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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Brom-5-(phenylthio)pyridin 67743-63-9 C11H8BrNS
    2-Brom-5-(phenylthio)pyridin
    —— 4-(4-acetamidophenylsulphanyl)-2-chloronitrobenzene 252019-38-8 C14H11ClN2O3S
    4-(4-acetamidophenylsulphanyl)-2-chloronitrobenzene
    —— (3-Methyl-4-bromo-phenyl)-3-methylbut-2-enylsulfide 135631-85-5 C12H15BrS
    (3-Methyl-4-bromo-phenyl)-3-methylbut-2-enylsulfide
    —— 2-<Chloromethylthio>-4.6-dimethylpyrimidin 19834-92-5 C7H9ClN2S
    2-<Chloromethylthio>-4.6-dimethylpyrimidin
    —— 4-Carboxy-5-(1-pentyl)hexylsulfanyl-1,2,3-triazole 190080-32-1 C14H25N3O2S
    4-Carboxy-5-(1-pentyl)hexylsulfanyl-1,2,3-triazole
    —— (E)-(4-(hept-2-enyl)phenyl)(methyl)sulfane 1378379-89-5 C14H20S
    (E)-(4-(hept-2-enyl)phenyl)(methyl)sulfane
    —— 7-phenyl-4-acetyl-2-phenyl-4H-pyridazino<4,5-e><1,3,4>thiadiazin-8(7H)-one 90330-75-9 C19H14N4O2S
    7-phenyl-4-acetyl-2-phenyl-4H-pyridazino<4,5-e><1,3,4>thiadiazin-8(7H)-one
    —— 2,7-diphenyl-4H-pyridazino<4,5-e><1,3,4>thiadiazin-8(7H)-one 90330-79-3 C17H12N4OS
    2,7-diphenyl-4H-pyridazino<4,5-e><1,3,4>thiadiazin-8(7H)-one
    —— 4-Methyl-4-(4-methylsulfanyl-benzyl)-5-trifluoromethyl-2,4-dihydro-pyrazol-3-one 181795-86-8 C13H13F3N2OS
    4-Methyl-4-(4-methylsulfanyl-benzyl)-5-trifluoromethyl-2,4-dihydro-pyrazol-3-one
    —— Buten-(2)-thiol-(2) 17516-74-4 C4H8S
    Buten-(2)-thiol-(2)
    —— bis(4-methylthiobenzyl)diselenide 1255907-89-1 C16H18S2Se2
    bis(4-methylthiobenzyl)diselenide
    —— 4'-(thiomethyl)phenylnitromethane 1337927-69-1 C8H9NO2S
    4'-(thiomethyl)phenylnitromethane
    —— 1-(1-Methylene-propyl)-3-methylsulfanyl-1H-[1,2,4]triazole 112390-14-4 C7H11N3S
    1-(1-Methylene-propyl)-3-methylsulfanyl-1H-[1,2,4]triazole
    —— 3-[(4-chlorophenyl)methylsulfanyl]-1-[2-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-1-yl]propan-2-yl]-1,2,4-triazole 118718-09-5 C21H20Cl2N6S2
    3-[(4-chlorophenyl)methylsulfanyl]-1-[2-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-1-yl]propan-2-yl]-1,2,4-triazole
    —— 1-(1-Benzyl-vinyl)-3-methylsulfanyl-1H-[1,2,4]triazole 112390-16-6 C12H13N3S
    1-(1-Benzyl-vinyl)-3-methylsulfanyl-1H-[1,2,4]triazole
    —— 1-[3,3-dimethyl-2-(3-methylsulfanyl-1,2,4-triazol-1-yl)butan-2-yl]-3-methylsulfanyl-1,2,4-triazole 118718-12-0 C12H20N6S2
    1-[3,3-dimethyl-2-(3-methylsulfanyl-1,2,4-triazol-1-yl)butan-2-yl]-3-methylsulfanyl-1,2,4-triazole
    —— Acetic acid 1-methyl-1-(3-methylsulfanyl-[1,2,4]triazol-1-yl)-propyl ester 112390-25-7 C9H15N3O2S
    Acetic acid 1-methyl-1-(3-methylsulfanyl-[1,2,4]triazol-1-yl)-propyl ester
    —— 1-((E)-1-Ethyl-propenyl)-3-methylsulfanyl-1H-[1,2,4]triazole 112390-19-9 C8H13N3S
    1-((E)-1-Ethyl-propenyl)-3-methylsulfanyl-1H-[1,2,4]triazole
    —— 1-Cyclopent-1-enyl-3-methylsulfanyl-1H-[1,2,4]triazole 118718-21-1 C8H11N3S
    1-Cyclopent-1-enyl-3-methylsulfanyl-1H-[1,2,4]triazole
    —— methyl N'-[(Z)-butan-2-ylideneamino]carbamimidothioate 112390-00-8 C6H13N3S
    methyl N'-[(Z)-butan-2-ylideneamino]carbamimidothioate
    —— 3-(4-Chloro-benzylsulfanyl)-1-isopropenyl-1H-[1,2,4]triazole 112390-18-8 C12H12ClN3S
    3-(4-Chloro-benzylsulfanyl)-1-isopropenyl-1H-[1,2,4]triazole
    —— 3-methylsulfanyl-1-[1-(3-methylsulfanyl-1,2,4-triazol-1-yl)cyclopentyl]-1,2,4-triazole 118718-13-1 C11H16N6S2
    3-methylsulfanyl-1-[1-(3-methylsulfanyl-1,2,4-triazol-1-yl)cyclopentyl]-1,2,4-triazole
    —— Acetic acid 1-[3-(4-chloro-benzylsulfanyl)-[1,2,4]triazol-1-yl]-1-methyl-ethyl ester 112390-26-8 C14H16ClN3O2S
    Acetic acid 1-[3-(4-chloro-benzylsulfanyl)-[1,2,4]triazol-1-yl]-1-methyl-ethyl ester
    —— Acetic acid 1-ethyl-1-(3-methylsulfanyl-[1,2,4]triazol-1-yl)-propyl ester 112418-05-0 C10H17N3O2S
    Acetic acid 1-ethyl-1-(3-methylsulfanyl-[1,2,4]triazol-1-yl)-propyl ester
    —— methyl N'-(cyclopentylideneamino)carbamimidothioate 10060-96-5 C7H13N3S
    methyl N'-(cyclopentylideneamino)carbamimidothioate
    —— methyl N'-(butan-2-ylideneamino)carbamimidothioate 112390-00-8 C6H13N3S
    methyl N'-(butan-2-ylideneamino)carbamimidothioate
    —— 1-[3-methyl-2-(3-methylsulfanyl-1,2,4-triazol-1-yl)butan-2-yl]-3-methylsulfanyl-1,2,4-triazole 118718-11-9 C11H18N6S2
    1-[3-methyl-2-(3-methylsulfanyl-1,2,4-triazol-1-yl)butan-2-yl]-3-methylsulfanyl-1,2,4-triazole
    —— 1-(2,2-Dimethyl-1-methylene-propyl)-3-methylsulfanyl-1H-[1,2,4]triazole 118718-20-0 C9H15N3S
    1-(2,2-Dimethyl-1-methylene-propyl)-3-methylsulfanyl-1H-[1,2,4]triazole
    —— 3-ethylthio-1-isopropenyl-1H-1,2,4-triazole 118718-19-7 C7H11N3S
    3-ethylthio-1-isopropenyl-1H-1,2,4-triazole
    —— 1-(5-methylcyclopent-1-enyl)-3-methylthio-1H-1,2,4-triazole 112390-21-3 C9H13N3S
    1-(5-methylcyclopent-1-enyl)-3-methylthio-1H-1,2,4-triazole
    —— 1-(2-Methyl-1-methylene-propyl)-3-methylsulfanyl-1H-[1,2,4]triazole 112390-15-5 C8H13N3S
    1-(2-Methyl-1-methylene-propyl)-3-methylsulfanyl-1H-[1,2,4]triazole
    —— 2-(3-methylthio-1H-1,2,4-triazol-1yl)propan-2-yl acetate 112390-24-6 C8H13N3O2S
    2-(3-methylthio-1H-1,2,4-triazol-1yl)propan-2-yl acetate
    —— 2-methylcyclopentanone 3-methylisothiosemicarbazone 112390-06-4 C8H15N3S
    2-methylcyclopentanone 3-methylisothiosemicarbazone
    —— 3-methylsulfanyl-1-[2-(3-methylsulfanyl-1,2,4-triazol-1-yl)butan-2-yl]-1,2,4-triazole 118718-10-8 C10H16N6S2
    3-methylsulfanyl-1-[2-(3-methylsulfanyl-1,2,4-triazol-1-yl)butan-2-yl]-1,2,4-triazole
    —— FP-Tztp F-18 161395-77-3 C11H16FN3S2
    FP-Tztp F-18
    —— 6-chloro-2-methylthio-4-[N-(2-morpholin-4-ylethyl)amino]-5-nitropyrimidine 1097966-92-1 C11H16ClN5O3S
    6-chloro-2-methylthio-4-[N-(2-morpholin-4-ylethyl)amino]-5-nitropyrimidine
    —— 2-(1-anilinoethylidene)-3(2H)-benzo{b}thiophenone 126318-42-1 C16H13NOS
    2-(1-anilinoethylidene)-3(2H)-benzo{b}thiophenone
    —— 6-chloro-N-cyclohexyl-2-(methylsulfanyl)-5-nitropyrimidin-4-amine 56035-28-0 C11H15ClN4O2S
    6-chloro-N-cyclohexyl-2-(methylsulfanyl)-5-nitropyrimidin-4-amine
    —— cyclohexyl-(2-methylsulfanyl-5-nitro-6-thiomorpholin-4-yl-pyrimidin-4-yl)-amine 56032-04-3 C15H23N5O2S2
    cyclohexyl-(2-methylsulfanyl-5-nitro-6-thiomorpholin-4-yl-pyrimidin-4-yl)-amine
    —— 2-Amino-6-benzyl-3-methylsulfanyl-2H-[1,2,4]triazin-5-one 89569-67-5 C11H12N4OS
    2-Amino-6-benzyl-3-methylsulfanyl-2H-[1,2,4]triazin-5-one
    —— 5-phenylthio-2,4-diethoxypyrimidine 1112995-14-8 C14H16N2O2S
    5-phenylthio-2,4-diethoxypyrimidine
    —— 5-phenylthio-2,4-di(iso-propoxy)pyrimidine 1112995-15-9 C16H20N2O2S
    5-phenylthio-2,4-di(iso-propoxy)pyrimidine
    —— 5-phenylthio-2,4-dimethoxypyrimidine 908080-80-8 C12H12N2O2S
    5-phenylthio-2,4-dimethoxypyrimidine
    —— 5H-Thiazolo(3,2-a)pyrimidin-5-one, 2,3-dihydro-3-(2-hydroxyethoxy)-6-(1-methylethyl)-7-(phenylmethyl)- 199852-39-6 C18H22N2O3S
    5H-Thiazolo(3,2-a)pyrimidin-5-one, 2,3-dihydro-3-(2-hydroxyethoxy)-6-(1-methylethyl)-7-(phenylmethyl)-
    —— (2,5-dimethylphenyl)-3-hydroxypentylsulfide 182426-12-6 C13H20OS
    (2,5-dimethylphenyl)-3-hydroxypentylsulfide
    —— Triphosphoric acid, P-(2-((3,4-dihydro-5-methyl-2,4-dioxo-6-(phenylthio)-1(2H)-pyrimidinyl)methoxy)ethyl) ester 125400-24-0 C14H19N2O13P3S
    Triphosphoric acid, P-(2-((3,4-dihydro-5-methyl-2,4-dioxo-6-(phenylthio)-1(2H)-pyrimidinyl)methoxy)ethyl) ester
    —— 2,2-Dimethyl-1-[2-(methylthio)-5-oxazolyl]propyl tetradecanoate 1170033-72-3 C23H41NO3S
    2,2-Dimethyl-1-[2-(methylthio)-5-oxazolyl]propyl tetradecanoate
    —— (R)-2,2,4-Trimethyl-[1,3]oxathiane 98033-18-2 C7H14OS
    (R)-2,2,4-Trimethyl-[1,3]oxathiane
    —— Pyrimidine, 2-((2-(4-methyl-1-piperazinyl)ethyl)thio)-4-(2-thienyl)- 129224-97-1 C15H20N4S2
    Pyrimidine, 2-((2-(4-methyl-1-piperazinyl)ethyl)thio)-4-(2-thienyl)-
    —— 1-<(2-hydroxyethoxy)methyl>-6-(phenylthio)-5-propyluracil 133563-28-7 C16H20N2O4S
    1-<(2-hydroxyethoxy)methyl>-6-(phenylthio)-5-propyluracil