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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3,5-dichloro-4-<i>o</i>-tolylsulfanyl-aniline 109218-80-6 C13H11Cl2NS
    3,5-dichloro-4-<i>o</i>-tolylsulfanyl-aniline
    —— [4-(5-formyl-6-methyl-pyridin-2-ylsulfanyl)-phenyl]-acetic acid methyl ester 926296-40-4 C16H15NO3S
    [4-(5-formyl-6-methyl-pyridin-2-ylsulfanyl)-phenyl]-acetic acid methyl ester
    —— methyl (Z)-4-(phenylthio)-3,5-hexadienoate 84132-34-3 C13H14O2S
    methyl (Z)-4-(phenylthio)-3,5-hexadienoate
    —— N-{4-[(5-formyl-6-methyl-2-pyridinyl)thio]phenyl}methanesulfonamide 1150617-08-5 C14H14N2O3S2
    N-{4-[(5-formyl-6-methyl-2-pyridinyl)thio]phenyl}methanesulfonamide
    —— methyl 5-(phenylthio)pentanoate 78742-75-3 C12H16O2S
    methyl 5-(phenylthio)pentanoate
    —— 4-acetylamino-3-methylsulfanyl-6-phenyl-4<i>H</i>-[1,2,4]triazin-5-one 22279-48-7 C12H12N4O2S
    4-acetylamino-3-methylsulfanyl-6-phenyl-4<i>H</i>-[1,2,4]triazin-5-one
    —— 4-amino-6-methyl-3-methylthio-1,2,4-triazin-5-thione 61609-93-6 C5H8N4S2
    4-amino-6-methyl-3-methylthio-1,2,4-triazin-5-thione
    —— 1,1-Ditert-butyl-3-phenylsulfanylsiletane 1240530-82-8 C17H28SSi
    1,1-Ditert-butyl-3-phenylsulfanylsiletane
    —— 2,2,3,3-tetrafluoropropanesulfenyl chloride 951788-59-3 C3H3ClF4S
    2,2,3,3-tetrafluoropropanesulfenyl chloride
    —— <i>N</i>-butyl-<i>N'</i>-cyclohexyl-thiourea 18884-16-7 C11H22N2S
    <i>N</i>-butyl-<i>N'</i>-cyclohexyl-thiourea
    —— 3-(Carbamoylmethylthio)-4-phenylfurazan 372945-82-9 C10H9N3O2S
    3-(Carbamoylmethylthio)-4-phenylfurazan
    —— 3-chloro-5-(methylthio)pyrazine-2-carbaldehyde 1620056-65-6 C6H5ClN2OS
    3-chloro-5-(methylthio)pyrazine-2-carbaldehyde
    —— 5-benzyl-3-methylsulfanyl-1,2,4-triazine 832686-79-0 C11H11N3S
    5-benzyl-3-methylsulfanyl-1,2,4-triazine
    —— 2-Benzyl-5-(ethylsulfanyl)-1,3,4-oxadiazole 717892-59-6 C11H12N2OS
    2-Benzyl-5-(ethylsulfanyl)-1,3,4-oxadiazole
    —— Propandisulfonsaeure-(1,3)-diazid 98025-64-0 C3H6N6O4S2
    Propandisulfonsaeure-(1,3)-diazid
    —— 4-Ethylsulfanyl-3-oxo-5-propyl-3H-isoxazole-2-carbonyl chloride 1027657-53-9 C9H12ClNO3S
    4-Ethylsulfanyl-3-oxo-5-propyl-3H-isoxazole-2-carbonyl chloride
    —— 4-ethylthio-3-hydroxy-5-propylisoxazole 271786-97-1 C8H13NO2S
    4-ethylthio-3-hydroxy-5-propylisoxazole
    —— 5-tert-Butyl-4-ethylsulfanyl-3-oxo-3H-isoxazole-2-carbonyl chloride 1026105-14-5 C10H14ClNO3S
    5-tert-Butyl-4-ethylsulfanyl-3-oxo-3H-isoxazole-2-carbonyl chloride
    —— 5-Ethyl-4-isopropylsulfanyl-3-oxo-3H-isoxazole-2-carbonyl chloride 1027564-52-8 C9H12ClNO3S
    5-Ethyl-4-isopropylsulfanyl-3-oxo-3H-isoxazole-2-carbonyl chloride
    —— 5-ethyl-3-hydroxy-4-isopropylthioisoxazole 271787-01-0 C8H13NO2S
    5-ethyl-3-hydroxy-4-isopropylthioisoxazole
    —— 5-tert-Butyl-4-ethylsulfanyl-isoxazol-3-ol 271787-00-9 C9H15NO2S
    5-tert-Butyl-4-ethylsulfanyl-isoxazol-3-ol
    —— 2',3'-O-isopropylidene-5-phenylthiomethyluridine 111476-31-4 C19H22N2O6S
    2',3'-O-isopropylidene-5-phenylthiomethyluridine
    —— 5-Methyl-4-propylsulfanyl-isoxazol-3-ol 107403-20-3 C7H11NO2S
    5-Methyl-4-propylsulfanyl-isoxazol-3-ol
    —— 3-hydroxy-4-(2-methoxyethylthio)-5-methylisoxazole 271787-02-1 C7H11NO3S
    3-hydroxy-4-(2-methoxyethylthio)-5-methylisoxazole
    —— 4-Ethylsulfanyl-5-isopropyl-3-oxo-3H-isoxazole-2-carbonyl chloride 1026233-89-5 C9H12ClNO3S
    4-Ethylsulfanyl-5-isopropyl-3-oxo-3H-isoxazole-2-carbonyl chloride
    —— 5-Methyl-3-oxo-4-propylsulfanyl-3H-isoxazole-2-carbonyl chloride 1026184-66-6 C8H10ClNO3S
    5-Methyl-3-oxo-4-propylsulfanyl-3H-isoxazole-2-carbonyl chloride
    —— p-tolyl 3-azido-2,3,6-trideoxy-1-thio-α-L-arabino-hexopyranoside 936330-82-4 C13H17N3O2S
    p-tolyl 3-azido-2,3,6-trideoxy-1-thio-α-L-arabino-hexopyranoside
    —— 2-Prop-2-ynylsulfanylpyridine-3-carbonitrile 1620074-99-8 C9H6N2S
    2-Prop-2-ynylsulfanylpyridine-3-carbonitrile
    —— 4-Isopropylsulfanyl-5-methyl-isoxazol-3-ol 107403-21-4 C7H11NO2S
    4-Isopropylsulfanyl-5-methyl-isoxazol-3-ol
    —— 5-ethyl-4-ethylthio-3-hydroxyisoxazole 149804-87-5 C7H11NO2S
    5-ethyl-4-ethylthio-3-hydroxyisoxazole
    —— 4-Ethylsulfanyl-5-isopropyl-isoxazol-3-ol 271786-99-3 C8H13NO2S
    4-Ethylsulfanyl-5-isopropyl-isoxazol-3-ol
    —— 1-(3-Pyridin-4-ylsulfanylphenyl)-3-[5-(trifluoromethyl)pyridin-2-yl]urea 432050-21-0 C18H13F3N4OS
    1-(3-Pyridin-4-ylsulfanylphenyl)-3-[5-(trifluoromethyl)pyridin-2-yl]urea
    —— 5-Ethyl-4-ethylsulfanyl-3-oxo-3H-isoxazole-2-carbonyl chloride 1027255-15-7 C8H10ClNO3S
    5-Ethyl-4-ethylsulfanyl-3-oxo-3H-isoxazole-2-carbonyl chloride
    —— 4-(2-Methoxy-ethylsulfanyl)-5-methyl-3-oxo-3H-isoxazole-2-carbonyl chloride 1027978-05-7 C8H10ClNO4S
    4-(2-Methoxy-ethylsulfanyl)-5-methyl-3-oxo-3H-isoxazole-2-carbonyl chloride
    —— N4-[4-(pyridin-4-ylsulfanyl)-phenyl]-6,7,8,9-tetrahydro-5H-cycloheptapyrimidine-2,4-diamine 569658-16-8 C20H21N5S
    N4-[4-(pyridin-4-ylsulfanyl)-phenyl]-6,7,8,9-tetrahydro-5H-cycloheptapyrimidine-2,4-diamine
    —— 5-Methyl-4-methylsulfanyl-isoxazol-3-ol 107403-18-9 C5H7NO2S
    5-Methyl-4-methylsulfanyl-isoxazol-3-ol
    —— 1-Methylcyclopentane-1-carbothioamide 1620693-53-9 C7H13NS
    1-Methylcyclopentane-1-carbothioamide
    —— N-(2-amino-6-ethyl-4-pyrimidinyl)-N-[4-(4-pyridinylsulfanyl)phenyl]amine 570415-41-7 C17H17N5S
    N-(2-amino-6-ethyl-4-pyrimidinyl)-N-[4-(4-pyridinylsulfanyl)phenyl]amine
    —— 5-Methyl-4-methylsulfanyl-3-oxo-3H-isoxazole-2-carbonyl chloride 1025937-25-0 C6H6ClNO3S
    5-Methyl-4-methylsulfanyl-3-oxo-3H-isoxazole-2-carbonyl chloride
    —— (7-methyl-2-methylthiothiazolo[4,5-d]pyrimidin-5-ylsulfanyl)acetic acid ethyl ester 321434-47-3 C11H13N3O2S3
    (7-methyl-2-methylthiothiazolo[4,5-d]pyrimidin-5-ylsulfanyl)acetic acid ethyl ester
    —— 4-benzylamino-2-methylthio-5-nitro-6-phenylethynylpyrimidine 1097967-02-6 C20H16N4O2S
    4-benzylamino-2-methylthio-5-nitro-6-phenylethynylpyrimidine
    —— 6-chloro-2-methylthio-4-pyrrolidino-5-nitropyrimidine 1097966-95-4 C9H11ClN4O2S
    6-chloro-2-methylthio-4-pyrrolidino-5-nitropyrimidine
    —— 2-methylthio-5-nitro-6-phenylethynyl-4-pyrrolidinopyrimidine 1097967-05-9 C17H16N4O2S
    2-methylthio-5-nitro-6-phenylethynyl-4-pyrrolidinopyrimidine
    —— N-{6-[(4-aminophenyl)thio]imidazo[1,2-b]pyridazin-2-yl}cyclopropanecarboxamide 1005782-38-6 C16H15N5OS
    N-{6-[(4-aminophenyl)thio]imidazo[1,2-b]pyridazin-2-yl}cyclopropanecarboxamide
    —— 4-(4-Chloro-phenylsulfanyl)-2-p-tolyl-thiazole 130775-33-6 C16H12ClNS2
    4-(4-Chloro-phenylsulfanyl)-2-p-tolyl-thiazole
    —— 1-(2-Methoxy-ethyl)-3-[4-(4-nitro-phenylsulfanyl)-phenyl]-urea 54457-56-6 C16H17N3O4S
    1-(2-Methoxy-ethyl)-3-[4-(4-nitro-phenylsulfanyl)-phenyl]-urea
    —— (7-chloro-8-methyl-3-phenylamino-1,1-dioxo-4H-1,5,2-benzo[f]dithiazepin-4-ylidene)acetic acid 1083063-87-9 C17H13ClN2O4S2
    (7-chloro-8-methyl-3-phenylamino-1,1-dioxo-4H-1,5,2-benzo[f]dithiazepin-4-ylidene)acetic acid
    —— ethyl 4-(2-methylphenylthio)-3-oxobutanoate 83821-43-6 C13H16O3S
    ethyl 4-(2-methylphenylthio)-3-oxobutanoate
    —— (3S,4S)-5-Cyano-4-cyclohexyl-6-methyl-2-[1-phenylsulfanyl-meth-(Z)-ylidene]-1,2,3,4-tetrahydro-pyridine-3-carboxylic acid ethyl ester 134968-41-5 C23H28N2O2S
    (3S,4S)-5-Cyano-4-cyclohexyl-6-methyl-2-[1-phenylsulfanyl-meth-(Z)-ylidene]-1,2,3,4-tetrahydro-pyridine-3-carboxylic acid ethyl ester
    —— ethyl 3-oxo-4-(4-pyridinylthio)butanoate 107975-76-8 C11H13NO3S
    ethyl 3-oxo-4-(4-pyridinylthio)butanoate