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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [(methoxymethyl)thio]acetic acid methyl ester 61677-76-7 C5H10O3S
    [(methoxymethyl)thio]acetic acid methyl ester
    —— 2,5-Dimethyl-3-(propylsulfanyl)furan 55764-24-4 C9H14OS
    2,5-Dimethyl-3-(propylsulfanyl)furan
    —— Oct-2-ene-1-thiol 61758-07-4 C8H16S
    Oct-2-ene-1-thiol
    —— 2-[(3-Fluorophenyl)thio]acetamide 705-85-1 C8H8FNOS
    2-[(3-Fluorophenyl)thio]acetamide
    —— 3-[(2-Methylfuran-3-yl)sulfanyl]butan-2-ol 59190-24-8 C9H14O2S
    3-[(2-Methylfuran-3-yl)sulfanyl]butan-2-ol
    —— 1-[(But-2-en-1-yl)sulfanyl]-4-methylbenzene 61529-83-7 C11H14S
    1-[(But-2-en-1-yl)sulfanyl]-4-methylbenzene
    —— 2,5-dimethyl-3-(2-methyl-furan-3-ylsulfanyl)-pyrazine 61720-49-8 C11H12N2OS
    2,5-dimethyl-3-(2-methyl-furan-3-ylsulfanyl)-pyrazine
    —— 2-[4-(4-chloro-benzylamino)-6-propyl-pyrimidin-2-ylsulfanyl]-<i>N</i>-hydroxy-acetamidine 59761-79-4 C16H20ClN5OS
    2-[4-(4-chloro-benzylamino)-6-propyl-pyrimidin-2-ylsulfanyl]-<i>N</i>-hydroxy-acetamidine
    —— 3-Aethylsulfinylpropin 25558-05-8 C5H8OS
    3-Aethylsulfinylpropin
    —— Aminoethyne-1-thiol 92681-08-8 C2H3NS
    Aminoethyne-1-thiol
    —— 3,3-Bisethylthiopropene 89975-79-1 C7H14S2
    3,3-Bisethylthiopropene
    —— 1,2-Bis(sulfanyl)butane-1,1-diol 26950-40-3 C4H10O2S2
    1,2-Bis(sulfanyl)butane-1,1-diol
    —— Methyl-4-isopropyl-1-thioallophanimidat 40943-39-3 C6H13N3OS
    Methyl-4-isopropyl-1-thioallophanimidat
    —— {3-(4-Fluorophenyl)-4-[2-(methylsulfanyl)pyrimidin-4-yl]-1,2-oxazol-5-yl}methanol 673451-64-4 C15H12FN3O2S
    {3-(4-Fluorophenyl)-4-[2-(methylsulfanyl)pyrimidin-4-yl]-1,2-oxazol-5-yl}methanol
    —— 4-[(2,2,2-Trifluoroethyl)sulfanyl]benzene-1,2-diamine 54029-83-3 C8H9F3N2S
    4-[(2,2,2-Trifluoroethyl)sulfanyl]benzene-1,2-diamine
    —— 1-Isothiocyanato-5-methylhexane 138584-06-2 C8H15NS
    1-Isothiocyanato-5-methylhexane
    —— Propane, 1-(ethylthio)-3-isothiocyanato- 1701597-03-6 C6H11NS2
    Propane, 1-(ethylthio)-3-isothiocyanato-
    —— pent-2-ene-1-thiol 89222-68-4 C5H10S
    pent-2-ene-1-thiol
    —— Aminomethanesulfonothioic O-acid 193206-15-4 CH5NO2S2
    Aminomethanesulfonothioic O-acid
    —— methyl N-[N-methoxycarbonyl-N'-[2-[(2-phenoxyacetyl)amino]-4-phenylsulfanylphenyl]carbamimidoyl]carbamate 73851-14-6 C25H24N4O6S
    methyl N-[N-methoxycarbonyl-N'-[2-[(2-phenoxyacetyl)amino]-4-phenylsulfanylphenyl]carbamimidoyl]carbamate
    —— 4-[(2,2,3,3,3-Pentafluoropropyl)sulfanyl]benzene-1,2-diamine 54029-85-5 C9H9F5N2S
    4-[(2,2,3,3,3-Pentafluoropropyl)sulfanyl]benzene-1,2-diamine
    —— 2-(4-chlorophenyl)sulfanyl-6-[3-methoxy-4-(2-pyrrolidin-1-ylethoxy)phenyl]-5H-pyrrolo[3,4-b]pyridin-7-one 1373433-03-4 C26H26ClN3O3S
    2-(4-chlorophenyl)sulfanyl-6-[3-methoxy-4-(2-pyrrolidin-1-ylethoxy)phenyl]-5H-pyrrolo[3,4-b]pyridin-7-one
    —— 3-(Ethenesulfonyl)-N-[3-(ethenesulfonyl)propyl]propan-1-amine 112078-52-1 C10H19NO4S2
    3-(Ethenesulfonyl)-N-[3-(ethenesulfonyl)propyl]propan-1-amine
    —— 6-[3-methoxy-4-(2-pyrrolidin-1-ylethoxy)phenyl]-2-(4-methylphenyl)sulfanyl-5H-pyrrolo[3,4-b]pyridin-7-one 1373433-04-5 C27H29N3O3S
    6-[3-methoxy-4-(2-pyrrolidin-1-ylethoxy)phenyl]-2-(4-methylphenyl)sulfanyl-5H-pyrrolo[3,4-b]pyridin-7-one
    —— (1R,2R)-2-[(2-Methylfuran-3-yl)sulfanyl]cyclohexan-1-ol 61295-48-5 C11H16O2S
    (1R,2R)-2-[(2-Methylfuran-3-yl)sulfanyl]cyclohexan-1-ol
    —— 2-(4-methoxyphenyl)sulfanyl-6-[3-methoxy-4-(2-pyrrolidin-1-ylethoxy)phenyl]-5H-pyrrolo[3,4-b]pyridin-7-one 1373433-05-6 C27H29N3O4S
    2-(4-methoxyphenyl)sulfanyl-6-[3-methoxy-4-(2-pyrrolidin-1-ylethoxy)phenyl]-5H-pyrrolo[3,4-b]pyridin-7-one
    —— 2-Dimethylamino-1,1-bis-trifluormethansulfonyl-ethen 58510-91-1 C6H7F6NO4S2
    2-Dimethylamino-1,1-bis-trifluormethansulfonyl-ethen
    —— 2-(3,4-difluorophenyl)sulfanyl-6-[3-methoxy-4-(2-pyrrolidin-1-ylethoxy)phenyl]-5H-pyrrolo[3,4-b]pyridin-7-one 1373433-08-9 C26H25F2N3O3S
    2-(3,4-difluorophenyl)sulfanyl-6-[3-methoxy-4-(2-pyrrolidin-1-ylethoxy)phenyl]-5H-pyrrolo[3,4-b]pyridin-7-one
    —— 2-(2,4-difluorophenyl)sulfanyl-6-[3-methoxy-4-(2-pyrrolidin-1-ylethoxy)phenyl]-5H-pyrrolo[3,4-b]pyridin-7-one 1373433-06-7 C26H25F2N3O3S
    2-(2,4-difluorophenyl)sulfanyl-6-[3-methoxy-4-(2-pyrrolidin-1-ylethoxy)phenyl]-5H-pyrrolo[3,4-b]pyridin-7-one
    —— 4-[3-[2-(dimethylamino)ethoxy]-11-ethyl-6H-benzo[c][1]benzothiocin-12-yl]phenol 85850-81-3 C27H29NO2S
    4-[3-[2-(dimethylamino)ethoxy]-11-ethyl-6H-benzo[c][1]benzothiocin-12-yl]phenol
    —— 1-(Trifluoromethanesulfonyl)heptane 61795-00-4 C8H15F3O2S
    1-(Trifluoromethanesulfonyl)heptane
    —— 1-[2-[(3,5-Dibromophenyl)methylsulfanyl]phenyl]guanidine 1314034-06-4 C14H13Br2N3S
    1-[2-[(3,5-Dibromophenyl)methylsulfanyl]phenyl]guanidine
    —— 7-(3-trifluoromethyl-phenylsulfanyl)-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole 1246244-92-7 C18H17F3N2S
    7-(3-trifluoromethyl-phenylsulfanyl)-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole
    —— 2-(6-hydroxy-6-methylheptylthio)-4-methyl-6-(5-methyl-1H-pyrazol-3-ylamino)nicotinonitrile 1024869-24-6 C19H27N5OS
    2-(6-hydroxy-6-methylheptylthio)-4-methyl-6-(5-methyl-1H-pyrazol-3-ylamino)nicotinonitrile
    —— 7-(4-trifluoromethyl-phenylsulfanyl)-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole 1246244-94-9 C18H17F3N2S
    7-(4-trifluoromethyl-phenylsulfanyl)-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole
    —— 7-p-tolylsulfanyl-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole 1246244-78-9 C18H20N2S
    7-p-tolylsulfanyl-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole
    —— 6-phenylthio-1,3-dihydro-1-hydroxy-2,1-benzoxaborole 906673-34-5 C13H11BO2S
    6-phenylthio-1,3-dihydro-1-hydroxy-2,1-benzoxaborole
    —— 1,2-Dicyclohexyl-3-[2-[(3,5-dibromophenyl)methylsulfanyl]phenyl]guanidine 1314034-07-5 C26H33Br2N3S
    1,2-Dicyclohexyl-3-[2-[(3,5-dibromophenyl)methylsulfanyl]phenyl]guanidine
    —— 7-(4-fluoro-phenylsulfanyl)-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole 1246244-82-5 C17H17FN2S
    7-(4-fluoro-phenylsulfanyl)-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole
    —— 7-(3-methoxy-phenylsulfanyl)-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole 1246244-86-9 C18H20N2OS
    7-(3-methoxy-phenylsulfanyl)-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole
    —— 7-o-tolylsulfanyl-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole 1246244-75-6 C18H20N2S
    7-o-tolylsulfanyl-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole
    —— 1-[2-[(4-Chlorophenyl)methylsulfanyl]phenyl]guanidine 1314033-98-1 C14H14ClN3S
    1-[2-[(4-Chlorophenyl)methylsulfanyl]phenyl]guanidine
    —— 3-[(4-Chlorophenyl)sulfanylmethyl]pyridine;hydrochloride 88594-68-7 C12H11Cl2NS
    3-[(4-Chlorophenyl)sulfanylmethyl]pyridine;hydrochloride
    —— 1-[2-[(4-Chlorophenyl)methylsulfanyl]phenyl]-2,3-dicyclohexyl-guanidine 1314033-99-2 C26H34ClN3S
    1-[2-[(4-Chlorophenyl)methylsulfanyl]phenyl]-2,3-dicyclohexyl-guanidine
    —— 7-(4-methoxy-phenylsulfanyl)-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole 1246244-88-1 C18H20N2OS
    7-(4-methoxy-phenylsulfanyl)-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole
    —— 1-[3-[(4-Chlorophenyl)methylsulfanyl]phenyl]-2,3-dicyclohexyl-guanidine 1314034-01-9 C26H34ClN3S
    1-[3-[(4-Chlorophenyl)methylsulfanyl]phenyl]-2,3-dicyclohexyl-guanidine
    —— 2-(3,5-Dibromobenzylthio)Aniline 1314034-08-6 C13H11Br2NS
    2-(3,5-Dibromobenzylthio)Aniline
    —— 7-(2-fluoro-phenylsulfanyl)-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole 1246244-80-3 C17H17FN2S
    7-(2-fluoro-phenylsulfanyl)-1,2,3,4,10,10a-hexahydro-pyrazino[1,2-a]indole
    —— 1,2-Dicyclohexyl-3-[4-[(3,5-dibromophenyl)methylsulfanyl]phenyl]guanidine 1314034-13-3 C26H33Br2N3S
    1,2-Dicyclohexyl-3-[4-[(3,5-dibromophenyl)methylsulfanyl]phenyl]guanidine
    —— 1-[3-[(4-Chlorophenyl)methylsulfanyl]phenyl]guanidine 1314034-00-8 C14H14ClN3S
    1-[3-[(4-Chlorophenyl)methylsulfanyl]phenyl]guanidine