-methanesulfonylphenylsulfanyl)-2-methyl-7-trifluoromethylindolizin-1-yl]acetic acid
    —— [7-cyano-3-(4-methanesulfonylphenylsulfanyl)-2-methylindolizin-1-yl]acetic acid 917761-14-9 C19H16N2O4S2
    [7-cyano-3-(4-methanesulfonylphenylsulfanyl)-2-methylindolizin-1-yl]acetic acid
    —— [3-(2-chloro-4-methanesulfonylphenylsulfanyl)-6-fluoro-2-methylindolizin-1-yl]acetic acid 917761-27-4 C18H15ClFNO4S2
    [3-(2-chloro-4-methanesulfonylphenylsulfanyl)-6-fluoro-2-methylindolizin-1-yl]acetic acid
    —— 5-benzylthio-1-methyl-4-(5-methyl-5H,6H-1,4,2-dioxazin-3-yl)pyrazole 868681-40-7 C15H17N3O2S
    5-benzylthio-1-methyl-4-(5-methyl-5H,6H-1,4,2-dioxazin-3-yl)pyrazole
    —— [3-(4-methanesulfonylphenylsulfanyl)-2-methylindolizin-1-yl]acetic acid 917760-65-7 C18H17NO4S2
    [3-(4-methanesulfonylphenylsulfanyl)-2-methylindolizin-1-yl]acetic acid
    —— [6-carbamoyl-3-(4-methanesulfonylphenylsulfanyl)-2-methylindolizin-1-yl]acetic acid 917761-04-7 C19H18N2O5S2
    [6-carbamoyl-3-(4-methanesulfonylphenylsulfanyl)-2-methylindolizin-1-yl]acetic acid
    —— [3-(4-ethanesulfonylaminophenylsulfanyl)-6-fluoro-2-methylindolizin-1-yl]acetic acid 917761-36-5 C19H19FN2O4S2
    [3-(4-ethanesulfonylaminophenylsulfanyl)-6-fluoro-2-methylindolizin-1-yl]acetic acid
    —— [6-fluoro-2-methyl-3-(4-methylsulfamoylphenylsulfanyl)indolizin-1-yl]acetic acid 917761-24-1 C18H17FN2O4S2
    [6-fluoro-2-methyl-3-(4-methylsulfamoylphenylsulfanyl)indolizin-1-yl]acetic acid
    —— {6-fluoro-2-methyl-3-[4-(morpholine-4-sulfonyl)phenylsulfanyl]indolizin-1-yl}acetic acid 917761-18-3 C21H21FN2O5S2
    {6-fluoro-2-methyl-3-[4-(morpholine-4-sulfonyl)phenylsulfanyl]indolizin-1-yl}acetic acid
    —— {5-chloro-6-fluoro-2-methyl-3-[4-(morpholine-4-sulfonyl)phenylsulfanyl]indolizin-1-yl}acetic acid 917761-19-4 C21H20ClFN2O5S2
    {5-chloro-6-fluoro-2-methyl-3-[4-(morpholine-4-sulfonyl)phenylsulfanyl]indolizin-1-yl}acetic acid
    —— 5-benzylthio-1,3-dimethyl-4-(6-methyl-5H,6H-1,4,2-dioxazin-3-yl)pyrazole 868681-23-6 C16H19N3O2S
    5-benzylthio-1,3-dimethyl-4-(6-methyl-5H,6H-1,4,2-dioxazin-3-yl)pyrazole
    —— 2,4,6-Tris{[3,4-bis(hexadecyloxy)phenyl]sulfanyl}-1,3,5-triazine 922712-85-4 C117H207N3O6S3
    2,4,6-Tris{[3,4-bis(hexadecyloxy)phenyl]sulfanyl}-1,3,5-triazine
    —— N-t-butoxycarbonyl-3-(3-methylthiophenyl)-2-oxopropylamine 955036-76-7 C15H21NO3S
    N-t-butoxycarbonyl-3-(3-methylthiophenyl)-2-oxopropylamine
    —— 3-Fluoro-4-(methylthio)-pyridine 902518-41-6 C6H6FNS
    3-Fluoro-4-(methylthio)-pyridine
    —— N-[2-[(3-chloro-2-fluorobenzyl)thio]-6-[(2-hydroxy-1-methylethyl)amino]-4-pyrimidinyl]-4-morpholinesulfonamide 654073-22-0 C18H23ClFN5O4S2
    N-[2-[(3-chloro-2-fluorobenzyl)thio]-6-[(2-hydroxy-1-methylethyl)amino]-4-pyrimidinyl]-4-morpholinesulfonamide
    —— 4-(2-chloropyridin-4-yl)-6-methyl-2-(methylthio)pyrimidine 861418-62-4 C11H10ClN3S
    4-(2-chloropyridin-4-yl)-6-methyl-2-(methylthio)pyrimidine