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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-amino-9-(2-isopropoxy-ethyl)-8-(3,4,5-trimethoxy-phenylsulfanyl)adenine 852030-66-1 C19H26N6O4S
    2-amino-9-(2-isopropoxy-ethyl)-8-(3,4,5-trimethoxy-phenylsulfanyl)adenine
    —— 1-(4-chloro-phenylsulfanyl)-cyclobutanecarboxylic acid ethyl ester 1004769-98-5 C13H15ClO2S
    1-(4-chloro-phenylsulfanyl)-cyclobutanecarboxylic acid ethyl ester
    —— 2-fluoro-8-(3,4,5-trimethoxy-phenylsulfanyl)adenine 852030-69-4 C14H14FN5O3S
    2-fluoro-8-(3,4,5-trimethoxy-phenylsulfanyl)adenine
    —— pyridazine-3,6-diylbissulfanyl-bis-acetic acid 89977-20-8 C8H8N2O4S2
    pyridazine-3,6-diylbissulfanyl-bis-acetic acid
    —— 10H-Pyrido(3,2-b)(1,4)benzothiazine-10-carbothioic acid, 8-fluoro-, S-(2-(diisopropylamino)ethyl) ester, maleate 63885-97-2 C44H52F2N6O6S4
    10H-Pyrido(3,2-b)(1,4)benzothiazine-10-carbothioic acid, 8-fluoro-, S-(2-(diisopropylamino)ethyl) ester, maleate
    —— 4-((2-((Dimethylamino)methyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt) 127906-27-8 C19H21NO5S
    4-((2-((Dimethylamino)methyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt)
    —— 2-((2,5-Dimethoxyphenyl)thio)benzenemethanamine (Z)-2-butenedioate (1:1) 127906-02-9 C19H21NO6S
    2-((2,5-Dimethoxyphenyl)thio)benzenemethanamine (Z)-2-butenedioate (1:1)
    —— (1S)-1-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]-3,3-bis(phenylsulfanyl)propan-1-ol 323582-35-0 C20H24O3S2
    (1S)-1-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]-3,3-bis(phenylsulfanyl)propan-1-ol
    —— 1-(1-Imino-2-(2-(phenylthio)phenyl)ethyl)-4-methylpiperazine dimaleate hydrate 117596-43-7 C27H31N3O8S
    1-(1-Imino-2-(2-(phenylthio)phenyl)ethyl)-4-methylpiperazine dimaleate hydrate
    —— 3-((2-((Methylamino)methyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt) 127906-38-1 C18H19NO5S
    3-((2-((Methylamino)methyl)phenyl)thio)phenol (Z)-2-butenedioate (1:1) (salt)
    —— 2-<Bis(methylthio)methyl>cyclopent-1-one 103381-84-6 C8H14OS2
    2-<Bis(methylthio)methyl>cyclopent-1-one
    —— N,N-Dimethyl-2-(5-bromo-2-thienylthio)benzylamine maleate 134478-68-5 C17H18BrNO4S2
    N,N-Dimethyl-2-(5-bromo-2-thienylthio)benzylamine maleate
    —— 2-isopropyl-2-(2-formylethynyl)-1,3-dithiolane 1072800-71-5 C9H12OS2
    2-isopropyl-2-(2-formylethynyl)-1,3-dithiolane
    —— isopropyl (3-cyano-6-methyl-4-oxo-1,4-dihydro-2-pyridinyl)thioacetate 942895-04-7 C12H14N2O3S
    isopropyl (3-cyano-6-methyl-4-oxo-1,4-dihydro-2-pyridinyl)thioacetate
    —— methyl (6-methyl-2-piperidin-1-yl-pyrimidin-4-yl)-sulfanylacetate 347846-67-7 C13H19N3O2S
    methyl (6-methyl-2-piperidin-1-yl-pyrimidin-4-yl)-sulfanylacetate
    —— 1-bromo-3-(2-methyl-propane-2-sulfonyl)-propane 5755-80-6 C7H15BrO2S
    1-bromo-3-(2-methyl-propane-2-sulfonyl)-propane
    —— 7,8,16,17-bisbenzo-10,14-diaza-1,6-dithia-cycloheptadecane 1228649-25-9 C21H28N2S2
    7,8,16,17-bisbenzo-10,14-diaza-1,6-dithia-cycloheptadecane
    —— ethyl (3-cyano-6-methyl-4-oxo-1,4-dihydro-2-pyridinyl)thioacetate 942857-10-5 C11H12N2O3S
    ethyl (3-cyano-6-methyl-4-oxo-1,4-dihydro-2-pyridinyl)thioacetate
    —— 2-(6-Methyl-2-piperidin-1-ylpyrimidin-4-yl)sulfanylacetohydrazide 807621-17-6 C12H19N5OS
    2-(6-Methyl-2-piperidin-1-ylpyrimidin-4-yl)sulfanylacetohydrazide
    —— β,β'-dichlorodipropyl sulfone 86240-76-8 C6H12Cl2O2S
    β,β'-dichlorodipropyl sulfone
    —— bis-(3-chloro-propyl) sulfone 7767-78-4 C6H12Cl2O2S
    bis-(3-chloro-propyl) sulfone
    —— 3-(2-isopropyl-1,3-dithiolan-2-yl)prop-2-yn-1-ol 1072800-31-7 C9H14OS2
    3-(2-isopropyl-1,3-dithiolan-2-yl)prop-2-yn-1-ol
    —— 6-<<2-(N-methylamino)phenyl>thio>uracil 164029-06-5 C11H11N3O2S
    6-<<2-(N-methylamino)phenyl>thio>uracil
    —— 5-[(6-methyl-2-piperidin-1-ylpyrimidin-4-yl)sulfanylmethyl]-3H-1,3,4-oxadiazole-2-thione 347846-75-7 C13H17N5OS2
    5-[(6-methyl-2-piperidin-1-ylpyrimidin-4-yl)sulfanylmethyl]-3H-1,3,4-oxadiazole-2-thione
    —— 4-chloro-6-((R)-1-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)ethoxy)-2-(4-fluorobenzylthio)pyrimidine 1418112-79-4 C18H20ClFN2O3S
    4-chloro-6-((R)-1-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)ethoxy)-2-(4-fluorobenzylthio)pyrimidine
    —— N-(6-((R)-1-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)ethoxy)-2-(4-fluorobenzyl-thio)pyrimidin-4-yl)-3-methylazetidine-1-sulfonamide 1418112-80-7 C22H29FN4O5S2
    N-(6-((R)-1-((S)-2,2-dimethyl-1,3-dioxolan-4-yl)ethoxy)-2-(4-fluorobenzyl-thio)pyrimidin-4-yl)-3-methylazetidine-1-sulfonamide
    —— 6-<(2-aminophenyl)thio>uracil 65693-68-7 C10H9N3O2S
    6-<(2-aminophenyl)thio>uracil
    —— 1-(Methylsulfanyl)non-1-ene 53634-35-8 C10H20S
    1-(Methylsulfanyl)non-1-ene
    —— dimethyl-thiocarbamic acid S-(4-phenoxyphenyl) ester 13511-99-4 C9H11NO2S
    dimethyl-thiocarbamic acid S-(4-phenoxyphenyl) ester
    —— 2H-1,2,4-triazole-3-thiol 305848-41-3 C4H3N3OS
    2H-1,2,4-triazole-3-thiol
    —— 1-methylsulfanyl-hex-1-ene 89795-38-0 C7H14S
    1-methylsulfanyl-hex-1-ene
    —— 4-Carboxymethylthio-3-nitropyridine 18504-85-3 C7H6N2O4S
    4-Carboxymethylthio-3-nitropyridine
    —— γ-phenylthiopropynal diethyl acetal 163189-53-5 C13H16O2S
    γ-phenylthiopropynal diethyl acetal
    —— 4-Methylmercapto-benzoldiazonium-chlorid 69360-76-5 C7H7N2S*Cl
    4-Methylmercapto-benzoldiazonium-chlorid
    —— 4-(1-(5-Chloro-2-((4-chlorophenyl)thio)phenyl)ethyl)-1-methylpiperazine bismaleate 112446-50-1 C27H30Cl2N2O8S
    4-(1-(5-Chloro-2-((4-chlorophenyl)thio)phenyl)ethyl)-1-methylpiperazine bismaleate
    —— 2-amino-4-(2-(phenylthio)quinolin-3-yl)-5-oxo-7-methyl-4,5-dihydropyrano[4,3-b]pyran-3-carbonitrile 1376342-22-1 C25H17N3O3S
    2-amino-4-(2-(phenylthio)quinolin-3-yl)-5-oxo-7-methyl-4,5-dihydropyrano[4,3-b]pyran-3-carbonitrile
    —— 2-amino-4-(2-(p-chlorophenylthio)quinolin-3-yl)-5-oxo-7-methyl-4,5-dihydropyrano[4,3-b]pyran-3-carbonitrile 1376342-30-1 C25H16ClN3O3S
    2-amino-4-(2-(p-chlorophenylthio)quinolin-3-yl)-5-oxo-7-methyl-4,5-dihydropyrano[4,3-b]pyran-3-carbonitrile
    —— 3-oxo-3,4-dihydro-2H-pyrido[3,2-b][1,4]thiazine-6-sulfonyl chloride 875551-27-2 C7H5ClN2O3S2
    3-oxo-3,4-dihydro-2H-pyrido[3,2-b][1,4]thiazine-6-sulfonyl chloride
    —— N,N-Dimethyl-2,2-dichloro-3-methylcyclopropanethioamide 155193-21-8 C7H11Cl2NS
    N,N-Dimethyl-2,2-dichloro-3-methylcyclopropanethioamide
    —— ethyl 2-methyl-2-phenylthiobut-3-enoate 73311-61-2 C13H16O2S
    ethyl 2-methyl-2-phenylthiobut-3-enoate
    —— (E)-ethyl 2-methyl-4-phenylthiobut-2-enoate 86895-84-3 C13H16O2S
    (E)-ethyl 2-methyl-4-phenylthiobut-2-enoate
    —— 4-bromo-3-(t-butylsulfanyl)thiophene-2-carbaldehyde 1391908-41-0 C9H11BrOS2
    4-bromo-3-(t-butylsulfanyl)thiophene-2-carbaldehyde
    —— 4-bromo-3-(t-butylsulfanyl)-2-ethynylthiophene 1391908-42-1 C10H11BrS2
    4-bromo-3-(t-butylsulfanyl)-2-ethynylthiophene
    —— 3-(4-chlorophenyl)-3-(phenylthio)-1-(thiophen-3-yl)propan-1-one 1373257-65-8 C19H15ClOS2
    3-(4-chlorophenyl)-3-(phenylthio)-1-(thiophen-3-yl)propan-1-one
    —— 2-methyl-2-(thiophen-3-yl)-1,3-dithiolane 83521-86-2 C8H10S3
    2-methyl-2-(thiophen-3-yl)-1,3-dithiolane
    —— 2-(thiophen-3-yl)-3-[(3,4,5-trimethoxyphenyl)thio]-1H-indole 1337932-87-2 C21H19NO3S2
    2-(thiophen-3-yl)-3-[(3,4,5-trimethoxyphenyl)thio]-1H-indole
    —— Bithifen 57484-86-3 C12H7Cl4O2S2
    Bithifen
    —— 2-[6-(2-Hydroxyethylsulfanyl)-4-methylthieno[2,3-c]pyrrol-5-yl]ethanol 1431866-04-4 C11H15NO2S2
    2-[6-(2-Hydroxyethylsulfanyl)-4-methylthieno[2,3-c]pyrrol-5-yl]ethanol
    —— 3-oxo-5-phenylthio-amyl mesylate 101750-87-2 C12H16O4S2
    3-oxo-5-phenylthio-amyl mesylate
    —— 2-(2-methylsulfanyl-ethyl)-buta-1,3-diene 57116-20-8 C7H12S
    2-(2-methylsulfanyl-ethyl)-buta-1,3-diene