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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2,3-dichloro-4-<(4-nitrophenyl)sulfenyl>phenetole 87181-25-7 C14H11Cl2NO3S
    2,3-dichloro-4-<(4-nitrophenyl)sulfenyl>phenetole
    —— 2,3-dichloro-4-<(4-nitrophenyl)sulfenyl>phenol 87181-27-9 C12H7Cl2NO3S
    2,3-dichloro-4-<(4-nitrophenyl)sulfenyl>phenol
    —— 4.5-Bis-(4-chlor-benzylmercapto)-2-phenyl-3-oxo-2.3-dihydro-pyridazin 5273-35-8 C24H18Cl2N2OS2
    4.5-Bis-(4-chlor-benzylmercapto)-2-phenyl-3-oxo-2.3-dihydro-pyridazin
    —— 1,4,7,10-Tetraoxa-15lambda6-thiacyclononadeca-12,17-diyne 15,15-dioxide 155015-38-6 C14H20O6S
    1,4,7,10-Tetraoxa-15lambda6-thiacyclononadeca-12,17-diyne 15,15-dioxide
    —— 1,1,4-trichloro-1-(phenylthio)-3,3,-dimethyl-2-butanone 146679-15-4 C12H13Cl3OS
    1,1,4-trichloro-1-(phenylthio)-3,3,-dimethyl-2-butanone
    —— Methanaminium, N-[(dimethylamino)(methylthio)methylene]-N-methyl- 54496-81-0 C6H15N2S+
    Methanaminium, N-[(dimethylamino)(methylthio)methylene]-N-methyl-
    —— 2-chloro-1-phenylthioethyl isocyanate 85212-30-2 C9H8ClNOS
    2-chloro-1-phenylthioethyl isocyanate
    —— N,N-dipropylcarbamothioate;nickel(2+) 47116-64-3 C14H28N2NiO2S2
    N,N-dipropylcarbamothioate;nickel(2+)
    —— 3-({4-[2-(diethylamino)ethoxy]phenyl}thio)-N-(3-methyl-1,2,4-thiadiazol-5-yl)-6-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]pyridine-2-carboxamide 1018966-32-9 C24H28N8O2S3
    3-({4-[2-(diethylamino)ethoxy]phenyl}thio)-N-(3-methyl-1,2,4-thiadiazol-5-yl)-6-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]pyridine-2-carboxamide
    —— S-3-(phenylthio)propyl-N,N-diethylthiolcarbamate 62850-35-5 C14H21NOS2
    S-3-(phenylthio)propyl-N,N-diethylthiolcarbamate
    —— Aethyl-(1-trichlormethyl-vinyl)-sulfon 98698-72-7 C5H10O2S
    Aethyl-(1-trichlormethyl-vinyl)-sulfon
    —— 2-Methylsulfonylhept-1-ene 98698-73-8 C8H16O2S
    2-Methylsulfonylhept-1-ene
    —— N,N-Diethylperfluorbutanthioamid 61881-10-5 C8H10F7NS
    N,N-Diethylperfluorbutanthioamid
    —— (Z)-1-phenylthio-2-butyl-3-phenyl-3-hydroxy-1-propene 1251831-17-0 C19H22OS
    (Z)-1-phenylthio-2-butyl-3-phenyl-3-hydroxy-1-propene
    —— chloromethyl 2-thienyl sulfide 131673-98-8 C5H5ClS2
    chloromethyl 2-thienyl sulfide
    —— 3-Methylene-2-pentyl-2,3-dihydrobenzo<b>thiophene-2-ol 146916-46-3 C14H18OS
    3-Methylene-2-pentyl-2,3-dihydrobenzo<b>thiophene-2-ol
    —— N,N-diethyl-2-[(1-pyridin-2-ylimidazol-2-yl)sulfanylmethyl]aniline 117323-04-3 C19H22N4S
    N,N-diethyl-2-[(1-pyridin-2-ylimidazol-2-yl)sulfanylmethyl]aniline
    —— 2,2-dimethyl-6-methylene-1-phenylthiomethylcyclohexane 88218-61-5 C16H22S
    2,2-dimethyl-6-methylene-1-phenylthiomethylcyclohexane
    —— N,N-diethyl-2-[[1-(3-methoxypyridin-2-yl)imidazol-2-yl]sulfanylmethyl]aniline 117323-02-1 C20H24N4OS
    N,N-diethyl-2-[[1-(3-methoxypyridin-2-yl)imidazol-2-yl]sulfanylmethyl]aniline
    —— 6-azido-2,3-dihydrobenzo<b>thiophen 89536-43-6 C8H7N3S
    6-azido-2,3-dihydrobenzo<b>thiophen
    —— γ-Isothiocyanatoallylchlorid 76855-03-3 C4H4ClNS
    γ-Isothiocyanatoallylchlorid
    —— 3-(phenylthiomethyl)pent-3-enoic acid 108378-65-0 C12H14O2S
    3-(phenylthiomethyl)pent-3-enoic acid
    —— 2,3-Dimethyl-4-phenylthio-2,5-dihydrothiophene 1,1-Dioxide 110026-90-9 C12H14O2S2
    2,3-Dimethyl-4-phenylthio-2,5-dihydrothiophene 1,1-Dioxide
    —— 1-Phenylthiooctan-2-on 71221-50-6 C14H20OS
    1-Phenylthiooctan-2-on
    —— 2-((E)-2,6-dimethyl-hepta-1,5-dienyl)-2-(3-methyl-but-2-enyl)-[1,3]dithiane 69301-62-8 C18H30S2
    2-((E)-2,6-dimethyl-hepta-1,5-dienyl)-2-(3-methyl-but-2-enyl)-[1,3]dithiane
    —— 4-Pyrimidinamine, 2-(butylthio)-6-(2-naphthalenylthio)- 284681-96-5 C18H19N3S2
    4-Pyrimidinamine, 2-(butylthio)-6-(2-naphthalenylthio)-
    —— 5-(3,5-Dichlorophenylthio)-2-dimethylaminomethyl-4-isopropyl-1-methyl-1H-imidazole 178979-69-6 C16H21Cl2N3S
    5-(3,5-Dichlorophenylthio)-2-dimethylaminomethyl-4-isopropyl-1-methyl-1H-imidazole
    —— 5-ethyl-1-ethoxymethyl-6-(3,5-dimethylphenylthio)uracil 136011-44-4 C17H22N2O3S
    5-ethyl-1-ethoxymethyl-6-(3,5-dimethylphenylthio)uracil
    —— 1-Benzyl-2-carbamoyloxymethyl-5-(3,5-dichlorophenylthio)-4-isopropyl-1H-imidazole 178979-35-6 C21H21Cl2N3O2S
    1-Benzyl-2-carbamoyloxymethyl-5-(3,5-dichlorophenylthio)-4-isopropyl-1H-imidazole
    —— 5-(3,5-Dichlorophenylthio)-2-carbamoyloxymethyl-4-isopropyl-1-(pyridin-3-ylmethyl)-1H-imidazole 178979-83-4 C20H20Cl2N4O2S
    5-(3,5-Dichlorophenylthio)-2-carbamoyloxymethyl-4-isopropyl-1-(pyridin-3-ylmethyl)-1H-imidazole
    —— 2-Aminomethyl-4-isopropyl-1-methyl-5-phenylthio-1H-imidazole 178979-65-2 C14H19N3S
    2-Aminomethyl-4-isopropyl-1-methyl-5-phenylthio-1H-imidazole
    —— 3-(5-(3,5-dichlorophenylthio)-1-(2-hydroxyethyl)-4-isopropyl-1H-imidazol-2-yl)-propan-1-ol 178980-57-9 C17H22Cl2N2O2S
    3-(5-(3,5-dichlorophenylthio)-1-(2-hydroxyethyl)-4-isopropyl-1H-imidazol-2-yl)-propan-1-ol
    —— 1H-Imidazole-2-ethanol, 1-((3-aminophenyl)methyl)-5-((3,5-dichlorophenyl)thio)-4-(1-methylethyl)- 178980-35-3 C21H23Cl2N3OS
    1H-Imidazole-2-ethanol, 1-((3-aminophenyl)methyl)-5-((3,5-dichlorophenyl)thio)-4-(1-methylethyl)-
    —— 2-phenylthiomethyl-3(S)-hydroxymethyl-4(S)-pentyl-γ-butyrolactone 777097-32-2 C17H24O3S
    2-phenylthiomethyl-3(S)-hydroxymethyl-4(S)-pentyl-γ-butyrolactone
    —— 5-(4-chlorobenzylthio)pyridazin-3(2H)-one 1243253-45-3 C11H9ClN2OS
    5-(4-chlorobenzylthio)pyridazin-3(2H)-one
    —— (Z)-1-cyclohexyl-2-phenylsulfanylhept-2-en-1-one 206278-56-0 C19H26OS
    (Z)-1-cyclohexyl-2-phenylsulfanylhept-2-en-1-one
    —— 2-But-3-enylsulfinylacetic acid 720719-10-8 C6H10O3S
    2-But-3-enylsulfinylacetic acid
    —— (Z)-2,2-dimethyl-4-phenylsulfanylnon-4-en-3-one 206278-57-1 C17H24OS
    (Z)-2,2-dimethyl-4-phenylsulfanylnon-4-en-3-one
    —— 4(1H)-Pyrimidinone, 2-chloro-6-(phenylthio)- 284682-02-6 C10H7ClN2OS
    4(1H)-Pyrimidinone, 2-chloro-6-(phenylthio)-
    —— (2S,3R)-5-oxo-2-pentyl-4-(phenylsulfanylmethyl)oxolane-3-carboxylic acid 1027976-62-0 C17H22O4S
    (2S,3R)-5-oxo-2-pentyl-4-(phenylsulfanylmethyl)oxolane-3-carboxylic acid
    —— 1,2,3,5,6-Pentathiepane, 4,7-dimethyl- 101517-94-6 C4H8S5
    1,2,3,5,6-Pentathiepane, 4,7-dimethyl-
    —— 1-methyl-2-chloro-3-phenylthioindole 108698-59-5 C15H12ClNS
    1-methyl-2-chloro-3-phenylthioindole
    —— [2-(5-fluoro-1H-indol-3-ylsulfanyl)-benzyl]-carbamic acid tert-butyl ester 857499-96-8 C20H21FN2O2S
    [2-(5-fluoro-1H-indol-3-ylsulfanyl)-benzyl]-carbamic acid tert-butyl ester
    —— 2-(5-fluoro-1H-indol-3-ylsulfanyl)-benzoic acid methyl ester 857499-93-5 C16H12FNO2S
    2-(5-fluoro-1H-indol-3-ylsulfanyl)-benzoic acid methyl ester
    —— methyl-(1-methylsulfanyl-ethyl)-disulfane 4413-29-0 C4H10S3
    methyl-(1-methylsulfanyl-ethyl)-disulfane
    —— (4R,5S)-4-<Tris(phenylthio)methyl>-5-pentyl-4,5-dihydro-2(3H)-furanone 165605-80-1 C28H30O2S3
    (4R,5S)-4-<Tris(phenylthio)methyl>-5-pentyl-4,5-dihydro-2(3H)-furanone
    —— 2-(7-bromo-3,5-dioxaheptylthio)-6-(3,5-dimethylbenzyl)-5-ethyl-pyrimidin-4(3H)-one 261899-98-3 C20H27BrN2O3S
    2-(7-bromo-3,5-dioxaheptylthio)-6-(3,5-dimethylbenzyl)-5-ethyl-pyrimidin-4(3H)-one
    —— 4-(3-Fluorobenzyl)-piperazine-1-carboxylic acid 4-(4,6-dimethyl-pyrimidin-2-ylsulfanyl)-phenyl ester 548768-72-5 C24H25FN4O2S
    4-(3-Fluorobenzyl)-piperazine-1-carboxylic acid 4-(4,6-dimethyl-pyrimidin-2-ylsulfanyl)-phenyl ester
    —— 2-Ethylthio-3-methyl-5-(2-methylbutyl)pyrazine 99784-28-8 C12H20N2S
    2-Ethylthio-3-methyl-5-(2-methylbutyl)pyrazine
    —— 3,3,4,4,5,5,6,6,7,7-Decafluoro-1,2-dithiepane 24345-54-8 C5F10S2
    3,3,4,4,5,5,6,6,7,7-Decafluoro-1,2-dithiepane