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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (1Z)-N'-hydroxy-2-(methylsulfonyl)ethanimidamide —— C3H8N2O3S
    (1Z)-N'-hydroxy-2-(methylsulfonyl)ethanimidamide
    —— (1,3,3-Tris(phenylthio)-2-propenyl)benzene 71341-82-7 C27H22S3
    (1,3,3-Tris(phenylthio)-2-propenyl)benzene
    —— 2-<Bis(phenylthio)methylene>pyrrolidine 145642-56-4 C17H17NS2
    2-<Bis(phenylthio)methylene>pyrrolidine
    —— 3-(dimethylamino)-2-(methylsulfonyl)-2-propenenitrile 106073-27-2 C6H10N2O2S
    3-(dimethylamino)-2-(methylsulfonyl)-2-propenenitrile
    —— 2-phenyl-benzo[<i>b</i>]thiophen-3-one 53614-69-0 C14H10OS
    2-phenyl-benzo[<i>b</i>]thiophen-3-one
    —— bis(methylthio)methylenemethylsulfonylacetonitrile 73618-36-7 C6H9NO2S3
    bis(methylthio)methylenemethylsulfonylacetonitrile
    —— thiacycloheptadeca-3,15-diyne-1,1-dioxide 514853-68-0 C16H24O2S
    thiacycloheptadeca-3,15-diyne-1,1-dioxide
    —— 3-Thiophenecarbothioamide, N-(4-chloro-3-((2E)-butenylthio)phenyl)-2-methyl- 178870-04-7 C16H16ClNS3
    3-Thiophenecarbothioamide, N-(4-chloro-3-((2E)-butenylthio)phenyl)-2-methyl-
    —— tert.-Butyl-<buten-(1-trans)-yl>-sulfid 121222-73-9 C8H16S
    tert.-Butyl-<buten-(1-trans)-yl>-sulfid
    —— methyl(pent-4-en-1-yl)sulfide 69632-05-9 C6H12S
    methyl(pent-4-en-1-yl)sulfide
    —— 1-cyano-2-(ethoxycarbonylmethylsulphinyl)ethane 74338-77-5 C7H11NO3S
    1-cyano-2-(ethoxycarbonylmethylsulphinyl)ethane
    —— 2,2'-ethanediylidenbis<benzo<b>thiophen-3(2H)-one> 74061-61-3 C18H10O2S2
    2,2'-ethanediylidenbis<benzo<b>thiophen-3(2H)-one>
    —— 1,1-difluoro-2-(phenylsulfanyl)hept-1-ene 73194-40-8 C13H16F2S
    1,1-difluoro-2-(phenylsulfanyl)hept-1-ene
    —— 6-Fluoro-2-methyl-5-phenylsulfanyl-4H-pyran-3-carboxylic acid ethyl ester 73194-36-2 C15H15FO3S
    6-Fluoro-2-methyl-5-phenylsulfanyl-4H-pyran-3-carboxylic acid ethyl ester
    —— (4Z)-5-methyl-4-[(5-nitro-2-pyridin-2-ylsulfanylphenyl)methylidene]-2-phenylpyrazol-3-one —— C22H16N4O3S
    (4Z)-5-methyl-4-[(5-nitro-2-pyridin-2-ylsulfanylphenyl)methylidene]-2-phenylpyrazol-3-one
    —— [(Z)-5-fluoroundec-5-en-6-yl]sulfanylbenzene 73194-42-0 C17H25FS
    [(Z)-5-fluoroundec-5-en-6-yl]sulfanylbenzene
    —— 1-(trifluoromethyl)ethenyl phenyl sulfide 73194-33-9 C9H7F3S
    1-(trifluoromethyl)ethenyl phenyl sulfide
    —— methyl 2-[(2S,3S,4R)-4-methyl-2-octyl-5-oxo-4-phenylsulfanyloxolan-3-yl]acetate 183626-21-3 C22H32O4S
    methyl 2-[(2S,3S,4R)-4-methyl-2-octyl-5-oxo-4-phenylsulfanyloxolan-3-yl]acetate
    —— methyl (2R)-2-hydroxy-2-[(2S,3S,4R)-4-methyl-2-octyl-5-oxo-4-phenylsulfanyloxolan-3-yl]acetate 183626-22-4 C22H32O5S
    methyl (2R)-2-hydroxy-2-[(2S,3S,4R)-4-methyl-2-octyl-5-oxo-4-phenylsulfanyloxolan-3-yl]acetate
    —— 2-ethyl-3-methylbutyl phenyl sulfide 170511-90-7 C13H20S
    2-ethyl-3-methylbutyl phenyl sulfide
    —— 2-(methylsulfonyl)acetaldehyde 13154-68-2 C3H6O3S
    2-(methylsulfonyl)acetaldehyde
    —— Tert-butyl-[[3-methyl-6,6-bis(trifluoromethylsulfonyl)cyclohex-3-en-1-yl]methoxy]-diphenylsilane —— C54H72NO5Pol
    Tert-butyl-[[3-methyl-6,6-bis(trifluoromethylsulfonyl)cyclohex-3-en-1-yl]methoxy]-diphenylsilane
    —— O,O-dimethyl 2-chloro-2-phenyl-1-phenylthioethylphosphonate 88691-27-4 C16H18ClO3PS
    O,O-dimethyl 2-chloro-2-phenyl-1-phenylthioethylphosphonate
    —— prop-2-ynyl thiocyanate 38341-88-7 C4H3NS
    prop-2-ynyl thiocyanate
    —— 6-methyl-2-oxo-4-(4-p-tolylsulfanyl-phenyl)-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester 1173658-49-5 C21H22N2O3S
    6-methyl-2-oxo-4-(4-p-tolylsulfanyl-phenyl)-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester
    —— 6-methyl-2-oxo-4-(4-phenylsulfanyl-phenyl)-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester 1173658-47-3 C20H20N2O3S
    6-methyl-2-oxo-4-(4-phenylsulfanyl-phenyl)-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester
    —— 4-(3-fluoro-4-methoxyphenylthio)benzaldehyde 1173658-46-2 C14H11FO2S
    4-(3-fluoro-4-methoxyphenylthio)benzaldehyde
    —— 4-phenylthiophenylhydroxylamine 21229-99-2 C12H11NOS
    4-phenylthiophenylhydroxylamine
    —— 4-[4-(3-fluoro-4-methoxy-phenylsulfanyl)-phenyl]-6-methyl-2-oxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester 1173658-61-1 C21H21FN2O4S
    4-[4-(3-fluoro-4-methoxy-phenylsulfanyl)-phenyl]-6-methyl-2-oxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester
    —— 6-methyl-2-thioxo-4-(4-p-tolylsulfanyl-phenyl)-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester 1173658-65-5 C21H22N2O2S2
    6-methyl-2-thioxo-4-(4-p-tolylsulfanyl-phenyl)-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester
    —— 5H,7H-dibenzo<b,g><1,5>dithiocin 60418-10-2 C14H12S2
    5H,7H-dibenzo<b,g><1,5>dithiocin
    —— 5-acetyl-6-methyl-4-(4-phenylsulfanyl-phenyl)-3,4-dihydro-1H-pyrimidin-2-one 1173658-48-4 C19H18N2O2S
    5-acetyl-6-methyl-4-(4-phenylsulfanyl-phenyl)-3,4-dihydro-1H-pyrimidin-2-one
    —— 1-[6-methyl-2-thioxo-4-(4-p-tolylsulfanyl-phenyl)-1,2,3,4-tetrahydro-pyrimidin-5-yl]-ethanone 1173658-66-6 C20H20N2OS2
    1-[6-methyl-2-thioxo-4-(4-p-tolylsulfanyl-phenyl)-1,2,3,4-tetrahydro-pyrimidin-5-yl]-ethanone
    —— 5-acetyl-6-methyl-4-(4-p-tolylsulfanyl-phenyl)-3,4-dihydro-1H-pyrimidin-2-one 1173658-50-8 C20H20N2O2S
    5-acetyl-6-methyl-4-(4-p-tolylsulfanyl-phenyl)-3,4-dihydro-1H-pyrimidin-2-one
    —— 5-acetyl-4-[4-(3-fluoro-4-methoxy-phenylsulfanyl)-phenyl]-6-methyl-2-oxo-3,4-dihydro-1H-pyrimidine-2-one 1173658-62-2 C20H19FN2O3S
    5-acetyl-4-[4-(3-fluoro-4-methoxy-phenylsulfanyl)-phenyl]-6-methyl-2-oxo-3,4-dihydro-1H-pyrimidine-2-one
    —— 4-[4-(2-chloro-6-methyl-phenylsulfanyl)-phenyl]-6-methyl-2-oxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester 1173658-59-7 C21H21ClN2O3S
    4-[4-(2-chloro-6-methyl-phenylsulfanyl)-phenyl]-6-methyl-2-oxo-1,2,3,4-tetrahydro-pyrimidine-5-carboxylic acid ethyl ester
    —— 4-methyl-3-thiophenesulfonyl isocyanate 81417-53-0 C6H5NO3S2
    4-methyl-3-thiophenesulfonyl isocyanate
    —— 2,3-bis(3-carbomethoxypyridyl-2-thio)indole 242491-41-4 C22H17N3O4S2
    2,3-bis(3-carbomethoxypyridyl-2-thio)indole
    —— 5-acetyl-4-[4-(2-chloro-6-methyl-phenylsulfanyl)-phenyl]-6-methyl-3,4-dihydro-1H-pyrimidin-2-one 1173658-60-0 C20H19ClN2O2S
    5-acetyl-4-[4-(2-chloro-6-methyl-phenylsulfanyl)-phenyl]-6-methyl-3,4-dihydro-1H-pyrimidin-2-one
    —— 2-chloro-n-prop-1-yl-sulfonyl isocyanate 4794-12-1 C4H6ClNO3S
    2-chloro-n-prop-1-yl-sulfonyl isocyanate
    —— 5,5'-bis(mesitylthio)-2,2'-bithiophene 291308-72-0 C26H26S4
    5,5'-bis(mesitylthio)-2,2'-bithiophene
    —— 3-((pyridin-4-ylmethyl)thio)-5,6-di-p-tolyl-1,2,4-triazine 1478982-08-9 C23H20N4S
    3-((pyridin-4-ylmethyl)thio)-5,6-di-p-tolyl-1,2,4-triazine
    —— (3aS,7aS)-5-methyl-7a-phenylsulfanyl-3,3a,4,7-tetrahydro-2H-inden-1-one 75781-77-0 C16H18OS
    (3aS,7aS)-5-methyl-7a-phenylsulfanyl-3,3a,4,7-tetrahydro-2H-inden-1-one
    —— bis(acetylthio)methane 2506-35-6 C5H8O2S2
    bis(acetylthio)methane
    —— 4-chloro-6-(3,5-dimethyl-1H-1,2,4-triazol-1-yl)-2-(methylthio)pyrimidine 1429634-94-5 C9H10ClN5S
    4-chloro-6-(3,5-dimethyl-1H-1,2,4-triazol-1-yl)-2-(methylthio)pyrimidine
    —— 6-(4-ethyl-2-thiazolylthio)-5-nitro-3H-isobenzofuran-1-one 181485-51-8 C13H10N2O4S2
    6-(4-ethyl-2-thiazolylthio)-5-nitro-3H-isobenzofuran-1-one
    —— 2-methyl-2-(phenylthio)-1,3-cyclopentanedione 72302-65-9 C12H12O2S
    2-methyl-2-(phenylthio)-1,3-cyclopentanedione
    —— Methyl (2E)-2-(4-methylpentan-2-ylidene)hydrazine-1-carbodithioate 60273-80-5 C8H16N2S2
    Methyl (2E)-2-(4-methylpentan-2-ylidene)hydrazine-1-carbodithioate
    —— (S)-S-1-formyl-4-methylcyclohex-3-enyl diisopropylcarbamothioate 1379479-90-9 C15H25NO2S
    (S)-S-1-formyl-4-methylcyclohex-3-enyl diisopropylcarbamothioate
    —— 5-Amino-6-(4-ethyl-2-thiazolylthio)-3H-isobenzofuran-1-one 181485-52-9 C13H12N2O2S2
    5-Amino-6-(4-ethyl-2-thiazolylthio)-3H-isobenzofuran-1-one