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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-N,N-di-n-propylamino-6-methyl-2-methylthiopyrimidine 111697-14-4 C12H21N3S
    4-N,N-di-n-propylamino-6-methyl-2-methylthiopyrimidine
    —— 1-(5-amino-2-chloro-4-fluoro-phenylthio)-cyclopropanecarboxylic acid 140909-31-5 C10H9ClFNO2S
    1-(5-amino-2-chloro-4-fluoro-phenylthio)-cyclopropanecarboxylic acid
    —— 3-(6-methyl-2-methylsulfanyl-pyrimidin-4-yl)-bicyclo[3.2.1]octane-2.4-dione 1111805-45-8 C14H16N2O2S
    3-(6-methyl-2-methylsulfanyl-pyrimidin-4-yl)-bicyclo[3.2.1]octane-2.4-dione
    —— 2-Methylmercapto-4-ethoxy-6-methyl-pyrimidin 7749-53-3 C8H12N2OS
    2-Methylmercapto-4-ethoxy-6-methyl-pyrimidin
    —— 4-benzylamino-6-methyl-2-methylthiopyrimidine 109389-09-5 C13H15N3S
    4-benzylamino-6-methyl-2-methylthiopyrimidine
    —— 2-(Methylthio)-6-methyl-pyrimidin-thiol-(4) 6310-04-9 C6H8N2S2
    2-(Methylthio)-6-methyl-pyrimidin-thiol-(4)
    —— N-isopropyl-6-methyl-2-(methylthio)pyrimidin-4-amine 874791-36-3 C9H15N3S
    N-isopropyl-6-methyl-2-(methylthio)pyrimidin-4-amine
    —— 4-(1-Bromo-2,2-diethoxyethyl)-6-methyl-2-methylsulfanylpyrimidine 874476-61-6 C12H19BrN2O2S
    4-(1-Bromo-2,2-diethoxyethyl)-6-methyl-2-methylsulfanylpyrimidine
    —— 4-N,N-di-n-butylamino-6-methyl-2-methylthiopyrimidine 111697-15-5 C14H25N3S
    4-N,N-di-n-butylamino-6-methyl-2-methylthiopyrimidine
    —— 4-methyl-2-methylthio-6-(2,2,2-trifluoroethylamino)pyrimidine 951153-47-2 C8H10F3N3S
    4-methyl-2-methylthio-6-(2,2,2-trifluoroethylamino)pyrimidine
    —— 4-cycloheptylamino-6-methyl-2-methylsulfanyl-pyrimidin-5-carbaldehyde 869219-81-8 C14H21N3OS
    4-cycloheptylamino-6-methyl-2-methylsulfanyl-pyrimidin-5-carbaldehyde
    —— 4-(1-(5-Bromo-2-(phenylthio)phenyl)ethyl)-1-methylpiperazine bismaleate 112446-64-7 C27H31BrN2O8S
    4-(1-(5-Bromo-2-(phenylthio)phenyl)ethyl)-1-methylpiperazine bismaleate
    —— Piperazine, 4-(1-(5-chloro-2-((3,4-dichlorophenyl)thio)phenyl)ethyl)-1-methyl-, (Z)-2-butenedioate, hydrate (1:2:1) 112446-51-2 C27H29Cl3N2O8S
    Piperazine, 4-(1-(5-chloro-2-((3,4-dichlorophenyl)thio)phenyl)ethyl)-1-methyl-, (Z)-2-butenedioate, hydrate (1:2:1)
    —— 5-(methylthio)thiophene-2-carboximidamide hydrochloride 1621363-56-1 C6H8N2S2*ClH
    5-(methylthio)thiophene-2-carboximidamide hydrochloride
    —— 2-Amino-4-phenylmercapto-6-methyl-pyrimidin 91347-37-4 C11H11N3S
    2-Amino-4-phenylmercapto-6-methyl-pyrimidin
    —— Piperazine, 1-(1-(5-chloro-2-((3,4-dichlorophenyl)thio)phenyl)ethyl)-4-(2-methoxyethyl)-, (Z)-2-butenedioate (1:2) 112446-56-7 C29H33Cl3N2O9S
    Piperazine, 1-(1-(5-chloro-2-((3,4-dichlorophenyl)thio)phenyl)ethyl)-4-(2-methoxyethyl)-, (Z)-2-butenedioate (1:2)
    —— N,2-bis(1-adamantyl)-2-oxoethanethioamide 1187551-52-5 C22H31NOS
    N,2-bis(1-adamantyl)-2-oxoethanethioamide
    —— N-(1-adamantyl)-3,3-dimethyl-2-oxobutanethioamide 1187551-51-4 C16H25NOS
    N-(1-adamantyl)-3,3-dimethyl-2-oxobutanethioamide
    —— (2-(Phenylthio)phenyl)acetamidine maleate 117596-36-8 C18H18N2O4S
    (2-(Phenylthio)phenyl)acetamidine maleate
    —— 4-(1-(5-Chloro-2-((2,5-dichlorophenyl)thio)phenyl)ethyl)-1-piperazineethanol bismaleate 112446-55-6 C28H31Cl3N2O9S
    4-(1-(5-Chloro-2-((2,5-dichlorophenyl)thio)phenyl)ethyl)-1-piperazineethanol bismaleate
    —— 1-Piperazineethanol, 4-(1-imino-2-(2-(phenylthio)phenyl)ethyl)-, (Z)-2-butenedioate (salt), hydrate (1:2:1) 117596-45-9 C28H33N3O9S
    1-Piperazineethanol, 4-(1-imino-2-(2-(phenylthio)phenyl)ethyl)-, (Z)-2-butenedioate (salt), hydrate (1:2:1)
    —— 2-(4-chlorophenyl)sulfanyl-N-methoxy-N-methylpyridine-3-carboxamide 639514-77-5 C14H13ClN2O2S
    2-(4-chlorophenyl)sulfanyl-N-methoxy-N-methylpyridine-3-carboxamide
    —— N-(2-amino-6-methyl-4-pyrimidinyl)-N-[3-fluoro-4-(4-pyridinylsulfanyl)phenyl]amine 570415-01-9 C16H14FN5S
    N-(2-amino-6-methyl-4-pyrimidinyl)-N-[3-fluoro-4-(4-pyridinylsulfanyl)phenyl]amine
    —— 4-(1-(5-Chloro-2-((2,5-dichlorophenyl)thio)phenyl)ethyl)-1-methylpiperazine bismaleate 112462-69-8 C27H29Cl3N2O8S
    4-(1-(5-Chloro-2-((2,5-dichlorophenyl)thio)phenyl)ethyl)-1-methylpiperazine bismaleate
    —— 4-(1-(5-Chloro-2-((2-chlorophenyl)thio)phenyl)ethyl)-1-piperazineethanol bismaleate 112446-53-4 C28H32Cl2N2O9S
    4-(1-(5-Chloro-2-((2-chlorophenyl)thio)phenyl)ethyl)-1-piperazineethanol bismaleate
    —— 3-fluoro-4-(4-pyridinylsulfanyl)aniline 569658-00-0 C11H9FN2S
    3-fluoro-4-(4-pyridinylsulfanyl)aniline
    —— 3,3-Dimethyl-6-(phenylthio)-4-hexenenitrile 143706-96-1 C14H17NS
    3,3-Dimethyl-6-(phenylthio)-4-hexenenitrile
    —— 3-Methylpent-2-cis-enylphenylsulfid 37905-01-4 C12H16S
    3-Methylpent-2-cis-enylphenylsulfid
    —— ethyl (1S,2S,3S,4R,5S)-3,4-bis[[tert-butyl(dimethyl)silyl]oxy]-2-(2-ethoxy-2-oxoethyl)-5-phenylsulfanylcyclopentane-1-carboxylate 121542-25-4 C30H52O6SSi2
    ethyl (1S,2S,3S,4R,5S)-3,4-bis[[tert-butyl(dimethyl)silyl]oxy]-2-(2-ethoxy-2-oxoethyl)-5-phenylsulfanylcyclopentane-1-carboxylate
    —— 2-methyl-4-(phenylthio)aniline 71300-13-5 C13H13NS
    2-methyl-4-(phenylthio)aniline
    —— S-phenyl N,N-dimethylselenothiocarbamate 118329-95-6 C9H11NSSe
    S-phenyl N,N-dimethylselenothiocarbamate
    —— 2-[(6aR,8R,9S,9aR)-8-(2,4-dioxopyrimidin-1-yl)-9-phenylsulfanyl-2,2,4,4-tetra(propan-2-yl)-6,6a,8,9a-tetrahydrofuro[3,2-f][1,3,5,2,4]trioxadisilocin-9-yl]acetonitrile 161258-60-2 C29H43N3O6SSi2
    2-[(6aR,8R,9S,9aR)-8-(2,4-dioxopyrimidin-1-yl)-9-phenylsulfanyl-2,2,4,4-tetra(propan-2-yl)-6,6a,8,9a-tetrahydrofuro[3,2-f][1,3,5,2,4]trioxadisilocin-9-yl]acetonitrile
    —— 3-Phenylsulfanylpent-4-enoic acid 80959-55-3 C11H12O2S
    3-Phenylsulfanylpent-4-enoic acid
    —— 2-nitro-5-phenylthiotoluene 60326-45-6 C13H11NO2S
    2-nitro-5-phenylthiotoluene
    —— 2-[(6aR,8R,9R,9aR)-8-(2,4-dioxopyrimidin-1-yl)-9-phenylsulfanyl-2,2,4,4-tetra(propan-2-yl)-6,6a,8,9a-tetrahydrofuro[3,2-f][1,3,5,2,4]trioxadisilocin-9-yl]acetonitrile 161258-57-7 C29H43N3O6SSi2
    2-[(6aR,8R,9R,9aR)-8-(2,4-dioxopyrimidin-1-yl)-9-phenylsulfanyl-2,2,4,4-tetra(propan-2-yl)-6,6a,8,9a-tetrahydrofuro[3,2-f][1,3,5,2,4]trioxadisilocin-9-yl]acetonitrile
    —— (1-methoxydodecyl)phenyl sulfide 1236031-79-0 C19H32OS
    (1-methoxydodecyl)phenyl sulfide
    —— 2-t-butylsulfonyl-3-thiophenyl-1 propene 97146-77-5 C13H18O2S2
    2-t-butylsulfonyl-3-thiophenyl-1 propene
    —— 4-phenylsulfanylcinnoline 766548-11-2 C14H10N2S
    4-phenylsulfanylcinnoline
    —— 1,1,2,2-tetrakis-(trifluoromethylsulfonyl)-ethane 129136-28-3 C6H2F12O8S4
    1,1,2,2-tetrakis-(trifluoromethylsulfonyl)-ethane
    —— 1,1-bis((trifluoromethyl)sulfonyl)hept-1-ene 1428869-57-1 C9H12F6O4S2
    1,1-bis((trifluoromethyl)sulfonyl)hept-1-ene
    —— 4,4-Bis(trifluormethylsulfonyl)buten-1 30354-36-0 C6H6F6O4S2
    4,4-Bis(trifluormethylsulfonyl)buten-1
    —— (E)-1,1-bis((trifluoromethyl)sulfonyl)hept-2-ene 1428869-59-3 C9H12F6O4S2
    (E)-1,1-bis((trifluoromethyl)sulfonyl)hept-2-ene
    —— BTSB-NB-OH 1370002-15-5 C14H18F6O6S2
    BTSB-NB-OH
    —— phenyl(1-m-tolylbut-3-enyl)sulfane 1382802-16-5 C17H18S
    phenyl(1-m-tolylbut-3-enyl)sulfane
    —— 5-methyl-6-(methylthio)-1,2,4-triazine 118459-16-8 C5H7N3S
    5-methyl-6-(methylthio)-1,2,4-triazine
    —— (E)-But-2-en-2-yl methyl sulfone 116088-89-2 C5H10O2S
    (E)-But-2-en-2-yl methyl sulfone
    —— Methyl 3-(6-chloropyrido[3,2-d]pyrimidin-4-yl)sulfanyl-4-methylbenzoate 1240349-49-8 C16H12ClN3O2S
    Methyl 3-(6-chloropyrido[3,2-d]pyrimidin-4-yl)sulfanyl-4-methylbenzoate
    —— 2,4-Dioxa-8,15-dithiadispiro(5.2.5.2)hexadecane 183-77-7 C12H20O2S2
    2,4-Dioxa-8,15-dithiadispiro(5.2.5.2)hexadecane
    —— 2-(2-Aminopropyl)-1-methyl-2-thiopseudourea 3810-32-0 C5H13N3S
    2-(2-Aminopropyl)-1-methyl-2-thiopseudourea
    —— 3-((4-bromophenylthio)methyl)-3-methyloxetane 1204129-89-4 C11H13BrOS
    3-((4-bromophenylthio)methyl)-3-methyloxetane