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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-(2,4-Dinitrophenyl)sulfanyl-5-[5-[5-(2,4-dinitrophenyl)sulfanyl-4-(3-fluorophenyl)-1,2,4-triazol-3-yl]pentyl]-4-(3-fluorophenyl)-1,2,4-triazole 128156-13-8 C33H24F2N10O8S2
    3-(2,4-Dinitrophenyl)sulfanyl-5-[5-[5-(2,4-dinitrophenyl)sulfanyl-4-(3-fluorophenyl)-1,2,4-triazol-3-yl]pentyl]-4-(3-fluorophenyl)-1,2,4-triazole
    —— 4-(3-Fluorophenyl)-3-[5-[4-(3-fluorophenyl)-5-(4-nitrophenyl)sulfanyl-1,2,4-triazol-3-yl]pentyl]-5-(4-nitrophenyl)sulfanyl-1,2,4-triazole 128156-12-7 C33H26F2N8O4S2
    4-(3-Fluorophenyl)-3-[5-[4-(3-fluorophenyl)-5-(4-nitrophenyl)sulfanyl-1,2,4-triazol-3-yl]pentyl]-5-(4-nitrophenyl)sulfanyl-1,2,4-triazole
    —— Cyclobutanemethanamine, 1-(ethylsulfonyl)- 1779131-51-9 C7H15NO2S
    Cyclobutanemethanamine, 1-(ethylsulfonyl)-
    —— 2-fluoro-4-phenylsulphanylaniline 76105-39-0 C12H10FNS
    2-fluoro-4-phenylsulphanylaniline
    —— 2-chloro-4-(methylthio)nicotinonitrile 1257072-10-8 C7H5ClN2S
    2-chloro-4-(methylthio)nicotinonitrile
    —— 131136-76-0 C4H6S
    —— Trifluoro-methanesulfonic acid 8-nitro-5-oxo-2,3-dihydro-5H-thiazolo[3,2-a]pyridin-7-yl ester 1303510-60-2 C8H5F3N2O6S2
    Trifluoro-methanesulfonic acid 8-nitro-5-oxo-2,3-dihydro-5H-thiazolo[3,2-a]pyridin-7-yl ester
    —— 1-(4-(2-(pyrrolidine-1-carbonyl)pyridin-4-ylthio)phenyl)-3-(3-(trifluoromethyl)phenyl)thiourea 1395063-26-9 C24H21F3N4OS2
    1-(4-(2-(pyrrolidine-1-carbonyl)pyridin-4-ylthio)phenyl)-3-(3-(trifluoromethyl)phenyl)thiourea
    —— 1-(4-chloro-3-(trifluoromethyl)phenyl)-3-(4-(2-(pyrrolidine-1-carbonyl)pyridin-4-ylthio)phenyl)thiourea 1395063-30-5 C24H20ClF3N4OS2
    1-(4-chloro-3-(trifluoromethyl)phenyl)-3-(4-(2-(pyrrolidine-1-carbonyl)pyridin-4-ylthio)phenyl)thiourea
    —— 1-(4-(2-(pyrrolidine-1-carbonyl)pyridin-4-ylthio)phenyl)-3-m-tolylthiourea 1417341-33-3 C24H24N4OS2
    1-(4-(2-(pyrrolidine-1-carbonyl)pyridin-4-ylthio)phenyl)-3-m-tolylthiourea
    —— 1-(3,5-bis(trifluoromethyl)phenyl)-3-(4-(2-(pyrrolidine-1-carbonyl)pyridin-4-ylthio)phenyl)thiourea 1417341-32-2 C25H20F6N4OS2
    1-(3,5-bis(trifluoromethyl)phenyl)-3-(4-(2-(pyrrolidine-1-carbonyl)pyridin-4-ylthio)phenyl)thiourea
    —— 1-(4-fluorophenyl)-3-(4-(2-(pyrrolidine-1-carbonyl)-pyridin-4-ylthio)phenyl)thiourea 1395063-29-2 C23H21FN4OS2
    1-(4-fluorophenyl)-3-(4-(2-(pyrrolidine-1-carbonyl)-pyridin-4-ylthio)phenyl)thiourea
    —— 1-(4-(2-(pyrrolidine-1-carbonyl)pyridin-4-ylthio)phenyl)-3-(4-(trifluoromethoxy)phenyl)thiourea 1395063-33-8 C24H21F3N4O2S2
    1-(4-(2-(pyrrolidine-1-carbonyl)pyridin-4-ylthio)phenyl)-3-(4-(trifluoromethoxy)phenyl)thiourea
    —— 3-benzyl-5-bromo-2-(methylthio)pyrimidin-4(3H)-one 1036763-71-9 C12H11BrN2OS
    3-benzyl-5-bromo-2-(methylthio)pyrimidin-4(3H)-one
    —— bis{6-[6-(2-pyridyl)-4-pyrimidinyl]-2-pyridyl} sulfide 350253-46-2 C28H18N8S
    bis{6-[6-(2-pyridyl)-4-pyrimidinyl]-2-pyridyl} sulfide
    —— N-hydroxy-N-[3-(methylsulfonyl)propyl]acetamide 1003599-76-5 C6H13NO4S
    N-hydroxy-N-[3-(methylsulfonyl)propyl]acetamide
    —— 3,3,5,5-tetramethyl-3,5-dihydro-4H-pyrazole-4-thione S-oxide 65927-19-7 C7H12N2OS
    3,3,5,5-tetramethyl-3,5-dihydro-4H-pyrazole-4-thione S-oxide
    —— Bisaldicarb sulfide 51717-80-7 C14H26N4O4S3
    Bisaldicarb sulfide
    —— 2-(vinylsulfonyl)acetic acid 20854-29-9 C4H6O4S
    2-(vinylsulfonyl)acetic acid
    —— Trimethyl-3,4,4-cyclopenten-2-thion 30221-53-5 C8H12S
    Trimethyl-3,4,4-cyclopenten-2-thion
    —— 2.7-Diaza-phenothiazin 262-01-1 C10H7N3S
    2.7-Diaza-phenothiazin
    —— 1,1,3,3,7,7-hexamethyl-8-oxo-8λ<sup>4</sup>-thia-5,6-diaza-spiro[3.4]oct-5-en-2-one 39257-47-1 C11H18N2O2S
    1,1,3,3,7,7-hexamethyl-8-oxo-8λ<sup>4</sup>-thia-5,6-diaza-spiro[3.4]oct-5-en-2-one
    —— 3,3,6,6,9,9-hexamethyl-4-thia-1,2,7,8-tetraaza-spiro[4.4]nona-1,7-diene 4-oxide 65927-20-0 C10H18N4OS
    3,3,6,6,9,9-hexamethyl-4-thia-1,2,7,8-tetraaza-spiro[4.4]nona-1,7-diene 4-oxide
    —— 2-Vinylsulfonyl-essigsaeure-aethylester 20854-28-8 C6H10O4S
    2-Vinylsulfonyl-essigsaeure-aethylester
    —— 2-chloromethyl-1,3-dithiepane 54237-86-4 C6H11ClS2
    2-chloromethyl-1,3-dithiepane
    —— N-Acetyl-2-vinyl-sulfonyl-aethylamin 20854-27-7 C6H11NO3S
    N-Acetyl-2-vinyl-sulfonyl-aethylamin
    —— 10-Methyl-9-oxo-7-thia-2,10-diazatricyclo[9.4.0.02,6]pentadeca-1(15),3,5,11,13-pentaene-5-carbaldehyde 123839-81-6 C14H12N2O2S
    10-Methyl-9-oxo-7-thia-2,10-diazatricyclo[9.4.0.02,6]pentadeca-1(15),3,5,11,13-pentaene-5-carbaldehyde
    —— 3-Bromo-10-methyl-7-thia-2,10-diazatricyclo[9.4.0.02,6]pentadeca-1(15),3,5,11,13-pentaen-9-one 123839-79-2 C13H11BrN2OS
    3-Bromo-10-methyl-7-thia-2,10-diazatricyclo[9.4.0.02,6]pentadeca-1(15),3,5,11,13-pentaen-9-one
    —— 3-[(Dimethylamino)methyl]-10-methyl-7-thia-2,10-diazatricyclo[9.4.0.02,6]pentadeca-1(15),3,5,11,13-pentaen-9-one 123839-80-5 C16H19N3OS
    3-[(Dimethylamino)methyl]-10-methyl-7-thia-2,10-diazatricyclo[9.4.0.02,6]pentadeca-1(15),3,5,11,13-pentaen-9-one
    —— 5,6-Dihydro-6-oxopyrrolo<1,2-a><3,1,6>benzothiadiazocine 99472-66-9 C12H10N2OS
    5,6-Dihydro-6-oxopyrrolo<1,2-a><3,1,6>benzothiadiazocine
    —— (2-phenylsulfanyl-4-trimethylsilylpyridin-3-yl) N,N-diethylcarbamate 151831-18-4 C19H26N2O2SSi
    (2-phenylsulfanyl-4-trimethylsilylpyridin-3-yl) N,N-diethylcarbamate
    —— 6-methoxy-2-methyl-4-phenylthiopyridazin-3(2H)-one 134428-68-5 C12H12N2O2S
    6-methoxy-2-methyl-4-phenylthiopyridazin-3(2H)-one
    —— N-cyclohexyl-4-(4-(3-(3-(trifluoromethyl)phenyl)thioureido)phenylthio)picolinamide 1395063-34-9 C26H25F3N4OS2
    N-cyclohexyl-4-(4-(3-(3-(trifluoromethyl)phenyl)thioureido)phenylthio)picolinamide
    —— 4-(4-(3-(4-chlorophenyl)thioureido)phenylthio)-N-cyclohexylpicolinamide 1395063-37-2 C25H25ClN4OS2
    4-(4-(3-(4-chlorophenyl)thioureido)phenylthio)-N-cyclohexylpicolinamide
    —— 6-methoxy-2-methyl-5-phenylthiopyridazin-3(2H)-one 134428-70-9 C12H12N2O2S
    6-methoxy-2-methyl-5-phenylthiopyridazin-3(2H)-one
    —— 4-(4-(3-(4-chloro-3-(trifluoromethyl)phenyl)thioureido)phenylthio)-N-cyclohexylpicolinamide 1395063-35-0 C26H24ClF3N4OS2
    4-(4-(3-(4-chloro-3-(trifluoromethyl)phenyl)thioureido)phenylthio)-N-cyclohexylpicolinamide
    —— 5,6-Dihydro-7-methyl-6-oxopyrrolo<1,2-a><3,1,6>benzothiadiazocine 99472-70-5 C13H12N2OS
    5,6-Dihydro-7-methyl-6-oxopyrrolo<1,2-a><3,1,6>benzothiadiazocine
    —— 2-methyl-2-(p-tolylthio)propanoic acid 58076-38-3 C11H14O2S
    2-methyl-2-(p-tolylthio)propanoic acid
    —— 2-[(E)-prop-1-enyl]-2-propyl-1,3-oxathiane 141246-39-1 C10H18OS
    2-[(E)-prop-1-enyl]-2-propyl-1,3-oxathiane
    —— 2-butyl-2-[(E)-prop-1-enyl]-1,3-oxathiane 141246-40-4 C11H20OS
    2-butyl-2-[(E)-prop-1-enyl]-1,3-oxathiane
    —— N,N-Diethyl-4-(phenylthio)picolinamide 141811-99-6 C16H18N2OS
    N,N-Diethyl-4-(phenylthio)picolinamide
    —— α-m-Tolylmercapto-isobuttersaeure 71173-08-5 C11H14O2S
    α-m-Tolylmercapto-isobuttersaeure
    —— α-o-Tolylmercapto-isobuttersaeure 76912-01-1 C11H14O2S
    α-o-Tolylmercapto-isobuttersaeure
    —— 4-[2-[6-(phenylthio)purin-9-yl]ethoxy]benzaldehyde 718639-79-3 C20H16N4O2S
    4-[2-[6-(phenylthio)purin-9-yl]ethoxy]benzaldehyde
    —— 2-[6-(phenylthio)purin-9-yl]ethanol 718639-75-9 C13H12N4OS
    2-[6-(phenylthio)purin-9-yl]ethanol
    —— Methyl (3-oxocyclopentyl)(phenylsulfanyl)acetate 125442-80-0 C14H16O3S
    Methyl (3-oxocyclopentyl)(phenylsulfanyl)acetate
    —— 12-(1''-Ethoxyethoxy)-1-[1'-(phenylsulfanyl)cyclohexyl]dodecan-1-ol 253152-10-2 C28H48O3S
    12-(1''-Ethoxyethoxy)-1-[1'-(phenylsulfanyl)cyclohexyl]dodecan-1-ol
    —— 3-Brom-1-adamanthiol 61065-74-5 C10H15BrS
    3-Brom-1-adamanthiol
    —— N-cyclopropyl-4-(4-(3-(3-(trifluoromethyl)phenyl)thioureido)phenylthio)picolinamide 1395063-38-3 C23H19F3N4OS2
    N-cyclopropyl-4-(4-(3-(3-(trifluoromethyl)phenyl)thioureido)phenylthio)picolinamide
    —— 2-methoxy-1,1'-di-p-tolylthio-octane 91191-99-0 C23H32OS2
    2-methoxy-1,1'-di-p-tolylthio-octane