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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Pyrimidinamine, 4,6-bis(2-(dimethylamino)ethoxy)-N,N-diethyl-5-(methylthio)-, dihydrobromide 57259-26-4 C17H35Br2N5O2S
    2-Pyrimidinamine, 4,6-bis(2-(dimethylamino)ethoxy)-N,N-diethyl-5-(methylthio)-, dihydrobromide
    —— Imidodicarbonimidic diamide, N-(4-((2-amino-4,5-dimethoxyphenyl)thio)phenyl)- 56948-13-1 C16H20N6O2S
    Imidodicarbonimidic diamide, N-(4-((2-amino-4,5-dimethoxyphenyl)thio)phenyl)-
    —— 3-(Thiophen-2-ylmethyl)-6-[3-(trifluoromethyl)phenyl]sulfanyl-[1,2,4]triazolo[4,3-b]pyridazine 1428566-00-0 C17H11F3N4S2
    3-(Thiophen-2-ylmethyl)-6-[3-(trifluoromethyl)phenyl]sulfanyl-[1,2,4]triazolo[4,3-b]pyridazine
    —— (2S,3R,4R,6R)-2,4-dimethyl-1-phenylsulfanyl-6-[(4S,5R)-2,2,5-trimethyl-1,3-dioxan-4-yl]heptan-3-ol 1351657-01-6 C22H36O3S
    (2S,3R,4R,6R)-2,4-dimethyl-1-phenylsulfanyl-6-[(4S,5R)-2,2,5-trimethyl-1,3-dioxan-4-yl]heptan-3-ol
    —— 5-nitrobenzo[b]thiophen-2(3H)-one 125772-34-1 C8H5NO3S
    5-nitrobenzo[b]thiophen-2(3H)-one
    —— [2-(2-phenylsulfanyl-ethylsulfanyl)-pyridin-3-yl]amine 1242435-97-7 C13H14N2S2
    [2-(2-phenylsulfanyl-ethylsulfanyl)-pyridin-3-yl]amine
    —— 4-[4,6-bis-(1-methyl-piperidin-4-yloxy)-5-methylsulfanyl-pyrimidin-2-yl]-morpholine 57304-24-2 C21H35N5O3S
    4-[4,6-bis-(1-methyl-piperidin-4-yloxy)-5-methylsulfanyl-pyrimidin-2-yl]-morpholine
    —— 4-phenylthio-2-buten-1-ol 20614-50-0 C10H12OS
    4-phenylthio-2-buten-1-ol
    —— 3-(5-Methylsulfanyl-furan-2-yl)-propionaldehyde 136093-81-7 C8H10O2S
    3-(5-Methylsulfanyl-furan-2-yl)-propionaldehyde
    —— (4S,5R)-2,2,5-trimethyl-4-[(2R,4R)-4-[(2R,3S)-3-(phenylsulfanylmethyl)oxiran-2-yl]pentan-2-yl]-1,3-dioxane 1351657-00-5 C21H32O3S
    (4S,5R)-2,2,5-trimethyl-4-[(2R,4R)-4-[(2R,3S)-3-(phenylsulfanylmethyl)oxiran-2-yl]pentan-2-yl]-1,3-dioxane
    —— 5-(benzylsulfanyl)-3-hydroxypyridin-2(1H)-one 1417709-95-5 C12H11NO2S
    5-(benzylsulfanyl)-3-hydroxypyridin-2(1H)-one
    —— 2-Pyrimidinamine, 4,6-bis((1-methyl-4-piperidinyl)oxy)-5-(methylthio)-N,N-diethyl-, hydrobromide, hydrate (1:2:1) 57259-13-9 C21H39Br2N5O2S
    2-Pyrimidinamine, 4,6-bis((1-methyl-4-piperidinyl)oxy)-5-(methylthio)-N,N-diethyl-, hydrobromide, hydrate (1:2:1)
    —— Pyrimidine, 4,6-bis((1-methyl-4-piperidinyl)oxy)-5-(methylthio)-2-(1-piperidinyl)-, dihydrobromide 57259-16-2 C22H39Br2N5O2S
    Pyrimidine, 4,6-bis((1-methyl-4-piperidinyl)oxy)-5-(methylthio)-2-(1-piperidinyl)-, dihydrobromide
    —— 2,4'-Diamino-4,5-dimethoxy-diphenylsulfid 56948-12-0 C14H16N2O2S
    2,4'-Diamino-4,5-dimethoxy-diphenylsulfid
    —— Thallium, dimethyl-, diethyldithiocarbamate 57025-28-2 C7H16NS2Tl
    Thallium, dimethyl-, diethyldithiocarbamate
    —— (E)-1-acetoxy-2-phenylthiohex-1-ene 123630-48-8 C14H18O2S
    (E)-1-acetoxy-2-phenylthiohex-1-ene
    —— 2-Pyrimidinamine, 4,6-bis(3-(dimethylamino)propoxy)-N,N-diethyl-5-(methylthio)-, dihydrobromide 57259-25-3 C19H39Br2N5O2S
    2-Pyrimidinamine, 4,6-bis(3-(dimethylamino)propoxy)-N,N-diethyl-5-(methylthio)-, dihydrobromide
    —— trans-2-allylcyclohexanethiol 63714-87-4 C9H16S
    trans-2-allylcyclohexanethiol
    —— 3-(adamant-1-yl)-1,1,1-tris(methylthio)propane 480425-03-4 C16H28S3
    3-(adamant-1-yl)-1,1,1-tris(methylthio)propane
    —— 2-Pyrimidinamine, 4-chloro-N,N-diethyl-6-((1-methyl-4-piperidinyl)oxy)-5-(methylthio)-, monohydrobromide 57259-19-5 C15H26BrClN4OS
    2-Pyrimidinamine, 4-chloro-N,N-diethyl-6-((1-methyl-4-piperidinyl)oxy)-5-(methylthio)-, monohydrobromide
    —— 2-Pyrimidinamine, 4,6-bis(2-(bis(1-methylethyl)amino)ethoxy)-N,N-diethyl-5-(methylthio)-, dihydrobromide 57259-27-5 C25H51Br2N5O2S
    2-Pyrimidinamine, 4,6-bis(2-(bis(1-methylethyl)amino)ethoxy)-N,N-diethyl-5-(methylthio)-, dihydrobromide
    —— N,N-diethyl-4-methoxy-6-(1-methylpiperidin-4-yl)oxy-5-methylsulfanylpyrimidin-2-amine;hydron;bromide —— C16H29BrN4O2S
    N,N-diethyl-4-methoxy-6-(1-methylpiperidin-4-yl)oxy-5-methylsulfanylpyrimidin-2-amine;hydron;bromide
    —— 2-(3-methylene-cyclopentyl)-2-(2-nitro-ethyl)-[1,3]dithiane 1254074-43-5 C12H19NO2S2
    2-(3-methylene-cyclopentyl)-2-(2-nitro-ethyl)-[1,3]dithiane
    —— (E)-2-acetoxy-1-phenylthiohex-1-ene 123630-47-7 C14H18O2S
    (E)-2-acetoxy-1-phenylthiohex-1-ene
    —— 3-(adamant-1-yl)-2-bromo-1,1-difluoro-1-methylthiopropane 480425-10-3 C14H21BrF2S
    3-(adamant-1-yl)-2-bromo-1,1-difluoro-1-methylthiopropane
    —— (E)-1-acetoxy-2-phenylthiopropene 123630-42-2 C11H12O2S
    (E)-1-acetoxy-2-phenylthiopropene
    —— 1-Propanamine, 3,3'-((5-(methylthio)-2-(4-morpholinyl)-4,6-pyrimidinediyl)bis(oxy))bis(N,N-dimethyl-, dihydrobromide 57259-24-2 C19H37Br2N5O3S
    1-Propanamine, 3,3'-((5-(methylthio)-2-(4-morpholinyl)-4,6-pyrimidinediyl)bis(oxy))bis(N,N-dimethyl-, dihydrobromide
    —— 4-[4-chloro-6-(1-methyl-piperidin-4-yloxy)-5-methylsulfanyl-pyrimidin-2-yl]-morpholine 57259-20-8 C15H23ClN4O2S
    4-[4-chloro-6-(1-methyl-piperidin-4-yloxy)-5-methylsulfanyl-pyrimidin-2-yl]-morpholine
    —— 1,2,4,5-Tetramethyl-3-phenylsulfanyl-benzene 77304-52-0 C16H18S
    1,2,4,5-Tetramethyl-3-phenylsulfanyl-benzene
    —— 5-<(4-Chlor-phenylthio)-methyl>-2,2,8-trimethyl-4H-m-dioxino<4,5-c>pyridin 6953-29-3 C17H18ClNO2S
    5-<(4-Chlor-phenylthio)-methyl>-2,2,8-trimethyl-4H-m-dioxino<4,5-c>pyridin
    —— (R,S)-1-<(1-benzyloxy-3-hydroxy-2-propoxy)methyl>-6-(phenylthio)thymine 162314-64-9 C22H24N2O5S
    (R,S)-1-<(1-benzyloxy-3-hydroxy-2-propoxy)methyl>-6-(phenylthio)thymine
    —— 5-Propylamino-3-methylmercapto-1,2,4-thiadiazol 89677-02-1 C6H11N3S2
    5-Propylamino-3-methylmercapto-1,2,4-thiadiazol
    —— 2-Pyrimidinamine, 4.6-bis(1-methyl-4-piperidinyl)oxy)-N-methyl-5-(methylthio)-N-(phenylmethyl)-, dihydrobromide 57259-18-4 C25H39Br2N5O2S
    2-Pyrimidinamine, 4.6-bis(1-methyl-4-piperidinyl)oxy)-N-methyl-5-(methylthio)-N-(phenylmethyl)-, dihydrobromide
    —— 5,5'-dinitro-2,2'-sulfanediyl-bis-benzenesulfonic acid 63216-88-6 C12H8N2O10S3
    5,5'-dinitro-2,2'-sulfanediyl-bis-benzenesulfonic acid
    —— Chlorocarbonylmethylsulfanylmethylsulfanyl-acetyl chloride 77697-89-3 C5H6Cl2O2S2
    Chlorocarbonylmethylsulfanylmethylsulfanyl-acetyl chloride
    —— 3-(bromomethyl)-5-fluoro-2-(4-fluorophenylthio)benzo[b]thiophene 820975-37-9 C15H9BrF2S2
    3-(bromomethyl)-5-fluoro-2-(4-fluorophenylthio)benzo[b]thiophene
    —— 4,7-dimethyl-5-(phenylthio)-2-(phenylthiomethyl)-2,3-dihydrobenzofuran 126708-20-1 C23H22OS2
    4,7-dimethyl-5-(phenylthio)-2-(phenylthiomethyl)-2,3-dihydrobenzofuran
    —— trans-1.2-Bis-ethylsulfonyl-ethylen 15383-60-5 C6H12O4S2
    trans-1.2-Bis-ethylsulfonyl-ethylen
    —— 2-(5-fluoro-2-(4-fluorophenylthio)benzo[b]thiophen-3-yl)acetonitrile 820975-39-1 C16H9F2NS2
    2-(5-fluoro-2-(4-fluorophenylthio)benzo[b]thiophen-3-yl)acetonitrile
    —— 5-fluoro-2-(4-fluorophenylthio)-3-methylbenzo[b]thiophene 820975-38-0 C15H10F2S2
    5-fluoro-2-(4-fluorophenylthio)-3-methylbenzo[b]thiophene
    —— 1,2,3,4-tetrakis[(2-pyridylsulfanyl)methyl]benzene 588691-62-7 C30H26N4S4
    1,2,3,4-tetrakis[(2-pyridylsulfanyl)methyl]benzene
    —— 2-(o-tolylthio)-4-methylcyclohexanone 89816-46-6 C14H18OS
    2-(o-tolylthio)-4-methylcyclohexanone
    —— 2-(p-tolylthio)-4-methylcyclohexanone 89816-47-7 C14H18OS
    2-(p-tolylthio)-4-methylcyclohexanone
    —— (E)-1-acetoxy-3,3-dimethyl-2-phenylthiobut-1-ene 123630-44-4 C14H18O2S
    (E)-1-acetoxy-3,3-dimethyl-2-phenylthiobut-1-ene
    —— 1-acetoxy-1,1-dideuterio-2-(phenylthio)ethane 109244-22-6 C10H12O2S
    1-acetoxy-1,1-dideuterio-2-(phenylthio)ethane
    —— 1-acetoxy-2,2-dideuterio-2-(phenylthio)ethane 109244-23-7 C10H12O2S
    1-acetoxy-2,2-dideuterio-2-(phenylthio)ethane
    —— 3-benzyl-2-methylthio-4-pyrimidone 81560-08-9 C12H12N2OS
    3-benzyl-2-methylthio-4-pyrimidone
    —— 5,5'-dinitro-2,2'-sulfanediyl-di-phenol 99971-06-9 C12H8N2O6S
    5,5'-dinitro-2,2'-sulfanediyl-di-phenol
    —— Aluminum, dimethyldithiocarbamate 60955-53-5 C9H18AlN3S6
    Aluminum, dimethyldithiocarbamate
    —— tert-butyl 2-ethylthio-2-iminoacetate 1351865-57-0 C8H15NO2S
    tert-butyl 2-ethylthio-2-iminoacetate