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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2,2-Dimethyl-propionic acid (Z)-(4R,5S,6R,9R)-5-(tert-butyl-dimethyl-silanyloxy)-10-[(2R,3R,4R,5S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-6-phenylsulfanyl-tetrahydro-pyran-2-yl]-9-hydroxy-2,4,6-trimethyl-dec-2-en-7-ynyl ester 153788-94-4 C43H74O6SSi2
    2,2-Dimethyl-propionic acid (Z)-(4R,5S,6R,9R)-5-(tert-butyl-dimethyl-silanyloxy)-10-[(2R,3R,4R,5S,6S)-4-(tert-butyl-dimethyl-silanyloxy)-3,5-dimethyl-6-phenylsulfanyl-tetrahydro-pyran-2-yl]-9-hydroxy-2,4,6-trimethyl-dec-2-en-7-ynyl ester
    —— [(2R,3R,4R,5S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-3,5-dimethyl-6-phenylsulfanyl-tetrahydro-pyran-2-yl]-acetaldehyde 153788-86-4 C21H34O3SSi
    [(2R,3R,4R,5S,6S)-4-(tert-Butyl-dimethyl-silanyloxy)-3,5-dimethyl-6-phenylsulfanyl-tetrahydro-pyran-2-yl]-acetaldehyde
    —— ((4-Isothiocyanatophenyl)thio)acetic acid 7501-98-6 C9H7NO2S2
    ((4-Isothiocyanatophenyl)thio)acetic acid
    —— 2,5-dimethylphenyl ethyl xanthate 89816-82-0 C11H14OS2
    2,5-dimethylphenyl ethyl xanthate
    —— cyclopentyl-(4,6-dichloro-2-methylsulfanyl-pyrimidin-5-yl)-methanol 864301-11-1 C11H14Cl2N2OS
    cyclopentyl-(4,6-dichloro-2-methylsulfanyl-pyrimidin-5-yl)-methanol
    —— 2,2-Bis-butylsulfanyl-propionic acid ethyl ester 71917-10-7 C13H26O2S2
    2,2-Bis-butylsulfanyl-propionic acid ethyl ester
    —— 1-Cyclohexyl-2-methyl-isothiourea 72320-98-0 C8H16N2S
    1-Cyclohexyl-2-methyl-isothiourea
    —— 3,4,6,7-tetrahydro-3,3,6,6-tetramethyl-9-(4-methylthiophenyl)-2H-xanthene-1,8(5H,9H)-dione 311794-07-7 C24H28O3S
    3,4,6,7-tetrahydro-3,3,6,6-tetramethyl-9-(4-methylthiophenyl)-2H-xanthene-1,8(5H,9H)-dione
    —— 2-(thiophen-2-ylthio)ethan-1-ol 55697-86-4 C6H8OS2
    2-(thiophen-2-ylthio)ethan-1-ol
    —— 1-Phenylsulfanyl-tricyclo[4.2.0.0<sup>2,7</sup>]octane 98577-43-6 C14H16S
    1-Phenylsulfanyl-tricyclo[4.2.0.0<sup>2,7</sup>]octane
    —— 2,3-dihydro-5H-benzo[e][1,4]oxathiepin-5-one 55212-06-1 C9H8O2S
    2,3-dihydro-5H-benzo[e][1,4]oxathiepin-5-one
    —— 3-[(3-chloropropyl)sulfanyl]-4-methyl-5-(oxan-4-yl)-4H-1,2,4-triazole 863681-38-3 C11H18ClN3OS
    3-[(3-chloropropyl)sulfanyl]-4-methyl-5-(oxan-4-yl)-4H-1,2,4-triazole
    —— ethyl 2-(ethoxycarbonylmethylthio)phenylethanoate 18926-44-8 C14H18O4S
    ethyl 2-(ethoxycarbonylmethylthio)phenylethanoate
    —— 6H,8H-7-Oxa-5,13-dithia-benzo[a]naphthacen-14-one 146173-73-1 C19H12O2S2
    6H,8H-7-Oxa-5,13-dithia-benzo[a]naphthacen-14-one
    —— 3-<4-Chlor-phenyl>-4-thiaisochromanon-(1) 38058-00-3 C14H9ClO2S
    3-<4-Chlor-phenyl>-4-thiaisochromanon-(1)
    —— 1-Bromo-10-(pentylthio)-decane 177583-96-9 C15H31BrS
    1-Bromo-10-(pentylthio)-decane
    —— 2-[(5-ethylpyridin-2-yl)methyl]thio-6-methyl-4(3H)-pyrimidinone —— C13H15N3OS
    2-[(5-ethylpyridin-2-yl)methyl]thio-6-methyl-4(3H)-pyrimidinone
    —— methyl 4-oxo-3-(phenylthio)pentanoate ethylene acetal 173310-59-3 C14H18O4S
    methyl 4-oxo-3-(phenylthio)pentanoate ethylene acetal
    —— 5-hydroxy-3-(phenylthio)butan-2-one ethylene acetal 173310-61-7 C13H18O3S
    5-hydroxy-3-(phenylthio)butan-2-one ethylene acetal
    —— 5-amino-3-(benzylsulfanyl)-N-butyl-1H-[1,2,4]triazole-1-carboxamide 496867-75-5 C14H19N5OS
    5-amino-3-(benzylsulfanyl)-N-butyl-1H-[1,2,4]triazole-1-carboxamide
    —— 5-oxo-6-(phenylthio)hexan-2-ol 173310-50-4 C12H16O2S
    5-oxo-6-(phenylthio)hexan-2-ol
    —— 2-methyl-2-<3-oxo-1-(phenylthio)propyl>-1,3-dioxolane 173310-63-9 C13H16O3S
    2-methyl-2-<3-oxo-1-(phenylthio)propyl>-1,3-dioxolane
    —— 2-methyl-2-(4,4,4-trifluorobutane-1-sulfonyl)propionic acid 1218915-25-3 C8H13F3O4S
    2-methyl-2-(4,4,4-trifluorobutane-1-sulfonyl)propionic acid
    —— 2-(benzylsulfanyl)-6-butyl-6,7-dihydro[1,2,4]triazolo[1,5-a][1,3,5]triazin-7-one 643754-98-7 C15H17N5OS
    2-(benzylsulfanyl)-6-butyl-6,7-dihydro[1,2,4]triazolo[1,5-a][1,3,5]triazin-7-one
    —— 2-Methyl-2-(4,4,4-trifluorobutylsulfonyl)propanamide 1356116-73-8 C8H14F3NO3S
    2-Methyl-2-(4,4,4-trifluorobutylsulfonyl)propanamide
    —— 2-methyl-2-(4,4,4-trifluorobutane-1-sulfonyl)propionic acid ethyl ester 1218915-22-0 C10H17F3O4S
    2-methyl-2-(4,4,4-trifluorobutane-1-sulfonyl)propionic acid ethyl ester
    —— 2-methyl-2-(3-methylbutane-1-sulfonyl)propionic acid 1218915-21-9 C9H18O4S
    2-methyl-2-(3-methylbutane-1-sulfonyl)propionic acid
    —— 4-(4,4-dimethyl-4,5-dihydro-2-oxazolinyl)-3-phenyl-5-(phenylthiomethyl)isoxazole 132632-37-2 C21H20N2O2S
    4-(4,4-dimethyl-4,5-dihydro-2-oxazolinyl)-3-phenyl-5-(phenylthiomethyl)isoxazole
    —— 2-(3-pyridyl)-5-(2-pyridylsulfanyl)thiazole 1512853-05-2 C13H9N3S2
    2-(3-pyridyl)-5-(2-pyridylsulfanyl)thiazole
    —— 4-Ethylmercapto-2,6-diamino-pyridin 18960-90-2 C7H11N3S
    4-Ethylmercapto-2,6-diamino-pyridin
    —— 2-Methyl-2-(4,4,4-trifluorobutylsulfonyl)propan-1-amine 1356116-75-0 C8H16F3NO2S
    2-Methyl-2-(4,4,4-trifluorobutylsulfonyl)propan-1-amine
    —— 4-methyl-6-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-pyridazin-3-ylamine 882500-14-3 C16H20N4O2S2
    4-methyl-6-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-pyridazin-3-ylamine
    —— 5-methyl-6-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-pyridazin-3-ylamine 882500-13-2 C16H20N4O2S2
    5-methyl-6-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-pyridazin-3-ylamine
    —— 4.5-Bis-benzylmercapto-3-oxo-2.3-dihydro-pyridazin 5592-55-2 C18H16N2OS2
    4.5-Bis-benzylmercapto-3-oxo-2.3-dihydro-pyridazin
    —— 3,4,5-Tris-(4-brom-benzylmercapto)-pyridazin 5589-91-3 C25H19Br3N2S3
    3,4,5-Tris-(4-brom-benzylmercapto)-pyridazin
    —— 1,3-Bis-dodecylmercapto-propan 18365-75-8 C27H56S2
    1,3-Bis-dodecylmercapto-propan
    —— 4-Benzylthio-5-methoxy-2-phenyl-3-pyridazinon 5509-77-3 C18H16N2O2S
    4-Benzylthio-5-methoxy-2-phenyl-3-pyridazinon
    —— 4-bromo-2-(3-pyridyl)-5-(2-pyridylsulfanyl)thiazole 1512853-06-3 C13H8BrN3S2
    4-bromo-2-(3-pyridyl)-5-(2-pyridylsulfanyl)thiazole
    —— (5-phenylsulfanyl-pyridine-2-yl)-thiazole-2-yl-amine 1144109-15-8 C14H11N3S2
    (5-phenylsulfanyl-pyridine-2-yl)-thiazole-2-yl-amine
    —— 4-chloro-2-(3-pyridyl)-5-(2-pyridylsulfanyl)thiazole 1512853-07-4 C13H8ClN3S2
    4-chloro-2-(3-pyridyl)-5-(2-pyridylsulfanyl)thiazole
    —— methyl 2-[(4-chlorophenyl)sulfanyl]-3,4,6-trimethyl-5-(phenylselanyl)benzoate 1254592-91-0 C23H21ClO2SSe
    methyl 2-[(4-chlorophenyl)sulfanyl]-3,4,6-trimethyl-5-(phenylselanyl)benzoate
    —— methyl 6-[(4-ethylphenyl)sulfanyl]-2,4-dimethyl-3-(phenylselanyl)benzoate 1254592-99-8 C24H24O2SSe
    methyl 6-[(4-ethylphenyl)sulfanyl]-2,4-dimethyl-3-(phenylselanyl)benzoate
    —— (1'S,3'R,7'S,8'Z,11'S)-1',8'-dimethylspiro[1,3-dithiolane-2,12'-tricyclo[9.3.0.03,7]tetradeca-5,8-diene]-2'-one 85269-19-8 C18H24OS2
    (1'S,3'R,7'S,8'Z,11'S)-1',8'-dimethylspiro[1,3-dithiolane-2,12'-tricyclo[9.3.0.03,7]tetradeca-5,8-diene]-2'-one
    —— 6-amino-4-(4-methylsulfanyl-phenyl)-2-oxo-1,2,3,4-tetrahydro-pyridine-3,5-dicarboxylic acid diethyl ester 52505-26-7 C18H22N2O5S
    6-amino-4-(4-methylsulfanyl-phenyl)-2-oxo-1,2,3,4-tetrahydro-pyridine-3,5-dicarboxylic acid diethyl ester
    —— 8-[1-Phenyl-meth-(Z)-ylidene]-1,5-dithia-spiro[5.5]undecane 1-oxide 89655-99-2 C16H20OS2
    8-[1-Phenyl-meth-(Z)-ylidene]-1,5-dithia-spiro[5.5]undecane 1-oxide
    —— methyl 6-[(4-methoxyphenyl)sulfanyl]-2,4-dimethyl-3-(phenylselanyl)benzoate 1254592-97-6 C23H22O3SSe
    methyl 6-[(4-methoxyphenyl)sulfanyl]-2,4-dimethyl-3-(phenylselanyl)benzoate
    —— 2-[(Tert-butylamino)methyl]-6-[3-[(tert-butylamino)methyl]-5-chloro-2-hydroxyphenyl]sulfanyl-4-chlorophenol 86366-94-1 C22H30Cl2N2O2S
    2-[(Tert-butylamino)methyl]-6-[3-[(tert-butylamino)methyl]-5-chloro-2-hydroxyphenyl]sulfanyl-4-chlorophenol
    —— methyl 2,4-dimethyl-6-[(4-methylphenyl)sulfanyl]-3-(phenylselanyl)benzoate 1254592-93-2 C23H22O2SSe
    methyl 2,4-dimethyl-6-[(4-methylphenyl)sulfanyl]-3-(phenylselanyl)benzoate
    —— methyl 2,4-dimethyl-3-(phenylselanyl)-6-(phenylsulfanyl)benzoate 1254592-90-9 C22H20O2SSe
    methyl 2,4-dimethyl-3-(phenylselanyl)-6-(phenylsulfanyl)benzoate
    —— 2-Isopropyliden-thiophenol 54225-78-4 C9H10OS
    2-Isopropyliden-thiophenol