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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-Hexanamine, N-ethyl-5-methyl-1-(methylsulfonyl)- 1250404-36-4 C10H23NO2S
    3-Hexanamine, N-ethyl-5-methyl-1-(methylsulfonyl)-
    —— 2-[(S)-2-Hydroxy-4-pentenyl]-2-[(R)-2-(methoxymethoxy)propanyl]-1,3-dithiane 1388627-17-5 C14H26O3S2
    2-[(S)-2-Hydroxy-4-pentenyl]-2-[(R)-2-(methoxymethoxy)propanyl]-1,3-dithiane
    —— [1-(14)C]thioacetamide 1356571-39-5 C2H5NS
    [1-(14)C]thioacetamide
    —— [1-(14)C]thioacetamide S-oxide 1356571-40-8 C2H5NOS
    [1-(14)C]thioacetamide S-oxide
    —— 1,3-diphenyl-1H-[1,2,4]triazino[6,5-b]phenothiazine 1359739-86-8 C25H16N4S
    1,3-diphenyl-1H-[1,2,4]triazino[6,5-b]phenothiazine
    —— (E)-ethyl 3-(5-(methylthio)-1H-tetrazol-1-yl)acrylate 1349709-83-6 C7H10N4O2S
    (E)-ethyl 3-(5-(methylthio)-1H-tetrazol-1-yl)acrylate
    —— 4-(4-isopropyl-phenylsulfanyl)-benzene-1,2-diol 1362410-19-2 C15H16O2S
    4-(4-isopropyl-phenylsulfanyl)-benzene-1,2-diol
    —— allyl 2,3-O-cyclopentylidene-5-deoxy-5-S-(1,2,4-triazol-3-yl)-β-D-ribofuranoside 1356821-69-6 C15H21N3O4S
    allyl 2,3-O-cyclopentylidene-5-deoxy-5-S-(1,2,4-triazol-3-yl)-β-D-ribofuranoside
    —— (I+/-S)-2-(Methylthio)-I+/--(trifluoromethyl)benzenemethanamine 878539-32-3 C9H10F3NS
    (I+/-S)-2-(Methylthio)-I+/--(trifluoromethyl)benzenemethanamine
    —— 2-(3-Chloro-5-(phenylthio)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 942069-61-6 C18H20BClO2S
    2-(3-Chloro-5-(phenylthio)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
    —— 4-Chloro-2-(propylthio)pyridine 1346707-21-8 C8H10ClNS
    4-Chloro-2-(propylthio)pyridine
    —— 2-(3-Bromo-5-(phenylthio)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 942069-55-8 C18H20BBrO2S
    2-(3-Bromo-5-(phenylthio)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
    —— 2-(3-Methoxy-5-(phenylthio)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 942069-83-2 C19H23BO3S
    2-(3-Methoxy-5-(phenylthio)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
    —— 3-Chloro-4-[(3-chlorophenyl)thio]-1,2,5-thiadiazole 1248914-27-3 C8H4Cl2N2S2
    3-Chloro-4-[(3-chlorophenyl)thio]-1,2,5-thiadiazole
    —— 2-Chloro-3-[[(3-chlorophenyl)thio]methyl]pyridine 1248794-33-3 C12H9Cl2NS
    2-Chloro-3-[[(3-chlorophenyl)thio]methyl]pyridine
    —— 2-[(3-Chlorophenyl)thio]butanoic acid 103040-44-4 C10H11ClO2S
    2-[(3-Chlorophenyl)thio]butanoic acid
    —— 1-(Ethanesulfinyl)but-2-ene 88170-50-7 C6H12OS
    1-(Ethanesulfinyl)but-2-ene
    —— 1,2-Diethoxy-13-phenyl-3,12,23-trithia-14-azahexacyclo[14.7.0.02,10.04,9.011,15.017,22]tricosa-4,6,8,10,13,15,17,19,21-nonaene 1403580-50-6 C29H23NO2S3
    1,2-Diethoxy-13-phenyl-3,12,23-trithia-14-azahexacyclo[14.7.0.02,10.04,9.011,15.017,22]tricosa-4,6,8,10,13,15,17,19,21-nonaene
    —— 2-(4-Chloro-phenylsulfanyl)-6-methyl-nicotinic acid 958-61-2 C13H10ClNO2S
    2-(4-Chloro-phenylsulfanyl)-6-methyl-nicotinic acid
    —— 4-Methyl-1-(methylthio)-2-pentanamine 1247496-39-4 C7H17NS
    4-Methyl-1-(methylthio)-2-pentanamine
    —— (2-(2-(hydroxymethyl)-4-methylphenylthio)phenyl)methanol 1062599-57-8 C15H16O2S
    (2-(2-(hydroxymethyl)-4-methylphenylthio)phenyl)methanol
    —— (4-fluoro-2-(2-(hydroxymethyl)phenylthio)phenyl)methanol 1062599-59-0 C14H13FO2S
    (4-fluoro-2-(2-(hydroxymethyl)phenylthio)phenyl)methanol
    —— bis-(5-amino-pentyl)-sulfide 91135-26-1 C10H24N2S
    bis-(5-amino-pentyl)-sulfide
    —— (2-(2-(hydroxymethyl)-6-methylphenylthio)phenyl)methanol 1062599-55-6 C15H16O2S
    (2-(2-(hydroxymethyl)-6-methylphenylthio)phenyl)methanol
    —— 1-Ethoxy-2-methyl-13-phenyl-3,12,23-trithia-14-azahexacyclo[14.7.0.02,10.04,9.011,15.017,22]tricosa-4,6,8,10,13,15,17,19,21-nonaene 1403580-47-1 C28H21NOS3
    1-Ethoxy-2-methyl-13-phenyl-3,12,23-trithia-14-azahexacyclo[14.7.0.02,10.04,9.011,15.017,22]tricosa-4,6,8,10,13,15,17,19,21-nonaene
    —— 2-Ethoxy-13-phenyl-3,12,23-trithia-14-azahexacyclo[14.7.0.02,10.04,9.011,15.017,22]tricosa-4,6,8,10,13,15,17,19,21-nonaene 1403580-43-7 C27H19NOS3
    2-Ethoxy-13-phenyl-3,12,23-trithia-14-azahexacyclo[14.7.0.02,10.04,9.011,15.017,22]tricosa-4,6,8,10,13,15,17,19,21-nonaene
    —— 2-Ethoxy-1-methyl-13-phenyl-3,12,23-trithia-14-azahexacyclo[14.7.0.02,10.04,9.011,15.017,22]tricosa-4,6,8,10,13,15,17,19,21-nonaene 1403580-45-9 C28H21NOS3
    2-Ethoxy-1-methyl-13-phenyl-3,12,23-trithia-14-azahexacyclo[14.7.0.02,10.04,9.011,15.017,22]tricosa-4,6,8,10,13,15,17,19,21-nonaene
    —— 7-Nitro-2,3-dihydro-1,4-benzoxathiine 1393598-58-7 C8H7NO3S
    7-Nitro-2,3-dihydro-1,4-benzoxathiine
    —— 1-Butanol, 4-[(3-methylcyclohexyl)thio]- 1339363-94-8 C11H22OS
    1-Butanol, 4-[(3-methylcyclohexyl)thio]-
    —— S-Prop-2-en-1-yl carbamothioate 62604-06-2 C4H7NOS
    S-Prop-2-en-1-yl carbamothioate
    —— 12-Aminododecane-1-thiol 158399-18-9 C12H27NS
    12-Aminododecane-1-thiol
    —— 1,4-Bis[(4-hydroxyphenyl)sulfanyl]butane-2,3-diol 95971-31-6 C16H18O4S2
    1,4-Bis[(4-hydroxyphenyl)sulfanyl]butane-2,3-diol
    —— 1,3-Dimethylbut-2-enyl-isopropyldisulfid 90728-13-5 C9H18S2
    1,3-Dimethylbut-2-enyl-isopropyldisulfid
    —— 2-ethyl-2-methyl-propane-1,3-dithiol 56472-20-9 C6H14S2
    2-ethyl-2-methyl-propane-1,3-dithiol
    —— 6-(4-Methylphenylthio)-3-hexen-2-one 1415577-52-4 C13H16OS
    6-(4-Methylphenylthio)-3-hexen-2-one
    —— Pyrimidine, 4-chloro-6-[[(3-methylphenyl)methyl]thio]- 1339071-25-8 C12H11ClN2S
    Pyrimidine, 4-chloro-6-[[(3-methylphenyl)methyl]thio]-
    —— 4-[(Phenylsulfanyl)methyl]hexahydro-2H-cyclopenta[b]furan-2-one 62639-70-7 C14H16O2S
    4-[(Phenylsulfanyl)methyl]hexahydro-2H-cyclopenta[b]furan-2-one
    —— 5,5,5-Trichlor-pentylmercaptan 60303-21-1 C5H9Cl3S
    5,5,5-Trichlor-pentylmercaptan
    —— 2-Methyl-1-[(2-methyl-1-penten-1-yl)sulfonyl]-1-pentene 4513-64-8 C12H22O2S
    2-Methyl-1-[(2-methyl-1-penten-1-yl)sulfonyl]-1-pentene
    —— O-Ethyl (2-cyclohexylethyl)carbamothioate 7286-66-0 C11H21NOS
    O-Ethyl (2-cyclohexylethyl)carbamothioate
    —— (3-Bromophenyl)(5-hydroxypentyl)sulfane 1215078-52-6 C11H15BrOS
    (3-Bromophenyl)(5-hydroxypentyl)sulfane
    —— ethyl 3-{4-cyano-3-hydroxy-5-[(2-oxopropyl)sulfanyl]thiophen-2-yl}-3-oxopropanoate 1448182-69-1 C13H13NO5S2
    ethyl 3-{4-cyano-3-hydroxy-5-[(2-oxopropyl)sulfanyl]thiophen-2-yl}-3-oxopropanoate
    —— S-hexanoylsulfanyl hexanethioate 62652-57-7 C12H22O2S2
    S-hexanoylsulfanyl hexanethioate
    —— 1-Methyl-sulfinyl-dodecen-(2) 13159-43-8 C13H26OS
    1-Methyl-sulfinyl-dodecen-(2)
    —— 2-Methylpent-3-ene-2-thiol 61758-11-0 C6H12S
    2-Methylpent-3-ene-2-thiol
    —— 2-Chloro-4-(4-morpholinyl)-6-(phenylthio)-1,3,5-triazine 544693-14-3 C13H13ClN4OS
    2-Chloro-4-(4-morpholinyl)-6-(phenylthio)-1,3,5-triazine
    —— 2-(Ethyldisulfanyl)ethane-1-thiol 63986-06-1 C4H10S3
    2-(Ethyldisulfanyl)ethane-1-thiol
    —— 1,3,5-Triazine, 2-chloro-4-ethoxy-6-[(5-methyl-1,3,4-oxadiazol-2-yl)thio]- 1284415-60-6 C8H8ClN5O2S
    1,3,5-Triazine, 2-chloro-4-ethoxy-6-[(5-methyl-1,3,4-oxadiazol-2-yl)thio]-
    —— 2-{[(1H-Imidazol-2-yl)sulfanyl]methyl}pyridine 86492-12-8 C9H9N3S
    2-{[(1H-Imidazol-2-yl)sulfanyl]methyl}pyridine
    —— 2-Chloro-4-[(4-chlorophenyl)thio]-6-(1-piperidinyl)-1,3,5-triazine 32998-31-5 C14H14Cl2N4S
    2-Chloro-4-[(4-chlorophenyl)thio]-6-(1-piperidinyl)-1,3,5-triazine