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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[[7-Chloro-5-[(phenylmethyl)thio]thiazolo[4,5-d]pyrimidin-2-yl]amino]-1-pentanol 259102-97-1 C17H19ClN4OS2
    2-[[7-Chloro-5-[(phenylmethyl)thio]thiazolo[4,5-d]pyrimidin-2-yl]amino]-1-pentanol
    —— 4-Acetylmercapto-3-chlor-2,5,6-trifluorpyridin 16572-71-7 C7H3ClF3NOS
    4-Acetylmercapto-3-chlor-2,5,6-trifluorpyridin
    —— 10,10-dimethyl-4,5,9-trithiaundeca-1,6-diene 1080588-41-5 C10H18S3
    10,10-dimethyl-4,5,9-trithiaundeca-1,6-diene
    —— 3-[[7-Chloro-5-[(phenylmethyl)thio]thiazolo[4,5-d]pyrimidin-2-yl]amino]-1-propanol 259103-23-6 C15H15ClN4OS2
    3-[[7-Chloro-5-[(phenylmethyl)thio]thiazolo[4,5-d]pyrimidin-2-yl]amino]-1-propanol
    —— (E)-4,5,9-trithiadodeca-1,6-diene 1080588-37-9 C9H16S3
    (E)-4,5,9-trithiadodeca-1,6-diene
    —— N-[2-[[7-Chloro-5-[(phenylmethyl)thio]thiazolo[4,5 d]pyrimidin-2-yl]amino]ethyl]-acetamide 259103-07-6 C16H16ClN5OS2
    N-[2-[[7-Chloro-5-[(phenylmethyl)thio]thiazolo[4,5 d]pyrimidin-2-yl]amino]ethyl]-acetamide
    —— 7-Chloro-N-methyl-5-[(phenylmethyl)thio]-thiazolo[4,5-d]pyrimidin-2-amine 259102-56-2 C13H11ClN4S2
    7-Chloro-N-methyl-5-[(phenylmethyl)thio]-thiazolo[4,5-d]pyrimidin-2-amine
    —— 7-Chloro-5-[(phenylmethyl)thio]-N-[(tetrahydro-2-furanyl)methyl]-thiazolo[4,5-d]pyrimidin-2-amine 259102-60-8 C17H17ClN4OS2
    7-Chloro-5-[(phenylmethyl)thio]-N-[(tetrahydro-2-furanyl)methyl]-thiazolo[4,5-d]pyrimidin-2-amine
    —— 7-Chloro-5-[(phenylmethyl)thio]-N-(4-piperidinyl)-thiazolo[4,5-d]pyrimidin-2-amine 259103-46-3 C17H18ClN5S2
    7-Chloro-5-[(phenylmethyl)thio]-N-(4-piperidinyl)-thiazolo[4,5-d]pyrimidin-2-amine
    —— 2-(N-methyl-3-piperidylmethylthio)pyridine-N-oxide 478620-32-5 C12H18N2OS
    2-(N-methyl-3-piperidylmethylthio)pyridine-N-oxide
    —— 1-Butene, 1-[(1-methylethyl)thio]-, (E)- 121222-72-8 C7H14S
    1-Butene, 1-[(1-methylethyl)thio]-, (E)-
    —— 1-[5-(3,5-dichloro-1-oxido-pyridin-1-ium-4-yl)sulfanyl-4-nitro-2-thienyl]ethanone 1247819-82-4 C11H6Cl2N2O4S2
    1-[5-(3,5-dichloro-1-oxido-pyridin-1-ium-4-yl)sulfanyl-4-nitro-2-thienyl]ethanone
    —— N-Hydroxy-4-(methylsulfanyl)benzene-1-carboximidoyl chloride 93394-07-1 C8H8ClNOS
    N-Hydroxy-4-(methylsulfanyl)benzene-1-carboximidoyl chloride
    —— Isobutyl-neopentyl-sulfon 10269-16-6 C9H20O2S
    Isobutyl-neopentyl-sulfon
    —— Dineopentyl-sulphon 10269-17-7 C10H22O2S
    Dineopentyl-sulphon
    —— 3,3'-Dithiodipropionamidin 15785-94-1 C6H14N4S2
    3,3'-Dithiodipropionamidin
    —— 1-{5-[(3,5-dichlorophenyl)thio]-4-nitrothiophen-2-yl}ethanone 1247819-69-7 C12H7Cl2NO3S2
    1-{5-[(3,5-dichlorophenyl)thio]-4-nitrothiophen-2-yl}ethanone
    —— (1-Azaniumyl-3-sulfanylpropan-2-yl)azanium;dibromide —— C3H12Br2N2S
    (1-Azaniumyl-3-sulfanylpropan-2-yl)azanium;dibromide
    —— 1-Methyl-2-phenylsulfanyl-cyclododecanol 112418-89-0 C19H30OS
    1-Methyl-2-phenylsulfanyl-cyclododecanol
    —— 1-[5-(3,5-dichloro-4-pyridylsulfanyl)-4-nitro-2-thienyl]ethanone 1247819-81-3 C11H6Cl2N2O3S2
    1-[5-(3,5-dichloro-4-pyridylsulfanyl)-4-nitro-2-thienyl]ethanone
    —— 1-[4-cyano-5-(2,4-dichlorophenyl)sulfanyl-2-thienyl]ethanone 1247819-88-0 C13H7Cl2NOS2
    1-[4-cyano-5-(2,4-dichlorophenyl)sulfanyl-2-thienyl]ethanone
    —— p-methylphenyl 2-deoxy-1-thio-6-O-triisopropylsilyl-D-galactopyranoside 918334-12-0 C22H38O4SSi
    p-methylphenyl 2-deoxy-1-thio-6-O-triisopropylsilyl-D-galactopyranoside
    —— hydroxymethyl-octyl sulfone 62954-90-9 C9H20O3S
    hydroxymethyl-octyl sulfone
    —— 1,1,3,3-tetramethylcyclobutane-2-spiro-2'-1,3-dithiolane-4'-spiro-2''-adamantane-2-one 100281-74-1 C19H28OS2
    1,1,3,3-tetramethylcyclobutane-2-spiro-2'-1,3-dithiolane-4'-spiro-2''-adamantane-2-one
    —— 4,5-dimethyl-[1,3]dioxolane-2-thione 24471-98-5 C5H8O2S
    4,5-dimethyl-[1,3]dioxolane-2-thione
    —— 6-(Hydroxymethyl)-2-(methylthio)nicotinonitrile 474823-68-2 C8H8N2OS
    6-(Hydroxymethyl)-2-(methylthio)nicotinonitrile
    —— 1,1,3,3,7,7,9,9-octamethyl-5,10-dithiadispiro[3.1.3.2]undecane-2,8-dione 23604-63-9 C17H26O2S2
    1,1,3,3,7,7,9,9-octamethyl-5,10-dithiadispiro[3.1.3.2]undecane-2,8-dione
    —— 2',2',4',4',6,6-hexamethyl-6,7-dihydrospiro-[1,3-benzoxathiole-2,1'-cyclobutane]-3',4(5H)-dione 1450644-23-1 C16H22O3S
    2',2',4',4',6,6-hexamethyl-6,7-dihydrospiro-[1,3-benzoxathiole-2,1'-cyclobutane]-3',4(5H)-dione
    —— 4-amino-3-allylthio-6-methyl-4H-1,2,4-triazin-5-one 220637-24-1 C7H10N4OS
    4-amino-3-allylthio-6-methyl-4H-1,2,4-triazin-5-one
    —— 2,3-Dimethyl-4-thiaoctane 66481-80-9 C9H20S
    2,3-Dimethyl-4-thiaoctane
    —— nonyl-propyl sulfide 62103-66-6 C12H26S
    nonyl-propyl sulfide
    —— 6-Thiadodecane 62103-67-7 C11H24S
    6-Thiadodecane
    —— Trithiacyclohexene 210237-55-1 C4H6S2
    Trithiacyclohexene
    —— Pyrazine, 3-methylthio-2-pentyl 113685-87-3 C10H16N2S
    Pyrazine, 3-methylthio-2-pentyl
    —— Isoamyl-n-amylsulfid 7352-01-4 C10H22S
    Isoamyl-n-amylsulfid
    —— 2,3-Dimethyl-4,5-dithiaoctane 72437-67-3 C8H18S2
    2,3-Dimethyl-4,5-dithiaoctane
    —— ethyl 2-(4-bromo-3-chlorophenylthio)acetate 1308279-94-8 C10H10BrClO2S
    ethyl 2-(4-bromo-3-chlorophenylthio)acetate
    —— 1-hydroxy-3-phenylthio-2-propanone 97798-47-5 C9H10O2S
    1-hydroxy-3-phenylthio-2-propanone
    —— 1,3-Dithiolo[4,5-b]furan, tetrahydro-3a-methyl- 67411-25-0 C6H10OS2
    1,3-Dithiolo[4,5-b]furan, tetrahydro-3a-methyl-
    —— 2-Allyl-2-phenylsulfanylmethyl-oxirane 159099-53-3 C12H14OS
    2-Allyl-2-phenylsulfanylmethyl-oxirane
    —— (5R,6R,9S)-9-Hydroxy-1-oxo-6-p-tolylsulfanyl-2-oxa-spiro[4.5]dec-7-ene-6-carboxylic acid methyl ester 141510-37-4 C18H20O5S
    (5R,6R,9S)-9-Hydroxy-1-oxo-6-p-tolylsulfanyl-2-oxa-spiro[4.5]dec-7-ene-6-carboxylic acid methyl ester
    —— dichloroplatinum;ethene;methylsulfinylmethane 31902-28-0 C4H10Cl2OPtS
    dichloroplatinum;ethene;methylsulfinylmethane
    —— 5-Isopropyl-3-methyl-2-(methylthio)pyrazine 99784-22-2 C9H14N2S
    5-Isopropyl-3-methyl-2-(methylthio)pyrazine
    —— Pyrazine, 2-(methylthio)-3-propyl- 68560-83-8 C8H12N2S
    Pyrazine, 2-(methylthio)-3-propyl-
    —— 2,2-bis(ethylthio)acetimidamide 1196536-37-4 C6H14N2S2
    2,2-bis(ethylthio)acetimidamide
    —— 3-Methyl-5-(2-methylpentyl)-2-(methylthio)pyrazine 78246-18-1 C12H20N2S
    3-Methyl-5-(2-methylpentyl)-2-(methylthio)pyrazine
    —— Methyl propyl tetrasulphide 87148-08-1 C4H10S4
    Methyl propyl tetrasulphide
    —— 1-(Propylthio)propyl methyl disulfide 126876-21-9 C7H16S3
    1-(Propylthio)propyl methyl disulfide
    —— 8-N-(cyclopropylmethyl)-4-N-(2-methylsulfanylphenyl)-2-(4-piperazin-1-ylpiperidin-1-yl)pyrimido[5,4-d]pyrimidine-4,8-diamine 1392889-18-7 C26H35N9S
    8-N-(cyclopropylmethyl)-4-N-(2-methylsulfanylphenyl)-2-(4-piperazin-1-ylpiperidin-1-yl)pyrimido[5,4-d]pyrimidine-4,8-diamine
    —— 3-(Phenylthio)methyl-2-oxolanon 54353-61-6 C11H12O2S
    3-(Phenylthio)methyl-2-oxolanon