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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (3-thienyl)methyl 3,3-bis(4-fluorophenylthio)-N-(phenyl)thiopropionimidate 1107009-21-1 C26H21F2NS4
    (3-thienyl)methyl 3,3-bis(4-fluorophenylthio)-N-(phenyl)thiopropionimidate
    —— 4-Propyl-2,3-dihydro-4H-pyrazino<2,3-b>-1,4-thiazinon-3 53265-25-1 C9H11N3OS
    4-Propyl-2,3-dihydro-4H-pyrazino<2,3-b>-1,4-thiazinon-3
    —— 4-Methyl-2,3-dihydro-4H-pyrazino<2,3-b>1,4-thiazinon-3 53265-21-7 C7H7N3OS
    4-Methyl-2,3-dihydro-4H-pyrazino<2,3-b>1,4-thiazinon-3
    —— Trimethyl-[4-(4-methylsulfanyl-phenylethynyl)-phenylethynyl]-silane 910467-68-4 C20H20SSi
    Trimethyl-[4-(4-methylsulfanyl-phenylethynyl)-phenylethynyl]-silane
    —— triisopropyl((4-(methylthio)phenyl)ethynyl)silane 1235968-75-8 C18H28SSi
    triisopropyl((4-(methylthio)phenyl)ethynyl)silane
    —— 1,12-bis(p-methylthiophenyl)dodeca-1,3,9,11-tetrayne 1227073-43-9 C26H22S2
    1,12-bis(p-methylthiophenyl)dodeca-1,3,9,11-tetrayne
    —— N-phenyl-3,3-bis(phenylthio)thiopropionamide 1107010-52-5 C21H19NS3
    N-phenyl-3,3-bis(phenylthio)thiopropionamide
    —— 2-<2,2-Bis(phenylthio)ethyl>cycloheptanone 151830-58-9 C21H24OS2
    2-<2,2-Bis(phenylthio)ethyl>cycloheptanone
    —— 3-Trifluoromethyl-2-(3-methyl-2-aminophenylthio) benzonitrile 146070-31-7 C15H11F3N2S
    3-Trifluoromethyl-2-(3-methyl-2-aminophenylthio) benzonitrile
    —— 2,5-bis(4-aminophenylenesulfanyl)selenophene 1188338-47-7 C16H14N2S2Se
    2,5-bis(4-aminophenylenesulfanyl)selenophene
    —— 2-Methyl-4-methyl-2,3-dihydro-4H-pyrazino<2,3-b>-1,4-thiazinon-3 53265-22-8 C8H9N3OS
    2-Methyl-4-methyl-2,3-dihydro-4H-pyrazino<2,3-b>-1,4-thiazinon-3
    —— 6-methyl-4-methylthio-2(1H)-pyridone 114361-56-7 C7H9NOS
    6-methyl-4-methylthio-2(1H)-pyridone
    —— 6-methyl-4-methylthio-2-oxo-2H-pyran-3-carboxamide 114361-66-9 C8H9NO3S
    6-methyl-4-methylthio-2-oxo-2H-pyran-3-carboxamide
    —— 6-methyl-4-methylthio-2-oxo-2H-pyran-3-carbonitrile 114361-52-3 C8H7NO2S
    6-methyl-4-methylthio-2-oxo-2H-pyran-3-carbonitrile
    —— 4-Chloro-5-ethylthio-3H-1,2-dithiole-3-thione 52444-69-6 C5H5ClS4
    4-Chloro-5-ethylthio-3H-1,2-dithiole-3-thione
    —— Diethyl (2-Methylthio-5-pyrimidinyloxy)malonate 80306-03-2 C12H16N2O5S
    Diethyl (2-Methylthio-5-pyrimidinyloxy)malonate
    —— 2-(benzylthio)-6-tert-butylpyridine 1429200-00-9 C16H19NS
    2-(benzylthio)-6-tert-butylpyridine
    —— 1,2,3,4-Tetrahydro-3-methyl-1-(2-methylpropyl)-2,4-dioxo-5-(2-thienylthio)-thieno[2,3-d]pyrimidine-6-carboxaldehyde 259862-29-8 C16H16N2O3S3
    1,2,3,4-Tetrahydro-3-methyl-1-(2-methylpropyl)-2,4-dioxo-5-(2-thienylthio)-thieno[2,3-d]pyrimidine-6-carboxaldehyde
    —— 4-Chlorbutyl-aethyl-sulfon 53903-87-0 C6H13ClO2S
    4-Chlorbutyl-aethyl-sulfon
    —— (S)-2-(((tert-butoxy)carbonyl)amino)-4-{2-chloro-4-((((2-tert-butoxy)carbonyl)oxy)-5-ethoxyphenylthio)phenyl}-2-propylbutan-1-ol 1383617-39-7 C31H44ClNO7S
    (S)-2-(((tert-butoxy)carbonyl)amino)-4-{2-chloro-4-((((2-tert-butoxy)carbonyl)oxy)-5-ethoxyphenylthio)phenyl}-2-propylbutan-1-ol
    —— 4-[2-(4-tert-butylphenylthio)thien-4-yl]-4-methoxytetrahydropyran 140618-67-3 C20H26O2S2
    4-[2-(4-tert-butylphenylthio)thien-4-yl]-4-methoxytetrahydropyran
    —— (R)-2-allyl-2-(((tert-butoxy)carbonyl)amino)-4-{2-chloro-4-((5-ethoxy-2-hydroxyphenyl)thio)phenyl}butan-1-ol 1383617-32-0 C26H34ClNO5S
    (R)-2-allyl-2-(((tert-butoxy)carbonyl)amino)-4-{2-chloro-4-((5-ethoxy-2-hydroxyphenyl)thio)phenyl}butan-1-ol
    —— (R)-2-allyl-2-amino-4-{2-chloro-4-((5-ethoxy-2-hydroxy)phenylthio)phenyl}butylphosphoric acid monoester 1383617-29-5 C21H27ClNO6PS
    (R)-2-allyl-2-amino-4-{2-chloro-4-((5-ethoxy-2-hydroxy)phenylthio)phenyl}butylphosphoric acid monoester
    —— 4-Benzyl-2,3-dihydro-4H-pyrazino<2,3-b>1,4-thiazinon-3 53265-27-3 C13H11N3OS
    4-Benzyl-2,3-dihydro-4H-pyrazino<2,3-b>1,4-thiazinon-3
    —— 3-bromo-5-trifluoromethylphenyl 4-tolyl sulphide 135049-05-7 C14H10BrF3S
    3-bromo-5-trifluoromethylphenyl 4-tolyl sulphide
    —— 5-(6-(6-amino-9-(3-(isopropylamino)propyl)-9H-purin-8-ylthio)benzo[d][1,3]dioxol-5-yl)furan-2-carbaldehyde 1289543-84-5 C23H24N6O4S
    5-(6-(6-amino-9-(3-(isopropylamino)propyl)-9H-purin-8-ylthio)benzo[d][1,3]dioxol-5-yl)furan-2-carbaldehyde
    —— 2-(5-formylfuran-2-ylthio)-N-tert-butylbenzamide 1002759-93-4 C16H17NO3S
    2-(5-formylfuran-2-ylthio)-N-tert-butylbenzamide
    —— 2-trifluoromethylsulfonylethylamine hydrochloride 1275596-06-9 C3H6F3NO2S*ClH
    2-trifluoromethylsulfonylethylamine hydrochloride
    —— 2-(2,2,2-trifluoroethylsulfonyl)ethylammonium chloride 1275596-05-8 C4H8F3NO2S*ClH
    2-(2,2,2-trifluoroethylsulfonyl)ethylammonium chloride
    —— bis(o-tolylthio)methane 69984-33-4 C15H16S2
    bis(o-tolylthio)methane
    —— 4,5-(2'-methoxy-1',3'-dithiapropano)-1,3-dithiole-2-one 116341-68-5 C5H4OS5
    4,5-(2'-methoxy-1',3'-dithiapropano)-1,3-dithiole-2-one
    —— 2-Methyl-4-ethyl-2,3-dihydro-4H-pyrazino<2,3-b>-1,4-thiazinon-3 53265-24-0 C9H11N3OS
    2-Methyl-4-ethyl-2,3-dihydro-4H-pyrazino<2,3-b>-1,4-thiazinon-3
    —— 5-(5-phenyl-1,3,4-oxadiazol-2-ylthio)-3-methoxybenzene-1,2-diol 1174331-76-0 C15H12N2O4S
    5-(5-phenyl-1,3,4-oxadiazol-2-ylthio)-3-methoxybenzene-1,2-diol
    —— 4-(5-phenyl-1,3,4-oxadiazol-2-ylthio)-3-methoxybenzene-1,2-diol 1174331-78-2 C15H12N2O4S
    4-(5-phenyl-1,3,4-oxadiazol-2-ylthio)-3-methoxybenzene-1,2-diol
    —— Benzyl alcohol, 4-(methylthio)-alpha-(1-(octylamino)propyl)-, hydrochloride 54767-56-5 C19H34ClNOS
    Benzyl alcohol, 4-(methylthio)-alpha-(1-(octylamino)propyl)-, hydrochloride
    —— 2-[(3,4-dihydroxy-5-methoxyphenyl)thio]quinazolin-4(3H)-one 1134436-20-6 C15H12N2O4S
    2-[(3,4-dihydroxy-5-methoxyphenyl)thio]quinazolin-4(3H)-one
    —— 4-(5-phenyl-1,3,4-oxadiazol-2-ylthio)-3-methylbenzene-1,2-diol 1174331-79-3 C15H12N2O3S
    4-(5-phenyl-1,3,4-oxadiazol-2-ylthio)-3-methylbenzene-1,2-diol
    —— 4-(benzo[d]thiazol-2'-ylthio)-3-methylbenzene-1,2-diol 1521221-52-2 C14H11NO2S2
    4-(benzo[d]thiazol-2'-ylthio)-3-methylbenzene-1,2-diol
    —— 5-(5-phenyl-1,3,4-oxadiazol-2-ylthio)-3-methylbenzene-1,2-diol 1174331-77-1 C15H12N2O3S
    5-(5-phenyl-1,3,4-oxadiazol-2-ylthio)-3-methylbenzene-1,2-diol
    —— Benzyl alcohol, 4-(ethylthio)-alpha-(1-(octylamino)propyl)-, hydrochloride 54767-58-7 C20H36ClNOS
    Benzyl alcohol, 4-(ethylthio)-alpha-(1-(octylamino)propyl)-, hydrochloride
    —— Acetic acid (4R,5R,6S)-2,2,5-trimethyl-6-phenylsulfanylmethyl-[1,3]dioxan-4-ylmethyl ester 193890-11-8 C17H24O4S
    Acetic acid (4R,5R,6S)-2,2,5-trimethyl-6-phenylsulfanylmethyl-[1,3]dioxan-4-ylmethyl ester
    —— ((4R,5R,6S)-2,2,5-Trimethyl-6-phenylsulfanylmethyl-[1,3]dioxan-4-yl)-methanol 193890-12-9 C15H22O3S
    ((4R,5R,6S)-2,2,5-Trimethyl-6-phenylsulfanylmethyl-[1,3]dioxan-4-yl)-methanol
    —— 2-Amino-4-(4-bromo-pyrazol-1-yl)-6-methylsulfanyl-pyrimidine-5-carbonitrile 357289-63-5 C9H7BrN6S
    2-Amino-4-(4-bromo-pyrazol-1-yl)-6-methylsulfanyl-pyrimidine-5-carbonitrile
    —— 4-(cyclopropylthio)-1H-pyrazole 1196875-57-6 C6H8N2S
    4-(cyclopropylthio)-1H-pyrazole
    —— 7,7-dimethoxy-5-(phenylthio)heptan-2-one 444168-98-3 C15H22O3S
    7,7-dimethoxy-5-(phenylthio)heptan-2-one
    —— Benzyl alcohol, alpha-(1-(butylamino)propyl)-4-(ethylthio)-, hydrochloride 54767-57-6 C16H28ClNOS
    Benzyl alcohol, alpha-(1-(butylamino)propyl)-4-(ethylthio)-, hydrochloride
    —— [4-Ethyl-5-(5-methyl-isoxazol-3-yl)-4H-[1,2,4]triazol-3-ylsulfanyl]-acetic acid 150535-98-1 C10H12N4O3S
    [4-Ethyl-5-(5-methyl-isoxazol-3-yl)-4H-[1,2,4]triazol-3-ylsulfanyl]-acetic acid
    —— 5-(2,4,6-Trimethyl-phenylsulfanylmethyl)-isoxazole-3-carboxylic acid ethyl ester 823219-91-6 C16H19NO3S
    5-(2,4,6-Trimethyl-phenylsulfanylmethyl)-isoxazole-3-carboxylic acid ethyl ester
    —— 5-(4-toluenesulfanylmethyl)-isoxazole-3-carboxylic acid hydroxyamide 823220-02-6 C12H12N2O3S
    5-(4-toluenesulfanylmethyl)-isoxazole-3-carboxylic acid hydroxyamide
    —— [4-Ethyl-5-(5-methyl-isoxazol-3-yl)-4H-[1,2,4]triazol-3-ylsulfanyl]-acetic acid methyl ester 150535-85-6 C11H14N4O3S
    [4-Ethyl-5-(5-methyl-isoxazol-3-yl)-4H-[1,2,4]triazol-3-ylsulfanyl]-acetic acid methyl ester