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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-Chloro-2-[(2-chlorophenyl)thio]benzoic acid 5101-46-2 C13H8Cl2O2S
    5-Chloro-2-[(2-chlorophenyl)thio]benzoic acid
    —— 5-Chloro-2-(dodecylthio)benzenamine 16423-55-5 C18H30ClNS
    5-Chloro-2-(dodecylthio)benzenamine
    —— 8-(6-bromo-benzo[1,3]dioxol-5-ylsulfanyl)-9-phenethyl-1,9-dihydro-purin-6-one 958014-14-7 C20H15BrN4O3S
    8-(6-bromo-benzo[1,3]dioxol-5-ylsulfanyl)-9-phenethyl-1,9-dihydro-purin-6-one
    —— 8-(benzo[1,3]dioxol-5-ylsulfanyl)-9-phenethyl-1,9-dihydro-purin-6-one 958014-12-5 C20H16N4O3S
    8-(benzo[1,3]dioxol-5-ylsulfanyl)-9-phenethyl-1,9-dihydro-purin-6-one
    —— 8-(2,5-Dimethoxyphenyl)sulfanyl-9-ethenylpurin-6-amine 958020-38-7 C15H15N5O2S
    8-(2,5-Dimethoxyphenyl)sulfanyl-9-ethenylpurin-6-amine
    —— 4-[2-(3,5-Dioxo-1,2-diphenylpyrazolidin-4-ylidene)-4,8-dihydroxy-[1,3]dithiolo[4,5-f][1,3]benzodithiol-6-ylidene]-1,2-diphenylpyrazolidine-3,5-dione 1116390-72-7 C38H22N4O6S4
    4-[2-(3,5-Dioxo-1,2-diphenylpyrazolidin-4-ylidene)-4,8-dihydroxy-[1,3]dithiolo[4,5-f][1,3]benzodithiol-6-ylidene]-1,2-diphenylpyrazolidine-3,5-dione
    —— O-tert-Butyl dimethylcarbamothioate 919477-06-8 C7H15NOS
    O-tert-Butyl dimethylcarbamothioate
    —— Butanoic acid, 4-[(2,4-dimethylphenyl)thio]-, hydrazide 1344046-15-6 C12H18N2OS
    Butanoic acid, 4-[(2,4-dimethylphenyl)thio]-, hydrazide
    —— 3-fluoro-5-(1-methylpiperidin-4-ylsulfanyl)phenylamine 790671-33-9 C12H17FN2S
    3-fluoro-5-(1-methylpiperidin-4-ylsulfanyl)phenylamine
    —— 1-(4-bromo-phenyl)-2-(2-fluoro-phenyl)-4-methylsulfanyl-6-oxo-1,6-dihydro-pyrimidine-5-carbonitrile 885619-00-1 C18H11BrFN3OS
    1-(4-bromo-phenyl)-2-(2-fluoro-phenyl)-4-methylsulfanyl-6-oxo-1,6-dihydro-pyrimidine-5-carbonitrile
    —— 5,6-dihydro-2H-thiazolo[2,3-c][1,2,4]triazol-3-one 1182359-48-3 C4H5N3OS
    5,6-dihydro-2H-thiazolo[2,3-c][1,2,4]triazol-3-one
    —— 3-(4-cyclohexylamino-2-methylsulfanyl-pyrimidin-5-yl)-3-oxo-propionic acid ethyl ester 1192132-86-7 C16H23N3O3S
    3-(4-cyclohexylamino-2-methylsulfanyl-pyrimidin-5-yl)-3-oxo-propionic acid ethyl ester
    —— N-(5-cyano-2-methylsulfanyl-pyrimidin-4-yl)-N-cyclobutyl-acetamide 1192132-94-7 C12H14N4OS
    N-(5-cyano-2-methylsulfanyl-pyrimidin-4-yl)-N-cyclobutyl-acetamide
    —— 4-[5-(5-methoxy-2-methylsulfanyl-pyrimidin-4-yl)thiophen-2-yl]-2-methylbutan-2-ol 778646-49-4 C15H20N2O2S2
    4-[5-(5-methoxy-2-methylsulfanyl-pyrimidin-4-yl)thiophen-2-yl]-2-methylbutan-2-ol
    —— (E)-4-[5-(2-methylsulfanylpyrimidin-4-yl)-thiophen-2-yl]-but-3-en-2-ol 778646-55-2 C13H14N2OS2
    (E)-4-[5-(2-methylsulfanylpyrimidin-4-yl)-thiophen-2-yl]-but-3-en-2-ol
    —— 5-Chloro-2-(methylthio)-3-nitropyridine 886373-50-8 C6H5ClN2O2S
    5-Chloro-2-(methylthio)-3-nitropyridine
    —— tert-butyl α-(methylsulphonyl)acrylate 73017-59-1 C8H14O4S
    tert-butyl α-(methylsulphonyl)acrylate
    —— 2-(2,2-diethoxy-ethylsulfanyl)-3<i>H</i>-pyrimidin-4-one 34662-60-7 C10H16N2O3S
    2-(2,2-diethoxy-ethylsulfanyl)-3<i>H</i>-pyrimidin-4-one
    —— 3-(1-chloro-2-cyclopropylethyl)-5-[(cyclopropylmethyl)thio]-4-methyl-4H-1,2,4-triazole 917383-09-6 C12H18ClN3S
    3-(1-chloro-2-cyclopropylethyl)-5-[(cyclopropylmethyl)thio]-4-methyl-4H-1,2,4-triazole
    —— 2-cyclopropyl-1-{5-[(cyclopropylmethyl)thio]-4-methyl-4H-1,2,4-triazol-3-yl}ethanone 917383-07-4 C12H17N3OS
    2-cyclopropyl-1-{5-[(cyclopropylmethyl)thio]-4-methyl-4H-1,2,4-triazol-3-yl}ethanone
    —— N,N-dimethyl-2-(methylsulfinyl)ethylamine 76429-58-8 C5H13NOS
    N,N-dimethyl-2-(methylsulfinyl)ethylamine
    —— 3-methylthio-2-[4-(4.4,5,5-tetramethyl(1,3,2-dioxaborolan-2-yl))phenyl]thiophene 851198-99-7 C17H21BO2S2
    3-methylthio-2-[4-(4.4,5,5-tetramethyl(1,3,2-dioxaborolan-2-yl))phenyl]thiophene
    —— acetic acid-[4-(4-amino-3-methoxy-phenylsulfanyl)-anilide] 861061-44-1 C15H16N2O2S
    acetic acid-[4-(4-amino-3-methoxy-phenylsulfanyl)-anilide]
    —— 4-(3-(benzyloxy)phenylthio)-2-chloroaniline 1007165-68-5 C19H16ClNOS
    4-(3-(benzyloxy)phenylthio)-2-chloroaniline
    —— 2(1H)-Pyridinone,1-[4-(methylthio)phenyl]-5-(trifluoromethyl)- 1198411-43-6 C13H10F3NOS
    2(1H)-Pyridinone,1-[4-(methylthio)phenyl]-5-(trifluoromethyl)-
    —— 1,2,3-Thiadiazol-5-amine, 4-[(4-pyrimidinylthio)methyl]- 1343062-16-7 C7H7N5S2
    1,2,3-Thiadiazol-5-amine, 4-[(4-pyrimidinylthio)methyl]-
    —— [2-chloro-4-(3-ethylphenylthio)phenyl]acetaldehyde 1006727-32-7 C16H15ClOS
    [2-chloro-4-(3-ethylphenylthio)phenyl]acetaldehyde
    —— S-3-(difluoromethyl)phenyl dimethylcarbamothioate 1006729-46-9 C10H11F2NOS
    S-3-(difluoromethyl)phenyl dimethylcarbamothioate
    —— 4-Chloro-5-isopropyl-6-(methylthio)pyrimidine 1341321-06-9 C8H11ClN2S
    4-Chloro-5-isopropyl-6-(methylthio)pyrimidine
    —— 1,2-Dimethyl-13-oxa-3,23-dithiahexacyclo[14.7.0.02,10.04,9.011,15.017,22]tricosa-4,6,8,10,15,17,19,21-octaene-12,14-dione 129199-48-0 C22H14O3S2
    1,2-Dimethyl-13-oxa-3,23-dithiahexacyclo[14.7.0.02,10.04,9.011,15.017,22]tricosa-4,6,8,10,15,17,19,21-octaene-12,14-dione
    —— Benzenamine, 3-chloro-2-[[(3-methyl-1H-1,2,4-triazol-5-yl)thio]methyl]- 1339602-01-5 C10H11ClN4S
    Benzenamine, 3-chloro-2-[[(3-methyl-1H-1,2,4-triazol-5-yl)thio]methyl]-
    —— 2-chloro-4-(1-methyl-1H-imidazol-2-ylthio)pyridine 945988-49-8 C9H8ClN3S
    2-chloro-4-(1-methyl-1H-imidazol-2-ylthio)pyridine
    —— 4-[(3-Bromophenyl)sulfanyl]-2-chloropyridine 1339375-57-3 C11H7BrClNS
    4-[(3-Bromophenyl)sulfanyl]-2-chloropyridine
    —— tert-butyl N-[4-(4,4-difluoropiperidin-1-yl)-6-[[1-(fluoromethyl)-5-methyl-1,2,4-triazol-3-yl]sulfanylmethyl]pyridin-2-yl]-N-(2,2,2-trifluoroethyl)carbamate 1186690-88-9 C22H28F6N6O2S
    tert-butyl N-[4-(4,4-difluoropiperidin-1-yl)-6-[[1-(fluoromethyl)-5-methyl-1,2,4-triazol-3-yl]sulfanylmethyl]pyridin-2-yl]-N-(2,2,2-trifluoroethyl)carbamate
    —— tert-butyl [2,2-dimethyl-3-(methylsulfonyl)propyl]carbamate 947664-69-9 C11H23NO4S
    tert-butyl [2,2-dimethyl-3-(methylsulfonyl)propyl]carbamate
    —— 2-[(2,4-Difluorophenyl)thio]benzaldehyde 947188-18-3 C13H8F2OS
    2-[(2,4-Difluorophenyl)thio]benzaldehyde
    —— 4-(2-Methylphenyl)sulfanylbenzaldehyde 1343678-63-6 C14H12OS
    4-(2-Methylphenyl)sulfanylbenzaldehyde
    —— [2-(2-Chloro-phenylsulfanyl)-phenyl]-methanol 13420-54-7 C13H11ClOS
    [2-(2-Chloro-phenylsulfanyl)-phenyl]-methanol
    —— Benzenemethanol, I+/--methyl-4-(2-thienylthio)- 1340270-69-0 C12H12OS2
    Benzenemethanol, I+/--methyl-4-(2-thienylthio)-
    —— Benzenemethanol, 2-[(2-fluorophenyl)thio]-I+/--methyl- 1467314-66-4 C14H13FOS
    Benzenemethanol, 2-[(2-fluorophenyl)thio]-I+/--methyl-
    —— (2-Chloro-6-phenylsulfanyl-phenyl)-methanol 13420-65-0 C13H11ClOS
    (2-Chloro-6-phenylsulfanyl-phenyl)-methanol
    —— 2-(2-Thienylthio)-benzylalkohol 16269-64-0 C11H10OS2
    2-(2-Thienylthio)-benzylalkohol
    —— 1-(Bromomethyl)-2-[(4-chlorophenyl)thio]benzene 41932-37-0 C13H10BrClS
    1-(Bromomethyl)-2-[(4-chlorophenyl)thio]benzene
    —— Imidazo[2,1-b]thiazole-5-ethanamine, 6-[(3-methyl-1H-1,2,4-triazol-5-yl)thio]- 1478111-18-0 C10H12N6S2
    Imidazo[2,1-b]thiazole-5-ethanamine, 6-[(3-methyl-1H-1,2,4-triazol-5-yl)thio]-
    —— 1-(4-Bromophenyl)sulfanyl-3,3-dimethyl-2-pyrimidin-5-ylbutan-2-ol 1261279-63-3 C16H19BrN2OS
    1-(4-Bromophenyl)sulfanyl-3,3-dimethyl-2-pyrimidin-5-ylbutan-2-ol
    —— 2-[[6-(difluoromethoxy)-1H-benzimidazol-2-yl]sulfanyl]-1,3-thiazole-4-carboxylic acid 1149756-94-4 C12H7F2N3O3S2
    2-[[6-(difluoromethoxy)-1H-benzimidazol-2-yl]sulfanyl]-1,3-thiazole-4-carboxylic acid
    —— 1-(dibenzotetrathiafulvalene-2-yl)ethylamine 1181734-36-0 C16H13NS4
    1-(dibenzotetrathiafulvalene-2-yl)ethylamine
    —— 2-(4-Methylsulfonylphenylthio)-benzylalkohol 16185-14-1 C14H14O3S2
    2-(4-Methylsulfonylphenylthio)-benzylalkohol
    —— [2-(3-Chlorophenyl)sulfanylphenyl]methanol 13420-59-2 C13H11ClOS
    [2-(3-Chlorophenyl)sulfanylphenyl]methanol
    —— 2-Methyl-1-(trifluoromethanesulfonyl)propane 61794-41-0 C5H9F3O2S
    2-Methyl-1-(trifluoromethanesulfonyl)propane