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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (methylthio-2 pyrazinyl-3)-3 dibromo-2,3 propenoate d'ethyl 74990-53-7 C10H12Br2N2O2S
    (methylthio-2 pyrazinyl-3)-3 dibromo-2,3 propenoate d'ethyl
    —— 7-(2-N,N-dimethylaminosulfonylaminoethyl)thio-2-(tri-n-butylstannyl)imidazo[5,1-b]thiazole 352469-99-9 C21H40N4O2S3Sn
    7-(2-N,N-dimethylaminosulfonylaminoethyl)thio-2-(tri-n-butylstannyl)imidazo[5,1-b]thiazole
    —— <(formyl-2 pyrazinyl-3) thio-2>acetate d'ethyle 74990-46-8 C9H10N2O3S
    <(formyl-2 pyrazinyl-3) thio-2>acetate d'ethyle
    —— 5,5-dimethyl-4,5-dihydro-4-oxofurano[2,3-b]thiophene 120280-09-3 C8H8O2S
    5,5-dimethyl-4,5-dihydro-4-oxofurano[2,3-b]thiophene
    —— 5-(1,1,1,3,3,3-hexamethyldisilazan-2-yl)-2-phenylsulfanylthiazole 1245530-68-0 C15H24N2S2Si2
    5-(1,1,1,3,3,3-hexamethyldisilazan-2-yl)-2-phenylsulfanylthiazole
    —— 7-phenylthioimidazo[5,1-b]thiazole 258839-50-8 C11H8N2S2
    7-phenylthioimidazo[5,1-b]thiazole
    —— 7-Phenylthio-2-(tri-n-butylstannyl)-imidazo[5,1-b]thiazole 258839-49-5 C23H34N2S2Sn
    7-Phenylthio-2-(tri-n-butylstannyl)-imidazo[5,1-b]thiazole
    —— tert-butyl [3-bromo-6-methyl-2-(methylthio)pyrazolo[5,1-b][1,3]thiazol-7-yl]carbamate 1290127-77-3 C12H16BrN3O2S2
    tert-butyl [3-bromo-6-methyl-2-(methylthio)pyrazolo[5,1-b][1,3]thiazol-7-yl]carbamate
    —— 1,1,5-Trimethyl-2,4-dithiobiuret 33885-76-6 C5H11N3S2
    1,1,5-Trimethyl-2,4-dithiobiuret
    —— N-((R)-(2-(methylsulfanyl)phenyl)([1,3]thiazolo[5,4-b]pyridin-2-yl)methyl)-3,4-dihydro-2H-1,5-benzodioxepine-7-sulfonamide 1402598-50-8 C23H21N3O4S3
    N-((R)-(2-(methylsulfanyl)phenyl)([1,3]thiazolo[5,4-b]pyridin-2-yl)methyl)-3,4-dihydro-2H-1,5-benzodioxepine-7-sulfonamide
    —— N-((S)-(2-(methylsulfanyl)phenyl)([1,3]thiazolo[5,4-b]pyridin-2-yl)methyl)-3,4-dihydro-2H-1,5-benzodioxepine-7-sulfonamide 1402598-49-5 C23H21N3O4S3
    N-((S)-(2-(methylsulfanyl)phenyl)([1,3]thiazolo[5,4-b]pyridin-2-yl)methyl)-3,4-dihydro-2H-1,5-benzodioxepine-7-sulfonamide
    —— 3-(2-bromophenyl)-7-methylthio-3,4-dihydro-1-(3-(2-hydroxyethyl)phenyl)pyrimido[4,5-d]pyrimidin-2(1H)-one 266314-36-7 C21H19BrN4O2S
    3-(2-bromophenyl)-7-methylthio-3,4-dihydro-1-(3-(2-hydroxyethyl)phenyl)pyrimido[4,5-d]pyrimidin-2(1H)-one
    —— 5-(2-bromoanilino)methyl-4-[3-(2-(tetrahydropyranyloxy)ethyl)phenyl]amino-2-methylthiopyrimidine 266314-35-6 C25H29BrN4O2S
    5-(2-bromoanilino)methyl-4-[3-(2-(tetrahydropyranyloxy)ethyl)phenyl]amino-2-methylthiopyrimidine
    —— 4,6,16,18-tetraaza-5,17-bis(methylsulfanyl)-2,8,14,20,26-pentaoxacalix[5]arene 1260029-60-4 C28H20N4O5S2
    4,6,16,18-tetraaza-5,17-bis(methylsulfanyl)-2,8,14,20,26-pentaoxacalix[5]arene
    —— 1-(2,6-dichlorophenyl)-6-(4-fluorophenylsulfanyl)-3,4-dihydro-1H-quinazolin-2-one 342433-96-9 C20H13Cl2FN2OS
    1-(2,6-dichlorophenyl)-6-(4-fluorophenylsulfanyl)-3,4-dihydro-1H-quinazolin-2-one
    —— 1-(2,6-dichlorophenylamino)-2-aminomethyl-4-(4-fluorophenylsulfanyl)-benzene 342434-02-0 C19H15Cl2FN2S
    1-(2,6-dichlorophenylamino)-2-aminomethyl-4-(4-fluorophenylsulfanyl)-benzene
    —— N-[4-[[4-[2-(dimethylamino)ethylamino]-6-[(5-methyl-1H-pyrazol-3-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide 1258424-08-6 C21H27N9OS
    N-[4-[[4-[2-(dimethylamino)ethylamino]-6-[(5-methyl-1H-pyrazol-3-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide
    —— 2-phenylthio-6-methyl-4H-3,1-benzoxazin-4-one 351435-64-8 C15H11NO2S
    2-phenylthio-6-methyl-4H-3,1-benzoxazin-4-one
    —— 1,5-Bis(dimethylamino)-3-thiapentan-3,3-dioxid 59406-68-7 C8H20N2O2S
    1,5-Bis(dimethylamino)-3-thiapentan-3,3-dioxid
    —— N-[4-[[4-chloro-6-(2-imino-5-methyl-1,3-thiazol-3-yl)-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide 1258424-39-3 C17H15ClN6OS2
    N-[4-[[4-chloro-6-(2-imino-5-methyl-1,3-thiazol-3-yl)-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide
    —— N-[4-[[4-[(5-methyl-1H-pyrazol-3-yl)amino]-6-pyrrolidin-1-yl-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide 1258424-06-4 C21H24N8OS
    N-[4-[[4-[(5-methyl-1H-pyrazol-3-yl)amino]-6-pyrrolidin-1-yl-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide
    —— N-[4-[[4-(butylamino)-6-[(5-methyl-1H-pyrazol-3-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide 1258424-10-0 C21H26N8OS
    N-[4-[[4-(butylamino)-6-[(5-methyl-1H-pyrazol-3-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide
    —— N-[4-[[4-amino-6-[(5-methyl-1H-pyrazol-3-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide 1258424-14-4 C17H18N8OS
    N-[4-[[4-amino-6-[(5-methyl-1H-pyrazol-3-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide
    —— N-(4-((4-((5-methyl-1H-pyrazol-3-yl)amino)-6-morpholino-1,3,5-triazin-2-yl)thio)phenyl)cyclopropanecarboxamide 1258424-05-3 C21H24N8O2S
    N-(4-((4-((5-methyl-1H-pyrazol-3-yl)amino)-6-morpholino-1,3,5-triazin-2-yl)thio)phenyl)cyclopropanecarboxamide
    —— N-[4-[[4-[2-(dimethylamino)ethyl-methylamino]-6-[(5-methyl-1H-pyrazol-3-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide 1258424-09-7 C22H29N9OS
    N-[4-[[4-[2-(dimethylamino)ethyl-methylamino]-6-[(5-methyl-1H-pyrazol-3-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide
    —— 6lambda6,11,20,25lambda6-Tetrathiaheptacyclo[24.2.2.22,5.27,10.212,15.216,19.221,24]tetraconta-1(29),2(40),3,5(39),7,9,12,14,16(34),17,19(33),21(32),22,24(31),26(30),27,35,37-octadecaene 6,6,25,25-tetraoxide 1204429-61-7 C36H24O4S4
    6lambda6,11,20,25lambda6-Tetrathiaheptacyclo[24.2.2.22,5.27,10.212,15.216,19.221,24]tetraconta-1(29),2(40),3,5(39),7,9,12,14,16(34),17,19(33),21(32),22,24(31),26(30),27,35,37-octadecaene 6,6,25,25-tetraoxide
    —— 4-Methyl-1-[(4-methylphenyl)sulfanyl]pentan-2-one 477761-13-0 C13H18OS
    4-Methyl-1-[(4-methylphenyl)sulfanyl]pentan-2-one
    —— (S)-(+)-1-(p-tolylsulfanyl)-4-methyl-2-pentanol 477761-27-6 C13H20OS
    (S)-(+)-1-(p-tolylsulfanyl)-4-methyl-2-pentanol
    —— 3-(2-chlorophenyl)-7-methylthio-1-phenyl-3,4-dihydropyrimido[4,5-d]-pyrimidin-2(1H)-one 335653-82-2 C19H15ClN4OS
    3-(2-chlorophenyl)-7-methylthio-1-phenyl-3,4-dihydropyrimido[4,5-d]-pyrimidin-2(1H)-one
    —— 5-(2-chlorophenyl)aminomethyl-4-phenylamino-2-methylthiopyrimidine 335653-81-1 C18H17ClN4S
    5-(2-chlorophenyl)aminomethyl-4-phenylamino-2-methylthiopyrimidine
    —— pyrimidin-4-ylsulfanyl-acetic acid methyl ester 64679-74-9 C7H8N2O2S
    pyrimidin-4-ylsulfanyl-acetic acid methyl ester
    —— [[2-(2,6-Dimethylheptyl)-1-cyclobutenyl]thio]benzene 63048-82-8 C19H28S
    [[2-(2,6-Dimethylheptyl)-1-cyclobutenyl]thio]benzene
    —— 1-<4-(p-hydroxyphenylthio)butyl>piperidinium hydrochloride 57055-93-3 C15H23NOS*ClH
    1-<4-(p-hydroxyphenylthio)butyl>piperidinium hydrochloride
    —— 2-(3-chloro-2-hydroxyphenyl)sulfanyl-N,N-diethylacetamide 681123-07-9 C12H16ClNO2S
    2-(3-chloro-2-hydroxyphenyl)sulfanyl-N,N-diethylacetamide
    —— 2-methyl-5-(2-(methylthio)phenyl)thiophene 1360610-85-0 C12H12S2
    2-methyl-5-(2-(methylthio)phenyl)thiophene
    —— 3-[(1R,2R)-2-(2,4-difluorophenyl)-2-hydroxy-1-methyl-3-(1,2,4-triazol-1-yl)propyl]-7-phenylsulfanyl-quinazolin-4-one 187949-61-7 C26H21F2N5O2S
    3-[(1R,2R)-2-(2,4-difluorophenyl)-2-hydroxy-1-methyl-3-(1,2,4-triazol-1-yl)propyl]-7-phenylsulfanyl-quinazolin-4-one
    —— 2-[2'-(methylsulfanyl)phenyl]-1,3-dithiane 765292-66-8 C11H14S3
    2-[2'-(methylsulfanyl)phenyl]-1,3-dithiane
    —— cis-(RS,SR)-γ-hydroxy-β-methyl-γ-<2-(methylthio)phenyl>butanoic acid lactone 133101-61-8 C12H14O2S
    cis-(RS,SR)-γ-hydroxy-β-methyl-γ-<2-(methylthio)phenyl>butanoic acid lactone
    —— N-((2-(methylsulfanyl)phenyl)([1,3]thiazolo[5,4-b]pyridin-2-yl)methyl)-3,4-dihydro-2H-1,5-benzodioxepine-7-sulfonamide 1402607-94-6 C23H21N3O4S3
    N-((2-(methylsulfanyl)phenyl)([1,3]thiazolo[5,4-b]pyridin-2-yl)methyl)-3,4-dihydro-2H-1,5-benzodioxepine-7-sulfonamide
    —— o-methylthiostyrene oxide 67764-86-7 C9H10OS
    o-methylthiostyrene oxide
    —— (2R,3S)-1-Chloro-1,1-difluoro-3-<(4-methylphenyl)thio>hept-6-en-2-ol 136310-16-2 C14H17ClF2OS
    (2R,3S)-1-Chloro-1,1-difluoro-3-<(4-methylphenyl)thio>hept-6-en-2-ol
    —— (R)-(+)-2-methyl-2,3-dihydrobenzo[b]thiophene 129388-08-5 C9H10S
    (R)-(+)-2-methyl-2,3-dihydrobenzo[b]thiophene
    —— 2-Methylmercpto-benzaldoxim 67764-84-5 C8H9NOS
    2-Methylmercpto-benzaldoxim
    —— 6-(2-(methylthio)phenyl)-3,4-dihydro-2H-pyran 1362860-32-9 C12H14OS
    6-(2-(methylthio)phenyl)-3,4-dihydro-2H-pyran
    —— (2S,3S)-1-Chloro-1,1-difluoro-3-<(4-methylphenyl)thio>hept-6-en-2-ol 136310-15-1 C14H17ClF2OS
    (2S,3S)-1-Chloro-1,1-difluoro-3-<(4-methylphenyl)thio>hept-6-en-2-ol
    —— (2S,3R)-1-Chloro-1,1-difluoro-3-<(4-methylphenyl)thio>hept-6-en-2-ol 156483-95-3 C14H17ClF2OS
    (2S,3R)-1-Chloro-1,1-difluoro-3-<(4-methylphenyl)thio>hept-6-en-2-ol
    —— (2R,3R)-1-Chloro-1,1-difluoro-3-<(4-methylphenyl)thio>hept-6-en-2-ol 136310-14-0 C14H17ClF2OS
    (2R,3R)-1-Chloro-1,1-difluoro-3-<(4-methylphenyl)thio>hept-6-en-2-ol
    —— (+)-2-methyl-cis-2,3-dihydroxy-2,3-dihydrobenzo[ b]thiophene 183812-29-5 C9H10O2S
    (+)-2-methyl-cis-2,3-dihydroxy-2,3-dihydrobenzo[ b]thiophene
    —— N-[4-[[4-(2-hydroxyethylamino)-6-[(5-methyl-1,3-thiazol-2-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide 1258423-53-8 C19H21N7O2S2
    N-[4-[[4-(2-hydroxyethylamino)-6-[(5-methyl-1,3-thiazol-2-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide
    —— N-[4-[[4-(butylamino)-6-[(5-methyl-1,3-thiazol-2-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide 1258423-63-0 C21H25N7OS2
    N-[4-[[4-(butylamino)-6-[(5-methyl-1,3-thiazol-2-yl)amino]-1,3,5-triazin-2-yl]sulfanyl]phenyl]cyclopropanecarboxamide