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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-(4-cyclopentylamino-2-methylsulfanylpyrimidin-5-yl)propan-1-ol 850628-71-6 C13H21N3OS
    1-(4-cyclopentylamino-2-methylsulfanylpyrimidin-5-yl)propan-1-ol
    —— 1,1,1,2,2,3,3,4,4-nonafluoro-4-prop-1-enylsulfonylbutane 66406-80-2 C7H5F9O2S
    1,1,1,2,2,3,3,4,4-nonafluoro-4-prop-1-enylsulfonylbutane
    —— Aethyl-N-aethylthio-carbamat 51552-67-1 C5H11NO2S
    Aethyl-N-aethylthio-carbamat
    —— 2-methyl-1-cyclohexenyl isothiocyanate 94516-64-0 C8H11NS
    2-methyl-1-cyclohexenyl isothiocyanate
    —— 1,2-Dichlor-1-methylmercaptoethan 19826-11-0 C3H6Cl2S
    1,2-Dichlor-1-methylmercaptoethan
    —— 2,5-dithiaheptane 76229-75-9 C5H12S2
    2,5-dithiaheptane
    —— 5-methyl-2-{[2-(methylsulfanyl)ethyl]sulfanyl}-6-(thiophen-2-ylmethyl)pyrimidin-4(3H)-one 1290637-15-8 C13H16N2OS3
    5-methyl-2-{[2-(methylsulfanyl)ethyl]sulfanyl}-6-(thiophen-2-ylmethyl)pyrimidin-4(3H)-one
    —— 6-{[2-(Methylsulfanyl)ethyl]sulfanyl}-1,2,4-triazine-3,5(2H,4H)-dione 184697-89-0 C6H9N3O2S2
    6-{[2-(Methylsulfanyl)ethyl]sulfanyl}-1,2,4-triazine-3,5(2H,4H)-dione
    —— N,N'-di-Boc-N''-triflyguanidine 862719-22-0 C12H19F3N2O6S
    N,N'-di-Boc-N''-triflyguanidine
    —— 4-[di(ethoxycarbonyl)methyl]-7-phenyl-6-phenylthio-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one 1353137-50-4 C24H26N2O5S
    4-[di(ethoxycarbonyl)methyl]-7-phenyl-6-phenylthio-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one
    —— 7-phenyl-4,6-di(phenylthio)-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one 1353137-58-2 C23H20N2OS2
    7-phenyl-4,6-di(phenylthio)-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one
    —— 4-cyano-7-phenyl-6-phenylthio-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one 1353137-47-9 C18H15N3OS
    4-cyano-7-phenyl-6-phenylthio-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one
    —— 7-phenyl-6-phenylthio-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one 1353137-56-0 C17H16N2OS
    7-phenyl-6-phenylthio-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one
    —— 6,7-Dihydro-2H-thiazolo<2,3-c><1,2,4>triazin-3,4-dion 77799-20-3 C5H5N3O2S
    6,7-Dihydro-2H-thiazolo<2,3-c><1,2,4>triazin-3,4-dion
    —— 4-hydroxymethyl-6-phenyl-5-phenylthio-1,2,3,4-tetrahydropyrimidin-2-one 1353137-45-7 C17H16N2O2S
    4-hydroxymethyl-6-phenyl-5-phenylthio-1,2,3,4-tetrahydropyrimidin-2-one
    —— N-Methyl-S.S-diaethyl-sulfoximid 35362-75-5 C5H13NOS
    N-Methyl-S.S-diaethyl-sulfoximid
    —— Ditert-butyl-[[ditert-butylphosphanylimino(diethyl)-lambda6-sulfanylidene]amino]phosphane 66435-91-4 C20H46N2P2S
    Ditert-butyl-[[ditert-butylphosphanylimino(diethyl)-lambda6-sulfanylidene]amino]phosphane
    —— 1-(4-Methylphenyl)sulfanylpentan-2-ol 1241769-20-9 C12H18OS
    1-(4-Methylphenyl)sulfanylpentan-2-ol
    —— Cyclohexyl-<α,α-dichlor-methyl>-sulfon 10038-12-7 C7H12Cl2O2S
    Cyclohexyl-<α,α-dichlor-methyl>-sulfon
    —— Benzo[c]thiophen-4(5H)-one,6,7-dihydro-6,6-dimethyl-3-(methylthio)-,oxime —— C11H15NOS2
    Benzo[c]thiophen-4(5H)-one,6,7-dihydro-6,6-dimethyl-3-(methylthio)-,oxime
    —— 2-Chloro-3-(4-methoxyphenylsulfanyl)-6-methylpyridine 777940-48-4 C13H12ClNOS
    2-Chloro-3-(4-methoxyphenylsulfanyl)-6-methylpyridine
    —— 5-acetamido-4-phenylthiopentanonitrile 117768-55-5 C13H16N2OS
    5-acetamido-4-phenylthiopentanonitrile
    —— 5-hydroxy-6-p-tolylthiohexanonitrile 108078-59-7 C13H17NOS
    5-hydroxy-6-p-tolylthiohexanonitrile
    —— 1-(4-Bromophenyl)sulfanylpentan-2-ol 1241769-22-1 C11H15BrOS
    1-(4-Bromophenyl)sulfanylpentan-2-ol
    —— 5-hydroxy-6-phenylthiohexanonitrile 108078-57-5 C12H15NOS
    5-hydroxy-6-phenylthiohexanonitrile
    —— 5-acetamido-6-p-tolylthiohexanonitrile 117768-60-2 C15H20N2OS
    5-acetamido-6-p-tolylthiohexanonitrile
    —— 6-acetamido-5-phenylthiohexanonitrile 117768-59-9 C14H18N2OS
    6-acetamido-5-phenylthiohexanonitrile
    —— 6-hydroxy-5-p-tolylthiohexanonitrile 108078-60-0 C13H17NOS
    6-hydroxy-5-p-tolylthiohexanonitrile
    —— 4,5-Dihydro-5-methyl-5-propyl-4-oxo-4H-thieno[2,3-b]thiophene 133209-66-2 C10H12OS2
    4,5-Dihydro-5-methyl-5-propyl-4-oxo-4H-thieno[2,3-b]thiophene
    —— 6-acetamido-5-p-tolylthiohexanonitrile 117768-61-3 C15H20N2OS
    6-acetamido-5-p-tolylthiohexanonitrile
    —— 4-acetamido-5-p-tolylthiopentanonitrile 117768-56-6 C14H18N2OS
    4-acetamido-5-p-tolylthiopentanonitrile
    —— 6-hydroxy-5-phenylthiohexanonitrile 108078-58-6 C12H15NOS
    6-hydroxy-5-phenylthiohexanonitrile
    —— 4-hydroxy-5-p-tolylthiopentanonitrile 108078-53-1 C12H15NOS
    4-hydroxy-5-p-tolylthiopentanonitrile
    —— 5-acetamido-4-p-tolylthiopentanonitrile 117768-57-7 C14H18N2OS
    5-acetamido-4-p-tolylthiopentanonitrile
    —— 4-hydroxy-5-phenylthiopentanonitrile 108078-51-9 C11H13NOS
    4-hydroxy-5-phenylthiopentanonitrile
    —— 5-hydroxy-4-p-tolylthiopentanonitrile 108078-54-2 C12H15NOS
    5-hydroxy-4-p-tolylthiopentanonitrile
    —— 5-hydroxy-4-phenylthiopentanonitrile 108078-52-0 C11H13NOS
    5-hydroxy-4-phenylthiopentanonitrile
    —— Dithiostearinsaeure 139759-10-7 C18H36S2
    Dithiostearinsaeure
    —— 3-nitro-2-(2-phenylsulfanyl-ethylsulfanyl)pyridine 1242435-96-6 C13H12N2O2S2
    3-nitro-2-(2-phenylsulfanyl-ethylsulfanyl)pyridine
    —— 1-Phenylmercapto-4-chlor-but-1-en 155068-04-5 C10H11ClS
    1-Phenylmercapto-4-chlor-but-1-en
    —— 2-(Phenylsulfanyl)ethyl nitrite 112752-00-8 C8H9NO2S
    2-(Phenylsulfanyl)ethyl nitrite
    —— [(Z)-N-(dimethylamino)-C-(1,1,2,2,3,3,3-heptafluoropropyl)carbonimidoyl]sulfanyl (1Z)-N-(dimethylamino)-2,2,3,3,4,4,4-heptafluorobutanimidothioate 4454-59-5 C12H12F14N4S2
    [(Z)-N-(dimethylamino)-C-(1,1,2,2,3,3,3-heptafluoropropyl)carbonimidoyl]sulfanyl (1Z)-N-(dimethylamino)-2,2,3,3,4,4,4-heptafluorobutanimidothioate
    —— 1-methylsulfanyl-2-phenylsulfanyl-ethane 90535-42-5 C9H12S2
    1-methylsulfanyl-2-phenylsulfanyl-ethane
    —— Ethyl4-hydroxy-7-nitroquinoline-3-carboxylate 175201-71-5 C8H13NO3S
    Ethyl4-hydroxy-7-nitroquinoline-3-carboxylate
    —— N,N-dimethyl-2-(phenylthio)ethan-1-amine 7319-95-1 C10H15NS
    N,N-dimethyl-2-(phenylthio)ethan-1-amine
    —— 1,3-Bis(phenylthio)pente-1-en 66278-76-0 C17H18S2
    1,3-Bis(phenylthio)pente-1-en
    —— 4-(2-phenylsulfanyl-ethyl)-morpholine; hydrochloride 69967-32-4 C12H17NOS*ClH
    4-(2-phenylsulfanyl-ethyl)-morpholine; hydrochloride
    —— O-Aethyl-<S-phenylmercapto-2-aethyl>-methylthiophosphat 79064-79-2 C11H17O2PS2
    O-Aethyl-<S-phenylmercapto-2-aethyl>-methylthiophosphat
    —— 1-Phenyl-4-(4-methylphenyl)-1,4-dithiabutan 65310-98-7 C15H16S2
    1-Phenyl-4-(4-methylphenyl)-1,4-dithiabutan
    —— 2-(dicyclohexylphosphino)ethyl phenyl thioether 29138-52-1 C20H31PS
    2-(dicyclohexylphosphino)ethyl phenyl thioether