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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (R,E)-2-amino-4-(tridecylthio)but-3-en-1-ol 1266326-14-0 C17H35NOS
    (R,E)-2-amino-4-(tridecylthio)but-3-en-1-ol
    —— deuterio-thioketene 70231-70-8 C2H2S
    deuterio-thioketene
    —— 4-methylthiophenyl-2-pyridinylmethanamine 95899-05-1 C13H14N2S
    4-methylthiophenyl-2-pyridinylmethanamine
    —— 2-nitro-3-thienyl-4'-nitrophenylsulfide 51679-11-9 C10H6N2O4S2
    2-nitro-3-thienyl-4'-nitrophenylsulfide
    —— 2,2'-dinitro-3,3'-dithienylsulfide 64729-08-4 C8H4N2O4S3
    2,2'-dinitro-3,3'-dithienylsulfide
    —— 4-phenylsulfanylphenoxyethyl tetrahydro-2H-pyran-2-yl ether 445283-57-8 C19H22O3S
    4-phenylsulfanylphenoxyethyl tetrahydro-2H-pyran-2-yl ether
    —— 2-amino-3,4-dimethylphenyl-2-nitro-3-thienylsulfide 239791-36-7 C12H12N2O2S2
    2-amino-3,4-dimethylphenyl-2-nitro-3-thienylsulfide
    —— N,N-Dimethyl-pentafluorthiopropionhydrazid 4454-49-3 C5H7F5N2S
    N,N-Dimethyl-pentafluorthiopropionhydrazid
    —— [4-chloro-6-(2,4,6-trimethyl-anilino)-pyrimidin-2-ylsulfanyl]-acetic acid ethyl ester 50892-19-8 C17H20ClN3O2S
    [4-chloro-6-(2,4,6-trimethyl-anilino)-pyrimidin-2-ylsulfanyl]-acetic acid ethyl ester
    —— 13,17-dithiabicyclo<10.6.0>octadec-1(12)-ene 98051-68-4 C16H28S2
    13,17-dithiabicyclo<10.6.0>octadec-1(12)-ene
    —— 3-mercaptopropyl propionylcarbamodithioate 1206892-93-4 C7H13NOS3
    3-mercaptopropyl propionylcarbamodithioate
    —— 5-ethyl-2-ethylmercapto-pyrimidine 98490-18-7 C8H12N2S
    5-ethyl-2-ethylmercapto-pyrimidine
    —— diisopentyl-thiocarbamic acid <i>S</i>-methyl ester 100387-11-9 C12H25NOS
    diisopentyl-thiocarbamic acid <i>S</i>-methyl ester
    —— Cyclopentadienthion 77825-99-1 C5H4S
    Cyclopentadienthion
    —— 4-o-Tolylsulfanylmethyl-phenylamine; hydrochloride 87740-21-4 C14H15NS*ClH
    4-o-Tolylsulfanylmethyl-phenylamine; hydrochloride
    —— 6-Chloro-3-methylthiopyridazine-1-oxide 40954-07-2 C5H5ClN2OS
    6-Chloro-3-methylthiopyridazine-1-oxide
    —— Diisopropyl-dithiocarbamic acid 6-methyl-pyridin-3-yl ester 882029-24-5 C13H20N2S2
    Diisopropyl-dithiocarbamic acid 6-methyl-pyridin-3-yl ester
    —— 3-Hydroxy-6-methylthio-pyridazin 66089-72-3 C5H6N2OS
    3-Hydroxy-6-methylthio-pyridazin
    —— 1,1-Dioxo-3-propan-2-ylimino-1lambda6,4,2-benzodithiazine-7-carboxylic acid 1429321-59-4 C11H12N2O4S2
    1,1-Dioxo-3-propan-2-ylimino-1lambda6,4,2-benzodithiazine-7-carboxylic acid
    —— 5-n-propylthio-1,3,4-oxadiazole-2-carbonyl chloride 62373-39-1 C6H7ClN2O2S
    5-n-propylthio-1,3,4-oxadiazole-2-carbonyl chloride
    —— tris(2,2,6,6-tetramethyl-8-{[2-(morpholin-4-yl)ethyl]carbonyl}-benzo[1,2-d;4,5-d']bis[1,3]dithiol-4-yl)methanol 1374260-17-9 C58H73N3O10S12
    tris(2,2,6,6-tetramethyl-8-{[2-(morpholin-4-yl)ethyl]carbonyl}-benzo[1,2-d;4,5-d']bis[1,3]dithiol-4-yl)methanol
    —— 5-isopropylthio-1,3,4-oxadiazole-2-carbonyl chloride 62373-38-0 C6H7ClN2O2S
    5-isopropylthio-1,3,4-oxadiazole-2-carbonyl chloride
    —— 2,3-dihydro-1λ<sup>6</sup>,4λ<sup>6</sup>-dithiine-1,1,4,4-tetrone 58950-91-7 C4H6O4S2
    2,3-dihydro-1λ<sup>6</sup>,4λ<sup>6</sup>-dithiine-1,1,4,4-tetrone
    —— 1-Thia-10-aza<2.2>metacyclophane 165391-94-6 C14H13NS
    1-Thia-10-aza<2.2>metacyclophane
    —— 1-[3-[(3,5-Dibromophenyl)methylsulfanyl]phenyl]guanidine 1314034-09-7 C14H13Br2N3S
    1-[3-[(3,5-Dibromophenyl)methylsulfanyl]phenyl]guanidine
    —— 3-(2-Morpholin-4-ylethylsulfanyl)aniline 223442-33-9 C12H18N2OS
    3-(2-Morpholin-4-ylethylsulfanyl)aniline
    —— N-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-4-methylsulfanyl-pyridine-2,6-diamine 1158786-13-0 C14H27N3OSSi
    N-[2-(tert-butyl-dimethyl-silanyloxy)-ethyl]-4-methylsulfanyl-pyridine-2,6-diamine
    —— 4-methylsulfanyl-pyridine-2,6-diamine 1158784-64-5 C6H9N3S
    4-methylsulfanyl-pyridine-2,6-diamine
    —— dodecyl-isopropyl sulfide 92867-66-8 C15H32S
    dodecyl-isopropyl sulfide
    —— 1,2-Dicyclohexyl-3-[3-[(3,5-dibromophenyl)methylsulfanyl]phenyl]guanidine 1314034-10-0 C26H33Br2N3S
    1,2-Dicyclohexyl-3-[3-[(3,5-dibromophenyl)methylsulfanyl]phenyl]guanidine
    —— Pentanedioic acid bis-{[3-(2-nitro-phenylsulfanyl)-phenyl]-amide} 188058-55-1 C29H24N4O6S2
    Pentanedioic acid bis-{[3-(2-nitro-phenylsulfanyl)-phenyl]-amide}
    —— (Z)-3-methylnon-2-en-4-yne-1-thiol 260543-71-3 C10H16S
    (Z)-3-methylnon-2-en-4-yne-1-thiol
    —— ethyl 2-((3-aminophenyl)thio)acetate 153242-32-1 C10H13NO2S
    ethyl 2-((3-aminophenyl)thio)acetate
    —— N,N'-Bis-[3-(2-nitro-phenylsulfanyl)-phenyl]-malonamide 188058-86-8 C27H20N4O6S2
    N,N'-Bis-[3-(2-nitro-phenylsulfanyl)-phenyl]-malonamide
    —— 3-(3-dimethoxymethyl-4-nitro-phenylsulfanyl)-phenylamine 1184181-24-5 C15H16N2O4S
    3-(3-dimethoxymethyl-4-nitro-phenylsulfanyl)-phenylamine
    —— 3-amino-S-t-butyloxycarbonyl thiophenol 179898-32-9 C11H15NO2S
    3-amino-S-t-butyloxycarbonyl thiophenol
    —— 1-ethylsulfanyl-3-methyl-buta-1,3-diene 49563-09-9 C7H12S
    1-ethylsulfanyl-3-methyl-buta-1,3-diene
    —— (Z)-5-((4-bromo-5-(p-tolylthio)thiophen-2-yl)methylene)-2-thioxothiazolidin-4-one 1489285-35-9 C15H10BrNOS4
    (Z)-5-((4-bromo-5-(p-tolylthio)thiophen-2-yl)methylene)-2-thioxothiazolidin-4-one
    —— N-(2-(methylsulfanyl)-4,5,6,7-tetrahydrofuro[2,3-b]azepin-8-yl)pent-4-enamide 438044-94-1 C14H19NO2S
    N-(2-(methylsulfanyl)-4,5,6,7-tetrahydrofuro[2,3-b]azepin-8-yl)pent-4-enamide
    —— methyl 3-((2-bromoethyl)sulfonyl)propanoate 1611496-86-6 C6H11BrO4S
    methyl 3-((2-bromoethyl)sulfonyl)propanoate
    —— 6-(4-Chloro-phenylsulfanyl)-3-methyl-2,4-dioxo-1,2,3,4-tetrahydro-pyrimidine-5-carbaldehyde 80947-60-0 C12H9ClN2O3S
    6-(4-Chloro-phenylsulfanyl)-3-methyl-2,4-dioxo-1,2,3,4-tetrahydro-pyrimidine-5-carbaldehyde
    —— 3-Methyl-2,4-dioxo-6-o-tolylsulfanyl-1,2,3,4-tetrahydro-pyrimidine-5-carbaldehyde 80947-63-3 C13H12N2O3S
    3-Methyl-2,4-dioxo-6-o-tolylsulfanyl-1,2,3,4-tetrahydro-pyrimidine-5-carbaldehyde
    —— 3-Methyl-2,4-dioxo-6-p-tolylsulfanyl-1,2,3,4-tetrahydro-pyrimidine-5-carbaldehyde 80947-61-1 C13H12N2O3S
    3-Methyl-2,4-dioxo-6-p-tolylsulfanyl-1,2,3,4-tetrahydro-pyrimidine-5-carbaldehyde
    —— 6-(4-Chloro-phenylsulfanyl)-3-methyl-1H-pyrimidine-2,4-dione 80947-50-8 C11H9ClN2O2S
    6-(4-Chloro-phenylsulfanyl)-3-methyl-1H-pyrimidine-2,4-dione
    —— 3-Methyl-6-o-tolylsulfanyl-1H-pyrimidine-2,4-dione 80947-53-1 C12H12N2O2S
    3-Methyl-6-o-tolylsulfanyl-1H-pyrimidine-2,4-dione
    —— 3-Methyl-6-p-tolylsulfanyl-1H-pyrimidine-2,4-dione 80947-51-9 C12H12N2O2S
    3-Methyl-6-p-tolylsulfanyl-1H-pyrimidine-2,4-dione
    —— S-propyl dipropylthiocarbamate S-oxide 51950-10-8 C10H21NO2S
    S-propyl dipropylthiocarbamate S-oxide
    —— 3-Methylmercapto-penta-1,3-dien 14044-73-6 C6H10S
    3-Methylmercapto-penta-1,3-dien
    —— 4-(3-chloro-benzylmercapto)-pyridine 87578-03-8 C12H10ClNS
    4-(3-chloro-benzylmercapto)-pyridine
    —— 4-(3-Chloro-benzylsulfanyl)-pyridine-2-carbonitrile 225112-47-0 C13H9ClN2S
    4-(3-Chloro-benzylsulfanyl)-pyridine-2-carbonitrile