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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-chloro-4-(3-methoxyphenylsulphanyl)pyrimidine 213747-63-8 C11H9ClN2OS
    2-chloro-4-(3-methoxyphenylsulphanyl)pyrimidine
    —— (1-cyclopropylvinylsulfanyl)-benzene 1187885-13-7 C11H12S
    (1-cyclopropylvinylsulfanyl)-benzene
    —— 2,2-Bis(methylsulfanyl)ethan-1-amine 57270-51-6 C4H11NS2
    2,2-Bis(methylsulfanyl)ethan-1-amine
    —— (4-methylphenyl) (1E)-N-hydroxy-2-methylpropanimidothioate —— C11H15NOS
    (4-methylphenyl) (1E)-N-hydroxy-2-methylpropanimidothioate
    —— 2,2,2-Trichloro-1-(6,11-dihydropyrrolo[2,1-c][1,4]benzothiazepin-9-yl)ethanone 221318-31-6 C14H10Cl3NOS
    2,2,2-Trichloro-1-(6,11-dihydropyrrolo[2,1-c][1,4]benzothiazepin-9-yl)ethanone
    —— 11-ethoxycarbonyl-5H,11H-pyrrolo<2,1-c><1,4>benzothiazepine 130534-49-5 C15H15NO2S
    11-ethoxycarbonyl-5H,11H-pyrrolo<2,1-c><1,4>benzothiazepine
    —— 5H,11H-pyrrolo<2,1-c><1,4>benzothiazepine-3-carboxylic acid 221318-34-9 C13H11NO2S
    5H,11H-pyrrolo<2,1-c><1,4>benzothiazepine-3-carboxylic acid
    —— 5H,11H-pyrrolo<2,1-c><1,4>benzothiazepine 130534-51-9 C12H11NS
    5H,11H-pyrrolo<2,1-c><1,4>benzothiazepine
    —— (3S,4'S)-2-benzyl-3-(2-phenylthio-[1,3]dioxolan-4-yl)-4-(2-trimethylsilylethoxy)-3,6-dihydro-2H-[1,2]oxazine 1163143-58-5 C25H33NO4SSi
    (3S,4'S)-2-benzyl-3-(2-phenylthio-[1,3]dioxolan-4-yl)-4-(2-trimethylsilylethoxy)-3,6-dihydro-2H-[1,2]oxazine
    —— (1S,5S,6S,8S)-2-benzyl-8-hydroxymethyl-6-phenylthio-3,7-dioxa-2-azabicyclo[3.3.1]-nonan-9-one 1163143-60-9 C20H21NO4S
    (1S,5S,6S,8S)-2-benzyl-8-hydroxymethyl-6-phenylthio-3,7-dioxa-2-azabicyclo[3.3.1]-nonan-9-one
    —— (1R,5S,6S,8S,9R)-2-benzyl-8-hydroxymethyl-6-phenylsulfanyl-3,7-dioxa-2-azabicyclo[3.3.1]nonan-9-ol 1163143-63-2 C20H23NO4S
    (1R,5S,6S,8S,9R)-2-benzyl-8-hydroxymethyl-6-phenylsulfanyl-3,7-dioxa-2-azabicyclo[3.3.1]nonan-9-ol
    —— 4-[5-(4-trifluoromethylphenylamino)-[1,3,4]thiadiazol-2-ylsulfanyl]-benzenesulfonylchloride 1076689-65-0 C15H9ClF3N3O2S3
    4-[5-(4-trifluoromethylphenylamino)-[1,3,4]thiadiazol-2-ylsulfanyl]-benzenesulfonylchloride
    —— 4-[5-(4-trifluoromethylphenylamino)-[1,3,4]thiadiazol-2-ylsulfanyl]-benzenesulfonamide 1076689-64-9 C15H11F3N4O2S3
    4-[5-(4-trifluoromethylphenylamino)-[1,3,4]thiadiazol-2-ylsulfanyl]-benzenesulfonamide
    —— 2-(methylsulfonyl)ethyl 2,2-difluoroacetate 1353998-75-0 C5H8F2O4S
    2-(methylsulfonyl)ethyl 2,2-difluoroacetate
    —— 3,3-Dimethyl-1-(methylsulfonyl)-2-butanone oxime 39196-09-3 C7H15NO3S
    3,3-Dimethyl-1-(methylsulfonyl)-2-butanone oxime
    —— (E)-1-allyl-2-(prop-1-en-1-yl) disulfane 122156-02-9 C6H10S2
    (E)-1-allyl-2-(prop-1-en-1-yl) disulfane
    —— 6-isopropylisothioquinanthrene 1021335-01-2 C21H16N2S2
    6-isopropylisothioquinanthrene
    —— 4-anilino-(7Z)-7-benzylidene-5-methoxy-2-methylthio-5,7-dihydrofuro[3,4-d]pyrimidine 1206804-92-3 C21H19N3O2S
    4-anilino-(7Z)-7-benzylidene-5-methoxy-2-methylthio-5,7-dihydrofuro[3,4-d]pyrimidine
    —— (7Z)-7-benzylidene-5-methoxy-2-methylthio-4-(pyrrolidin-1-yl)-5,7-dihydrofuro[3,4-d]pyrimidine 1067892-87-8 C19H21N3O2S
    (7Z)-7-benzylidene-5-methoxy-2-methylthio-4-(pyrrolidin-1-yl)-5,7-dihydrofuro[3,4-d]pyrimidine
    —— (7Z)-7-benzylidene-5-methoxy-2-methylthio-4-(morpholin-4-yl)-5,7-dihydrofuro[3,4-d]pyrimidine 1067892-94-7 C19H21N3O3S
    (7Z)-7-benzylidene-5-methoxy-2-methylthio-4-(morpholin-4-yl)-5,7-dihydrofuro[3,4-d]pyrimidine
    —— 2,2,5-Trimethyl-4-(O-(methylcarbamoyl)oximino)-1,3-dithiolane 93503-00-5 C8H14N2O2S2
    2,2,5-Trimethyl-4-(O-(methylcarbamoyl)oximino)-1,3-dithiolane
    —— 3',4-di(methylthio)-3,4'-diquinolinyl sulfide 86474-67-1 C20H16N2S3
    3',4-di(methylthio)-3,4'-diquinolinyl sulfide
    —— 2'-isopropyl-4-methoxy-3'-methylthio-3,4'-diquinolinyl sulfide 1021335-15-8 C23H22N2OS2
    2'-isopropyl-4-methoxy-3'-methylthio-3,4'-diquinolinyl sulfide
    —— 2'-isopropyl-4-methoxy-4'-methylthio-3,3'-diquinolinyl sulfide 1021335-19-2 C23H22N2OS2
    2'-isopropyl-4-methoxy-4'-methylthio-3,3'-diquinolinyl sulfide
    —— 4-amino-2-methylthio-6-(phenylethynyl)pyrimidine-5-carbaldehyde 867193-35-9 C14H11N3OS
    4-amino-2-methylthio-6-(phenylethynyl)pyrimidine-5-carbaldehyde
    —— di-(pent-1-ynyl)-sulfane 94408-98-7 C10H14S
    di-(pent-1-ynyl)-sulfane
    —— 2,2'-diisopropyl-4-methoxy-3'-methylthio-3,4'-diquinolinyl sulfide 1021335-17-0 C26H28N2OS2
    2,2'-diisopropyl-4-methoxy-3'-methylthio-3,4'-diquinolinyl sulfide
    —— 6,12-diisopropylthioquinanthrene 1021334-95-1 C24H22N2S2
    6,12-diisopropylthioquinanthrene
    —— 6,8-diisopropylisothioquinanthrene 1021335-03-4 C24H22N2S2
    6,8-diisopropylisothioquinanthrene
    —— 2,2'-diisopropyl-4-methoxy-4'-methylthio-3,3'-diquinolinyl sulfide 1021335-21-6 C26H28N2OS2
    2,2'-diisopropyl-4-methoxy-4'-methylthio-3,3'-diquinolinyl sulfide
    —— N,N-diethylthiopentanamide 5309-99-9 C9H19NS
    N,N-diethylthiopentanamide
    —— 1-(2-cyclopentenyl)-4-methylthio-2(1H)-pyrimidinone 146886-41-1 C10H12N2OS
    1-(2-cyclopentenyl)-4-methylthio-2(1H)-pyrimidinone
    —— 2,4-dichloro-5-trifluoromethylsulphanyl-pyrimidine 108222-71-5 C5HCl2F3N2S
    2,4-dichloro-5-trifluoromethylsulphanyl-pyrimidine
    —— 2,4-Dibromo-5-(trifluoromethylsulfanyl)pyrimidine 108222-72-6 C5HBr2F3N2S
    2,4-Dibromo-5-(trifluoromethylsulfanyl)pyrimidine
    —— (E,E)-6-Ethyl-4,5,7-trithiadeca-2,8-diene 144304-11-0 C9H16S3
    (E,E)-6-Ethyl-4,5,7-trithiadeca-2,8-diene
    —— 5-Trifluormethylmercapto-2,4-difluor-pyrimidin 108222-74-8 C5HF5N2S
    5-Trifluormethylmercapto-2,4-difluor-pyrimidin
    —— (E)-S-1-propenyl methanesulfonothioate 144304-08-5 C4H8O2S2
    (E)-S-1-propenyl methanesulfonothioate
    —— (E,E)-5,8-Diethyl-4,6,7,9-tetrathiadodeca-2,10-diene 197566-27-1 C12H22S4
    (E,E)-5,8-Diethyl-4,6,7,9-tetrathiadodeca-2,10-diene
    —— (E,E)-6-Ethyl-4,5,7-trithiadeca-2,8-diene 7-oxide 197304-31-7 C9H16OS3
    (E,E)-6-Ethyl-4,5,7-trithiadeca-2,8-diene 7-oxide
    —— bis(trimethylgermyl)methoxy(phenylsulfanyl)methane 303128-91-8 C14H26Ge2OS
    bis(trimethylgermyl)methoxy(phenylsulfanyl)methane
    —— 2-Oxocyclohexan-1-carbothioamid 51978-91-7 C7H11NOS
    2-Oxocyclohexan-1-carbothioamid
    —— 3,3-Bis(phenylthio)cyclobutanecarbonitrile 91003-30-4 C17H15NS2
    3,3-Bis(phenylthio)cyclobutanecarbonitrile
    —— bis-(1,1-dimethyl-allyl)-disulfane 34801-26-8 C10H18S2
    bis-(1,1-dimethyl-allyl)-disulfane
    —— 2-<<2'-(N-methylpiperazino)ethyl>thio>pyrimidine 131407-87-9 C11H18N4S
    2-<<2'-(N-methylpiperazino)ethyl>thio>pyrimidine
    —— 2,5-bis<2'-<<2''-(N-methylpiperazino)ethyl>thio>pyrimidin-4'-yl>thiophene 129224-99-3 C26H36N8S3
    2,5-bis<2'-<<2''-(N-methylpiperazino)ethyl>thio>pyrimidin-4'-yl>thiophene
    —— Bis-(1-methylundecyl)-sulfid 50688-05-6 C24H50S
    Bis-(1-methylundecyl)-sulfid
    —— 6-amino-2-ethyl-2-methyl-4-phenyl-4H-1,3-dithiine-5-carbonitrile 94639-09-5 C14H16N2S2
    6-amino-2-ethyl-2-methyl-4-phenyl-4H-1,3-dithiine-5-carbonitrile
    —— (Z)-S-1-propenyl methanesulfonothioate 144304-07-4 C4H8O2S2
    (Z)-S-1-propenyl methanesulfonothioate
    —— 3-Methylsulfanylfuran-2-carbaldehyde 337514-13-3 C6H6O2S
    3-Methylsulfanylfuran-2-carbaldehyde
    —— methyl (2S)-2-hydroxy-2-[(2R,3R,4R)-4-methyl-5-oxo-4-phenylsulfanyl-2-tridecyloxolan-3-yl]acetate 180267-05-4 C27H42O5S
    methyl (2S)-2-hydroxy-2-[(2R,3R,4R)-4-methyl-5-oxo-4-phenylsulfanyl-2-tridecyloxolan-3-yl]acetate