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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-(2-Chloromethyl-allyl)-2-phenylsulfanyl-cyclopentanone 77517-77-2 C15H17ClOS
    3-(2-Chloromethyl-allyl)-2-phenylsulfanyl-cyclopentanone
    —— 1-methyl-4-(7-phenylhept-4-ene-2,6-diynylsulfanyl)benzene 1445996-66-6 C20H16S
    1-methyl-4-(7-phenylhept-4-ene-2,6-diynylsulfanyl)benzene
    —— 3,3-[1,3-propanediyl-bis(thio)]-n-heptan-2-one 68578-41-6 C10H18OS2
    3,3-[1,3-propanediyl-bis(thio)]-n-heptan-2-one
    —— 1.6-Bis-(2.4-dichlor-benzylmercapto)-dipyridazo<4,5-b;4,5-e>-1.4-dithiin 13616-24-5 C22H12Cl4N4S4
    1.6-Bis-(2.4-dichlor-benzylmercapto)-dipyridazo<4,5-b;4,5-e>-1.4-dithiin
    —— S,S'-bis[2-(allyloxycarbonylthio)ethyl]dithiocarbonate 1028810-22-1 C13H18O5S4
    S,S'-bis[2-(allyloxycarbonylthio)ethyl]dithiocarbonate
    —— 5-sec-butyl-4-chloro-6-(4-methylpiperidin-1-yl)-2-methylthiopyrimidine 944740-20-9 C15H24ClN3S
    5-sec-butyl-4-chloro-6-(4-methylpiperidin-1-yl)-2-methylthiopyrimidine
    —— N-(5-fluoro-2-methylsulfanylpyrimidin-4-yl)-N,N-dimethylformamidine 1312324-58-5 C8H11FN4S
    N-(5-fluoro-2-methylsulfanylpyrimidin-4-yl)-N,N-dimethylformamidine
    —— 1-neopentyl-2-tert-butyl-4-nitro-5-imidazolyl 2-carbomethoxyphenyl sulfide 135217-05-9 C20H27N3O4S
    1-neopentyl-2-tert-butyl-4-nitro-5-imidazolyl 2-carbomethoxyphenyl sulfide
    —— methyl 2-[6-(1-bromo-ethyl)-5-fluoropyrimidin-4-yl-sulfanyl]benzoate 1258386-28-5 C14H12BrFN2O2S
    methyl 2-[6-(1-bromo-ethyl)-5-fluoropyrimidin-4-yl-sulfanyl]benzoate
    —— methyl 2-{[4-(4-oxo-4H-1,3-benzothiazin-2-yl)-2-pyridyl]thio}benzoate 501375-52-6 C21H14N2O3S2
    methyl 2-{[4-(4-oxo-4H-1,3-benzothiazin-2-yl)-2-pyridyl]thio}benzoate
    —— methyl 2-(imidazo[1,2-b]pyridazin-6-ylthio)benzoate 1005787-62-1 C14H11N3O2S
    methyl 2-(imidazo[1,2-b]pyridazin-6-ylthio)benzoate
    —— 2-[2-(4-methyl)phenylthio-3-pyridyl]-4H-1,3-benzothiazine-4 501375-65-1 C20H14N2OS2
    2-[2-(4-methyl)phenylthio-3-pyridyl]-4H-1,3-benzothiazine-4
    —— methyl 2-({2-[(cyclopropylcarbonyl)amino]imidazo[1,2-b]pyridazin-6-yl}thio)benzoate 1005788-36-2 C18H16N4O3S
    methyl 2-({2-[(cyclopropylcarbonyl)amino]imidazo[1,2-b]pyridazin-6-yl}thio)benzoate
    —— 1-(2-benzylthiobenzyl)pyrrole-2-carboxaldehyde 99141-20-5 C19H17NOS
    1-(2-benzylthiobenzyl)pyrrole-2-carboxaldehyde
    —— 1-(2-benzylthiobenzyl)pyrrole-2-carbonitrile 99141-22-7 C19H16N2S
    1-(2-benzylthiobenzyl)pyrrole-2-carbonitrile
    —— 2-[1-(3,5-difluoro-benzyl)-6-methoxy-1H-indol-3-ylsulfanyl]-benzoic acid methyl ester 691400-14-3 C24H19F2NO3S
    2-[1-(3,5-difluoro-benzyl)-6-methoxy-1H-indol-3-ylsulfanyl]-benzoic acid methyl ester
    —— 1-(2-benzylthiobenzyl)pyrrole-2-carboxylic acid 99141-23-8 C19H17NO2S
    1-(2-benzylthiobenzyl)pyrrole-2-carboxylic acid
    —— 11-Oxo-5H,11H-pyrrolo<2,1-c><1,4>benzothiazepine 99141-28-3 C12H9NOS
    11-Oxo-5H,11H-pyrrolo<2,1-c><1,4>benzothiazepine
    —— 2-(4-bromo-2-nitrophenylsulfanyl) benzoic acid methyl ester 200280-46-2 C14H10BrNO4S
    2-(4-bromo-2-nitrophenylsulfanyl) benzoic acid methyl ester
    —— 4-hydroxy-3,5-dimethyl-3-phenylsulfanyl-dihydro-furan-2-one 950765-88-5 C12H14O3S
    4-hydroxy-3,5-dimethyl-3-phenylsulfanyl-dihydro-furan-2-one
    —— 5-phenylsulfanyl-1H-imidazole —— C9H8N2S
    5-phenylsulfanyl-1H-imidazole
    —— 1,1'-((2-(2-(phenylthio)phenylthio)phenyl)methylene)bis(3,5-isopropyl-1H-pyrazole) 1210393-68-2 C37H44N4S2
    1,1'-((2-(2-(phenylthio)phenylthio)phenyl)methylene)bis(3,5-isopropyl-1H-pyrazole)
    —— 4-chloro-5,7-dihydro-2-(methylthio)furo[3,4-d]pyrimidine 1007396-05-5 C7H7ClN2OS
    4-chloro-5,7-dihydro-2-(methylthio)furo[3,4-d]pyrimidine
    —— 2,2-difluoro-1-(2'-methoxyethoxymethoxy)-1-(4''-thioanisoyl)ethene 1388707-71-8 C13H16F2O3S
    2,2-difluoro-1-(2'-methoxyethoxymethoxy)-1-(4''-thioanisoyl)ethene
    —— 2-allyl-1,3-dithiane-2-carbaldehyde 75266-68-1 C8H12OS2
    2-allyl-1,3-dithiane-2-carbaldehyde
    —— 1,1-difluoro-2-(2'-methoxyethoxymethoxy)-4,4-[1,3]dithian-2-ylhepta-1,6-dien-3-ol 864532-93-4 C14H22F2O4S2
    1,1-difluoro-2-(2'-methoxyethoxymethoxy)-4,4-[1,3]dithian-2-ylhepta-1,6-dien-3-ol
    —— 3-allyloxy-1,1-difluoro-2-(2'-methoxyethoxymethoxy)-4,4-[1,3]dithian-2-ylhepta-1,6-diene 864532-95-6 C17H26F2O4S2
    3-allyloxy-1,1-difluoro-2-(2'-methoxyethoxymethoxy)-4,4-[1,3]dithian-2-ylhepta-1,6-diene
    —— 4,4-difluoro-7-([1,3]dithian-2-yl)-5-(2'-methoxyethoxymethoxy)deca-1,5Z,9-trien-3-ol 864532-98-9 C17H26F2O4S2
    4,4-difluoro-7-([1,3]dithian-2-yl)-5-(2'-methoxyethoxymethoxy)deca-1,5Z,9-trien-3-ol
    —— 1,1'-(Hexa-2,4-diyne-1,6-diyldisulfanediyl)bis(4-methylbenzene) 75368-08-0 C20H18S2
    1,1'-(Hexa-2,4-diyne-1,6-diyldisulfanediyl)bis(4-methylbenzene)
    —— 2-(6-chloro-2-methylsulfanyl-pyrimidin-4-yl-amino)-ethanol 932046-82-7 C7H10ClN3OS
    2-(6-chloro-2-methylsulfanyl-pyrimidin-4-yl-amino)-ethanol
    —— bis(1,2-tributylstannyl)-3-p-tolylthiopropene 155197-75-4 C34H64SSn2
    bis(1,2-tributylstannyl)-3-p-tolylthiopropene
    —— (2E,6E)-2,7-Dimethyl-1,8-bis(phenylthio)octa-2,6-diene 128243-73-2 C22H26S2
    (2E,6E)-2,7-Dimethyl-1,8-bis(phenylthio)octa-2,6-diene
    —— tert-butyl N-[(2S)-2-(1,3-benzodithiol-2-yl)-3-hydroxypropyl]-N-methylcarbamate 1333204-00-4 C16H23NO3S2
    tert-butyl N-[(2S)-2-(1,3-benzodithiol-2-yl)-3-hydroxypropyl]-N-methylcarbamate
    —— 3-(3-(tert-butylthio)pyridin-2-yl)propanenitrile 1147849-33-9 C12H16N2S
    3-(3-(tert-butylthio)pyridin-2-yl)propanenitrile
    —— 2-(3-(tert-butylthio)pyridin-2-yl)ethanamine 1147849-29-3 C11H18N2S
    2-(3-(tert-butylthio)pyridin-2-yl)ethanamine
    —— phosphoric acid diethyl ester 5-ethylsulfanyl-1-methyl-6-oxo-1,6-dihydro-pyridazin-4-yl ester 37839-90-0 C11H19N2O5PS
    phosphoric acid diethyl ester 5-ethylsulfanyl-1-methyl-6-oxo-1,6-dihydro-pyridazin-4-yl ester
    —— 1,3,5-tris(phenylthio)benzene 3379-62-2 C24H18S3
    1,3,5-tris(phenylthio)benzene
    —— (5-bromo-1,3-phenylene)bis(methylsulfane) 149428-38-6 C8H9BrS2
    (5-bromo-1,3-phenylene)bis(methylsulfane)
    —— 3.5-dibromophenyl 4-tert-butylphenyl sulphide 135049-37-5 C16H16Br2S
    3.5-dibromophenyl 4-tert-butylphenyl sulphide
    —— 5-cyano-2-methyl-6-methylthio-1-phenylpyrimidin-4(1H)-one 111479-75-5 C13H11N3OS
    5-cyano-2-methyl-6-methylthio-1-phenylpyrimidin-4(1H)-one
    —— 5-cyano-2-methyl-6-methylthio-3-phenylpyrimidin-4(3H)-one 111479-74-4 C13H11N3OS
    5-cyano-2-methyl-6-methylthio-3-phenylpyrimidin-4(3H)-one
    —— tert-butyl-2-({4-[((2-methoxyethyl){2-[3-methylphenyl]pyrimidin-4-yl}amino)methyl]phenyl}-thio)-2-methylpropanoate 881687-39-4 C29H37N3O3S
    tert-butyl-2-({4-[((2-methoxyethyl){2-[3-methylphenyl]pyrimidin-4-yl}amino)methyl]phenyl}-thio)-2-methylpropanoate
    —— 2-Methylamino-aethyl-2-methylamino-aethanthiolsulfonat 90993-34-3 C6H16N2O2S2
    2-Methylamino-aethyl-2-methylamino-aethanthiolsulfonat
    —— 4-(2,6-Dinitro-4-trifluoromethyl-phenylsulfanyl)-phenylamine 128730-87-0 C13H8F3N3O4S
    4-(2,6-Dinitro-4-trifluoromethyl-phenylsulfanyl)-phenylamine
    —— Aethyl-N-vinylformimidat 30698-08-9 C5H9NS
    Aethyl-N-vinylformimidat
    —— 1,1,3-(trisphenylthio)propane 69519-81-9 C21H20S3
    1,1,3-(trisphenylthio)propane
    —— 1-Methoxy-1-phenylthio-2-propin 13864-98-7 C10H10OS
    1-Methoxy-1-phenylthio-2-propin
    —— 4,6-dichloro-2-[(2,3-difluorobenzyl)thio]pyrimidine-5-carbaldehyde oxime 666752-62-1 C12H7Cl2F2N3OS
    4,6-dichloro-2-[(2,3-difluorobenzyl)thio]pyrimidine-5-carbaldehyde oxime
    —— Triacontyl carbamimidothioate 5249-97-8 C31H64N2S
    Triacontyl carbamimidothioate
    —— (S)-4-[2'-(4''-Hydroxybutyl)-1',3'-dithian-2'-yl]butane-1,3-diol 319911-64-3 C12H24O3S2
    (S)-4-[2'-(4''-Hydroxybutyl)-1',3'-dithian-2'-yl]butane-1,3-diol