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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 6-Methyl-2-(1-methyl-1H-imidazol-2-ylsulfanyl)-pyridin-3-ylamine 96592-33-5 C10H12N4S
    6-Methyl-2-(1-methyl-1H-imidazol-2-ylsulfanyl)-pyridin-3-ylamine
    —— 8-[4-(2-Pyridyl)thiazol-2-ylmethyl]-10H-pyrazino[2,3-b][1,4]benzothiazine 203655-34-9 C19H13N5S2
    8-[4-(2-Pyridyl)thiazol-2-ylmethyl]-10H-pyrazino[2,3-b][1,4]benzothiazine
    —— 4,6-dichloro-N-(3-(7-nitrobenzo[c][1,2,5]oxadiazol-4-ylthio)phenyl)-1,3,5-triazin-2-aminium chloride 1602768-48-8 C15H7Cl2N7O3S*ClH
    4,6-dichloro-N-(3-(7-nitrobenzo[c][1,2,5]oxadiazol-4-ylthio)phenyl)-1,3,5-triazin-2-aminium chloride
    —— 4,6-dichloro-N-(3-(7-nitrobenzo[c][1,2,5]oxadiazol-4-ylthio)phenyl)-1,3,5-triazin-2-amine 1602768-45-5 C15H7Cl2N7O3S
    4,6-dichloro-N-(3-(7-nitrobenzo[c][1,2,5]oxadiazol-4-ylthio)phenyl)-1,3,5-triazin-2-amine
    —— 4-methyl-N-(3-(7-nitrobenzo[c][1,2,5]oxadiazol-4-ylthio)phenylcarbamoyl)benzenesulfonamide 1602768-43-3 C20H15N5O6S2
    4-methyl-N-(3-(7-nitrobenzo[c][1,2,5]oxadiazol-4-ylthio)phenylcarbamoyl)benzenesulfonamide
    —— N-(naphthalen-2-ylmethyl)-3-(7-nitrobenzo[c][1,2,5]oxadiazol-4-ylthio)benzenamine 1602768-53-5 C23H16N4O3S
    N-(naphthalen-2-ylmethyl)-3-(7-nitrobenzo[c][1,2,5]oxadiazol-4-ylthio)benzenamine
    —— 4-amino-3-methylsulfanyl-phenol 37407-24-2 C7H9NOS
    4-amino-3-methylsulfanyl-phenol
    —— (10H-pyrazino[2,3-b][1,4]benzothiazin-8-yl)thioacetamide 203657-45-8 C12H10N4S2
    (10H-pyrazino[2,3-b][1,4]benzothiazin-8-yl)thioacetamide
    —— 1,1,2,2-Tetrafluor-1-aethylenmercapto-aethan 428-95-5 C4H6F4S
    1,1,2,2-Tetrafluor-1-aethylenmercapto-aethan
    —— 4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-(tetrazol-1-ylmethyl)pyridin-2(1H)-one 1185190-27-5 C16H16IN5OS
    4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-(tetrazol-1-ylmethyl)pyridin-2(1H)-one
    —— 1,3,4,6-tetrakis(isopropylthio)-2λ<sup>4</sup>δ<sup>2</sup>-thieno<3,4-c>thiophene 98088-21-2 C18H28S6
    1,3,4,6-tetrakis(isopropylthio)-2λ<sup>4</sup>δ<sup>2</sup>-thieno<3,4-c>thiophene
    —— 4-[(4-bromophenyl)sulfanyl]furo[3,2-c]pyridine 1609581-10-3 C13H8BrNOS
    4-[(4-bromophenyl)sulfanyl]furo[3,2-c]pyridine
    —— 4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-(tetrazol-2-ylmethyl)pyridin-2(1H)-one 1185190-17-3 C16H16IN5OS
    4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-(tetrazol-2-ylmethyl)pyridin-2(1H)-one
    —— 6,6-Dimethyl-3-isopropylthio-1-(tetrazol-5-yl)-4,5,6,7-tetrahydrobenzo[c]thiophen-4-one 207307-78-6 C14H18N4OS2
    6,6-Dimethyl-3-isopropylthio-1-(tetrazol-5-yl)-4,5,6,7-tetrahydrobenzo[c]thiophen-4-one
    —— 2-Nitro-1-(phenylsulfanylmethyl)imidazole 1569296-97-4 C10H9N3O2S
    2-Nitro-1-(phenylsulfanylmethyl)imidazole
    —— (R)-1-(phenylthio)-2-aminopropane hydrochloride 56216-00-3 C9H13NS*ClH
    (R)-1-(phenylthio)-2-aminopropane hydrochloride
    —— 2-(2-(methylthio)phenyl)-4,5-dihydrooxazole 1445591-10-5 C10H11NOS
    2-(2-(methylthio)phenyl)-4,5-dihydrooxazole
    —— 4-(phenylthio)-6-phenylpyrimido[4,5-b][1,4]benzothiazepine 873106-33-3 C23H15N3S2
    4-(phenylthio)-6-phenylpyrimido[4,5-b][1,4]benzothiazepine
    —— Ethyl 2,4-dimethyl-5-({[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetyl)-1H-pyrrole-3-carboxylate 785711-83-3 C18H18N4O4S
    Ethyl 2,4-dimethyl-5-({[5-(pyridin-4-yl)-1,3,4-oxadiazol-2-yl]sulfanyl}acetyl)-1H-pyrrole-3-carboxylate
    —— 4-(p-tolylthio)-6-phenyl-8-methylpyrimido[4,5-b][1,4]benzothiazepine 873106-41-3 C25H19N3S2
    4-(p-tolylthio)-6-phenyl-8-methylpyrimido[4,5-b][1,4]benzothiazepine
    —— 2-[(5-Anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-[2,5-dimethyl-1-(3-methylbutyl)pyrrol-3-yl]ethanone 5519-26-6 C21H26N4OS2
    2-[(5-Anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-[2,5-dimethyl-1-(3-methylbutyl)pyrrol-3-yl]ethanone
    —— 2-phenylthioacetylbutylamide 71433-00-6 C12H17NOS
    2-phenylthioacetylbutylamide
    —— 1-methyl-3-methylthiopropylamine 105882-51-7 C5H13NS
    1-methyl-3-methylthiopropylamine
    —— 3-Propylsulfanylpyridin-2-amine 1532517-79-5 C8H12N2S
    3-Propylsulfanylpyridin-2-amine
    —— 5-Bromo-3-propylsulfanylpyridin-2-amine 1532517-80-8 C8H11BrN2S
    5-Bromo-3-propylsulfanylpyridin-2-amine
    —— 1-methyl-2-(2-methylphenylthio)ethylamine 104864-69-9 C10H15NS
    1-methyl-2-(2-methylphenylthio)ethylamine
    —— N,N-dimethyl-3-((5-nitropyridin-2-yl)thio)-3-phenylpropan-1-amine 1584114-13-5 C16H19N3O2S
    N,N-dimethyl-3-((5-nitropyridin-2-yl)thio)-3-phenylpropan-1-amine
    —— N-(2,2-dimethoxy-ethyl)-2-(acetyl-methylamino)-3,3-dimethyl-thiobutyric acid amide 866784-81-8 C13H26N2O3S
    N-(2,2-dimethoxy-ethyl)-2-(acetyl-methylamino)-3,3-dimethyl-thiobutyric acid amide
    —— (E)-4-(di-sec-butylboryl)-5-(butylthio)-3-methyl-4-nonene 403519-55-1 C22H45BS
    (E)-4-(di-sec-butylboryl)-5-(butylthio)-3-methyl-4-nonene
    —— 2-Butylsulfanyl-1-tert-butylethyne 127894-33-1 C10H18S
    2-Butylsulfanyl-1-tert-butylethyne
    —— 2,3-Bis(phenylthio)-N-methylmaleinimid 74353-20-1 C17H13NO2S2
    2,3-Bis(phenylthio)-N-methylmaleinimid
    —— D-4-HYDROXYMETHYL-5-[4-(METHYLMERCAPTO)PHENYL]-2-PHENYL-2-OXAZOLINE 126429-07-0 C17H17NO2S
    D-4-HYDROXYMETHYL-5-[4-(METHYLMERCAPTO)PHENYL]-2-PHENYL-2-OXAZOLINE
    —— 1-Thiomethyl-3-methyl-allen 34262-50-5 C5H8S
    1-Thiomethyl-3-methyl-allen
    —— 2-pyridin-2-ylsulfanyl-acetamide 10002-31-0 C7H8N2OS
    2-pyridin-2-ylsulfanyl-acetamide
    —— tert-butyl 2-(trimethylsilyl)ethyl sulfoxide 156090-86-7 C9H22OSSi
    tert-butyl 2-(trimethylsilyl)ethyl sulfoxide
    —— 3,5-dichloro-2,6-difluoro-4-phenylthiopyridine 51066-41-2 C11H5Cl2F2NS
    3,5-dichloro-2,6-difluoro-4-phenylthiopyridine
    —— 5-((3,5-dichloropyridin-4-yl)thio)-N-((2,3-dihydrobenzofuran-5-yl)methyl)-4-nitrothiophene-2-carboxamide 1247820-70-7 C19H13Cl2N3O4S2
    5-((3,5-dichloropyridin-4-yl)thio)-N-((2,3-dihydrobenzofuran-5-yl)methyl)-4-nitrothiophene-2-carboxamide
    —— 1-Methylmercapto-1.2.4-pentatrien 19429-99-3 C6H8S
    1-Methylmercapto-1.2.4-pentatrien
    —— N-methoxy-N-methyl-2-(phenylthio)pent-4-enamide 754201-16-6 C13H17NO2S
    N-methoxy-N-methyl-2-(phenylthio)pent-4-enamide
    —— 2,3-Dimethyl-2,4-pentadien-diethylthioamid 52412-20-1 C11H19NS
    2,3-Dimethyl-2,4-pentadien-diethylthioamid
    —— 5-[(3,5-dichloro-4-pyridyl)sulfanyl]-N-isopropyl-4-nitro-thiophene-2-carboxamide 1247820-27-4 C13H11Cl2N3O3S2
    5-[(3,5-dichloro-4-pyridyl)sulfanyl]-N-isopropyl-4-nitro-thiophene-2-carboxamide
    —— (E)-3-dimethylamino-2-methylsulfonylpropenenitrile 858135-91-8 C6H10N2O2S
    (E)-3-dimethylamino-2-methylsulfonylpropenenitrile
    —— 2-(4-dimethylaminobutoxy)-diphenyl sulfide hydrochloride 62232-58-0 C18H23NOS*ClH
    2-(4-dimethylaminobutoxy)-diphenyl sulfide hydrochloride
    —— 1-pentyl-3-[(Z)-12-(1H-1,2,4-triazol-5-ylsulfanyl)dodec-5-enyl]urea 1402547-56-1 C20H37N5OS
    1-pentyl-3-[(Z)-12-(1H-1,2,4-triazol-5-ylsulfanyl)dodec-5-enyl]urea
    —— Pyrrolidine, 1-[[[5-(2-thienyl)-1,3,4-oxadiazol-2-yl]thio]acetyl]- 459846-08-3 C12H13N3O2S2
    Pyrrolidine, 1-[[[5-(2-thienyl)-1,3,4-oxadiazol-2-yl]thio]acetyl]-
    —— 4-Chloro-2-isothiocyanato-2-methyl-pentane 691359-03-2 C7H12ClNS
    4-Chloro-2-isothiocyanato-2-methyl-pentane
    —— Bis-<7-nitro-benz<2,1,3-thiadizolyl-(4)>-sulfid 7668-44-2 C12H4N6O4S3
    Bis-<7-nitro-benz<2,1,3-thiadizolyl-(4)>-sulfid
    —— 4-isothiocyanato-4-methyl-2-pentanol 691359-06-5 C7H13NOS
    4-isothiocyanato-4-methyl-2-pentanol
    —— 6-(ethylthio)-2,3-difluoropyridine 1257071-62-7 C7H7F2NS
    6-(ethylthio)-2,3-difluoropyridine
    —— 2-ethyl-3-hydroxy-6-(phenylthio)-4(1H)-pyridinone 221695-79-0 C13H13NO2S
    2-ethyl-3-hydroxy-6-(phenylthio)-4(1H)-pyridinone