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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-(4-aminophenyl)sulfanyl-N-[(1R)-indan-1-yl]-3-[(7-isopropylpyrido[2,3-d]pyrimidin-4-yl)amino]benzamide 943780-63-0 C32H30N6OS
    4-(4-aminophenyl)sulfanyl-N-[(1R)-indan-1-yl]-3-[(7-isopropylpyrido[2,3-d]pyrimidin-4-yl)amino]benzamide
    —— N-[3-Amino-4-[(4-hydroxyphenyl)thio]phenyl]-4-(trifluoromethyl)cyclohexanecarboxamide 1260026-23-0 C20H21F3N2O2S
    N-[3-Amino-4-[(4-hydroxyphenyl)thio]phenyl]-4-(trifluoromethyl)cyclohexanecarboxamide
    —— 4-(4-aminophenyl)sulfanyl-3-[(7-isopropylpyrido[2,3-d]pyrimidin-4-yl)amino]-N-[1-(2-thienyl)ethyl]benzamide 943779-25-7 C29H28N6OS2
    4-(4-aminophenyl)sulfanyl-3-[(7-isopropylpyrido[2,3-d]pyrimidin-4-yl)amino]-N-[1-(2-thienyl)ethyl]benzamide
    —— 4-(4-aminophenyl)sulfanyl-N-[(1S)-indan-1-yl]-3-[(7-isopropylpyrido[2,3-d]pyrimidin-4-yl)amino]benzamide 943779-40-6 C32H30N6OS
    4-(4-aminophenyl)sulfanyl-N-[(1S)-indan-1-yl]-3-[(7-isopropylpyrido[2,3-d]pyrimidin-4-yl)amino]benzamide
    —— N-(2-(4-(5-(2-amino-1H-imidazol-4-yl)pentyl)-1H-1,2,3-triazol-1-yl)ethyl)-2-(phenylthio)acetamide hydrochloride 1192357-54-2 C20H27N7OS*ClH
    N-(2-(4-(5-(2-amino-1H-imidazol-4-yl)pentyl)-1H-1,2,3-triazol-1-yl)ethyl)-2-(phenylthio)acetamide hydrochloride
    —— 2-(2-Methylsulfanyl-imidazol-1-yl)-ethylamine 1202690-39-8 C6H11N3S
    2-(2-Methylsulfanyl-imidazol-1-yl)-ethylamine
    —— (R)-N1-isopropyl-N1-methyl-4-(phenylthio)butane-1,3-diamine 1235865-16-3 C14H24N2S
    (R)-N1-isopropyl-N1-methyl-4-(phenylthio)butane-1,3-diamine
    —— 2-(3-fluoro-4-methylsulfanylphenyl)ethanol 919360-44-4 C9H11FOS
    2-(3-fluoro-4-methylsulfanylphenyl)ethanol
    —— 7-(5-Dicyclopropylmethyl-thiazol-2-ylsulfanyl)-1-phenyl-[1,2,4]triazolo[4,3-a]quinoline 944924-32-7 C26H22N4S2
    7-(5-Dicyclopropylmethyl-thiazol-2-ylsulfanyl)-1-phenyl-[1,2,4]triazolo[4,3-a]quinoline
    —— 4-[6-(Imidazo[1,2-a]quinolin-7-ylsulfanyl)-pyridin-2-yl]-tetrahydro-pyran-4-carbonitrile 944921-47-5 C22H18N4OS
    4-[6-(Imidazo[1,2-a]quinolin-7-ylsulfanyl)-pyridin-2-yl]-tetrahydro-pyran-4-carbonitrile
    —— 4-[3-([1,2,4]Triazolo[1,5-a]quinolin-7-ylsulfanyl)-phenyl]-tetrahydro-pyran-4-carbonitrile 944924-07-6 C22H18N4OS
    4-[3-([1,2,4]Triazolo[1,5-a]quinolin-7-ylsulfanyl)-phenyl]-tetrahydro-pyran-4-carbonitrile
    —— (Z)-4-cyclopentyl-2-(5-methylsulfanyl-thiophen-2-yl)-but-2-enoic acid ethyl ester 731017-55-3 C16H22O2S2
    (Z)-4-cyclopentyl-2-(5-methylsulfanyl-thiophen-2-yl)-but-2-enoic acid ethyl ester
    —— 4-[3-(4-Oxo-1-phenyl-4,5-dihydro-[1,2,4]triazolo[4,3-a]quinoxalin-7-ylsulfanyl)-phenyl]-tetrahydro-pyran-4-carbonitrile 944924-04-3 C27H21N5O2S
    4-[3-(4-Oxo-1-phenyl-4,5-dihydro-[1,2,4]triazolo[4,3-a]quinoxalin-7-ylsulfanyl)-phenyl]-tetrahydro-pyran-4-carbonitrile
    —— 4-[6-(1-Pyridin-2-yl-[1,2,4]triazolo[4,3-a]quinolin-7-ylsulfanyl)-pyridin-2-yl]-tetrahydro-pyran-4-carbonitrile 944923-28-8 C26H20N6OS
    4-[6-(1-Pyridin-2-yl-[1,2,4]triazolo[4,3-a]quinolin-7-ylsulfanyl)-pyridin-2-yl]-tetrahydro-pyran-4-carbonitrile
    —— 4-[3-(5-Methyl-4-oxo-1-phenyl-4,5-dihydro-[1,2,4]triazolo[4,3-a]quinoxalin-7-ylsulfanyl)-phenyl]-tetrahydro-pyran-4-carbonitrile 944924-05-4 C28H23N5O2S
    4-[3-(5-Methyl-4-oxo-1-phenyl-4,5-dihydro-[1,2,4]triazolo[4,3-a]quinoxalin-7-ylsulfanyl)-phenyl]-tetrahydro-pyran-4-carbonitrile
    —— 2-chloro-4-(ethylsulfonyl)-1-[(5-fluoro-2-methoxyphenyl)thio]benzene 942268-29-3 C15H14ClFO3S2
    2-chloro-4-(ethylsulfonyl)-1-[(5-fluoro-2-methoxyphenyl)thio]benzene
    —— [2-chloro-4-(methylthio)phenyl]boronic acid 882689-60-3 C7H8BClO2S
    [2-chloro-4-(methylthio)phenyl]boronic acid
    —— 2-{[2-chloro-4-(ethylsulfonyl)phenyl]thio}-4-fluorophenol 942268-30-6 C14H12ClFO3S2
    2-{[2-chloro-4-(ethylsulfonyl)phenyl]thio}-4-fluorophenol
    —— 8-(6-(1H-pyrazol-4-yl)benzo[d][1,3]dioxol-5-ylthio)-9-(3-(isopropylamino)propyl)-9H-purin-6-amine 1289543-86-7 C21H24N8O2S
    8-(6-(1H-pyrazol-4-yl)benzo[d][1,3]dioxol-5-ylthio)-9-(3-(isopropylamino)propyl)-9H-purin-6-amine
    —— 8-(6-(1H-pyrrol-2-yl)benzo[d][1,3]dioxol-5-ylthio)-9-(3-(isopropylamino)propyl)-9H-purin-6-amine 1289543-85-6 C22H25N7O2S
    8-(6-(1H-pyrrol-2-yl)benzo[d][1,3]dioxol-5-ylthio)-9-(3-(isopropylamino)propyl)-9H-purin-6-amine
    —— 3-(pentylsulfonyl)azetidine hydrochloride 1309207-52-0 C8H17NO2S*ClH
    3-(pentylsulfonyl)azetidine hydrochloride
    —— 3-(thiophen-2-ylthio)azetidine hydrochloride 1309209-12-8 C7H9NS2*ClH
    3-(thiophen-2-ylthio)azetidine hydrochloride
    —— Methyl [(6-aminopyridazin-3-yl)sulfanyl]acetate 920276-08-0 C7H9N3O2S
    Methyl [(6-aminopyridazin-3-yl)sulfanyl]acetate
    —— 2-(3-chloro-4-methylsulfanyl-phenyl)-3-oxetan-3-yl-propionic acid methyl ester 1003013-78-2 C14H17ClO3S
    2-(3-chloro-4-methylsulfanyl-phenyl)-3-oxetan-3-yl-propionic acid methyl ester
    —— 2-[(4-Chlorophenyl)thio]-1-(6-methoxy-3-pyridinyl)ethanone 1199806-35-3 C14H12ClNO2S
    2-[(4-Chlorophenyl)thio]-1-(6-methoxy-3-pyridinyl)ethanone
    —— 5-[(2,2,2-trifluoroethyl)thio]-1H-1,2,3-triazole-4-carboxylic acid 862111-86-2 C5H4F3N3O2S
    5-[(2,2,2-trifluoroethyl)thio]-1H-1,2,3-triazole-4-carboxylic acid
    —— ethyl 5-[(2,2,2-trifluoroethyl)thio]-1H-1,2,3-triazole-4-carboxylate 862111-85-1 C7H8F3N3O2S
    ethyl 5-[(2,2,2-trifluoroethyl)thio]-1H-1,2,3-triazole-4-carboxylate
    —— 4-(phenethylthio)-1H-pyrrole-2-carboxylic acid 945720-67-2 C13H13NO2S
    4-(phenethylthio)-1H-pyrrole-2-carboxylic acid
    —— (Ethenesulfinyl)cyclohexane 61926-35-0 C8H14OS
    (Ethenesulfinyl)cyclohexane
    —— 4-[4-methyl-2-(2-methyl-1,4,7,9,9b-pentaaza-cyclopenta[a]naphthalen-6-ylamino)-phenylsulfanyl]-phenol 1076222-47-3 C22H18N6OS
    4-[4-methyl-2-(2-methyl-1,4,7,9,9b-pentaaza-cyclopenta[a]naphthalen-6-ylamino)-phenylsulfanyl]-phenol
    —— 4-[4-(3-bromo-benzyloxy)-2-(1,4,7,9,9b-pentaaza-cyclopenta[a]naphthalen-6-ylamino)-phenylsulfanyl]-phenol 1076222-46-2 C27H19BrN6O2S
    4-[4-(3-bromo-benzyloxy)-2-(1,4,7,9,9b-pentaaza-cyclopenta[a]naphthalen-6-ylamino)-phenylsulfanyl]-phenol
    —— 2-cyclopentyl-2-(3,3,3-trifluoropropylsulfonyl)acetonitrile 1097630-40-4 C10H14F3NO2S
    2-cyclopentyl-2-(3,3,3-trifluoropropylsulfonyl)acetonitrile
    —— 4-[2-(2-methyl-1,4,7,9,9b-pentaaza-cyclopenta[a]naphthalen-6-ylamino)-4-(3-trifluoromethylbenzyloxy)-phenylsulfanyl]phenol 1076222-49-5 C29H21F3N6O2S
    4-[2-(2-methyl-1,4,7,9,9b-pentaaza-cyclopenta[a]naphthalen-6-ylamino)-4-(3-trifluoromethylbenzyloxy)-phenylsulfanyl]phenol
    —— 2-[2,6-Dichloro-4-(2,4-dichloro-benzenesulfonylamino)-phenylsulfanyl]-benzothiazole-5-carboxylic acid amide 315225-43-5 C20H11Cl4N3O3S3
    2-[2,6-Dichloro-4-(2,4-dichloro-benzenesulfonylamino)-phenylsulfanyl]-benzothiazole-5-carboxylic acid amide
    —— 2-(2-Chloro-4-nitro-phenylsulfanyl)-benzothiazole-5-carboxylic acid methyl ester 315228-84-3 C15H9ClN2O4S2
    2-(2-Chloro-4-nitro-phenylsulfanyl)-benzothiazole-5-carboxylic acid methyl ester
    —— 1-(6-amino-4-methylsulfanyl-pyridin-2-yl)-3-methyl-urea 1158784-63-4 C8H12N4OS
    1-(6-amino-4-methylsulfanyl-pyridin-2-yl)-3-methyl-urea
    —— 2-(4-amino-2-chloro-phenylsulfanyl)-benzothiazole-5-carboxylic acid methyl ester 315228-98-9 C15H11ClN2O2S2
    2-(4-amino-2-chloro-phenylsulfanyl)-benzothiazole-5-carboxylic acid methyl ester
    —— (2R)-2-amino-3-[(2-fluorophenyl)sulfanyl]propan-1-ol 866760-14-7 C9H12FNOS
    (2R)-2-amino-3-[(2-fluorophenyl)sulfanyl]propan-1-ol
    —— 6-methyl-4-methylsulfanyl-pyridin-2-ylamine 1158787-56-4 C7H10N2S
    6-methyl-4-methylsulfanyl-pyridin-2-ylamine
    —— N-({6-[(2-(tert-butyl-dimethyl-silanyloxy)-ethyl)amino]-4-(methylthio)pyridin-2-yl}carbamoyl)-5-(2-methoxyethyl)-4-methylthiophene-2-sulfonamide 1158786-11-8 C23H38N4O5S3Si
    N-({6-[(2-(tert-butyl-dimethyl-silanyloxy)-ethyl)amino]-4-(methylthio)pyridin-2-yl}carbamoyl)-5-(2-methoxyethyl)-4-methylthiophene-2-sulfonamide
    —— 6-(5-methyl-[1,2,4]oxadiazol-3-yl)-4-methylsulfanyl-pyridin-2-ylamine 1158788-72-7 C9H10N4OS
    6-(5-methyl-[1,2,4]oxadiazol-3-yl)-4-methylsulfanyl-pyridin-2-ylamine
    —— 6-bromomethyl-4-methylsulfanyl-pyridin-2-ylamine 1158787-62-2 C7H9BrN2S
    6-bromomethyl-4-methylsulfanyl-pyridin-2-ylamine
    —— 2-cyclopropyl-1-{5-[(cyclopropylmethyl)thio]-4-methyl-4H-1,2,4-triazol-3-yl}ethanol 917383-08-5 C12H19N3OS
    2-cyclopropyl-1-{5-[(cyclopropylmethyl)thio]-4-methyl-4H-1,2,4-triazol-3-yl}ethanol
    —— tert-butyl 7-chloro-2,3-dihydro-1H-pyrido[2,3-b][1,4]thiazine-1-carboxylate 1259514-38-9 C12H15ClN2O2S
    tert-butyl 7-chloro-2,3-dihydro-1H-pyrido[2,3-b][1,4]thiazine-1-carboxylate
    —— 5-methylthio-3-pyridinol 910649-52-4 C6H7NOS
    5-methylthio-3-pyridinol
    —— ethyl 3-(4-chlorophenylthio)benzofuran-2-carboxylate 20798-22-5 C17H13ClO3S
    ethyl 3-(4-chlorophenylthio)benzofuran-2-carboxylate
    —— 4-(isobutylthio)pyridine-1-oxide 129598-76-1 C9H13NOS
    4-(isobutylthio)pyridine-1-oxide
    —— 4-(2-Ethoxy-vinyl)-2-methylsulfanyl-pyrimidine 329794-47-0 C9H12N2OS
    4-(2-Ethoxy-vinyl)-2-methylsulfanyl-pyrimidine
    —— 1-(Phenylsulfanyl)-4-propoxy-9H-thioxanthen-9-one 201862-95-5 C22H18O2S2
    1-(Phenylsulfanyl)-4-propoxy-9H-thioxanthen-9-one
    —— methyl 2-methylthio-3-(phenylthio)acrylate 1107010-79-6 C11H12O2S2
    methyl 2-methylthio-3-(phenylthio)acrylate