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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— tert-Butyl-((R)-2-methoxymethoxy-7-phenylsulfanyl-heptyloxy)-diphenyl-silane 201472-34-6 C31H42O3SSi
    tert-Butyl-((R)-2-methoxymethoxy-7-phenylsulfanyl-heptyloxy)-diphenyl-silane
    —— 6-(3,5-dimethylbenzyl)-5-ethyl-2-(methylthio)pyrimidine-4(1H)-one 1056025-54-7 C16H20N2OS
    6-(3,5-dimethylbenzyl)-5-ethyl-2-(methylthio)pyrimidine-4(1H)-one
    —— S-n-Butyl (phenylthio)thioacetate 63006-69-9 C12H16OS2
    S-n-Butyl (phenylthio)thioacetate
    —— 1-Oxa-4-thiaspiro[4.4]nonane, 6,9-dimethyl- 57156-88-4 C9H16OS
    1-Oxa-4-thiaspiro[4.4]nonane, 6,9-dimethyl-
    —— 1,4-Dithiacyclohept-2-ene 70063-50-2 C5H8S2
    1,4-Dithiacyclohept-2-ene
    —— 2-phenyl-2-allyl-1,3-dithiane 84537-35-9 C13H16S2
    2-phenyl-2-allyl-1,3-dithiane
    —— bis(N,N-dibutylcarbamoyl)disulfide 91481-37-7 C18H36N2O2S2
    bis(N,N-dibutylcarbamoyl)disulfide
    —— Dodecanethioamide, N,N-diethyl- 143593-91-3 C16H33NS
    Dodecanethioamide, N,N-diethyl-
    —— (R)-3-(tert-butyldimethylsilyloxy)-4-(2-ethyl-1,3-dithian-2-yl)butanal 1221821-51-7 C16H32O2S2Si
    (R)-3-(tert-butyldimethylsilyloxy)-4-(2-ethyl-1,3-dithian-2-yl)butanal
    —— 4-((R)-Butane-1-sulfinyl)-but-1-ene 188954-51-0 C8H16OS
    4-((R)-Butane-1-sulfinyl)-but-1-ene
    —— 1-isopentyl-7-(methylthio)-1H-pyrimido[4,5-d][1,3]oxazine-2,4-dione 1186049-75-1 C12H15N3O3S
    1-isopentyl-7-(methylthio)-1H-pyrimido[4,5-d][1,3]oxazine-2,4-dione
    —— 1,1-di(phenylthio)-2-cyclohexylcyclobutane 122732-91-6 C22H26S2
    1,1-di(phenylthio)-2-cyclohexylcyclobutane
    —— 1-Oxa-6,6a-dithiapentalen 25336-68-9 C5H4OS2
    1-Oxa-6,6a-dithiapentalen
    —— 1-(1-Adamantylcarbonyl)-3,5-dimethyl-4-(phenylsulfanyl)-1H-pyrazole 5322-27-0 C22H26N2OS
    1-(1-Adamantylcarbonyl)-3,5-dimethyl-4-(phenylsulfanyl)-1H-pyrazole
    —— (S)-(+)-2-t-butylthio-3-cyclohexyl-propanal 155996-75-1 C13H24OS
    (S)-(+)-2-t-butylthio-3-cyclohexyl-propanal
    —— 2-Methyl-pent-4-ynethioic acid diethylamide 35946-24-8 C10H17NS
    2-Methyl-pent-4-ynethioic acid diethylamide
    —— 1-adamantylethylurea 25444-84-2 C13H22N2S
    1-adamantylethylurea
    —— Adamantan-1-dithiocarbonsaeure 139759-11-8 C11H16S2
    Adamantan-1-dithiocarbonsaeure
    —— 1-(3-Hydroxy-2-pyridilthio)-propanon-2 30221-74-0 C8H9NO2S
    1-(3-Hydroxy-2-pyridilthio)-propanon-2
    —— 2-(2,4-dinitro-phenylsulfanyl)-benzoic acid methyl ester 309253-52-9 C14H10N2O6S
    2-(2,4-dinitro-phenylsulfanyl)-benzoic acid methyl ester
    —— α,α'-bis[(5-amino-1,3,4-thiadiazol-2-yl)thio]-o-xylene 499992-37-9 C12H12N6S4
    α,α'-bis[(5-amino-1,3,4-thiadiazol-2-yl)thio]-o-xylene
    —— 3-Hexene, 3-chloro-4-(methylthio)-, (E)- 112303-27-2 C7H13ClS
    3-Hexene, 3-chloro-4-(methylthio)-, (E)-
    —— bis(4-cyano-2,3,5,6-tetrafluorophenyl) sulfide 60435-74-7 C14F8N2S
    bis(4-cyano-2,3,5,6-tetrafluorophenyl) sulfide
    —— 4-(3-Buten-1-yl)-6-chloro-2-(methylthio)pyrimidine 845534-15-8 C9H11ClN2S
    4-(3-Buten-1-yl)-6-chloro-2-(methylthio)pyrimidine
    —— 1,2-di(phenylthiomethyl)benzene 105961-94-2 C20H18S2
    1,2-di(phenylthiomethyl)benzene
    —— (2R)-2-[[2-Bromo-5-[[(2,3-difluorophenyl)methyl]thio]thiazolo[4,5-d)pyrimidin-7-yl]amino]-1-propanol 333743-04-7 C15H13BrF2N4OS2
    (2R)-2-[[2-Bromo-5-[[(2,3-difluorophenyl)methyl]thio]thiazolo[4,5-d)pyrimidin-7-yl]amino]-1-propanol
    —— 2-(1-hydroxy-3-methylbutyl)-2-ethyl-1,3-dithiane 332048-49-4 C11H22OS2
    2-(1-hydroxy-3-methylbutyl)-2-ethyl-1,3-dithiane
    —— (Z)-3-(2-Amino-phenylsulfanyl)-acrylic acid ethyl ester 74675-57-3 C11H13NO2S
    (Z)-3-(2-Amino-phenylsulfanyl)-acrylic acid ethyl ester
    —— (2R)-2-[[2-Bromo-5-[[(2-methyl-4-thiazolyl)methyl]thio]thiazolo[4,5-d]pyrimidin-7-yl]amino]-1-propanol 333743-42-3 C13H14BrN5OS3
    (2R)-2-[[2-Bromo-5-[[(2-methyl-4-thiazolyl)methyl]thio]thiazolo[4,5-d]pyrimidin-7-yl]amino]-1-propanol
    —— (2R)-2-[[2-amino-5-[(3-chloro-2-fluorophenyl)methylsulfanyl]-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]amino]propan-1-ol 942408-19-7 C15H15ClFN5OS2
    (2R)-2-[[2-amino-5-[(3-chloro-2-fluorophenyl)methylsulfanyl]-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]amino]propan-1-ol
    —— 7-[[(1R)-2-hydroxy-1-methylethyl]amino]-5-[[(2-methyl-4-thiazolyl)methyl]thio]thiazolo[4,5-d]pyrimidin-2(3H)-one 333742-66-8 C13H15N5O2S3
    7-[[(1R)-2-hydroxy-1-methylethyl]amino]-5-[[(2-methyl-4-thiazolyl)methyl]thio]thiazolo[4,5-d]pyrimidin-2(3H)-one
    —— 4,5-dibromo-2-[3-(2-phenylthio-3H-imidazol-4-yl)propyl]-1H-pyrrole-2-carboxamide 848899-39-8 C17H16Br2N4OS
    4,5-dibromo-2-[3-(2-phenylthio-3H-imidazol-4-yl)propyl]-1H-pyrrole-2-carboxamide
    —— AZD-8309 333742-48-6 C15H14F2N4O2S2
    AZD-8309
    —— (R)-2-[[2-Bromo-5-[(phenylmethyl)thio]thiazolo[4,5-d]pyrimidin-7-yl]amino]-1-propanol 333743-00-3 C15H15BrN4OS2
    (R)-2-[[2-Bromo-5-[(phenylmethyl)thio]thiazolo[4,5-d]pyrimidin-7-yl]amino]-1-propanol
    —— (2R)-2-[[5-[[(2,3-difluorophenyl)methyl]thio]-2-methoxythiazolo[4,5-d]pyrimidin-7-yl]amino]-1-propanol 333743-05-8 C16H16F2N4O2S2
    (2R)-2-[[5-[[(2,3-difluorophenyl)methyl]thio]-2-methoxythiazolo[4,5-d]pyrimidin-7-yl]amino]-1-propanol
    —— (7E,11S,20E,24S)-11,24-bis(trifluoromethyl)-10,23-dioxa-1,5,15,19-tetrathiadispiro[5.7.5.7]hexacosa-7,20-diene-9,22-dione 251558-27-7 C22H26F6O4S4
    (7E,11S,20E,24S)-11,24-bis(trifluoromethyl)-10,23-dioxa-1,5,15,19-tetrathiadispiro[5.7.5.7]hexacosa-7,20-diene-9,22-dione
    —— (2R)-2-[[2-methoxy-5-[[(2-methyl-4-thiazolyl)methyl]thio]thiazolo[4,5-d]pyrimidin-7-yl]amino]-1-propanol 333743-43-4 C14H17N5O2S3
    (2R)-2-[[2-methoxy-5-[[(2-methyl-4-thiazolyl)methyl]thio]thiazolo[4,5-d]pyrimidin-7-yl]amino]-1-propanol
    —— (2R)-2-[[2-Amino-5-[(2-furanylmethyl)thio]thiazolo[4,5-d]pyrimidin-7-yl]amino]-1-propanol 354565-88-1 C13H15N5O2S2
    (2R)-2-[[2-Amino-5-[(2-furanylmethyl)thio]thiazolo[4,5-d]pyrimidin-7-yl]amino]-1-propanol
    —— (R)-2-[[2-Methoxy-5-[(phenylmethyl)thio]thiazolo[4,5-d]pyrimidin-7-yl]amino]-1-propanol 333743-01-4 C16H18N4O2S2
    (R)-2-[[2-Methoxy-5-[(phenylmethyl)thio]thiazolo[4,5-d]pyrimidin-7-yl]amino]-1-propanol
    —— Diethyl-(3-triethylsilanyl-propylsulfanylmethyl)-amine 50965-43-0 C14H33NSSi
    Diethyl-(3-triethylsilanyl-propylsulfanylmethyl)-amine
    —— 2-phenylthio-5-(3-chloropropyl)-1-(N,N-dimethylsulfamoyl)imidazole 848899-36-5 C12H15N3S
    2-phenylthio-5-(3-chloropropyl)-1-(N,N-dimethylsulfamoyl)imidazole
    —— dimethyl-2-(phenylthio)maleate 90305-01-4 C12H12O4S
    dimethyl-2-(phenylthio)maleate
    —— (S)-2-[3-(tert-butyldimethylsiloxy)-4,4,4-trifluorobutyl][1,3]dithiane-2-carbaldehyde 251558-22-2 C15H27F3O2S2Si
    (S)-2-[3-(tert-butyldimethylsiloxy)-4,4,4-trifluorobutyl][1,3]dithiane-2-carbaldehyde
    —— (3,3-Dimethyl-2-phenylsulfanyl-butyl)-diethyl-amine 54441-99-5 C16H27NS
    (3,3-Dimethyl-2-phenylsulfanyl-butyl)-diethyl-amine
    —— 3-Phenylthio-1-piperidino-4,5-pyrazoldicarbonsaeure-dimethylester 78365-69-2 C18H21N3O4S
    3-Phenylthio-1-piperidino-4,5-pyrazoldicarbonsaeure-dimethylester
    —— 5-(Phenylthio)-1-piperidino-3,4-pyrazoldicarbonsaeure-dimethylester 79489-86-4 C18H21N3O4S
    5-(Phenylthio)-1-piperidino-3,4-pyrazoldicarbonsaeure-dimethylester
    —— 1-Dimethylamino-3-phenylthio-4,5-pyrazoldicarbonsaeure-dimethylester 78365-68-1 C15H17N3O4S
    1-Dimethylamino-3-phenylthio-4,5-pyrazoldicarbonsaeure-dimethylester
    —— methyl (E)-2-(phenylthio)crotonate 85020-98-0 C11H12O2S
    methyl (E)-2-(phenylthio)crotonate
    —— 1-Morpholino-5-(phenylthio)-3,4-pyrazoldicarbonsaeure-dimethylester 79489-84-2 C17H19N3O5S
    1-Morpholino-5-(phenylthio)-3,4-pyrazoldicarbonsaeure-dimethylester
    —— 4-[3-(2-ethylhexanoylamino)propylthio]pyridine hydrochloride 155965-65-4 C16H26N2OS*ClH
    4-[3-(2-ethylhexanoylamino)propylthio]pyridine hydrochloride