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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-(4-(difluoromethylthio)phenylamino)-1,3,4-thiadiazole-2-thiol 571149-73-0 C9H7F2N3S3
    5-(4-(difluoromethylthio)phenylamino)-1,3,4-thiadiazole-2-thiol
    —— 4-(3,4-dimethoxyphenyl)-5-(5-nitrothiazol-2-ylthio)-4H-1,2,4-triazol-3-ol 1064664-89-6 C13H11N5O5S2
    4-(3,4-dimethoxyphenyl)-5-(5-nitrothiazol-2-ylthio)-4H-1,2,4-triazol-3-ol
    —— 5-nitro-2-(4-phenyl-5-(pyridin-4-yl)-4H-1,2,4-triazol-3-ylthio)thiazole 1138221-33-6 C16H10N6O2S2
    5-nitro-2-(4-phenyl-5-(pyridin-4-yl)-4H-1,2,4-triazol-3-ylthio)thiazole
    —— 4-(4-nitrophenyl)-5-(5-nitrothiazol-2-ylthio)-4H-1,2,4-triazol-3-ol 1064664-95-4 C11H6N6O5S2
    4-(4-nitrophenyl)-5-(5-nitrothiazol-2-ylthio)-4H-1,2,4-triazol-3-ol
    —— BI-90E7 1208264-64-5 C9H11N5O2S3
    BI-90E7
    —— 2-(4-(3-methoxyphenyl)-5-phenyl-4H-1,2,4-triazol-3-ylthio)-5-nitrothiazole 1138221-30-3 C18H13N5O3S2
    2-(4-(3-methoxyphenyl)-5-phenyl-4H-1,2,4-triazol-3-ylthio)-5-nitrothiazole
    —— 4-(benzo[d][1,3]dioxol-5-yl)-5-(5-nitrothiazol-2-ylthio)-4H-1,2,4-triazol-3-ol 1064664-77-2 C12H7N5O5S2
    4-(benzo[d][1,3]dioxol-5-yl)-5-(5-nitrothiazol-2-ylthio)-4H-1,2,4-triazol-3-ol
    —— 4-methyl-2-(5-nitro-thiazol-2-ylsulfanyl)-pyrimidine 40045-68-9 C8H6N4O2S2
    4-methyl-2-(5-nitro-thiazol-2-ylsulfanyl)-pyrimidine
    —— 4-(2,4-dimethoxyphenyl)-5-(5-nitrothiazol-2-ylthio)-4H-1,2,4-triazol-3-ol 1064664-83-0 C13H11N5O5S2
    4-(2,4-dimethoxyphenyl)-5-(5-nitrothiazol-2-ylthio)-4H-1,2,4-triazol-3-ol
    —— 4-(naphthalen-1-yl)-5-(5-nitrothiazol-2-ylthio)-4H-1,2,4-triazol-3-ol 1138221-23-4 C15H9N5O3S2
    4-(naphthalen-1-yl)-5-(5-nitrothiazol-2-ylthio)-4H-1,2,4-triazol-3-ol
    —— 4-(3,4-difluorophenyl)-5-(5-nitrothiazol-2-ylthio)-4H-1,2,4-triazol-3-ol 1064664-98-7 C11H5F2N5O3S2
    4-(3,4-difluorophenyl)-5-(5-nitrothiazol-2-ylthio)-4H-1,2,4-triazol-3-ol
    —— 5-nitro-2-(4-phenyl-5-(thiophen-2-yl)-4H-1,2,4-triazol-3-ylthio)-thiazole 1099449-04-3 C15H9N5O2S3
    5-nitro-2-(4-phenyl-5-(thiophen-2-yl)-4H-1,2,4-triazol-3-ylthio)-thiazole
    —— 4-(3-methoxyphenyl)-5-(5-nitrothiazol-2-ylthio)-4H-1,2,4-triazol-3-ol 1064665-01-5 C12H9N5O4S2
    4-(3-methoxyphenyl)-5-(5-nitrothiazol-2-ylthio)-4H-1,2,4-triazol-3-ol
    —— 2-(4-(2,3-dihydrobenzo[b][1,4]dioxin-6-yl)-5-phenyl-4H-1,2,4-triazol-3-ylthio)-5-nitrothiazole 1138221-27-8 C19H13N5O4S2
    2-(4-(2,3-dihydrobenzo[b][1,4]dioxin-6-yl)-5-phenyl-4H-1,2,4-triazol-3-ylthio)-5-nitrothiazole
    —— 4-(2,5-dimethoxyphenyl)-5-(5-nitrothiazol-2-ylthio)-4H-1,2,4-triazol-3-ol 1064664-91-0 C13H11N5O5S2
    4-(2,5-dimethoxyphenyl)-5-(5-nitrothiazol-2-ylthio)-4H-1,2,4-triazol-3-ol
    —— 4-(3,5-dimethoxyphenyl)-5-(5-nitrothiazol-2-ylthio)-4H-1,2,4-triazol-3-ol 1064664-86-3 C13H11N5O5S2
    4-(3,5-dimethoxyphenyl)-5-(5-nitrothiazol-2-ylthio)-4H-1,2,4-triazol-3-ol
    —— 4-(3-fluorophenyl)-5-(5-nitrothiazol-2-ylthio)-4H-1,2,4-triazol-3-ol 1064664-99-8 C11H6FN5O3S2
    4-(3-fluorophenyl)-5-(5-nitrothiazol-2-ylthio)-4H-1,2,4-triazol-3-ol
    —— 5-(5-nitrothiazol-2-ylthio)-4-(4-(trifluoromethoxy)phenyl)-4H-1,2,4-triazol-3-ol 1064664-93-2 C12H6F3N5O4S2
    5-(5-nitrothiazol-2-ylthio)-4-(4-(trifluoromethoxy)phenyl)-4H-1,2,4-triazol-3-ol
    —— 4-(4-tert-butylphenyl)-5-(5-nitrothiazol-2-ylthio)-4H-1,2,4-triazol-3-ol 1064664-75-0 C15H15N5O3S2
    4-(4-tert-butylphenyl)-5-(5-nitrothiazol-2-ylthio)-4H-1,2,4-triazol-3-ol
    —— 5-(5-nitrothiazol-2-ylthio)-4-(4-(trifluoromethyl)phenyl)-4H-1,2,4-triazol-3-ol 1064665-05-9 C12H6F3N5O3S2
    5-(5-nitrothiazol-2-ylthio)-4-(4-(trifluoromethyl)phenyl)-4H-1,2,4-triazol-3-ol
    —— 5-(5-nitrothiazol-2-ylthio)-4-(3-(trifluoromethyl)phenyl)-4H-1,2,4-triazol-3-ol 1064665-04-8 C12H6F3N5O3S2
    5-(5-nitrothiazol-2-ylthio)-4-(3-(trifluoromethyl)phenyl)-4H-1,2,4-triazol-3-ol
    —— 5-bromo-2-(4-isopropylphenylthio)benzoic acid 91527-96-7 C16H15BrO2S
    5-bromo-2-(4-isopropylphenylthio)benzoic acid
    —— 5-((4-methyl-5-(5-nitrothiazol-2-ylthio)-4H-1,2,4-triazol-3-yl)methyl)-3-(pyrazin-2-yl)-1,2,4-oxadiazole 1138221-34-7 C13H9N9O3S2
    5-((4-methyl-5-(5-nitrothiazol-2-ylthio)-4H-1,2,4-triazol-3-yl)methyl)-3-(pyrazin-2-yl)-1,2,4-oxadiazole
    —— 2-(4-(2,4-dichlorophenyl)-5-(1-methyl-1H-pyrrol-2-yl)-4H-1,2,4-triazol-3-ylthio)-5-nitrothiazole 1138221-28-9 C16H10Cl2N6O2S2
    2-(4-(2,4-dichlorophenyl)-5-(1-methyl-1H-pyrrol-2-yl)-4H-1,2,4-triazol-3-ylthio)-5-nitrothiazole
    —— 2-((2,3,5,6-Tetramethylphenyl)thio)propionic acid ethyl ester 72462-74-9 C15H22O2S
    2-((2,3,5,6-Tetramethylphenyl)thio)propionic acid ethyl ester
    —— Propionic acid, 3-((2,3,5,6-tetramethylphenyl)thio)-, ethyl ester 72462-78-3 C15H22O2S
    Propionic acid, 3-((2,3,5,6-tetramethylphenyl)thio)-, ethyl ester
    —— 2-(3-amino-phenylsulfanyl)-benzoic acid 191154-83-3 C13H11NO2S
    2-(3-amino-phenylsulfanyl)-benzoic acid
    —— 2-((2,3,5,6-Tetramethylphenyl)thio)butyric acid ethyl ester 72462-76-1 C16H24O2S
    2-((2,3,5,6-Tetramethylphenyl)thio)butyric acid ethyl ester
    —— 2,3,5,6-Tetramethylphenylthio-ethylacetat 72462-72-7 C14H20O2S
    2,3,5,6-Tetramethylphenylthio-ethylacetat
    —— Propionic acid, 2-methyl-2-((2,3,5,6-tetramethylphenyl)thio)-, ethyl ester 72462-77-2 C16H24O2S
    Propionic acid, 2-methyl-2-((2,3,5,6-tetramethylphenyl)thio)-, ethyl ester
    —— N,N-Dimethyl-carbamidsaeure-S-(2,3,5,6-tetramethyl-phenylester) 13511-95-0 C13H19NOS
    N,N-Dimethyl-carbamidsaeure-S-(2,3,5,6-tetramethyl-phenylester)
    —— N-cyclohexyl-4-(4-(3-(3,4-difluorophenyl)thioureido)phenylthio)picolinamide 1395063-36-1 C25H24F2N4OS2
    N-cyclohexyl-4-(4-(3-(3,4-difluorophenyl)thioureido)phenylthio)picolinamide
    —— 2,4,6-tri(3-carboxyphenylthio)-1,3,5-triazine 1312883-96-7 C24H15N3O6S3
    2,4,6-tri(3-carboxyphenylthio)-1,3,5-triazine
    —— 2-chloro-5<i>H</i>,7<i>H</i>-dibenzo[<i>b</i>,<i>g</i>][1,4]thiazocin-6-one 54920-96-6 C14H10ClNOS
    2-chloro-5<i>H</i>,7<i>H</i>-dibenzo[<i>b</i>,<i>g</i>][1,4]thiazocin-6-one
    —— 2-cyclohexyl-5-(4-methylbenzamido)-6-(phenylthio)-1H-benzo[d]imidazole 1448875-47-5 C27H27N3OS
    2-cyclohexyl-5-(4-methylbenzamido)-6-(phenylthio)-1H-benzo[d]imidazole
    —— 4-(4-(3-(3,4-difluorophenyl)thioureido)phenylthio)-N-methylpicolinamide 1417344-61-6 C20H16F2N4OS2
    4-(4-(3-(3,4-difluorophenyl)thioureido)phenylthio)-N-methylpicolinamide
    —— 3-(4-Chlorophenyl)-5-[4-(methylsulfanyl)phenyl]-4,5-dihydro-1H-pyrazole-1-carbothioamide 1029793-23-4 C17H16ClN3S2
    3-(4-Chlorophenyl)-5-[4-(methylsulfanyl)phenyl]-4,5-dihydro-1H-pyrazole-1-carbothioamide
    —— 4-(4-(3-(3,4-difluorophenyl)thioureido)phenylthio)-N-ethylpicolinamide 1395063-42-9 C21H18F2N4OS2
    4-(4-(3-(3,4-difluorophenyl)thioureido)phenylthio)-N-ethylpicolinamide
    —— N-cyclopropyl-4-(4-(3-(3,4-difluorophenyl)thioureido)phenylthio)picolinamide 1395063-40-7 C22H18F2N4OS2
    N-cyclopropyl-4-(4-(3-(3,4-difluorophenyl)thioureido)phenylthio)picolinamide
    —— N-benzyl-4-(4-(3-(3,4-difluorophenyl)thioureido)phenylthio)picolinamide 1395063-28-1 C26H20F2N4OS2
    N-benzyl-4-(4-(3-(3,4-difluorophenyl)thioureido)phenylthio)picolinamide
    —— 6-Amino-4-thiacapronsaeuresulfon 20960-87-6 C5H11NO4S
    6-Amino-4-thiacapronsaeuresulfon
    —— 6-Amino-4-thiacapronsaeuresulfoxid 20960-86-5 C5H11NO3S
    6-Amino-4-thiacapronsaeuresulfoxid
    —— 1-(adamantan-1-yl)-2-{[5-(trifluoromethyl)pyridin-2-yl]sulfanyl}ethan-1-one 1185752-65-1 C18H20F3NOS
    1-(adamantan-1-yl)-2-{[5-(trifluoromethyl)pyridin-2-yl]sulfanyl}ethan-1-one
    —— (1-adamantyl) phenylthiomethyl ketone 77270-23-6 C18H22OS
    (1-adamantyl) phenylthiomethyl ketone
    —— 1-(adamantan-1-yl)-2-({4-[(4-chlorophenyl)methyl]-5-methyl-4H-1,2,4-triazol-3-yl}sulfanyl)ethan-1-one 1185752-97-9 C22H26ClN3OS
    1-(adamantan-1-yl)-2-({4-[(4-chlorophenyl)methyl]-5-methyl-4H-1,2,4-triazol-3-yl}sulfanyl)ethan-1-one
    —— 5-amino-2-cyclohexyl-6-(4-fluorophenylthio)-1H-benzo[d]imidazole 1448876-55-8 C19H20FN3S
    5-amino-2-cyclohexyl-6-(4-fluorophenylthio)-1H-benzo[d]imidazole
    —— 1-(adamantan-1-yl)-2-{[4-methyl-5-(thiophen-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}ethanone 1185752-94-6 C19H23N3OS2
    1-(adamantan-1-yl)-2-{[4-methyl-5-(thiophen-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}ethanone
    —— 1-(adamantan-1-yl)-2-{[5-methyl-4-(propan-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}ethanone 1185752-95-7 C18H27N3OS
    1-(adamantan-1-yl)-2-{[5-methyl-4-(propan-2-yl)-4H-1,2,4-triazol-3-yl]sulfanyl}ethanone
    —— 1,4-dimethoxy-2-p-tolylsulfenylbenzene 110624-68-5 C15H16O2S
    1,4-dimethoxy-2-p-tolylsulfenylbenzene
    —— 5-amino-2-cyclohexyl-6-(phenylthio)-1H-benzo[d]imidazole 1448876-38-7 C19H21N3S
    5-amino-2-cyclohexyl-6-(phenylthio)-1H-benzo[d]imidazole