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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— S-2,2-diethyl-4-oxocyclobutyl O-neopentyl carbonodithioate 1170673-33-2 C14H24O2S2
    S-2,2-diethyl-4-oxocyclobutyl O-neopentyl carbonodithioate
    —— 2-[4,5-Bis(methylsulfanyl)-1,3-dithiol-2-ylidene]-4,5-bis[[2-[4,5-bis(methylsulfanyl)-1,3-dithiol-2-ylidene]-5-methylsulfanyl-1,3-dithiol-4-yl]sulfanylmethylsulfanyl]-1,3-dithiole 1308660-11-8 C28H28S24
    2-[4,5-Bis(methylsulfanyl)-1,3-dithiol-2-ylidene]-4,5-bis[[2-[4,5-bis(methylsulfanyl)-1,3-dithiol-2-ylidene]-5-methylsulfanyl-1,3-dithiol-4-yl]sulfanylmethylsulfanyl]-1,3-dithiole
    —— 2-(4-bromophenylthio)-N-phenylpyridin-3-amine 1410071-27-0 C17H13BrN2S
    2-(4-bromophenylthio)-N-phenylpyridin-3-amine
    —— 6-(2-Ethyl-1,3-dithian-2-yl)-5-hydroxy-4-methylheptan-3-one 1415754-59-4 C14H26O2S2
    6-(2-Ethyl-1,3-dithian-2-yl)-5-hydroxy-4-methylheptan-3-one
    —— 6-(4-diethylaminophenyl)-4-methylsulfanyl-2-oxo-2H-pyran-3-carbonitrile 1346239-32-4 C17H18N2O2S
    6-(4-diethylaminophenyl)-4-methylsulfanyl-2-oxo-2H-pyran-3-carbonitrile
    —— [(6R,9R,10S)-9-[(2S)-6-(2-ethyl-1,3-dithiolan-2-yl)-4-methyl-3,5-dioxoheptan-2-yl]-6,10-dimethyl-1,4,8-trioxaspiro[4.5]decan-7-yl] 2,2-dimethylpropanoate 1228184-06-2 C27H44O7S2
    [(6R,9R,10S)-9-[(2S)-6-(2-ethyl-1,3-dithiolan-2-yl)-4-methyl-3,5-dioxoheptan-2-yl]-6,10-dimethyl-1,4,8-trioxaspiro[4.5]decan-7-yl] 2,2-dimethylpropanoate
    —— 3-(4-Chlorophenyl)sulfanyl-1-methylpiperidin-2-one 1421271-78-4 C12H14ClNOS
    3-(4-Chlorophenyl)sulfanyl-1-methylpiperidin-2-one
    —— 53198-53-1 C8H9LiS
    —— (2R,4aR,6S,9aS)-2-phenyl-6-phenylsulfanyl-4a,6,7,8,9,9a-hexahydro-4H-[1,3]dioxino[5,4-b]oxepine 1548668-81-0 C20H22O3S
    (2R,4aR,6S,9aS)-2-phenyl-6-phenylsulfanyl-4a,6,7,8,9,9a-hexahydro-4H-[1,3]dioxino[5,4-b]oxepine
    —— 2-phenyl-5-(3,4,5-trimethoxyphenylthio)-1,3,4-oxadiazole 1569303-98-5 C17H16N2O4S
    2-phenyl-5-(3,4,5-trimethoxyphenylthio)-1,3,4-oxadiazole
    —— 2-(3,4,5-trimethoxyphenylthio)pyrimidine 1569303-95-2 C13H14N2O3S
    2-(3,4,5-trimethoxyphenylthio)pyrimidine
    —— 2-Ethenylsulfanyl-5-[(4-fluorophenyl)methyl]-4-phenylthiophene-3-carbonitrile 1593011-90-5 C20H14FNS2
    2-Ethenylsulfanyl-5-[(4-fluorophenyl)methyl]-4-phenylthiophene-3-carbonitrile
    —— 1-Methyl-3-(4-methylphenyl)sulfanylpiperidin-2-one 1421271-77-3 C13H17NOS
    1-Methyl-3-(4-methylphenyl)sulfanylpiperidin-2-one
    —— 5-Benzyl-2-ethenylsulfanyl-4-phenylthiophene-3-carbonitrile 1593011-79-0 C20H15NS2
    5-Benzyl-2-ethenylsulfanyl-4-phenylthiophene-3-carbonitrile
    —— 7-[(2-bromophenyl)thio]-4-(trifluoromethyl)-2H-pyrimido[1,2-b]pyridazin-2-one 1629613-55-3 C14H7BrF3N3OS
    7-[(2-bromophenyl)thio]-4-(trifluoromethyl)-2H-pyrimido[1,2-b]pyridazin-2-one
    —— 4,5-Bis(2-methylbutylsulfanyl)-1,3-dithiole-2-thione 1402215-09-1 C13H22S5
    4,5-Bis(2-methylbutylsulfanyl)-1,3-dithiole-2-thione
    —— Phenylmethylsulfanylbenzene 125407-64-9 C13H11S
    Phenylmethylsulfanylbenzene
    —— (R)-N,N-dimethyl-3-phenyl-3-(phenylthio)propanethioamide 1402449-08-4 C17H19NS2
    (R)-N,N-dimethyl-3-phenyl-3-(phenylthio)propanethioamide
    —— (R)-3-((2-aminophenyl)thio)-3-(furan-2-yl)-N,N-dimethylpropanethioamide 1402449-17-5 C15H18N2OS2
    (R)-3-((2-aminophenyl)thio)-3-(furan-2-yl)-N,N-dimethylpropanethioamide
    —— 3-(2-methylhydrazino)pyrido[4,3-e]-1,4,2-dithiazine 1,1-dioxide 1078160-02-7 C7H8N4O2S2
    3-(2-methylhydrazino)pyrido[4,3-e]-1,4,2-dithiazine 1,1-dioxide
    —— Acetic acid (R)-2-hydroxymethyl-3-phenylsulfanyl-propyl ester 213011-54-2 C12H16O3S
    Acetic acid (R)-2-hydroxymethyl-3-phenylsulfanyl-propyl ester
    —— 2-Amino-4-butyl-6-phenylsulfanylpyridine-3,5-dicarbonitrile 1202481-88-6 C17H16N4S
    2-Amino-4-butyl-6-phenylsulfanylpyridine-3,5-dicarbonitrile
    —— 3-(pyrimidin-2-ylthio)benzonitrile 1569303-94-1 C11H7N3S
    3-(pyrimidin-2-ylthio)benzonitrile
    —— 5-bromo-4-phenylsulfanyl-[3]pyridylamine 99851-83-9 C11H9BrN2S
    5-bromo-4-phenylsulfanyl-[3]pyridylamine
    —— 4-Thiazolemethanol, 2-[4-(methylthio)phenyl]- 1344046-01-0 C11H11NOS2
    4-Thiazolemethanol, 2-[4-(methylthio)phenyl]-
    —— 1-[5-(Ethylthio)-2-furanyl]ethanone 28569-34-8 C8H10O2S
    1-[5-(Ethylthio)-2-furanyl]ethanone
    —— Cyclopentanemethanamine, N-[2-(propylsulfonyl)ethyl]- 1691609-19-4 C11H23NO2S
    Cyclopentanemethanamine, N-[2-(propylsulfonyl)ethyl]-
    —— 2-Propanol, 1-[(1,1-dimethylethyl)amino]-3-[(1-methyl-1H-1,2,4-triazol-5-yl)thio]- 1566410-00-1 C10H20N4OS
    2-Propanol, 1-[(1,1-dimethylethyl)amino]-3-[(1-methyl-1H-1,2,4-triazol-5-yl)thio]-
    —— 3-(Octylthio)phenol 24312-56-9 C14H22OS
    3-(Octylthio)phenol
    —— benzotetrathiafulvalene-1-carbonyl chloride 1379685-48-9 C11H5ClOS4
    benzotetrathiafulvalene-1-carbonyl chloride
    —— 6,7,15,16,24,25,33,34-Octakis(tert-butylsulfanyl)-2,5,8,11,14,17,20,23,26,29,32,35,37,38,39,40-hexadecazanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13(18),14,16,19(39),20,22(27),23,25,28(38),30(37),31(36),32,34-nonadecaene 927874-92-8 C56H74N16S8
    6,7,15,16,24,25,33,34-Octakis(tert-butylsulfanyl)-2,5,8,11,14,17,20,23,26,29,32,35,37,38,39,40-hexadecazanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13(18),14,16,19(39),20,22(27),23,25,28(38),30(37),31(36),32,34-nonadecaene
    —— 6-benzylthio-7-methyl-2-(1-methyl-4-nitroimidazol-5-ylthio)purine 1198406-00-6 C17H15N7O2S2
    6-benzylthio-7-methyl-2-(1-methyl-4-nitroimidazol-5-ylthio)purine
    —— 7-methyl-6-thioxo-1,6-dihydro-2-(1-methyl-4-nitroimidazol-5-ylthio)purine 1198405-97-8 C10H9N7O2S2
    7-methyl-6-thioxo-1,6-dihydro-2-(1-methyl-4-nitroimidazol-5-ylthio)purine
    —— 7,7-bis(methylthio)benzocyclooctan-5-ol 1196708-28-7 C14H20OS2
    7,7-bis(methylthio)benzocyclooctan-5-ol
    —— cyclohexa-2,5-dien-4-one spiro-1,2'-(1',3'-dithiane) 125016-61-7 C9H10OS2
    cyclohexa-2,5-dien-4-one spiro-1,2'-(1',3'-dithiane)
    —— (2S)-1-{2-[(phenylthio)methyl]pyrrolidin-1-yl}-1H-imidazole 1246655-27-5 C14H17N3S
    (2S)-1-{2-[(phenylthio)methyl]pyrrolidin-1-yl}-1H-imidazole
    —— 9,10,20,21,22,23-hexahydro-5H,12H-dibenzo[b,n][1,7,10,16,4,13]tetrathiadiazacycloicosine-6,13(7H,14H)-dione 1227404-54-7 C22H26N2O2S4
    9,10,20,21,22,23-hexahydro-5H,12H-dibenzo[b,n][1,7,10,16,4,13]tetrathiadiazacycloicosine-6,13(7H,14H)-dione
    —— methyl(2-((2-(phenylethynyl)phenyl)ethynyl)phenyl)sulfane 1367458-40-9 C23H16S
    methyl(2-((2-(phenylethynyl)phenyl)ethynyl)phenyl)sulfane
    —— 7-(1,3-Benzodithiol-2-ylidene)-3,11-dithiatricyclo[6.3.0.02,6]undeca-1(8),2(6),4,9-tetraene 143736-74-7 C16H8S4
    7-(1,3-Benzodithiol-2-ylidene)-3,11-dithiatricyclo[6.3.0.02,6]undeca-1(8),2(6),4,9-tetraene
    —— cis-2-thiabicyclo<6.1.0>nonan-7β-ol 2,2-dioxide 134333-93-0 C8H14O3S
    cis-2-thiabicyclo<6.1.0>nonan-7β-ol 2,2-dioxide
    —— 1,1,1-Trideuterio-3-ethylsulfanylpropane 139097-68-0 C5H12S
    1,1,1-Trideuterio-3-ethylsulfanylpropane
    —— 2,2'-[(Hexafluoro-1-cyclopentene-1,2-diyl)bisthio]bisethanol 16325-85-2 C9H10F6O2S2
    2,2'-[(Hexafluoro-1-cyclopentene-1,2-diyl)bisthio]bisethanol
    —— 2,2'-(1-phenylethane-1,2-diylidene)bis(1,3-benzodithiole) 1156544-15-8 C22H14S4
    2,2'-(1-phenylethane-1,2-diylidene)bis(1,3-benzodithiole)
    —— 2-[[3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]methylsulfanyl]pyrimidine 1260900-84-2 C17H21BN2O2S
    2-[[3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]methylsulfanyl]pyrimidine
    —— (2',8'-dimethoxyspiro[1,3-dithiane-2,5'-4,5a,6,7,8a,8b-hexahydro-2H-cyclopenta[g][1]benzofuran]-8'-yl)oxy-tri(propan-2-yl)silane 1280709-73-0 C25H44O4S2Si
    (2',8'-dimethoxyspiro[1,3-dithiane-2,5'-4,5a,6,7,8a,8b-hexahydro-2H-cyclopenta[g][1]benzofuran]-8'-yl)oxy-tri(propan-2-yl)silane
    —— tris(8-(S)-α-methylbenzylaminocarbonyl-2,2,6,6-tetramethylbenzo[1,2-d;4,5-d']bis[1,3]dithiol-4-yl)methanol 1308384-86-2 C64H67N3O4S12
    tris(8-(S)-α-methylbenzylaminocarbonyl-2,2,6,6-tetramethylbenzo[1,2-d;4,5-d']bis[1,3]dithiol-4-yl)methanol
    —— (3R,4S)-3-methyl-5-(4-methylphenyl)sulfanyl-4-phenyloxolan-2-one 1022912-27-1 C18H18O2S
    (3R,4S)-3-methyl-5-(4-methylphenyl)sulfanyl-4-phenyloxolan-2-one
    —— 2,2,2-Trichloroethyl 5,5-dimethyl-2,2-dioxo-4-(phenylsulfanylmethyl)-1,2,3,6-oxathiadiazinane-6-carboxylate 1310054-44-4 C14H17Cl3N2O5S2
    2,2,2-Trichloroethyl 5,5-dimethyl-2,2-dioxo-4-(phenylsulfanylmethyl)-1,2,3,6-oxathiadiazinane-6-carboxylate
    —— 1-[1,2-Bis[(4-methylphenyl)sulfanyl]ethyl]-3-methylbenzene 1313220-41-5 C23H24S2
    1-[1,2-Bis[(4-methylphenyl)sulfanyl]ethyl]-3-methylbenzene
    —— 3-(1H-benzimidazol-2-ylsulfanyl)phenol 1018987-20-6 C13H10N2OS
    3-(1H-benzimidazol-2-ylsulfanyl)phenol