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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— cyclohexanespiro-2'-S-oxide-1',3'-oxathiolan-5'-one 35348-17-5 C8H12O3S
    cyclohexanespiro-2'-S-oxide-1',3'-oxathiolan-5'-one
    —— 3-methyl-1-(2-methylpropyl)-6-(1-naphthalenylmethyl)-5-[(5-nitropyridin-2-yl)thio]thieno[2,3-d]pyrimidine-2,4-(1H, 3H)-dione 216685-63-1 C27H24N4O4S2
    3-methyl-1-(2-methylpropyl)-6-(1-naphthalenylmethyl)-5-[(5-nitropyridin-2-yl)thio]thieno[2,3-d]pyrimidine-2,4-(1H, 3H)-dione
    —— 3-[3-(2-morpholin-4-yl-ethoxy)-phenyl]-6-(5-nitro-pyridin-2-ylsulfanyl)-[1,2,4]triazolo[4,3-a]pyridine 1241507-41-4 C23H22N6O4S
    3-[3-(2-morpholin-4-yl-ethoxy)-phenyl]-6-(5-nitro-pyridin-2-ylsulfanyl)-[1,2,4]triazolo[4,3-a]pyridine
    —— 5-hydroxy-3-(4-methylphenylsulfanyl)-2H,5H-pyrano[3,2-c]chromen-2-one 1135238-34-4 C19H14O4S
    5-hydroxy-3-(4-methylphenylsulfanyl)-2H,5H-pyrano[3,2-c]chromen-2-one
    —— 3-(4-bromo-2-fluorophenylsulfanyl)-6-methoxypyridazine 474370-36-0 C11H8BrFN2OS
    3-(4-bromo-2-fluorophenylsulfanyl)-6-methoxypyridazine
    —— S-[2-[4-[2-[6-amino-8-[(6-bromo-2,3-dihydro-1,4-benzodioxin-7-yl)sulfanyl]purin-9-yl]ethyl]piperidin-1-yl]-2-oxoethyl] ethanethioate 1156469-44-1 C24H27BrN6O4S2
    S-[2-[4-[2-[6-amino-8-[(6-bromo-2,3-dihydro-1,4-benzodioxin-7-yl)sulfanyl]purin-9-yl]ethyl]piperidin-1-yl]-2-oxoethyl] ethanethioate
    —— 2,2,4-Trimethyl-4-(3-oxocyclohexyl)-1,3-oxathiolan-5-one 61366-86-7 C12H18O3S
    2,2,4-Trimethyl-4-(3-oxocyclohexyl)-1,3-oxathiolan-5-one
    —— [3-(Butylthio)propyl]amine 53056-87-4 C7H17NS
    [3-(Butylthio)propyl]amine
    —— 5-phenylsulfanylmethyl-oxazolidin-2-one 6548-10-3 C10H11NO2S
    5-phenylsulfanylmethyl-oxazolidin-2-one
    —— 2,2,4-trimethyl-4-octyl-[1,3]oxathiolan-5-one 1024810-14-7 C14H26O2S
    2,2,4-trimethyl-4-octyl-[1,3]oxathiolan-5-one
    —— 4,4-Dibenzyl-2,2-dimethyl-1,3-oxathiolan-5-one 88802-43-1 C19H20O2S
    4,4-Dibenzyl-2,2-dimethyl-1,3-oxathiolan-5-one
    —— 5-(phenylthio)methyl-3-methyloxazolidinone 897927-88-7 C11H13NO2S
    5-(phenylthio)methyl-3-methyloxazolidinone
    —— 4-[Hydroxy(phenyl)methyl]-2,2,4-trimethyl-1,3-oxathiolan-5-one 344444-71-9 C13H16O3S
    4-[Hydroxy(phenyl)methyl]-2,2,4-trimethyl-1,3-oxathiolan-5-one
    —— 2,2,4,4-Tetramethyl-1,3-oxathiolan-5-one 87602-19-5 C7H12O2S
    2,2,4,4-Tetramethyl-1,3-oxathiolan-5-one
    —— 4-(2-Hydroxypropan-2-yl)-2,2,4-trimethyl-1,3-oxathiolan-5-one 88802-45-3 C9H16O3S
    4-(2-Hydroxypropan-2-yl)-2,2,4-trimethyl-1,3-oxathiolan-5-one
    —— 2,2,4-Trimethyl-4-(prop-2-en-1-yl)-1,3-oxathiolan-5-one 88802-42-0 C9H14O2S
    2,2,4-Trimethyl-4-(prop-2-en-1-yl)-1,3-oxathiolan-5-one
    —— 4-Benzyl-2,2,4-trimethyl-1,3-oxathiolan-5-one 88802-41-9 C13H16O2S
    4-Benzyl-2,2,4-trimethyl-1,3-oxathiolan-5-one
    —— 4-(1-Hydroxyethyl)-2,2,4-trimethyl-1,3-oxathiolan-5-one 344750-11-4 C8H14O3S
    4-(1-Hydroxyethyl)-2,2,4-trimethyl-1,3-oxathiolan-5-one
    —— 2,2,4-Trimethyl-4-(3-oxobutyl)-1,3-oxathiolan-5-one 88802-54-4 C10H16O3S
    2,2,4-Trimethyl-4-(3-oxobutyl)-1,3-oxathiolan-5-one
    —— Methylthio-2-propanol-1 20463-93-8 C4H10OS
    Methylthio-2-propanol-1
    —— 2-methyl-1-methylsulfanyl-butane 15013-37-3 C6H14S
    2-methyl-1-methylsulfanyl-butane
    —— 4-chloro-2-[(4,4-difluoro-3-butenyl)thio]-pyrimidine 155957-30-5 C8H7ClF2N2S
    4-chloro-2-[(4,4-difluoro-3-butenyl)thio]-pyrimidine
    —— 8-hydroxy-5-phenylsulfanyl-[1,6]naphthyridine-7-carboxylic acid 3,5-dichlorobenzylamide 410543-60-1 C22H15Cl2N3O2S
    8-hydroxy-5-phenylsulfanyl-[1,6]naphthyridine-7-carboxylic acid 3,5-dichlorobenzylamide
    —— 2-<(methylthio)methyl>phenyl phenyl sulfide 112399-07-2 C14H14S2
    2-<(methylthio)methyl>phenyl phenyl sulfide
    —— Methanthiolsulfonsaeure-(2-acetamido-aethylester) 88891-66-1 C5H11NO3S2
    Methanthiolsulfonsaeure-(2-acetamido-aethylester)
    —— 2-(2-phenylthioethyl)pyrrolidine hydrochloride 86026-71-3 C12H17NS*ClH
    2-(2-phenylthioethyl)pyrrolidine hydrochloride
    —— 4,5-bis(bromomethyl)-1,3-dioxolane-2-thione 1051374-80-1 C5H6Br2O2S
    4,5-bis(bromomethyl)-1,3-dioxolane-2-thione
    —— (5R,6R)-5,6-dihydro-5,6-di(methoxymethyl)-1,3-dithiolo[4,5-b]1,4-dithiin-2-thione 355117-99-6 C9H12O2S5
    (5R,6R)-5,6-dihydro-5,6-di(methoxymethyl)-1,3-dithiolo[4,5-b]1,4-dithiin-2-thione
    —— 2-amino-4-(2-bromo-1,3-thiazol-4-yl)-6-({[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)pyridine-3,5-dicarbonitrile 1187543-48-1 C20H10BrClN6S3
    2-amino-4-(2-bromo-1,3-thiazol-4-yl)-6-({[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)pyridine-3,5-dicarbonitrile
    —— 2-Amino-4-[2-(3-{[tert-butyl (dimethyl)silyl]oxy}prop-1-yn-1-yl)-1,3-thiazol-4-yl]-6-({[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)pyridine-3,5-dicarbonitrile 1187543-49-2 C29H27ClN6OS3Si
    2-Amino-4-[2-(3-{[tert-butyl (dimethyl)silyl]oxy}prop-1-yn-1-yl)-1,3-thiazol-4-yl]-6-({[2-(4-chlorophenyl)-1,3-thiazol-4-yl]methyl}sulfanyl)pyridine-3,5-dicarbonitrile
    —— Methyl 3-(3-benzyloxy-5-methylthio-2-thienyl)propenoate 197314-96-8 C16H16O3S2
    Methyl 3-(3-benzyloxy-5-methylthio-2-thienyl)propenoate
    —— 4-(3-(dichloroamino)-3-methylbutylsulfonyl)butane-1,2,3-triol 1373433-65-8 C9H19Cl2NO5S
    4-(3-(dichloroamino)-3-methylbutylsulfonyl)butane-1,2,3-triol
    —— O-[4-(4'-chlorophenylthio)phenyl] O-ethyl S-isobutyl phosphorothiolate 59010-97-8 C18H22ClO3PS2
    O-[4-(4'-chlorophenylthio)phenyl] O-ethyl S-isobutyl phosphorothiolate
    —— (5R,6R)-5,6-bis(methoxymethyl)-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-2-one 355118-00-2 C9H12O3S4
    (5R,6R)-5,6-bis(methoxymethyl)-5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-2-one
    —— 4-(methylthio)furo[3,2-d]pyrimidine 655255-10-0 C7H6N2OS
    4-(methylthio)furo[3,2-d]pyrimidine
    —— 2-methylthio-5-pyridinemethanamine 680602-29-3 C7H10N2S
    2-methylthio-5-pyridinemethanamine
    —— 2-(Diethoxymethyl)-4-methylsulfanyl-1,3-thiazole 1578155-94-8 C9H15NO2S2
    2-(Diethoxymethyl)-4-methylsulfanyl-1,3-thiazole
    —— 4-Amino-2,6-dimethylmercapto-pyrimidin 6299-28-1 C6H9N3S2
    4-Amino-2,6-dimethylmercapto-pyrimidin
    —— 1-{[6-(methylthio)-2-(trifluoromethyl)imidazo[1,2-b]pyridazin-3-yl]methyl}-4-propylpyrrolidin-2-one 916253-63-9 C16H19F3N4OS
    1-{[6-(methylthio)-2-(trifluoromethyl)imidazo[1,2-b]pyridazin-3-yl]methyl}-4-propylpyrrolidin-2-one
    —— 1-bromo-3,4-bis(methylthio)benzene 138709-30-5 C8H9BrS2
    1-bromo-3,4-bis(methylthio)benzene
    —— NVC-727 1373433-55-6 C8H17Cl2NO4S
    NVC-727
    —— 3-(3-Chloro-2-methylthio-5-pyridyl)-5,5-dimethyl-4,5-dihydroisoxazole 405267-27-8 C11H13ClN2OS
    3-(3-Chloro-2-methylthio-5-pyridyl)-5,5-dimethyl-4,5-dihydroisoxazole
    —— 3-chloro-5-(methylthio)isonicotinonitrile 1149586-84-4 C7H5ClN2S
    3-chloro-5-(methylthio)isonicotinonitrile
    —— (2R)-3-[3-(dichloroamino)-3-methylbutyl]sulfonylpropane-1,2-diol 1458630-91-5 C8H17Cl2NO4S
    (2R)-3-[3-(dichloroamino)-3-methylbutyl]sulfonylpropane-1,2-diol
    —— 3-(methylthio)pyrazin-2-amine 87444-50-6 C5H7N3S
    3-(methylthio)pyrazin-2-amine
    —— 2-bromo-4-chloro-5-methylsulfanyl-phenylamine 1232688-57-1 C7H7BrClNS
    2-bromo-4-chloro-5-methylsulfanyl-phenylamine
    —— N,N-dichloro-4-(2-(2-(2-tert-butoxyethoxy)ethoxy)ethylsulfonyl)-2-methylbutan-2-amine 1373434-11-7 C15H31Cl2NO5S
    N,N-dichloro-4-(2-(2-(2-tert-butoxyethoxy)ethoxy)ethylsulfonyl)-2-methylbutan-2-amine
    —— 5-bromo-4-methyl-2-methylsulfanyl-pyridine 247135-44-0 C7H8BrNS
    5-bromo-4-methyl-2-methylsulfanyl-pyridine
    —— 5-tert-butyl-2-(methylsulfanyl)-1H-pyrrole-3-carbonitrile 1240948-90-6 C10H14N2S
    5-tert-butyl-2-(methylsulfanyl)-1H-pyrrole-3-carbonitrile
    —— 1-(6-(methylthio)pyridin-3-yl)ethanone 828276-48-8 C8H9NOS
    1-(6-(methylthio)pyridin-3-yl)ethanone