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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-methylthiobis(2-acryloyloxyethyl)dithio-acetal benzene 199800-42-5 C18H22O4S3
    4-methylthiobis(2-acryloyloxyethyl)dithio-acetal benzene
    —— 4-[[4-Benzyl-5-(3-thienyl)-1,2,4-triazol-3-yl]sulfanylmethyl]pyridine 1012073-86-7 C19H16N4S2
    4-[[4-Benzyl-5-(3-thienyl)-1,2,4-triazol-3-yl]sulfanylmethyl]pyridine
    —— 2-chloro-3-methyl-2-methylsulfonylmethyl-2H-azirine 880497-05-2 C5H8ClNO2S
    2-chloro-3-methyl-2-methylsulfonylmethyl-2H-azirine
    —— 5-cyano-4-methylthio-2-phenyl-1,3-oxazine-6-thione 80532-88-3 C12H8N2OS2
    5-cyano-4-methylthio-2-phenyl-1,3-oxazine-6-thione
    —— 1-Carbamoyloxy-2-carbamoyloxymethyl-2-(4-methylmercapto-phenyl)-propan 96651-90-0 C13H18N2O4S
    1-Carbamoyloxy-2-carbamoyloxymethyl-2-(4-methylmercapto-phenyl)-propan
    —— 2-Hydroxymethyl-2-(4-methylmercapto-phenyl)-propan-1-ol 91968-79-5 C11H16O2S
    2-Hydroxymethyl-2-(4-methylmercapto-phenyl)-propan-1-ol
    —— 2-hydroxyethyl tridecafluorohexyl sulfide 113326-27-5 C8H5F13OS
    2-hydroxyethyl tridecafluorohexyl sulfide
    —— 2-chloroethyl tridecafluorohexyl sulfide 680187-80-8 C8H4ClF13S
    2-chloroethyl tridecafluorohexyl sulfide
    —— 1-Propyl-3-[4-[4-(trifluoromethyl)phenyl]sulfanylphenyl]urea 54457-23-7 C17H17F3N2OS
    1-Propyl-3-[4-[4-(trifluoromethyl)phenyl]sulfanylphenyl]urea
    —— 2-Hydroxy-1-isopropylamino-3-phenylmercapto-propan 21217-44-7 C12H19NOS
    2-Hydroxy-1-isopropylamino-3-phenylmercapto-propan
    —— 3-dimethylamino-1,4,2-benzodithiazine 1,1-dioxide 137552-03-5 C9H10N2O2S2
    3-dimethylamino-1,4,2-benzodithiazine 1,1-dioxide
    —— S-propan-2-yl N-methylcarbamothioate 39076-38-5 C5H11NOS
    S-propan-2-yl N-methylcarbamothioate
    —— N,N-dimethyl-4-hydroxy-2-(3-methoxyphenylthio)benzylamine 134987-22-7 C16H19NO2S
    N,N-dimethyl-4-hydroxy-2-(3-methoxyphenylthio)benzylamine
    —— (E)-7-azido-3-(phenylthio)-1,3-heptadiene 108782-19-0 C13H15N3S
    (E)-7-azido-3-(phenylthio)-1,3-heptadiene
    —— (2-methylsulfanyl-benzyl)-carbamic acid tert-butyl ester 866782-03-8 C13H19NO2S
    (2-methylsulfanyl-benzyl)-carbamic acid tert-butyl ester
    —— N,N-dimethyl-2-(3-methoxyphenylthio)-3-thenylamine 134478-46-9 C14H17NOS2
    N,N-dimethyl-2-(3-methoxyphenylthio)-3-thenylamine
    —— 2-(3-methoxyphenylthio)thiophene-3-carboxylic acid 134478-45-8 C12H10O3S2
    2-(3-methoxyphenylthio)thiophene-3-carboxylic acid
    —— Methyl 1-(2-acetyloxyethoxymethyl)-5-(3-methoxyphenyl)sulfanyl-1,2,4-triazole-3-carboxylate 1237741-58-0 C16H19N3O6S
    Methyl 1-(2-acetyloxyethoxymethyl)-5-(3-methoxyphenyl)sulfanyl-1,2,4-triazole-3-carboxylate
    —— N-[4-(3-Methoxyphenyl)thiophenyl] butanamide 244128-91-4 C17H19NO2S
    N-[4-(3-Methoxyphenyl)thiophenyl] butanamide
    —— 2-amino-8-(3-methoxyphenyl)sulfanyl-9-(propan-2-yloxymethyl)-1H-purin-6-one 1062530-54-4 C16H19N5O3S
    2-amino-8-(3-methoxyphenyl)sulfanyl-9-(propan-2-yloxymethyl)-1H-purin-6-one
    —— N-{2-[(3-methoxyphenyl)sulfanyl]benzyl}-N-methylamine 127926-82-3 C15H17NOS
    N-{2-[(3-methoxyphenyl)sulfanyl]benzyl}-N-methylamine
    —— S-Methyl 3,3-bis(methylsulfanyl)propanethioate 88640-31-7 C6H12OS3
    S-Methyl 3,3-bis(methylsulfanyl)propanethioate
    —— 4-chloro-5-((3-methoxyphenyl)thio)-7-((2-(trimethylsilyl)ethoxy)methyl)-7H-pyrrolo[2,3-d]pyrimidine 1605329-14-3 C19H24ClN3O2SSi
    4-chloro-5-((3-methoxyphenyl)thio)-7-((2-(trimethylsilyl)ethoxy)methyl)-7H-pyrrolo[2,3-d]pyrimidine
    —— 3-[2-[(Dipropylamino)methyl]phenyl]sulfanylphenol 127906-58-5 C19H25NOS
    3-[2-[(Dipropylamino)methyl]phenyl]sulfanylphenol
    —— N,N-dimethyl-4-(3-methoxyphenylthio)benzylamine 141358-03-4 C16H19NOS
    N,N-dimethyl-4-(3-methoxyphenylthio)benzylamine
    —— 5-[6-(3-Methoxyphenyl)sulfanyl-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]-1,3-thiazole 1428566-12-4 C15H11N5OS2
    5-[6-(3-Methoxyphenyl)sulfanyl-[1,2,4]triazolo[4,3-b]pyridazin-3-yl]-1,3-thiazole
    —— (S)-Ethyl 2-(6-hydroxy-2,3-dihydrobenzo[b]thiophen-3-yl)acetate 1022979-99-2 C12H14O3S
    (S)-Ethyl 2-(6-hydroxy-2,3-dihydrobenzo[b]thiophen-3-yl)acetate
    —— 3-[2-(Diethylaminomethyl)phenyl]sulfanylphenol 127906-55-2 C17H21NOS
    3-[2-(Diethylaminomethyl)phenyl]sulfanylphenol
    —— N,N-dimethyl-3-(3-methoxyphenylthio)-2-thenylamine 134478-44-7 C14H17NOS2
    N,N-dimethyl-3-(3-methoxyphenylthio)-2-thenylamine
    —— 5-Chlor-2-(3-methoxyphenylthio)-benzylchlorid 63186-38-9 C14H12Cl2OS
    5-Chlor-2-(3-methoxyphenylthio)-benzylchlorid
    —— 4-tert-Butyl-N-[5-(2-hydroxy-ethyl)-4-(3-methoxy-phenylsulfanyl)-isoxazol-3-yl]-benzenesulfonamide 302957-78-4 C22H26N2O5S2
    4-tert-Butyl-N-[5-(2-hydroxy-ethyl)-4-(3-methoxy-phenylsulfanyl)-isoxazol-3-yl]-benzenesulfonamide
    —— 1-(2-(3-methoxyphenylthio)phenyl)-2-propylamine 128958-98-5 C16H19NOS
    1-(2-(3-methoxyphenylthio)phenyl)-2-propylamine
    —— 2-(3-Methoxyphenylthio)-5-nitrobenzylalkohol 63186-35-6 C14H13NO4S
    2-(3-Methoxyphenylthio)-5-nitrobenzylalkohol
    —— [2-(3-Methoxyphenyl)sulfanylphenyl]methanamine 127905-93-5 C14H15NOS
    [2-(3-Methoxyphenyl)sulfanylphenyl]methanamine
    —— N,N-dimethyl-2-(3-hydroxyphenylthio)benzylamine 127906-18-7 C15H17NOS
    N,N-dimethyl-2-(3-hydroxyphenylthio)benzylamine
    —— N,N-dimethyl-4-(3-hydroxyphenylthio)benzylamine 141358-04-5 C15H17NOS
    N,N-dimethyl-4-(3-hydroxyphenylthio)benzylamine
    —— 3-[2-(Methylaminomethyl)phenyl]sulfanylphenol 127906-33-6 C14H15NOS
    3-[2-(Methylaminomethyl)phenyl]sulfanylphenol
    —— 2-(3-Methoxyphenyl)sulfanylbenzamide 127905-45-7 C14H13NO2S
    2-(3-Methoxyphenyl)sulfanylbenzamide
    —— 3-[2-(Aminomethyl)phenyl]sulfanylphenol 127906-44-9 C13H13NOS
    3-[2-(Aminomethyl)phenyl]sulfanylphenol
    —— N,N-diethyl-2-(3-methoxyphenyl)sulfanylbenzamide 127905-61-7 C18H21NO2S
    N,N-diethyl-2-(3-methoxyphenyl)sulfanylbenzamide
    —— 1-(2-(3-Methoxyphenylthio)phenyl)ethanol 127906-81-4 C15H16O2S
    1-(2-(3-Methoxyphenylthio)phenyl)ethanol
    —— N,N-Dimethyl-2-(3-methoxyphenylthio)benzylamine 127905-71-9 C16H19NOS
    N,N-Dimethyl-2-(3-methoxyphenylthio)benzylamine
    —— (2R)-2-amino-4-{2-chloro-4-[(3-methoxyphenyl)sulfanyl]phenyl}-2-methyl-butan-1-ol 1618092-58-2 C18H22ClNO2S
    (2R)-2-amino-4-{2-chloro-4-[(3-methoxyphenyl)sulfanyl]phenyl}-2-methyl-butan-1-ol
    —— 4-((3-methoxyphenyl)thio)aniline 747383-57-9 C13H13NOS
    4-((3-methoxyphenyl)thio)aniline
    —— (+/-)-N,N-dimethyl-1-(2-(3-hydroxyphenylthio)phenyl)ethylamine 127906-72-3 C16H19NOS
    (+/-)-N,N-dimethyl-1-(2-(3-hydroxyphenylthio)phenyl)ethylamine
    —— 3-cyano-N-(2,4-dimethoxybenzyl)-4-[(3-methoxyphenyl)thio]-N-1,2,4-thiadiazol-5-ylbenzenesulfonamide 1354917-73-9 C25H22N4O5S3
    3-cyano-N-(2,4-dimethoxybenzyl)-4-[(3-methoxyphenyl)thio]-N-1,2,4-thiadiazol-5-ylbenzenesulfonamide
    —— 2,2,2-Trifluoro-1-[4-(3-methoxyphenyl)sulfanyl-3-(2,2,2-trifluoroacetyl)naphthalen-1-yl]ethanone 142991-53-5 C21H12F6O3S
    2,2,2-Trifluoro-1-[4-(3-methoxyphenyl)sulfanyl-3-(2,2,2-trifluoroacetyl)naphthalen-1-yl]ethanone
    —— 2,4-diamino-5-methyl-6-(3'-methoxyphenylsulfanyl)furo[2,3-d]pyrimidine 1217309-59-5 C14H14N4O2S
    2,4-diamino-5-methyl-6-(3'-methoxyphenylsulfanyl)furo[2,3-d]pyrimidine
    —— 2-[1-(phenylsulfanyl)cyclopropyl]epoxide 1026510-76-8 C11H12OS
    2-[1-(phenylsulfanyl)cyclopropyl]epoxide
    —— 4-Chloro-3-(3-methoxylphenylthio)-9H-thioxanthen-9-one 1372152-33-4 C20H13ClO2S2
    4-Chloro-3-(3-methoxylphenylthio)-9H-thioxanthen-9-one