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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-tert-butyl-3-(methylthio)furan-2-carboxamide 98331-14-7 C10H15NO2S
    N-tert-butyl-3-(methylthio)furan-2-carboxamide
    —— 3-(phenylthio)thiophene-2,5-dicarboxylic acid 81028-79-7 C12H8O4S2
    3-(phenylthio)thiophene-2,5-dicarboxylic acid
    —— N,N-diisopropyl-2-(phenylthio)cyclohex-3-enecarboxamide 109639-64-7 C19H27NOS
    N,N-diisopropyl-2-(phenylthio)cyclohex-3-enecarboxamide
    —— (N-phenylthiomethyl-trimethylsilylamino)-trimethylsilylamino-tris(methylsilylimino)-trimethylsiloxy-phosphorane 63698-94-2 C19H44N3OPSSi4
    (N-phenylthiomethyl-trimethylsilylamino)-trimethylsilylamino-tris(methylsilylimino)-trimethylsiloxy-phosphorane
    —— 3-methylsulfanyl-benzo[<i>d</i>][1,2,4]triazino[6,5-<i>f</i>][1,3]oxazepine 41384-23-0 C11H8N4OS
    3-methylsulfanyl-benzo[<i>d</i>][1,2,4]triazino[6,5-<i>f</i>][1,3]oxazepine
    —— 2,5,9,12-Tetrathia-14,15-diaza-bicyclo[11.2.2]heptadeca-1(16),13(17),14-triene 144785-96-6 C11H16N2S4
    2,5,9,12-Tetrathia-14,15-diaza-bicyclo[11.2.2]heptadeca-1(16),13(17),14-triene
    —— N-cyclopropyl-N'-methylthiourea 59814-63-0 C5H10N2S
    N-cyclopropyl-N'-methylthiourea
    —— 1-methyl-3-(2-methoxypropyl)-thiourea 62971-63-5 C6H14N2OS
    1-methyl-3-(2-methoxypropyl)-thiourea
    —— N-Ethyl-N'-butylthioharnstoff 31182-25-9 C7H16N2S
    N-Ethyl-N'-butylthioharnstoff
    —— 1,2-dihydro-5-[(2-pyridinylthio)methyl]-3H-pyrazol-3-one 1294000-31-9 C9H9N3OS
    1,2-dihydro-5-[(2-pyridinylthio)methyl]-3H-pyrazol-3-one
    —— 2,2,2-trifluoro-1-p-tolylsulfanylmethylethylamine 1070753-99-9 C10H12F3NS
    2,2,2-trifluoro-1-p-tolylsulfanylmethylethylamine
    —— 2,6,11,15-Tetrathia-8,9,17,18-tetrazatricyclo[14.2.2.27,10]docosa-1(18),7,9,16,19,21-hexaene 144785-95-5 C14H16N4S4
    2,6,11,15-Tetrathia-8,9,17,18-tetrazatricyclo[14.2.2.27,10]docosa-1(18),7,9,16,19,21-hexaene
    —— 2,5,8,13,16,19-Hexathia-10,11,21,22-tetrazatricyclo[18.2.2.29,12]hexacosa-1(22),9,11,20,23,25-hexaene 150360-49-9 C16H20N4S6
    2,5,8,13,16,19-Hexathia-10,11,21,22-tetrazatricyclo[18.2.2.29,12]hexacosa-1(22),9,11,20,23,25-hexaene
    —— 2,6,11,15,20,24-Hexathia-8,9,17,18,26,27-hexazatetracyclo[23.2.2.27,10.216,19]tritriaconta-1(27),7,9,16,18,25,28,30,32-nonaene 144785-94-4 C21H24N6S6
    2,6,11,15,20,24-Hexathia-8,9,17,18,26,27-hexazatetracyclo[23.2.2.27,10.216,19]tritriaconta-1(27),7,9,16,18,25,28,30,32-nonaene
    —— 5-[(3,4-Dimethoxy-2-methoxymethoxy-phenyl)-methoxymethoxy-methyl]-1-methyl-2-phenylsulfanyl-1H-imidazole 157331-32-3 C23H28N2O6S
    5-[(3,4-Dimethoxy-2-methoxymethoxy-phenyl)-methoxymethoxy-methyl]-1-methyl-2-phenylsulfanyl-1H-imidazole
    —— 5-[(tert-Butyl-dimethyl-silanyloxy)-(3,4-dimethoxy-2-methoxymethoxy-phenyl)-methyl]-1-methyl-2-phenylsulfanyl-1H-imidazole 197151-41-0 C27H38N2O5SSi
    5-[(tert-Butyl-dimethyl-silanyloxy)-(3,4-dimethoxy-2-methoxymethoxy-phenyl)-methyl]-1-methyl-2-phenylsulfanyl-1H-imidazole
    —— 2-(3-trifluoromethyl-4-chlorophenylthio)phenylacetonitrile 61150-43-4 C15H9ClF3NS
    2-(3-trifluoromethyl-4-chlorophenylthio)phenylacetonitrile
    —— N-[2,2,2-Trifluoro-1-(2-phenyl-[1,3]dithian-2-yl)-ethyl]-acetamide 148112-54-3 C14H16F3NOS2
    N-[2,2,2-Trifluoro-1-(2-phenyl-[1,3]dithian-2-yl)-ethyl]-acetamide
    —— 5(4)-methylmercaptoimidazole-4(5)-thiocarboxamide 83256-01-3 C5H7N3S2
    5(4)-methylmercaptoimidazole-4(5)-thiocarboxamide
    —— 5-[(3,5-difluorophenyl)sulfanyl]pyridin-2-carbonitrile 1454252-73-3 C12H6F2N2S
    5-[(3,5-difluorophenyl)sulfanyl]pyridin-2-carbonitrile
    —— 1-Methyl-2-methylthio-1,3-benzazaphosphol 89005-49-2 C9H10NPS
    1-Methyl-2-methylthio-1,3-benzazaphosphol
    —— (E)-β-Ethylmercapto-methacrylnitril 28976-85-4 C6H9NS
    (E)-β-Ethylmercapto-methacrylnitril
    —— methyl-(1-propylsulfanyl-ethyl)-disulfane 69078-87-1 C6H14S3
    methyl-(1-propylsulfanyl-ethyl)-disulfane
    —— 1,2,5,6-Tetrathiocin 293-23-2 C4H4S4
    1,2,5,6-Tetrathiocin
    —— N-(α-phenylthiobenzylidene)methylammonium triflate 76894-33-2 CHF3O3S*C14H13NS
    N-(α-phenylthiobenzylidene)methylammonium triflate
    —— 4,5-Diamino-1-methyl-3-(methylthio)pyridazinium Iodide 76756-64-4 C6H11N4S*I
    4,5-Diamino-1-methyl-3-(methylthio)pyridazinium Iodide
    —— 2,6-Dimethyl-4-(methylthio)imidazo<4,5-d>pyridazine 76756-68-8 C8H10N4S
    2,6-Dimethyl-4-(methylthio)imidazo<4,5-d>pyridazine
    —— 1<i>c</i>-ethylsulfanyl-3,3-dimethyl-but-1-ene 64707-11-5 C8H16S
    1<i>c</i>-ethylsulfanyl-3,3-dimethyl-but-1-ene
    —— (Z)-β-Ethylmercapto-methacrylnitril 28976-84-3 C6H9NS
    (Z)-β-Ethylmercapto-methacrylnitril
    —— 3,3'-Dicyano-4,4'-diamino-diphenylsulfid 61382-02-3 C14H10N4S
    3,3'-Dicyano-4,4'-diamino-diphenylsulfid
    —— 2-(4'-tert-butylthiophenyl)thiophene 756899-88-4 C14H16S2
    2-(4'-tert-butylthiophenyl)thiophene
    —— 1-(7-Methyl-1,5-dithia-spiro[5.5]undec-8-en-8-yl)-ethanone 76160-01-5 C12H18OS2
    1-(7-Methyl-1,5-dithia-spiro[5.5]undec-8-en-8-yl)-ethanone
    —— Decanedithioic acid ethyl ester 81066-69-5 C12H24S2
    Decanedithioic acid ethyl ester
    —— N-Benzyl-2,2,2-trifluoro-N-((2S,3S)-2-fluoromethyl-2-hydroxy-3-p-tolylsulfanyl-butyl)-acetamide 214957-00-3 C21H23F4NO2S
    N-Benzyl-2,2,2-trifluoro-N-((2S,3S)-2-fluoromethyl-2-hydroxy-3-p-tolylsulfanyl-butyl)-acetamide
    —— 4,5-diisopropylthio-1,2-dithiole-3-thione 233685-26-2 C9H14S5
    4,5-diisopropylthio-1,2-dithiole-3-thione
    —— 3-(2-aminophenylthio)-1-(2-tienyl)prop-1-yne 260803-78-9 C13H11NS2
    3-(2-aminophenylthio)-1-(2-tienyl)prop-1-yne
    —— methyl 4-[4-(2-[2,2,2-trifluoroethyl]guanidino)pyrimid-2-ylthio]butyrimidate 84406-42-8 C12H17F3N6OS
    methyl 4-[4-(2-[2,2,2-trifluoroethyl]guanidino)pyrimid-2-ylthio]butyrimidate
    —— S-[2-{N-3'-(2-thienyl)prop-2'-ynyl}aminophenyl]-N,N-dimethylthiocarbamate 352556-31-1 C16H16N2OS2
    S-[2-{N-3'-(2-thienyl)prop-2'-ynyl}aminophenyl]-N,N-dimethylthiocarbamate
    —— 6-methylidenespiro[1,2,3a,4,5,6a-hexahydropentalene-3,2'-1,3-dithiolane] 142981-43-9 C11H16S2
    6-methylidenespiro[1,2,3a,4,5,6a-hexahydropentalene-3,2'-1,3-dithiolane]
    —— 2-[3-(4-[2-(2,2,2-trifluoroethyl)guanidino]pyrimid-2-ylthio)propyl]-1-imidazoline 84406-86-0 C13H18F3N7S
    2-[3-(4-[2-(2,2,2-trifluoroethyl)guanidino]pyrimid-2-ylthio)propyl]-1-imidazoline
    —— (E)-1-phenyl-2-(phenylthio)but-1-ene 66164-65-6 C16H16S
    (E)-1-phenyl-2-(phenylthio)but-1-ene
    —— 1-(4-chlorophenylamino)-4-(pyridin-4-ylthio)phthalazine 852989-59-4 C19H13ClN4S
    1-(4-chlorophenylamino)-4-(pyridin-4-ylthio)phthalazine
    —— (E)-1-bromo-1-phenyl-2-(phenylthio)but-1-ene 152959-18-7 C16H15BrS
    (E)-1-bromo-1-phenyl-2-(phenylthio)but-1-ene
    —— (Z)-1-phenyl-2-(phenylthio)but-1-ene 66164-53-2 C16H16S
    (Z)-1-phenyl-2-(phenylthio)but-1-ene
    —— 5,7-diamino-3-phenyl-2-(3,4-dimethoxyphenylthio)quinoxaline 958797-40-5 C22H20N4O2S
    5,7-diamino-3-phenyl-2-(3,4-dimethoxyphenylthio)quinoxaline
    —— 1-Bromo-5-ethylsulfanyl-pentane 115412-79-8 C7H15BrS
    1-Bromo-5-ethylsulfanyl-pentane
    —— 2-Methyldithiobenzoesaeurephenylester 112291-35-7 C14H12S2
    2-Methyldithiobenzoesaeurephenylester
    —— 2-(1-Methyl-3-phenylsulfanyl-prop-2-ynyl)-3-oxo-hexanoic acid methyl ester 199919-22-7 C17H20O3S
    2-(1-Methyl-3-phenylsulfanyl-prop-2-ynyl)-3-oxo-hexanoic acid methyl ester
    —— (Z)-4-(dimethyl(phenyl)silyl)-4-(phenylthio)but-3-en-2-ol 1622445-75-3 C18H22OSSi
    (Z)-4-(dimethyl(phenyl)silyl)-4-(phenylthio)but-3-en-2-ol
    —— Butadiyl-(1,4)-bis-(aethyl-sulfon) 92099-02-0 C8H18O4S2
    Butadiyl-(1,4)-bis-(aethyl-sulfon)