丁-3-烯-2-硫醇 | 5937-82-6

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醇
• 中文名称: 丁-3-烯-2-硫醇
• 英文名称: 3-butene-2-thiol
• 英文别名: but-3-ene-2-thiol；methyl-2 propene-1 thiol；2-Mercapto-but-3-en；Buten-(1)-thiol-(3)；3-Buten-2-thiol
• CAS: 5937-82-6
• 化学式: C₄H₈S
• 分子量: 88.1735
• InChiKey: FRBFUAKXOIGPDP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  5
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

安全信息

• 海关编码：
  2930909090

反应信息

• 作为反应物：
  描述：

  丁-3-烯-2-硫醇 在 双氧水 、 丙酮 作用下， 生成 ethyl-vinyl sulfoxide
  参考文献：
  名称：

  Reppe et al., Justus Liebigs Annalen der Chemie, 1956, vol. 601, p. 81,104

  摘要：

  DOI：
• 作为产物：
  描述：

  S-(1-methylallyl) S-methyl dithiocarbonate 在 C.I.酸性橙108 作用下， 生成 丁-3-烯-2-硫醇
  参考文献：
  名称：

  Harano,K.; Taguchi,T., Chemical and pharmaceutical bulletin, 1972, vol. 20, p. 2348 - 2356

  摘要：

  DOI：

文献信息

• Identification of Novel Aroma-Active Thiols in Pan-Roasted White Sesame Seeds
  作者：Hitoshi Tamura、Akira Fujita、Martin Steinhaus、Eisuke Takahisa、Hiroyuki Watanabe、Peter Schieberle

  DOI：10.1021/jf100623a

  日期：2010.6.23

  Screening for aroma-active compounds in an aroma distillate obtained from freshly pan-roasted sesame seeds by aroma extract dilution analysis revealed 32 odorants in the FD factor range of 2-2048, 29 of which could be identified. The highest FD factors were found for the coffee-like smelling 2-furfurylthiol, the caramel-like smelling 4-hydroxy-2,5-dimethyl-3(2H)-furanone, the coffee-like smelling 2-thenylthiol (thiophen-2-yl-methylthiol), and the clove-like smelling 2-methoxy-4-vinylphenol. In addition, 9 odor-active thiols with sulfurous, meaty, and/or catty, black-currant-like odors were identified for the first time in roasted sesame seeds. Among them, 2-methyl-1-propene-1-thiol, (Z)-3-methyl-1-butene-1-thiol, (E)-3-methyl-1-butene-1-thiol, (Z)-2-methyl-1-butene-1-thiol, (E)-2-methyl-1-butene-1-thiol, and 4-mercapto-3-hexanone were previously unknown as food constituents. Their structures were confirmed by comparing their mass spectra and retention indices as well as their sensory properties with those of synthesized reference compounds. The relatively unstable 1-alkene-1-thiols represent a new class of food odorants and are suggested as the key contributors to the characteristic, but quickly vanishing, aroma of freshly ground roasted sesame seeds.
• An improvement in syntheses of mercaptans via thiolesters
  作者：Tanezo Taguchi、Yoshimoto Kiyoshima、Osamu Komori、Masato Mori

  DOI：10.1016/s0040-4039(01)88473-2

  日期：——
• Thiosulfoxides. Intermediates in rearrangement and reduction of allylic disulfides
  作者：G. Hoefle、J. E. Baldwin

  DOI：10.1021/ja00752a073

  日期：1971.11
• Oxidation of vinyl sulphides
  申请人：IG FARBENINDUSTRIE AG

  公开号：US02163180A1

  公开（公告）日：1939-06-20
• DE635396
  申请人：——

  公开号：——

  公开（公告）日：——