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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2,2-Dimethyl-3-[5-(trifluoromethyl)pyridin-2-yl]sulfanylpropan-1-ol 1415577-96-6 C11H14F3NOS
    2,2-Dimethyl-3-[5-(trifluoromethyl)pyridin-2-yl]sulfanylpropan-1-ol
    —— 2-butylsulfanyl-4-N,6-N-bis(2-morpholin-4-ylethyl)pyrimidine-4,5,6-triamine 1415583-64-0 C20H37N7O2S
    2-butylsulfanyl-4-N,6-N-bis(2-morpholin-4-ylethyl)pyrimidine-4,5,6-triamine
    —— 3-Hydroxy-5-[2-(4-methylphenyl)sulfanylethyl]cyclohex-2-en-1-one 1415577-54-6 C15H18O2S
    3-Hydroxy-5-[2-(4-methylphenyl)sulfanylethyl]cyclohex-2-en-1-one
    —— 2-butylsulfanyl-4-N,6-N-bis(2-morpholin-4-ylethyl)-5-phenyldiazenylpyrimidine-4,6-diamine 1415583-63-9 C26H40N8O2S
    2-butylsulfanyl-4-N,6-N-bis(2-morpholin-4-ylethyl)-5-phenyldiazenylpyrimidine-4,6-diamine
    —— 3-Hydroxy-5-[2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylethyl]-2-(2,4,6-trimethylphenyl)cyclohex-2-en-1-one 1415575-79-9 C23H24F3NO2S
    3-Hydroxy-5-[2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylethyl]-2-(2,4,6-trimethylphenyl)cyclohex-2-en-1-one
    —— 3-Hydroxy-5-[1-[5-(trifluoromethyl)pyridin-2-yl]sulfanylbutan-2-yl]cyclohex-2-en-1-one 1415577-89-7 C16H18F3NO2S
    3-Hydroxy-5-[1-[5-(trifluoromethyl)pyridin-2-yl]sulfanylbutan-2-yl]cyclohex-2-en-1-one
    —— 2-(2,6-Diethyl-4-methylphenyl)-3-hydroxy-5-[2-(4-methylsulfanylphenyl)sulfanylethyl]cyclohex-2-en-1-one 1415576-79-2 C26H32O2S2
    2-(2,6-Diethyl-4-methylphenyl)-3-hydroxy-5-[2-(4-methylsulfanylphenyl)sulfanylethyl]cyclohex-2-en-1-one
    —— 2-(2,6-Diethyl-4-methylphenyl)-3-hydroxy-5-[2-(4-methylphenyl)sulfanylethyl]cyclohex-2-en-1-one 1415575-81-3 C26H32O2S
    2-(2,6-Diethyl-4-methylphenyl)-3-hydroxy-5-[2-(4-methylphenyl)sulfanylethyl]cyclohex-2-en-1-one
    —— 3-Hydroxy-5-[2-methyl-1-[5-(trifluoromethyl)pyridin-2-yl]sulfanylpropan-2-yl]cyclohex-2-en-1-one 1415578-00-5 C16H18F3NO2S
    3-Hydroxy-5-[2-methyl-1-[5-(trifluoromethyl)pyridin-2-yl]sulfanylpropan-2-yl]cyclohex-2-en-1-one
    —— 2-(2,6-Diethyl-4-methylphenyl)-3-hydroxy-5-[2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylethyl]cyclohex-2-en-1-one 1415575-78-8 C25H28F3NO2S
    2-(2,6-Diethyl-4-methylphenyl)-3-hydroxy-5-[2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylethyl]cyclohex-2-en-1-one
    —— 2-(2,6-Diethyl-4-methylphenyl)-3-hydroxy-5-(2-pyridin-4-ylsulfanylethyl)cyclohex-2-en-1-one 1415576-07-6 C24H29NO2S
    2-(2,6-Diethyl-4-methylphenyl)-3-hydroxy-5-(2-pyridin-4-ylsulfanylethyl)cyclohex-2-en-1-one
    —— 5,8-bis((4-methoxyphenyl)thio)-2,3-dimethylquinoxaline 1417568-85-4 C24H22N2O2S2
    5,8-bis((4-methoxyphenyl)thio)-2,3-dimethylquinoxaline
    —— 2-[(phenylsulfanyl)methyl]-5-(tetrahydro-2H-pyran-2-yloxy)pyrimidin-4(3H)-one 1417817-97-0 C16H18N2O3S
    2-[(phenylsulfanyl)methyl]-5-(tetrahydro-2H-pyran-2-yloxy)pyrimidin-4(3H)-one
    —— 2-methoxy-5,8-bis((4-methoxyphenyl)thio)quinoxaline 1417569-26-6 C23H20N2O3S2
    2-methoxy-5,8-bis((4-methoxyphenyl)thio)quinoxaline
    —— 2-(3-chlorobenzylthio)-5-hydroxypyrimidin-4(3H)-one 1417817-06-1 C11H9ClN2O2S
    2-(3-chlorobenzylthio)-5-hydroxypyrimidin-4(3H)-one
    —— 2-[(3-chlorobenzyl)sulfanyl]-5-(tetrahydro-2H-pyran-2-yloxy)pyrimidin-4(3H)-one 1417817-45-8 C16H17ClN2O3S
    2-[(3-chlorobenzyl)sulfanyl]-5-(tetrahydro-2H-pyran-2-yloxy)pyrimidin-4(3H)-one
    —— 2-(benzylsulfanyl)-5-(tetrahydro-2H-pyran-2-yloxy)pyrimidin-4(3H)-one 1417818-09-7 C16H18N2O3S
    2-(benzylsulfanyl)-5-(tetrahydro-2H-pyran-2-yloxy)pyrimidin-4(3H)-one
    —— 2-(3-Bromophenyl)sulfanyl-4-methyl-1-nitrobenzene 770719-33-0 C13H10BrNO2S
    2-(3-Bromophenyl)sulfanyl-4-methyl-1-nitrobenzene
    —— N-(6-(((2R,3S)-3,4-dihydroxybutan-2-yl)oxy)-2-((4-fluorobenzyl)thio)pyrimidin-4-yl)-3-methylazetidine-1-sulfonamide 1418112-77-2 C19H25FN4O5S2
    N-(6-(((2R,3S)-3,4-dihydroxybutan-2-yl)oxy)-2-((4-fluorobenzyl)thio)pyrimidin-4-yl)-3-methylazetidine-1-sulfonamide
    —— 1-methyl-8-((2-methylbenzyl)thio)-3,4-dihydro-1H-pyrimido[1,6-a]pyrimidin-6(2H)-one 1420368-62-2 C16H19N3OS
    1-methyl-8-((2-methylbenzyl)thio)-3,4-dihydro-1H-pyrimido[1,6-a]pyrimidin-6(2H)-one
    —— 4-[2-Methylsulfanyl-6-[(4-methylsulfonylpiperazin-1-yl)methyl]imidazo[2,1-f][1,2,4]triazin-4-yl]morpholine 1316761-54-2 C16H25N7O3S2
    4-[2-Methylsulfanyl-6-[(4-methylsulfonylpiperazin-1-yl)methyl]imidazo[2,1-f][1,2,4]triazin-4-yl]morpholine
    —— 1-benzyl-4-((1-((1-benzyl-1H-1,2,3-triazol-4-yl)methyl)-5-tert-butyl-1H-1,2,4-triazol-3-ylthio)methyl)-1H-1,2,3-triazole 1333412-11-5 C26H29N9S
    1-benzyl-4-((1-((1-benzyl-1H-1,2,3-triazol-4-yl)methyl)-5-tert-butyl-1H-1,2,4-triazol-3-ylthio)methyl)-1H-1,2,3-triazole
    —— 1-benzyl-4-[(5-tert-butyl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]triazole 1333412-07-9 C16H20N6S
    1-benzyl-4-[(5-tert-butyl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]triazole
    —— 1,4-Thiazepane-1,1-dioxide TFA salt 756815-81-3 C8H14F3NO3S
    1,4-Thiazepane-1,1-dioxide TFA salt
    —— Spiro(1,3-dithiolane-2,2'(1'H)-(5H-5a,8)methano(11H)cyclohepta(c)furo(3,4-e)(1)benzopyran) 595-93-7 C19H18O2S2
    Spiro(1,3-dithiolane-2,2'(1'H)-(5H-5a,8)methano(11H)cyclohepta(c)furo(3,4-e)(1)benzopyran)
    —— Antimony(5+) phenylbis[4-(phenylsulfanyl)phenyl]sulfanium fluoride (1/1/6) 101200-60-6 C30H23F6S3Sb
    Antimony(5+) phenylbis[4-(phenylsulfanyl)phenyl]sulfanium fluoride (1/1/6)
    —— Antimony(5+) diphenyl(4-{[4-(phenylsulfanyl)phenyl]sulfanyl}phenyl)sulfanium fluoride (1/1/6) 101200-61-7 C30H23F6S3Sb
    Antimony(5+) diphenyl(4-{[4-(phenylsulfanyl)phenyl]sulfanyl}phenyl)sulfanium fluoride (1/1/6)
    —— 4-Chloro-2-((2-fluorobenzyl)thio)pyridine 1346707-43-4 C12H9ClFNS
    4-Chloro-2-((2-fluorobenzyl)thio)pyridine
    —— 4-Chloro-2-((3-chlorobenzyl)thio)pyridine 1346707-50-3 C12H9Cl2NS
    4-Chloro-2-((3-chlorobenzyl)thio)pyridine
    —— 4-((Piperidin-4-ylmethyl)thio)pyridine hydrochloride 1417793-98-6 C11H17ClN2S
    4-((Piperidin-4-ylmethyl)thio)pyridine hydrochloride
    —— 4-Chloro-2-(pentan-2-ylthio)pyridine 1346707-32-1 C10H14ClNS
    4-Chloro-2-(pentan-2-ylthio)pyridine
    —— 4-Chloro-2-((3-fluorobenzyl)thio)pyridine 1346707-44-5 C12H9ClFNS
    4-Chloro-2-((3-fluorobenzyl)thio)pyridine
    —— 4-Chloro-2-((pyridin-2-ylmethyl)thio)pyridine 1346707-82-1 C11H9ClN2S
    4-Chloro-2-((pyridin-2-ylmethyl)thio)pyridine
    —— 2-(Tert-butylthio)-4-chloropyridine 1346707-28-5 C9H12ClNS
    2-(Tert-butylthio)-4-chloropyridine
    —— 4-Chloro-2-((2-methylbutyl)thio)pyridine 1346707-31-0 C10H14ClNS
    4-Chloro-2-((2-methylbutyl)thio)pyridine
    —— 4-Chloro-2-((2-chlorobenzyl)thio)pyridine 1346707-49-0 C12H9Cl2NS
    4-Chloro-2-((2-chlorobenzyl)thio)pyridine
    —— 4-Chloro-2-((4-fluorobenzyl)thio)pyridine 1346707-45-6 C12H9ClFNS
    4-Chloro-2-((4-fluorobenzyl)thio)pyridine
    —— 4-Chloro-2-((4-chlorobenzyl)thio)pyridine 1346707-51-4 C12H9Cl2NS
    4-Chloro-2-((4-chlorobenzyl)thio)pyridine
    —— 4-Chloro-2-(isopentylthio)pyridine 1346707-30-9 C10H14ClNS
    4-Chloro-2-(isopentylthio)pyridine
    —— 2-(Sec-butylthio)-4-chloropyridine 1346707-27-4 C9H12ClNS
    2-(Sec-butylthio)-4-chloropyridine
    —— 2-Bromo-6-((piperidin-3-ylmethyl)thio)pyridine hydrochloride 1417794-00-3 C11H16BrClN2S
    2-Bromo-6-((piperidin-3-ylmethyl)thio)pyridine hydrochloride
    —— 2-(Butylthio)-4-chloropyridine 1346707-24-1 C9H12ClNS
    2-(Butylthio)-4-chloropyridine
    —— 4-Chloro-2-(neopentylthio)pyridine 1346707-34-3 C10H14ClNS
    4-Chloro-2-(neopentylthio)pyridine
    —— 4-Chloro-2-((pyridin-3-ylmethyl)thio)pyridine 1346707-83-2 C11H9ClN2S
    4-Chloro-2-((pyridin-3-ylmethyl)thio)pyridine
    —— 4-Chloro-2-(cyclopentylthio)pyridine 1346707-37-6 C10H12ClNS
    4-Chloro-2-(cyclopentylthio)pyridine
    —— 4-Chloro-2-((cyclopentylmethyl)thio)pyridine 1346707-41-2 C11H14ClNS
    4-Chloro-2-((cyclopentylmethyl)thio)pyridine
    —— 4-Chloro-2-((pyridin-4-ylmethyl)thio)pyridine 1346707-84-3 C11H9ClN2S
    4-Chloro-2-((pyridin-4-ylmethyl)thio)pyridine
    —— 4-Chloro-2-(pentylthio)pyridine 1346707-29-6 C10H14ClNS
    4-Chloro-2-(pentylthio)pyridine
    —— 4-Chloro-2-((cyclopropylmethyl)thio)pyridine 1346707-39-8 C9H10ClNS
    4-Chloro-2-((cyclopropylmethyl)thio)pyridine
    —— 4-Chloro-2-(cyclopropylthio)pyridine 1346707-35-4 C8H8ClNS
    4-Chloro-2-(cyclopropylthio)pyridine