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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N,N-diethyl-2-[(Z)-[(5-ethyl-1,3-thiazol-2-yl)-[3-(trifluoromethylsulfanyl)phenyl]methylidene]amino]oxypropan-1-amine;hydron;chloride —— C20H27ClF3N3OS2
    N,N-diethyl-2-[(Z)-[(5-ethyl-1,3-thiazol-2-yl)-[3-(trifluoromethylsulfanyl)phenyl]methylidene]amino]oxypropan-1-amine;hydron;chloride
    —— 1-methyl-5-(3-cyclohexylcarbonylpropyl)thio-1,2,3,4-tetrazole 80087-21-4 C12H20N4OS
    1-methyl-5-(3-cyclohexylcarbonylpropyl)thio-1,2,3,4-tetrazole
    —— 5-<2-Amino-phenylmercapto>-4-chlor-3(2H)-pyridazinon 2843-05-2 C10H8ClN3OS
    5-<2-Amino-phenylmercapto>-4-chlor-3(2H)-pyridazinon
    —— 12-mercapto-1-dodecanol 131215-93-5 C12H26OS
    12-mercapto-1-dodecanol
    —— 3-(3-Phenylsulfanylpropyl)cyclohexan-1-one 133188-97-3 C15H20OS
    3-(3-Phenylsulfanylpropyl)cyclohexan-1-one
    —— (2R)-4,4-bis(ethylthio)oct-5-yn-2-ol 333347-46-9 C12H22OS2
    (2R)-4,4-bis(ethylthio)oct-5-yn-2-ol
    —— 9-(3,5-dihydro-2H-1,4-benzodioxepin-3-yl)-6-phenylsulfanylpurine 1020397-72-1 C20H16N4O2S
    9-(3,5-dihydro-2H-1,4-benzodioxepin-3-yl)-6-phenylsulfanylpurine
    —— 9-(3,5-dihydro-2H-1,4-benzodioxepin-3-yl)-6-(4-fluorophenyl)sulfanylpurine 1020397-75-4 C20H15FN4O2S
    9-(3,5-dihydro-2H-1,4-benzodioxepin-3-yl)-6-(4-fluorophenyl)sulfanylpurine
    —— 7-(3,5-dihydro-2H-1,4-benzodioxepin-3-yl)-6-(4-fluorophenyl)sulfanylpurine 1020397-91-4 C20H15FN4O2S
    7-(3,5-dihydro-2H-1,4-benzodioxepin-3-yl)-6-(4-fluorophenyl)sulfanylpurine
    —— 6-(2,4-dichlorophenyl)sulfanyl-9-(3,5-dihydro-2H-1,4-benzodioxepin-3-yl)purine 1020397-68-5 C20H14Cl2N4O2S
    6-(2,4-dichlorophenyl)sulfanyl-9-(3,5-dihydro-2H-1,4-benzodioxepin-3-yl)purine
    —— 6-(2,4-dichlorophenyl)sulfanyl-7-(3,5-dihydro-2H-1,4-benzodioxepin-3-yl)purine 1020397-84-5 C20H14Cl2N4O2S
    6-(2,4-dichlorophenyl)sulfanyl-7-(3,5-dihydro-2H-1,4-benzodioxepin-3-yl)purine
    —— 7-(3,5-dihydro-2H-1,4-benzodioxepin-3-yl)-6-phenylsulfanylpurine 1020397-89-0 C20H16N4O2S
    7-(3,5-dihydro-2H-1,4-benzodioxepin-3-yl)-6-phenylsulfanylpurine
    —— (2R)-1-(2-but-1-ynyl-1,3-dithian-2-yl)propan-2-ol 333347-44-7 C11H18OS2
    (2R)-1-(2-but-1-ynyl-1,3-dithian-2-yl)propan-2-ol
    —— chlordimethylmercaptomethan 62999-77-3 C3H7ClS2
    chlordimethylmercaptomethan
    —— 1,1-bis-ethylsulfanyl-pent-2-yne 22230-76-8 C9H16S2
    1,1-bis-ethylsulfanyl-pent-2-yne
    —— 2-[(R)-2-(2-hydroxypropyl)-1,3-dithian-2-yl]phenol 475644-99-6 C13H18O2S2
    2-[(R)-2-(2-hydroxypropyl)-1,3-dithian-2-yl]phenol
    —— (2R)-4-(phenylthio)oct-5-yn-2-ol 333347-42-5 C14H18OS
    (2R)-4-(phenylthio)oct-5-yn-2-ol
    —— Aldicarb oxime sulfoxide 7635-32-7 C5H11NO2S
    Aldicarb oxime sulfoxide
    —— 3-(R)-2-hydroxypropylthiophenylboronic acid 956388-64-0 C9H13BO3S
    3-(R)-2-hydroxypropylthiophenylboronic acid
    —— 3-(3-mercaptopropyl)cyclohexene 63715-29-7 C9H16S
    3-(3-mercaptopropyl)cyclohexene
    —— 2,8-bis(trifluoromethyl)-4-quinolyl p-tolylsulphide 177092-30-7 C18H11F6NS
    2,8-bis(trifluoromethyl)-4-quinolyl p-tolylsulphide
    —— 2-(4-amino-5-cyano-6-methylsulfanyl-pyrimidin-2-yl)-1,1-diethyl-3-phenyl-isothiourea 72367-49-8 C17H20N6S2
    2-(4-amino-5-cyano-6-methylsulfanyl-pyrimidin-2-yl)-1,1-diethyl-3-phenyl-isothiourea
    —— N-(3-Chlorophenyl)-N'-(2-(6,7-dimethoxyquinolin-4-ylsulfanyl)thiazol-5-yl)urea 417715-39-0 C21H17ClN4O3S2
    N-(3-Chlorophenyl)-N'-(2-(6,7-dimethoxyquinolin-4-ylsulfanyl)thiazol-5-yl)urea
    —— 3-phenylmercapto-2-chloro-4,4-ethylenedioxycyclopent-2-en-1-one 677308-56-4 C13H11ClO3S
    3-phenylmercapto-2-chloro-4,4-ethylenedioxycyclopent-2-en-1-one
    —— 2-(3-bromophenylthio)-3-(3-(pyridin-2-yl)propoxy)pyridine 263390-88-1 C19H17BrN2OS
    2-(3-bromophenylthio)-3-(3-(pyridin-2-yl)propoxy)pyridine
    —— (+)-2,2-dicyclohexyl-5-[(dimethylamino)methyl]-1,3-oxathiolane methiodide 101990-82-3 C19H36NOS*I
    (+)-2,2-dicyclohexyl-5-[(dimethylamino)methyl]-1,3-oxathiolane methiodide
    —— 4,4'-di(3-methyl)pyridyl sulfide 78285-58-2 C12H12N2S
    4,4'-di(3-methyl)pyridyl sulfide
    —— 2,3,2',3'-Tetramethyl-diphenylsulfid 1215-72-1 C16H18S
    2,3,2',3'-Tetramethyl-diphenylsulfid
    —— bis(indol-3-yl) sulfide 1484-18-0 C16H12N2S
    bis(indol-3-yl) sulfide
    —— 5-phenylsulfanyl-2-tert-butyl-4(3H)-quinazolinone 733017-17-9 C18H18N2OS
    5-phenylsulfanyl-2-tert-butyl-4(3H)-quinazolinone
    —— 5-phenylsulfanyl-2-tert-butylquinazoline 766548-35-0 C18H18N2S
    5-phenylsulfanyl-2-tert-butylquinazoline
    —— 1-[(E)-(4-methylsulfanylphenyl)methylideneamino]-3-prop-2-enylthiourea 1608505-30-1 C12H15N3S2
    1-[(E)-(4-methylsulfanylphenyl)methylideneamino]-3-prop-2-enylthiourea
    —— 2-methylsulfanyl-cyclopentylamine 98278-54-7 C6H13NS
    2-methylsulfanyl-cyclopentylamine
    —— (3R,5R)-trans-2,2-dicyclohexyl-5-<(dimethylamino)methyl>-1,3-oxathiolane 3-oxide methiodide 114882-86-9 C19H36NO2S*I
    (3R,5R)-trans-2,2-dicyclohexyl-5-<(dimethylamino)methyl>-1,3-oxathiolane 3-oxide methiodide
    —— 2,2-dicyclohexyl-2-hydroxy-N,N-dibutylthioacetamide 59408-48-9 C22H41NOS
    2,2-dicyclohexyl-2-hydroxy-N,N-dibutylthioacetamide
    —— 3-(3,4,5-trimethoxy-phenylsulfanyl)-1H-indol-5-ol 939035-70-8 C17H17NO4S
    3-(3,4,5-trimethoxy-phenylsulfanyl)-1H-indol-5-ol
    —— (3S,5R)-cis-2,2-dicyclohexyl-5-<(dimethylamino)methyl>-1,3-oxathiolane 3-oxide methiodide 114882-87-0 C19H36NO2S*I
    (3S,5R)-cis-2,2-dicyclohexyl-5-<(dimethylamino)methyl>-1,3-oxathiolane 3-oxide methiodide
    —— 2,2-dicyclohexyl-5-<(dimethylamino)methyl>-1,3-oxathiolane 114882-83-6 C18H33NOS
    2,2-dicyclohexyl-5-<(dimethylamino)methyl>-1,3-oxathiolane
    —— 2-amino-6-(benzothiazol-2-ylsulfanyl)-4-(indol-3-yl)-4H-chromene-3-carbonitrile 1257314-56-9 C25H16N4OS2
    2-amino-6-(benzothiazol-2-ylsulfanyl)-4-(indol-3-yl)-4H-chromene-3-carbonitrile
    —— 3-(2,4-dimethoxyphenylthio)-1H-indol-5-ol 1448175-26-5 C16H15NO3S
    3-(2,4-dimethoxyphenylthio)-1H-indol-5-ol
    —— 2-{[5-(Dodecylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl}acetic acid 128016-39-7 C16H28N2O2S3
    2-{[5-(Dodecylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl}acetic acid
    —— 2-n-Dodecylthio-4-chloromethyl-1,3,4-thiadiazole-5-thione 128016-44-4 C15H27ClN2S3
    2-n-Dodecylthio-4-chloromethyl-1,3,4-thiadiazole-5-thione
    —— N,N-Dimethyl-N-n-octyl-N-(2-dodecylthio-1,3,4-thiadiazole-5-thioethyl)ammonium Bromide 128016-46-6 Br*C26H52N3S3
    N,N-Dimethyl-N-n-octyl-N-(2-dodecylthio-1,3,4-thiadiazole-5-thioethyl)ammonium Bromide
    —— 2-<p-Hydroxy-phenylthio>-benzothiazol 3804-08-8 C13H9NOS2
    2-<p-Hydroxy-phenylthio>-benzothiazol
    —— 2-n-Dodecylthio-5-(β-dimethylaminoethyl)-1,3,4-thiadiazole 128016-47-7 C18H35N3S3
    2-n-Dodecylthio-5-(β-dimethylaminoethyl)-1,3,4-thiadiazole
    —— N-(2-Methyl-2-phenylthiopropyl)benzamide 141363-01-1 C17H19NOS
    N-(2-Methyl-2-phenylthiopropyl)benzamide
    —— 2-n-Dodecylthio-4-hydroxymethyl-1,3,4-thiadiazole-5-thione 128016-43-3 C15H28N2OS3
    2-n-Dodecylthio-4-hydroxymethyl-1,3,4-thiadiazole-5-thione
    —— 2-n-Dodecylthio-4-phenylthiomethyl-1,3,4-thiadiazole-5-thione 128016-45-5 C21H32N2S4
    2-n-Dodecylthio-4-phenylthiomethyl-1,3,4-thiadiazole-5-thione
    —— N,N-Dimethylthiocarbaminsaeure-S-1-hexen-3-ylester 39707-41-0 C9H17NOS
    N,N-Dimethylthiocarbaminsaeure-S-1-hexen-3-ylester
    —— 1-Methyl-mercapto-hexen-(2) 89795-39-1 C7H14S
    1-Methyl-mercapto-hexen-(2)