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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-bromo-5-[(3-methoxyphenyl)thio]thiophene-2-carbaldehyde 1138032-94-6 C12H9BrO2S2
    4-bromo-5-[(3-methoxyphenyl)thio]thiophene-2-carbaldehyde
    —— 3-(phenylthio)isonicotinic acid 412339-07-2 C12H9NO2S
    3-(phenylthio)isonicotinic acid
    —— methyl 2,2-bis(phenylthio)-1-methylcyclopropanecarboxylate 100082-42-6 C18H18O2S2
    methyl 2,2-bis(phenylthio)-1-methylcyclopropanecarboxylate
    —— 1-octylsulfonyl-2-butene 78652-00-3 C12H24O2S
    1-octylsulfonyl-2-butene
    —— 6-((3-Oxohept-1-en-1-yl)thio)-1,2,4-triazine-3,5(2H,4H)-dione 80037-02-1 C10H13N3O3S
    6-((3-Oxohept-1-en-1-yl)thio)-1,2,4-triazine-3,5(2H,4H)-dione
    —— 3-t-Butyl-9-methyl-9-trichloromethyl-1,5-dithiaspiro[5.5]undecane 130338-07-7 C15H25Cl3S2
    3-t-Butyl-9-methyl-9-trichloromethyl-1,5-dithiaspiro[5.5]undecane
    —— Isobutyl-N-isobutoxycarbonylthiocarbamat 39142-39-7 C10H19NO3S
    Isobutyl-N-isobutoxycarbonylthiocarbamat
    —— 2,2-bis(3-methylthio-1H-1,2,4-triazol-1-yl)-propane 118718-07-3 C9H14N6S2
    2,2-bis(3-methylthio-1H-1,2,4-triazol-1-yl)-propane
    —— 1,4-diacetyl-5,5-dimethyl-3-methylsulfonyl-4,5-dihydro-1H-1,2,4-triazole 118807-27-5 C9H15N3O4S
    1,4-diacetyl-5,5-dimethyl-3-methylsulfonyl-4,5-dihydro-1H-1,2,4-triazole
    —— 1-(3,3-dimethyl-5-methylsulfonyl-1H-1,2,4-triazol-2-yl)ethanone 118807-33-3 C7H13N3O3S
    1-(3,3-dimethyl-5-methylsulfonyl-1H-1,2,4-triazol-2-yl)ethanone
    —— 2-(3-ethylthio-1H-1,2,4-triazol-1-yl)-2-(3-methylthio-1H-1,2,4-triazol-1-yl)propane 118718-18-6 C10H16N6S2
    2-(3-ethylthio-1H-1,2,4-triazol-1-yl)-2-(3-methylthio-1H-1,2,4-triazol-1-yl)propane
    —— 3-ethylsulfanyl-1-[2-(3-ethylsulfanyl-1,2,4-triazol-1-yl)propan-2-yl]-1,2,4-triazole 118718-08-4 C11H18N6S2
    3-ethylsulfanyl-1-[2-(3-ethylsulfanyl-1,2,4-triazol-1-yl)propan-2-yl]-1,2,4-triazole
    —— methyl (1E)-N-[methyl-[methyl-[(Z)-1-methylsulfanylethylideneamino]oxycarbonylamino]sulfanylcarbamoyl]oxyethanimidothioate 59669-26-0 C10H18N4O4S3
    methyl (1E)-N-[methyl-[methyl-[(Z)-1-methylsulfanylethylideneamino]oxycarbonylamino]sulfanylcarbamoyl]oxyethanimidothioate
    —— 2-phenylsulfanyl-[1]naphthylamine 858431-60-4 C16H13NS
    2-phenylsulfanyl-[1]naphthylamine
    —— 6-Amino-2-methyl-2-phenylsulfanylhexan-3-ol 852806-73-6 C13H21NOS
    6-Amino-2-methyl-2-phenylsulfanylhexan-3-ol
    —— 1,3-bis[(Z)-dodecylideneamino]thiourea 7400-39-7 C25H50N4S
    1,3-bis[(Z)-dodecylideneamino]thiourea
    —— bis(2-methyltetrahydrothienyl-2)sulfide 62308-53-6 C10H18S3
    bis(2-methyltetrahydrothienyl-2)sulfide
    —— 2-<<(p-bromophenyl)thio>methyl>-6-chloropyridine 83782-48-3 C12H9BrClNS
    2-<<(p-bromophenyl)thio>methyl>-6-chloropyridine
    —— ethyl n-octyl sulfone 34008-69-0 C10H22O2S
    ethyl n-octyl sulfone
    —— N-(4-hydroxy-5-methyl-5-phenylsulfanylhexyl)formamide 852806-78-1 C14H21NO2S
    N-(4-hydroxy-5-methyl-5-phenylsulfanylhexyl)formamide
    —— methyl N-(4-hydroxy-5-methyl-5-phenylsulfanylhexyl)carbamate 852806-74-7 C15H23NO3S
    methyl N-(4-hydroxy-5-methyl-5-phenylsulfanylhexyl)carbamate
    —— ethyl octyl sulfoxide 13126-09-5 C10H22OS
    ethyl octyl sulfoxide
    —— (E)-2-ethylsulfanylhept-2-enenitrile 68872-39-9 C9H15NS
    (E)-2-ethylsulfanylhept-2-enenitrile
    —— (-)-(1S,6S,9S)-8-phenylthio-5,5,9-trimethyltricyclo[7.2.1.0<sup>1,6</sup>]dodec-7-en-10-one 674781-50-1 C21H26OS
    (-)-(1S,6S,9S)-8-phenylthio-5,5,9-trimethyltricyclo[7.2.1.0<sup>1,6</sup>]dodec-7-en-10-one
    —— 4-(2-Bromophenyl)sulfanylbenzene-1,2-diamine 164801-40-5 C12H11BrN2S
    4-(2-Bromophenyl)sulfanylbenzene-1,2-diamine
    —— methyl N-[(E)-4-methylpentan-2-ylideneamino]carbamodithioate —— C8H16N2S2
    methyl N-[(E)-4-methylpentan-2-ylideneamino]carbamodithioate
    —— bis(3,6-dioxopyridazino[4,5-d])tetrathiafuvlalene 1359021-04-7 C10H4N4O4S4
    bis(3,6-dioxopyridazino[4,5-d])tetrathiafuvlalene
    —— 6-oxo-3-vinyl-6,7-dihydro-5H-pyridazino[3,4-b][1,4]thiazine 495415-03-7 C8H7N3OS
    6-oxo-3-vinyl-6,7-dihydro-5H-pyridazino[3,4-b][1,4]thiazine
    —— 2,3',4'-Triamino-diphenylsulfid 19667-84-6 C12H13N3S
    2,3',4'-Triamino-diphenylsulfid
    —— 2-[(5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]acetic acid 1489284-65-2 C19H14N2O5S3
    2-[(5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]acetic acid
    —— 4-methylethylenedithio-1,3-dithiole-2-one 118148-18-8 C6H6OS4
    4-methylethylenedithio-1,3-dithiole-2-one
    —— 2-(4,5-bis(butylthio)-1,3-dithiol-2-ylidene)-7-methoxy-[1,3]dithiolo[4,5-d]pyridazin-4(5H)-one 1359021-06-9 C17H22N2O2S6
    2-(4,5-bis(butylthio)-1,3-dithiol-2-ylidene)-7-methoxy-[1,3]dithiolo[4,5-d]pyridazin-4(5H)-one
    —— methyl (1E)-2-methyl-N-(methylcarbamoyloxy)propanimidothioate 17564-93-1 C7H14N2O2S
    methyl (1E)-2-methyl-N-(methylcarbamoyloxy)propanimidothioate
    —— 3-{4-[(o-methoxy)phenylthio]-1,2-phenylenediamine}-5,5-dimethyl-2-cyclohexenone 1027562-84-0 C21H24N2O2S
    3-{4-[(o-methoxy)phenylthio]-1,2-phenylenediamine}-5,5-dimethyl-2-cyclohexenone
    —— 2-isopropyl-2-<3'(1,3-dithiolanyl)butyl>thiazolidine 156000-15-6 C12H23NS3
    2-isopropyl-2-<3'(1,3-dithiolanyl)butyl>thiazolidine
    —— 5-(4-chlorophenylthio)-2-nitroaniline 60853-98-7 C12H9ClN2O2S
    5-(4-chlorophenylthio)-2-nitroaniline
    —— 4-(4-Chlorophenyl)sulfanylbenzene-1,2-diamine 164801-39-2 C12H11ClN2S
    4-(4-Chlorophenyl)sulfanylbenzene-1,2-diamine
    —— 5-chloro-5,6-dihydro[1,3]dithiolo[4,5-b][1,4]dithiin-2-one 292050-38-5 C5H3ClOS4
    5-chloro-5,6-dihydro[1,3]dithiolo[4,5-b][1,4]dithiin-2-one
    —— 2-(4,7-dihydroxybenzo[1,3]dithiol-2-ylidene)-[1,3]dithiole-4,5-dicarboxylic acid dimethyl ester 884902-20-9 C14H10O6S4
    2-(4,7-dihydroxybenzo[1,3]dithiol-2-ylidene)-[1,3]dithiole-4,5-dicarboxylic acid dimethyl ester
    —— 2-(4,7-di(tert-butyldiphenylsilyloxy)benzo[1,3]dithiol-2-ylidene)-[1,3]dithiole-4,5-dicarboxylic acid dimethyl ester 884902-11-8 C46H46O6S4Si2
    2-(4,7-di(tert-butyldiphenylsilyloxy)benzo[1,3]dithiol-2-ylidene)-[1,3]dithiole-4,5-dicarboxylic acid dimethyl ester
    —— Methoxy-oxo-(phenylsulfanylmethyl)phosphanium 7351-36-2 C8H10O2PS+
    Methoxy-oxo-(phenylsulfanylmethyl)phosphanium
    —— 1-benzenesulfonyl-2-ethoxymethyl-3-phenylsulfanyl-1H-indole 1186301-29-0 C23H21NO3S2
    1-benzenesulfonyl-2-ethoxymethyl-3-phenylsulfanyl-1H-indole
    —— formic acid 1-benzenesulfonyl-3-phenylsulfanyl-1H-indol-2-ylmethyl ester 1186301-26-7 C22H17NO4S2
    formic acid 1-benzenesulfonyl-3-phenylsulfanyl-1H-indol-2-ylmethyl ester
    —— 1-benzenesulfonyl-3-phenylsulfanyl-2-p-tolyloxymethyl-1H-indole 1186301-31-4 C28H23NO3S2
    1-benzenesulfonyl-3-phenylsulfanyl-2-p-tolyloxymethyl-1H-indole
    —— 1-benzenesulfonyl-2-isobutoxymethyl-3-phenylsulfanyl-1H-indole 1186301-30-3 C25H25NO3S2
    1-benzenesulfonyl-2-isobutoxymethyl-3-phenylsulfanyl-1H-indole
    —— 1-benzenesulfonyl-2-methoxymethyl-3-phenylsulfanyl-1H-indole 1186301-28-9 C22H19NO3S2
    1-benzenesulfonyl-2-methoxymethyl-3-phenylsulfanyl-1H-indole
    —— methyl-{3-[6-(4-methyl-4H-[1,2,4]triazol-3-ylsulfanyl)-quinolin-4-ylsulfanyl]-[1,2,4]triazolo[4,3-b]pyridazin-6-yl}-amine 1022151-30-9 C18H15N9S2
    methyl-{3-[6-(4-methyl-4H-[1,2,4]triazol-3-ylsulfanyl)-quinolin-4-ylsulfanyl]-[1,2,4]triazolo[4,3-b]pyridazin-6-yl}-amine
    —— 4,6-bis(6-methylamino-[1,2,4]triazolo[4,3-b]pyridazin-3-ylsulfanyl)-quinoline 1022151-05-8 C21H17N11S2
    4,6-bis(6-methylamino-[1,2,4]triazolo[4,3-b]pyridazin-3-ylsulfanyl)-quinoline
    —— methyl-{3-[4-(4-methyl-4H-[1,2,4]triazol-3-ylsulfanyl)-quinolin-6-ylsulfanyl]-[1,2,4]triazolo[4,3-b]pyridazin-6-yl}-amine 1022151-04-7 C18H15N9S2
    methyl-{3-[4-(4-methyl-4H-[1,2,4]triazol-3-ylsulfanyl)-quinolin-6-ylsulfanyl]-[1,2,4]triazolo[4,3-b]pyridazin-6-yl}-amine
    —— isobutylxanthate monoanion 44744-64-1 C5H9OS2
    isobutylxanthate monoanion