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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (5-Cyano-2-hydrazinopyrimidinyl-4-thio)acetic acid ethyl ester 136271-41-5 C9H11N5O2S
    (5-Cyano-2-hydrazinopyrimidinyl-4-thio)acetic acid ethyl ester
    —— Diazo-(pentane-1-sulfonyl)-acetic acid ethyl ester 921755-25-1 C9H16N2O4S
    Diazo-(pentane-1-sulfonyl)-acetic acid ethyl ester
    —— Trimethyl-((E)-1-phenylsulfanyl-propenyloxy)-silane 101765-66-6 C12H18OSSi
    Trimethyl-((E)-1-phenylsulfanyl-propenyloxy)-silane
    —— 1-methyl-2-(3-chloropropylthio)imidazole 136995-80-7 C7H11ClN2S
    1-methyl-2-(3-chloropropylthio)imidazole
    —— 2-(isopropylthio)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine 1611001-48-9 C14H22BNO2S
    2-(isopropylthio)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine
    —— 5-(Benzylsulfanyl)-1,2-dihydropyrimido[5,4-e][1,2,4]triazine 21308-89-4 C12H11N5S
    5-(Benzylsulfanyl)-1,2-dihydropyrimido[5,4-e][1,2,4]triazine
    —— <5-Chlor-pyridyl-(2)-mercapto>-aceton 5898-33-9 C8H8ClNOS
    <5-Chlor-pyridyl-(2)-mercapto>-aceton
    —— 2-(2-Oxo-cyclohexylmercapto)-pyridin 5898-24-8 C11H13NOS
    2-(2-Oxo-cyclohexylmercapto)-pyridin
    —— (1,3-dimethyl-5-benzylthiopyrazol-4-yl)-N-(2-hydroxyisopropoxy)carboxylic acid amide 868681-22-5 C16H21N3O3S
    (1,3-dimethyl-5-benzylthiopyrazol-4-yl)-N-(2-hydroxyisopropoxy)carboxylic acid amide
    —— 3-Propan-2-yl-6-(2,4,6-trichlorophenyl)sulfanyl-[1,2,4]triazolo[4,3-a]pyridine 876461-42-6 C15H12Cl3N3S
    3-Propan-2-yl-6-(2,4,6-trichlorophenyl)sulfanyl-[1,2,4]triazolo[4,3-a]pyridine
    —— N-[3-(2-hydroxyethyl)phenyl]-4-(3-methoxyphenylsulphanyl)-2-pyrimidineamine 213747-36-5 C19H19N3O2S
    N-[3-(2-hydroxyethyl)phenyl]-4-(3-methoxyphenylsulphanyl)-2-pyrimidineamine
    —— N-[3,5-dimethoxy-4-(2-hydroxyethoxy)phenyl]-4-(3-methoxyphenylsulphanyl)-2-pyrimidineamine 213747-71-8 C21H23N3O5S
    N-[3,5-dimethoxy-4-(2-hydroxyethoxy)phenyl]-4-(3-methoxyphenylsulphanyl)-2-pyrimidineamine
    —— 1-(Dimethylsulfamoyl)-4-fluoro-5-(2,4,6-trichlorophenylthio)pyrazole 143535-55-1 C11H9Cl3FN3O2S2
    1-(Dimethylsulfamoyl)-4-fluoro-5-(2,4,6-trichlorophenylthio)pyrazole
    —— 3,4-methylenedithiopyrrole 851346-12-8 C5H5NS2
    3,4-methylenedithiopyrrole
    —— 2-<2.2-Diaethoxy-aethylmercapto>-pyrimidin 55862-33-4 C10H16N2O2S
    2-<2.2-Diaethoxy-aethylmercapto>-pyrimidin
    —— thiacyclotrideca-3,11-diyne-1,1-dioxide 514853-59-9 C12H16O2S
    thiacyclotrideca-3,11-diyne-1,1-dioxide
    —— thiacyclotetradeca-3,11-diyne-1,1-dioxide 514853-61-3 C13H18O2S
    thiacyclotetradeca-3,11-diyne-1,1-dioxide
    —— 2-cyanoethylthio-5-ethylthio-1,3-dithiole-2-thione 846571-59-3 C8H9NS5
    2-cyanoethylthio-5-ethylthio-1,3-dithiole-2-thione
    —— 4-{5-[(cyclopropylmethyl)thio]-4-methyl-4H-1,2,4-triazol-3-yl}butyl methanesulfonate 913062-84-7 C12H21N3O3S2
    4-{5-[(cyclopropylmethyl)thio]-4-methyl-4H-1,2,4-triazol-3-yl}butyl methanesulfonate
    —— Acetic acid (2R,3S)-2-acetoxymethyl-6-phenylsulfanyl-tetrahydro-pyran-3-yl ester 143087-25-6 C16H20O5S
    Acetic acid (2R,3S)-2-acetoxymethyl-6-phenylsulfanyl-tetrahydro-pyran-3-yl ester
    —— 2-<Pyridyl-(2)-mercapto>-cyclopentanon 46201-24-5 C10H11NOS
    2-<Pyridyl-(2)-mercapto>-cyclopentanon
    —— 5-Methyl-2-(naphth-2-yl-mercapto)-pyridin 92856-71-8 C16H13NS
    5-Methyl-2-(naphth-2-yl-mercapto)-pyridin
    —— N-Cyanomethyl-2,2,2-trifluoro-N-(2-methanesulfonyl-ethyl)-acetamide 552334-87-9 C7H9F3N2O3S
    N-Cyanomethyl-2,2,2-trifluoro-N-(2-methanesulfonyl-ethyl)-acetamide
    —— 2-(5-Nitro-pyridyl-(2)-mercapto)-cyclohexanon 5898-29-3 C11H12N2O3S
    2-(5-Nitro-pyridyl-(2)-mercapto)-cyclohexanon
    —— N-(trifluoroacetyl)-N-(methanesulphonylethyl)-aminomethylthioamide 231278-74-3 C7H11F3N2O3S2
    N-(trifluoroacetyl)-N-(methanesulphonylethyl)-aminomethylthioamide
    —— (E)-5,6-epoxy-2-hexen-1-yl phenyl sulfide 145939-34-0 C12H14OS
    (E)-5,6-epoxy-2-hexen-1-yl phenyl sulfide
    —— N-(4-phenyl-thio-3-cyanophenyl)-3,3,3,-trifluoro-2-hydroxy-2-methylpropanamide 147696-56-8 C17H13F3N2O2S
    N-(4-phenyl-thio-3-cyanophenyl)-3,3,3,-trifluoro-2-hydroxy-2-methylpropanamide
    —— 4-(Benzylsulfanyl)-6-hydrazinylpyrimidin-5-amine 21308-87-2 C11H13N5S
    4-(Benzylsulfanyl)-6-hydrazinylpyrimidin-5-amine
    —— 6-methyl-4-[4-(methylthio)benzyl]pyridazin-3(2H)-one 1449104-88-4 C13H14N2OS
    6-methyl-4-[4-(methylthio)benzyl]pyridazin-3(2H)-one
    —— 2-Methyl-2-[2-methyl-2-(2-methylidenecyclopentyl)propyl]-1,3-dithiane 1242434-31-6 C15H26S2
    2-Methyl-2-[2-methyl-2-(2-methylidenecyclopentyl)propyl]-1,3-dithiane
    —— ethyl (1RS,5RS,6SR)-4,4-ethylendithio-6-fluoro-2-oxobicyclo[3.1.0]hexane-6-carboxylate —— C11H13FO3S2
    ethyl (1RS,5RS,6SR)-4,4-ethylendithio-6-fluoro-2-oxobicyclo[3.1.0]hexane-6-carboxylate
    —— Cyano-bis-phenylsulfanyl-acetic acid ethyl ester 79296-17-6 C17H15NO2S2
    Cyano-bis-phenylsulfanyl-acetic acid ethyl ester
    —— 2-(4-chlorophenyl)-5-methylthio-1,3,4-thiadiazole 63857-86-3 C9H7ClN2S2
    2-(4-chlorophenyl)-5-methylthio-1,3,4-thiadiazole
    —— 6-Isothiocyanatohexansaeurechlorid 39243-52-2 C7H10ClNOS
    6-Isothiocyanatohexansaeurechlorid
    —— 2-(Aethoxy)-thioacetamid 54129-83-8 C4H9NOS
    2-(Aethoxy)-thioacetamid
    —— tert-Amyl-n-butylsulfid 24487-59-0 C9H20S
    tert-Amyl-n-butylsulfid
    —— (2R,3S)-1,1-Dichloro-1-fluoro-3-<(4-methylphenyl)thio>hept-6-en-2-ol 165317-20-4 C14H17Cl2FOS
    (2R,3S)-1,1-Dichloro-1-fluoro-3-<(4-methylphenyl)thio>hept-6-en-2-ol
    —— {4-chloro-6-[1-(4-chloro-phenyl)-ethylamino]-pyrimidin-2-ylsulfanyl}-acetic acid 50892-32-5 C14H13Cl2N3O2S
    {4-chloro-6-[1-(4-chloro-phenyl)-ethylamino]-pyrimidin-2-ylsulfanyl}-acetic acid
    —— 4-Aza-phenothiazin-10-carbonsaeure-N-aethyl-piperidyl-(4)-ester 99004-28-1 C19H21N3O2S
    4-Aza-phenothiazin-10-carbonsaeure-N-aethyl-piperidyl-(4)-ester
    —— (2S,3R)-1,1-Dichloro-1-fluoro-3-<(4-methylphenyl)thio>hept-6-en-2-ol 165317-18-0 C14H17Cl2FOS
    (2S,3R)-1,1-Dichloro-1-fluoro-3-<(4-methylphenyl)thio>hept-6-en-2-ol
    —— 5-(3,5-Dichlorophenylthio)-1-ethyl-4-isopropyl-1H-imidazol-2-ylmethyl lauroylcarbamate 196406-03-8 C28H41Cl2N3O3S
    5-(3,5-Dichlorophenylthio)-1-ethyl-4-isopropyl-1H-imidazol-2-ylmethyl lauroylcarbamate
    —— (2S,3S)-1,1-Dichloro-1-fluoro-3-<(4-methylphenyl)thio>hept-6-en-2-ol 139965-01-8 C14H17Cl2FOS
    (2S,3S)-1,1-Dichloro-1-fluoro-3-<(4-methylphenyl)thio>hept-6-en-2-ol
    —— (2R,3R)-1,1-Dichloro-1-fluoro-3-<(4-methylphenyl)thio>hept-6-en-2-ol 165317-19-1 C14H17Cl2FOS
    (2R,3R)-1,1-Dichloro-1-fluoro-3-<(4-methylphenyl)thio>hept-6-en-2-ol
    —— 5-(Methylsulfanyl)-1,2-dihydropyrimido[5,4-e][1,2,4]triazine 21308-95-2 C6H7N5S
    5-(Methylsulfanyl)-1,2-dihydropyrimido[5,4-e][1,2,4]triazine
    —— 5-(Methylsulfanyl)pyrimido[5,4-e][1,2,4]triazine 21308-97-4 C6H5N5S
    5-(Methylsulfanyl)pyrimido[5,4-e][1,2,4]triazine
    —— (S)-trans-1-(tert-Butylsulfinyl)-1-hepten-6-yne 389842-81-3 C11H18OS
    (S)-trans-1-(tert-Butylsulfinyl)-1-hepten-6-yne
    —— (R)-1-(4-ethyl-5(4-methylphenylsulfanyl)-4H-[1,2,4]triazol-3-yl)-ethylamine 945732-94-5 C13H18N4S
    (R)-1-(4-ethyl-5(4-methylphenylsulfanyl)-4H-[1,2,4]triazol-3-yl)-ethylamine
    —— [2-(2-amino-5-methyl-sulfanyl-phenylamino)-ethyl]-carbamic acid tert-butyl ester 947258-39-1 C14H23N3O2S
    [2-(2-amino-5-methyl-sulfanyl-phenylamino)-ethyl]-carbamic acid tert-butyl ester
    —— (2S,3R)-3-fluoro-1-<(4-methylphenyl)sulfenyl>-5-hexen-2-ol 121911-12-4 C13H17FOS
    (2S,3R)-3-fluoro-1-<(4-methylphenyl)sulfenyl>-5-hexen-2-ol
    —— cyclopropanesulfenyl chloride 68846-58-2 C3H5ClS
    cyclopropanesulfenyl chloride