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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 6-Methylmercapto-1,3,2-benzothiazathiolium-chlorid 15182-79-3 C7H6NS3*Cl
    6-Methylmercapto-1,3,2-benzothiazathiolium-chlorid
    —— 6-Amino-2-(3'methylbutyl)thiouracil 62459-18-1 C9H15N3OS
    6-Amino-2-(3'methylbutyl)thiouracil
    —— 2-(1-(2-fluorobenzyl)-5-(isoxazol-3-yl)-1H-pyrazol-3-yl)-5-(pyridin-2-ylthio)pyrimidin-4-ol 1446358-67-3 C22H15FN6O2S
    2-(1-(2-fluorobenzyl)-5-(isoxazol-3-yl)-1H-pyrazol-3-yl)-5-(pyridin-2-ylthio)pyrimidin-4-ol
    —— 4-(tert-butyldimethylsilyloxy)-6-(1H-indol-3-ylthio)-2,3-dimethylphenol 1448175-37-8 C22H29NO2SSi
    4-(tert-butyldimethylsilyloxy)-6-(1H-indol-3-ylthio)-2,3-dimethylphenol
    —— 2-(1H-pyrrol-2-yl)-3-[(3,4,5-trimethoxyphenyl)thio]-1H-indole 1314802-66-8 C21H20N2O3S
    2-(1H-pyrrol-2-yl)-3-[(3,4,5-trimethoxyphenyl)thio]-1H-indole
    —— 2-(1-(2-fluorobenzyl)-5-(isoxazol-3-yl)-1H-pyrazol-3-yl)-5-(4-fluorophenylthio)pyrimidin-4-ol 1446358-64-0 C23H15F2N5O2S
    2-(1-(2-fluorobenzyl)-5-(isoxazol-3-yl)-1H-pyrazol-3-yl)-5-(4-fluorophenylthio)pyrimidin-4-ol
    —— (4-trifluoromethylthiophenyl)-oxirane 67764-94-7 C9H7F3OS
    (4-trifluoromethylthiophenyl)-oxirane
    —— (2-chloro-ethyl)-dodecyl sulfone 20413-39-2 C14H29ClO2S
    (2-chloro-ethyl)-dodecyl sulfone
    —— 1-nitro-2-methyl-2-phenylthiobutane 109585-25-3 C11H15NO2S
    1-nitro-2-methyl-2-phenylthiobutane
    —— 5-(Benzylthio)-3-methylpyrimido<5,4-e>-as-triazin 51934-19-1 C13H11N5S
    5-(Benzylthio)-3-methylpyrimido<5,4-e>-as-triazin
    —— 1-(2-aminoethyl)-5-(2,4-dinitrophenylthio)-tetrazole hydrochloride 63612-43-1 C9H9N7O4S*ClH
    1-(2-aminoethyl)-5-(2,4-dinitrophenylthio)-tetrazole hydrochloride
    —— 2-nitro-5-(4-nitro-phenylsulfanyl)-furan 6277-16-3 C10H6N2O5S
    2-nitro-5-(4-nitro-phenylsulfanyl)-furan
    —— Dicyclopropylsulfon 57899-47-5 C6H10O2S
    Dicyclopropylsulfon
    —— 5,5'-Dinitro-difuryl-(2,2')-sulfid 4819-02-7 C8H4N2O6S
    5,5'-Dinitro-difuryl-(2,2')-sulfid
    —— 3-t-butyl-5-carboethoxymethylthio-1H-1,2,4-triazole 110895-85-7 C10H17N3O2S
    3-t-butyl-5-carboethoxymethylthio-1H-1,2,4-triazole
    —— 3-((1H-tetrazol-5-yl)thio)-5-bromo-1-methyl-1H-indole 1569090-34-1 C10H8BrN5S
    3-((1H-tetrazol-5-yl)thio)-5-bromo-1-methyl-1H-indole
    —— Brom-dimethylsulfonyl-methan 38564-52-2 C3H7BrO4S2
    Brom-dimethylsulfonyl-methan
    —— 2-Phenylthio-2-(trimethylsilylmethyl)cycloheptanol 104281-75-6 C17H28OSSi
    2-Phenylthio-2-(trimethylsilylmethyl)cycloheptanol
    —— Trimethyl-vinylsulfanylmethyl-silane 51771-36-9 C6H14SSi
    Trimethyl-vinylsulfanylmethyl-silane
    —— Allylsulfanylmethylene-cyclohexane 29517-57-5 C10H16S
    Allylsulfanylmethylene-cyclohexane
    —— 4-{5-[(cyclopropylmethyl)thio]-4-methyl-4H-1,2,4-triazol-3-yl}-1-butanol 913062-30-3 C11H19N3OS
    4-{5-[(cyclopropylmethyl)thio]-4-methyl-4H-1,2,4-triazol-3-yl}-1-butanol
    —— 4-[4-methyl-5-(methylthio)-4H-1,2,4-triazol-3-yl]-1-butanol 913062-29-0 C8H15N3OS
    4-[4-methyl-5-(methylthio)-4H-1,2,4-triazol-3-yl]-1-butanol
    —— 1-(4-ethylthiophenyl)-2-butanone oxime 1204749-40-5 C12H17NOS
    1-(4-ethylthiophenyl)-2-butanone oxime
    —— 1-(2-(cyclohex-1-enyl)ethyl)-6-(phenylsulfanyl)piperidin-2-one 328058-61-3 C19H25NOS
    1-(2-(cyclohex-1-enyl)ethyl)-6-(phenylsulfanyl)piperidin-2-one
    —— 4-[4-methyl-5-(methylthio)-4H-1,2,4-triazol-3-yl]butanal 913062-31-4 C8H13N3OS
    4-[4-methyl-5-(methylthio)-4H-1,2,4-triazol-3-yl]butanal
    —— 4-(4-(3-(4-chlorophenyl)thioureido)phenylthio)-N-methylpicolinamide 1417344-60-5 C20H17ClN4OS2
    4-(4-(3-(4-chlorophenyl)thioureido)phenylthio)-N-methylpicolinamide
    —— N-benzyl-4-(4-(3-(4-chlorophenyl)thioureido)phenylthio)picolinamide 1395063-25-8 C26H21ClN4OS2
    N-benzyl-4-(4-(3-(4-chlorophenyl)thioureido)phenylthio)picolinamide
    —— N-(2-fluoro-ethyl)-4-methylsulfanyl-pyridine-2,6-diamine 1158785-98-8 C8H12FN3S
    N-(2-fluoro-ethyl)-4-methylsulfanyl-pyridine-2,6-diamine
    —— 2-Phenyl-1,3-dithiolane-2-carboxylic acid 23118-19-6 C10H10O2S2
    2-Phenyl-1,3-dithiolane-2-carboxylic acid
    —— 2-(trifluoromethanesulfonyl)-1,3-cyclohexadiene 235746-99-3 C7H7F3O2S
    2-(trifluoromethanesulfonyl)-1,3-cyclohexadiene
    —— 7-Amino-5-benzylthio-pyrimido<5,4-e>as-triazine 31736-48-8 C12H10N6S
    7-Amino-5-benzylthio-pyrimido<5,4-e>as-triazine
    —— 4-chlorophenyl-(1-fluoroundec-1-yl)thioether 1245924-30-4 C17H26ClFS
    4-chlorophenyl-(1-fluoroundec-1-yl)thioether
    —— 4-Benzylsulfanyl-5-bromo-6-furan-2-yl-pyrimidin-2-yl-amine 357286-71-6 C15H12BrN3OS
    4-Benzylsulfanyl-5-bromo-6-furan-2-yl-pyrimidin-2-yl-amine
    —— 5-Bromo-4-ethylsulfanyl-6-furan-2-yl-pyrimidin-2-yl-amine 357286-72-7 C10H10BrN3OS
    5-Bromo-4-ethylsulfanyl-6-furan-2-yl-pyrimidin-2-yl-amine
    —— 2-Amino-4-benzo[1,3]dioxol-5-yl-6-phenylsulfanyl-pyrimidine-5-carbonitrile 357285-48-4 C18H12N4O2S
    2-Amino-4-benzo[1,3]dioxol-5-yl-6-phenylsulfanyl-pyrimidine-5-carbonitrile
    —— 1,2-bis[3-(pyrid-3-yl)-1,2,5-thiadiazol-4-ylthio]ethane 390799-91-4 C16H12N6S4
    1,2-bis[3-(pyrid-3-yl)-1,2,5-thiadiazol-4-ylthio]ethane
    —— 3-(2-(2-fluoroethoxy)ethylthio)-4-(1-methyl-1,2,5,6-tetrahydropyridin-3-yl)-1,2,5-thiadiazole 1262964-25-9 C12H18FN3OS2
    3-(2-(2-fluoroethoxy)ethylthio)-4-(1-methyl-1,2,5,6-tetrahydropyridin-3-yl)-1,2,5-thiadiazole
    —— 3-(3-butylthio-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide 131988-52-8 C12H16N3S2*I
    3-(3-butylthio-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide
    —— 3-(3-methylthio-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide 131988-53-9 C9H10N3S2*I
    3-(3-methylthio-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide
    —— 3-(3-(ethylthio)-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridine oxalate salt 141064-33-7 C2H2O4*C10H15N3S2
    3-(3-(ethylthio)-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridine oxalate salt
    —— 3-(3-Octylthio-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridineoxalate 141064-40-6 C2H2O4*C16H27N3S2
    3-(3-Octylthio-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridineoxalate
    —— Tazomeline oxalate 141064-37-1 C2H2O4*C14H23N3S2
    Tazomeline oxalate
    —— 3-(3-propylthio-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide 131988-51-7 C11H14N3S2*I
    3-(3-propylthio-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide
    —— 3-(3-octylthio-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide 131988-58-4 C16H24N3S2*I
    3-(3-octylthio-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide
    —— 3-(3-Butylthio-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridineoxalate 141064-35-9 C2H2O4*C12H19N3S2
    3-(3-Butylthio-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridineoxalate
    —— 3-(3-ethylthio-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide 131988-59-5 C10H12N3S2*I
    3-(3-ethylthio-1,2,5-thiadiazol-4-yl)-1-methylpyridinium iodide
    —— 3-(3-Propylthio-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridine oxalate 141064-34-8 C2H2O4*C11H17N3S2
    3-(3-Propylthio-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridine oxalate
    —— 3-(3-methylthio-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridine oxalate 141064-32-6 C2H2O4*C9H13N3S2
    3-(3-methylthio-1,2,5-thiadiazol-4-yl)-1,2,5,6-tetrahydro-1-methylpyridine oxalate
    —— 3-[4-(3-Phenyl-propylsulfanyl)-[1,2,5]thiadiazol-3-yl]-pyridine 169542-77-2 C16H15N3S2
    3-[4-(3-Phenyl-propylsulfanyl)-[1,2,5]thiadiazol-3-yl]-pyridine
    —— 2-amino-6-methyl-5-[(5-chlorobenzimidazol-2-yl)sulfanyl]-3,4-dihydro-4-oxo-7H-pyrrolo[2,3-d]pyrimidine 1224513-98-7 C14H11ClN6OS
    2-amino-6-methyl-5-[(5-chlorobenzimidazol-2-yl)sulfanyl]-3,4-dihydro-4-oxo-7H-pyrrolo[2,3-d]pyrimidine