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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-Cyclooctylmethyl-2-(N-cyclooctylmethyl-carbamimidoylmethyldisulfanyl)-acetamidine 90379-44-5 C22H42N4S2
    N-Cyclooctylmethyl-2-(N-cyclooctylmethyl-carbamimidoylmethyldisulfanyl)-acetamidine
    —— 6-(2-fluorophenylthio)-8-methyl-2-(tetrahydro-2H-pyran-4-ylamino)pyrido[2,3-d]pyrimidin-7(8H)-one 1280218-06-5 C19H19FN4O2S
    6-(2-fluorophenylthio)-8-methyl-2-(tetrahydro-2H-pyran-4-ylamino)pyrido[2,3-d]pyrimidin-7(8H)-one
    —— S,S'-Bis(γ-triethylsilyl-propyl)disulfid 55743-44-7 C18H42S2Si2
    S,S'-Bis(γ-triethylsilyl-propyl)disulfid
    —— 8-(6-(4-(dimethylamino)phenyl)benzo[d][1,3]dioxol-5-ylthio)-9-(3-(isopropylamino)propyl)-9H-purin-6-amine 1289543-77-6 C26H31N7O2S
    8-(6-(4-(dimethylamino)phenyl)benzo[d][1,3]dioxol-5-ylthio)-9-(3-(isopropylamino)propyl)-9H-purin-6-amine
    —— (4-(cycloheptylamino)-2-(methylthio)pyrimidin-5-yl)methanol 211247-47-1 C13H21N3OS
    (4-(cycloheptylamino)-2-(methylthio)pyrimidin-5-yl)methanol
    —— 2-(trimethylsilyl)-1,3-benzodithiole 175167-20-1 C10H14S2Si
    2-(trimethylsilyl)-1,3-benzodithiole
    —— 2-cyclohexylmethyl-2-isopropyl-1,3-benzodithiole-1,1,3,3-tetraoxide 121183-90-2 C17H24O4S2
    2-cyclohexylmethyl-2-isopropyl-1,3-benzodithiole-1,1,3,3-tetraoxide
    —— 2,2-bis(dimethylsilyl)-1,3-benzodithiole 377726-34-6 C11H18S2Si2
    2,2-bis(dimethylsilyl)-1,3-benzodithiole
    —— 2-methylsulfanyl-4-(tetrahydro-2H-pyran-4-ylamino)pyrimidine-5-carbaldehyde 933795-01-8 C11H15N3O2S
    2-methylsulfanyl-4-(tetrahydro-2H-pyran-4-ylamino)pyrimidine-5-carbaldehyde
    —— (4-isopropylamino-2-methylsulfanyl-pyridine-5-yl)-methanol 321690-72-6 C9H15N3OS
    (4-isopropylamino-2-methylsulfanyl-pyridine-5-yl)-methanol
    —— 2-dimethylsilyl-1,3-benzodithiole 377726-32-4 C9H12S2Si
    2-dimethylsilyl-1,3-benzodithiole
    —— 6-(2-fluorophenylsulfanyl)-8-methyl-2-methylsulfanyl-8H-pyrido[2,3-d]pyrimidin-7-one 1280218-23-6 C15H12FN3OS2
    6-(2-fluorophenylsulfanyl)-8-methyl-2-methylsulfanyl-8H-pyrido[2,3-d]pyrimidin-7-one
    —— 8-methyl-2-(methylthio)-6-(phenylthio) pyrido[2,3-d]pyrimidin-7(8H)-one 449808-54-2 C15H13N3OS2
    8-methyl-2-(methylthio)-6-(phenylthio) pyrido[2,3-d]pyrimidin-7(8H)-one
    —— 3-methyl-2-phenylsulfanylbut-2-enal 89005-38-9 C11H12OS
    3-methyl-2-phenylsulfanylbut-2-enal
    —— N-[3,4-dihydro-1,5-benzoxathiepin-3-yl]-(R)-3-methanesulfonyloxy-2-(R)-methyl-propionamide 1169760-42-2 C14H19NO5S2
    N-[3,4-dihydro-1,5-benzoxathiepin-3-yl]-(R)-3-methanesulfonyloxy-2-(R)-methyl-propionamide
    —— 3-[1-Phenylsulfanyl-meth-(E)-ylidene]-5-propyl-dihydro-furan-2-one 87531-42-8 C14H16O2S
    3-[1-Phenylsulfanyl-meth-(E)-ylidene]-5-propyl-dihydro-furan-2-one
    —— 2-([2-(4-Chlorophenyl)-1,3-thiazol-4-yl]methylsulfanyl)-6-(3-hydroxyazetidin-1-yl)-4-(1,3-thiazol-5-yl)pyridine-3,5-dicarbonitrile 1187542-99-9 C23H15ClN6OS3
    2-([2-(4-Chlorophenyl)-1,3-thiazol-4-yl]methylsulfanyl)-6-(3-hydroxyazetidin-1-yl)-4-(1,3-thiazol-5-yl)pyridine-3,5-dicarbonitrile
    —— 2,2-dimethyl-4-(<2-<4-(tetrahydropyran-2-yloxy)butyl>-1,3-dithian-2-yl>methyl)-1,3-dioxane 152882-72-9 C20H36O4S2
    2,2-dimethyl-4-(<2-<4-(tetrahydropyran-2-yloxy)butyl>-1,3-dithian-2-yl>methyl)-1,3-dioxane
    —— 4-<2-(4-hydroxybutyl)-1,3-dithian-2-yl>butane-1,3-diol 152754-98-8 C12H24O3S2
    4-<2-(4-hydroxybutyl)-1,3-dithian-2-yl>butane-1,3-diol
    —— (1-(4-bromophenyl)but-3-enyl)(phenyl)sulfane 1382802-10-9 C16H15BrS
    (1-(4-bromophenyl)but-3-enyl)(phenyl)sulfane
    —— 2-Phenethyl-3-phenylsulfanyl-furan 105621-14-5 C18H16OS
    2-Phenethyl-3-phenylsulfanyl-furan
    —— (E)-3-(1-(methoxymethyl)-2-(phenylthio)-1H-imidazol-5-yl)acrylamide 1309961-46-3 C14H15N3O2S
    (E)-3-(1-(methoxymethyl)-2-(phenylthio)-1H-imidazol-5-yl)acrylamide
    —— 2-(phenylthio)-4-methoxybenzo[d]thiazole 1448856-32-3 C14H11NOS2
    2-(phenylthio)-4-methoxybenzo[d]thiazole
    —— spiro<bicyclo<3.2.0>hept<3>en-6,2'-<1,3>dithiolan>-7-on 56380-60-0 C9H10OS2
    spiro<bicyclo<3.2.0>hept<3>en-6,2'-<1,3>dithiolan>-7-on
    —— 3,5-difluoro-2-hydrxyphenyl methyl sulfide 210350-67-7 C7H6F2OS
    3,5-difluoro-2-hydrxyphenyl methyl sulfide
    —— 1,3-Dimethyl-2-methylsulfanyl-cyclopentene 86049-98-1 C8H14S
    1,3-Dimethyl-2-methylsulfanyl-cyclopentene
    —— 3,5-bis(phenylthio)acetanilide 131195-89-6 C20H17NOS2
    3,5-bis(phenylthio)acetanilide
    —— 5-(pyridin-2-ylthio)pyridin-2-amine 68559-45-5 C10H9N3S
    5-(pyridin-2-ylthio)pyridin-2-amine
    —— N-ethylacetothioacetamide 69583-04-6 C6H11NOS
    N-ethylacetothioacetamide
    —— 5-(4-chloro-phenylsulfanyl)-pyridin-2-ylamine 64064-93-3 C11H9ClN2S
    5-(4-chloro-phenylsulfanyl)-pyridin-2-ylamine
    —— (R)-1-(2-methyl-2-oxiranylmethyl)-4-nitro-2-(4-nitrophenylthio)imidazole 683276-51-9 C13H12N4O5S
    (R)-1-(2-methyl-2-oxiranylmethyl)-4-nitro-2-(4-nitrophenylthio)imidazole
    —— 2-(4-Phenylsulfanyl-phenylamino)-ethanol 51026-08-5 C14H15NOS
    2-(4-Phenylsulfanyl-phenylamino)-ethanol
    —— 6,8-Dimethyl-3-phenyl-1H,8H-pyrimido[4,5-e][1,3,4]thiadiazine-5,7-dione 99261-94-6 C13H12N4O2S
    6,8-Dimethyl-3-phenyl-1H,8H-pyrimido[4,5-e][1,3,4]thiadiazine-5,7-dione
    —— tert.-Butyl-<1,3-dimethyl-but-2-enyl>-disulfid 91009-93-7 C10H20S2
    tert.-Butyl-<1,3-dimethyl-but-2-enyl>-disulfid
    —— 1-n-Butylthio-2-methyl-aethin 18212-33-4 C7H12S
    1-n-Butylthio-2-methyl-aethin
    —— 4-nitro-2-(4-nitrophenylthio)-imidazole 683276-48-4 C9H6N4O4S
    4-nitro-2-(4-nitrophenylthio)-imidazole
    —— Pyridinium, 1,1'-(oxydimethylene)bis(4-(methylthio)-, dichloride 51276-93-8 C14H18Cl2N2OS2
    Pyridinium, 1,1'-(oxydimethylene)bis(4-(methylthio)-, dichloride
    —— 1-[4-(Phenylsulfanyl)but-1-EN-1-YL]pyrrolidine 113541-81-4 C14H19NS
    1-[4-(Phenylsulfanyl)but-1-EN-1-YL]pyrrolidine
    —— 3,7-dibromo-2H,6H-benzo<1,2-b:4,5-b'>dithiophene-2,6-dione 87522-80-3 C10H2Br2O2S2
    3,7-dibromo-2H,6H-benzo<1,2-b:4,5-b'>dithiophene-2,6-dione
    —— 3-Methyl-5-methylsulfanyl-1,3,4-thiadiazol-3-ium-2-amine;iodide —— C4H8IN3S2
    3-Methyl-5-methylsulfanyl-1,3,4-thiadiazol-3-ium-2-amine;iodide
    —— 1-Methoxy-1,5-bis-phenylsulfanyl-pentan-2-one 89171-39-1 C18H20O2S2
    1-Methoxy-1,5-bis-phenylsulfanyl-pentan-2-one
    —— 1-Methoxy-6-methyl-1-phenylsulfanyl-hept-5-en-2-one 89171-38-0 C15H20O2S
    1-Methoxy-6-methyl-1-phenylsulfanyl-hept-5-en-2-one
    —— (R)-2-Phenylsulfanyl-propionaldehyde 125660-37-9 C9H10OS
    (R)-2-Phenylsulfanyl-propionaldehyde
    —— 1-[1-Butylsulfanyl-meth-(E)-ylidene]-3-methyl-2-methylene-cyclohexane 65839-84-1 C13H22S
    1-[1-Butylsulfanyl-meth-(E)-ylidene]-3-methyl-2-methylene-cyclohexane
    —— 5-chloro-2,3-dihydro-3-phenylbenzo[b]thiophene 147620-09-5 C14H11ClS
    5-chloro-2,3-dihydro-3-phenylbenzo[b]thiophene
    —— 5-chloro-2,3-dihydro-2-phenylbenzo[b]thiophene 147620-10-8 C14H11ClS
    5-chloro-2,3-dihydro-2-phenylbenzo[b]thiophene
    —— S-[(3R)-hex-1-en-3-yl] N-butylcarbamothioate 1228454-00-9 C11H21NOS
    S-[(3R)-hex-1-en-3-yl] N-butylcarbamothioate
    —— 1,1-bis(phenylthio)-2-butylcyclopropane 100045-90-7 C19H22S2
    1,1-bis(phenylthio)-2-butylcyclopropane
    —— (2R<sup>*</sup>,2'S<sup>*</sup>)-2-<1-(phenylthio)propyl>-2,3-dihydro-4H-pyran-4-one 140928-69-4 C14H16O2S
    (2R<sup>*</sup>,2'S<sup>*</sup>)-2-<1-(phenylthio)propyl>-2,3-dihydro-4H-pyran-4-one
    —— (2R<sup>*</sup>,2'S<sup>*</sup>)-2-<2-methyl-1-(phenylthio)propyl>-2,3-dihydro-4H-pyran-4-one 140928-73-0 C15H18O2S
    (2R<sup>*</sup>,2'S<sup>*</sup>)-2-<2-methyl-1-(phenylthio)propyl>-2,3-dihydro-4H-pyran-4-one