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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Butoxy-3-methylbutyl-phenylsulfid 66165-02-4 C15H24OS
    2-Butoxy-3-methylbutyl-phenylsulfid
    —— 1,1-Diethoxy-3-methanesulfinyl-propan-2-one 87084-03-5 C8H16O4S
    1,1-Diethoxy-3-methanesulfinyl-propan-2-one
    —— 6-[bis(ethyloxy)methyl]-2-[(phenylmethyl)thio]-4(1H)-pyrimidinone 525559-02-8 C16H20N2O3S
    6-[bis(ethyloxy)methyl]-2-[(phenylmethyl)thio]-4(1H)-pyrimidinone
    —— 6<i>H</i>-benzo[5,6][1,4]dithiino[2,3-<i>b</i>]indole 24122-62-1 C14H9NS2
    6<i>H</i>-benzo[5,6][1,4]dithiino[2,3-<i>b</i>]indole
    —— (5S,7S)-5-hydroxy-7-phenyl-3,5,6,7-tetrahydro-2H-thiopyrano[2,3-d]thiazol-2-one 1433721-28-8 C12H11NO2S2
    (5S,7S)-5-hydroxy-7-phenyl-3,5,6,7-tetrahydro-2H-thiopyrano[2,3-d]thiazol-2-one
    —— 2-octadecylmercapto-thiophene 102945-08-4 C22H40S2
    2-octadecylmercapto-thiophene
    —— 5-dodecylmercapto-thiophene-2-carbaldehyde 62702-57-2 C17H28OS2
    5-dodecylmercapto-thiophene-2-carbaldehyde
    —— 8,8-dimethyl-5,8-dihydro-2H-[1,3]thiazolo[5',4':5,6]thiopyrano[2,3-d][1,3]thiazol-2,6(3H)-dione 924856-48-4 C9H8N2O2S3
    8,8-dimethyl-5,8-dihydro-2H-[1,3]thiazolo[5',4':5,6]thiopyrano[2,3-d][1,3]thiazol-2,6(3H)-dione
    —— spiro[cyclohexane-1,8'-(5,8-dihydro-2H-[1,3]thiazolo[5',4':5,6]thiopyrano[2,3-d][1,3]thiazol)]-2,6(3H)-dione 924875-50-3 C12H12N2O2S3
    spiro[cyclohexane-1,8'-(5,8-dihydro-2H-[1,3]thiazolo[5',4':5,6]thiopyrano[2,3-d][1,3]thiazol)]-2,6(3H)-dione
    —— 5-octadecylmercapto-thiophene-2-carbaldehyde 102899-22-9 C23H40OS2
    5-octadecylmercapto-thiophene-2-carbaldehyde
    —— 2-Phenylthiododecan-1-ol 66185-36-2 C18H30OS
    2-Phenylthiododecan-1-ol
    —— 1,2,5-dithiazepane hydrochloride 23353-11-9 C4H9NS2*ClH
    1,2,5-dithiazepane hydrochloride
    —— 5-isopropylmercapto-thiophene-2-carbaldehyde 106166-76-1 C8H10OS2
    5-isopropylmercapto-thiophene-2-carbaldehyde
    —— 5-ethylsulfanyl-thiophene-2-carbaldehyde 89639-68-9 C7H8OS2
    5-ethylsulfanyl-thiophene-2-carbaldehyde
    —— 2-ethylmercapto-5-hydroxymethyl-thiophene 98272-25-4 C7H10OS2
    2-ethylmercapto-5-hydroxymethyl-thiophene
    —— 5-(6,7-dichloro-3-(1-methyl-1H-tetrazole-5-ylthio)quinoxaline-2-yl)thiazole-2-ol 1337928-01-4 C13H7Cl2N7OS2
    5-(6,7-dichloro-3-(1-methyl-1H-tetrazole-5-ylthio)quinoxaline-2-yl)thiazole-2-ol
    —— cyclohexylidenedimercapto-di-acetic acid diethyl ester 101099-34-7 C14H24O4S2
    cyclohexylidenedimercapto-di-acetic acid diethyl ester
    —— 5-(6,7-dichloro-3-(1-isopropyl-1H-tetrazole-5-ylthio)quinoxaline-2-yl)thiazole-2-ol 1337928-08-1 C15H11Cl2N7OS2
    5-(6,7-dichloro-3-(1-isopropyl-1H-tetrazole-5-ylthio)quinoxaline-2-yl)thiazole-2-ol
    —— 1-(5-(6,7-dichloro-3-(1-isopropyl-1H-tetrazole-5-ylthio)quinoxaline-2-yl)thiazole-2-yloxy)propane-2-ol 1337928-09-2 C18H17Cl2N7O2S2
    1-(5-(6,7-dichloro-3-(1-isopropyl-1H-tetrazole-5-ylthio)quinoxaline-2-yl)thiazole-2-yloxy)propane-2-ol
    —— Dimethylphosphonylmethyl-p-tolylsulfid 63231-20-9 C10H15O3PS
    Dimethylphosphonylmethyl-p-tolylsulfid
    —— 7,7-Bis(methylthio)norcarane 36369-43-4 C9H16S2
    7,7-Bis(methylthio)norcarane
    —— 3-Methylmercapto-6-(4-methyl-benzyl)-as-triazin-5(4H)-on 118740-02-6 C12H13N3OS
    3-Methylmercapto-6-(4-methyl-benzyl)-as-triazin-5(4H)-on
    —— 1-(5-(6,7-dichloro-3-(1-methyl-1H-tetrazole-5-ylthio)quinoxaline-2-yl)thiazole-2-yloxy)propane-2-ol 1337928-02-5 C16H13Cl2N7O2S2
    1-(5-(6,7-dichloro-3-(1-methyl-1H-tetrazole-5-ylthio)quinoxaline-2-yl)thiazole-2-yloxy)propane-2-ol
    —— 5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-one oxime 7675-05-0 C7H7NOS2
    5,6-dihydro-4H-thieno[2,3-b]thiopyran-4-one oxime
    —— 1-Methyl-4-[{[(4-methylphenyl)methyl]sulfanyl}(phenylsulfanyl)methyl]benzene 62740-58-3 C22H22S2
    1-Methyl-4-[{[(4-methylphenyl)methyl]sulfanyl}(phenylsulfanyl)methyl]benzene
    —— 3,4-dihydrothieno[3,2-f]-1,4-thiazepine-5(2H)-thione 187834-22-6 C7H7NS3
    3,4-dihydrothieno[3,2-f]-1,4-thiazepine-5(2H)-thione
    —— 2,5-bis(4-methylbenzylthio)-1,3,4-thiadiazole 401641-23-4 C18H18N2S3
    2,5-bis(4-methylbenzylthio)-1,3,4-thiadiazole
    —— 4,5-bis(p-methyl-benzyl-thio)-1,3-dithiol-2-thione 176037-54-0 C19H18S5
    4,5-bis(p-methyl-benzyl-thio)-1,3-dithiol-2-thione
    —— 5-butylmercapto-thiophene-2-carbaldehyde 98954-28-0 C9H12OS2
    5-butylmercapto-thiophene-2-carbaldehyde
    —— tert-butyl<<(S)-2,3-dihydro-4-(phenylthio)-2-furyl>methoxy>dimethylsilane 221459-12-7 C17H26O2SSi
    tert-butyl<<(S)-2,3-dihydro-4-(phenylthio)-2-furyl>methoxy>dimethylsilane
    —— ethyl 3-(4-cyano-3-hydroxy-5-{[(4-methylphenyl)methyl]sulfanyl}thiophen-2-yl)-3-oxopropanoate 1448182-02-2 C18H17NO4S2
    ethyl 3-(4-cyano-3-hydroxy-5-{[(4-methylphenyl)methyl]sulfanyl}thiophen-2-yl)-3-oxopropanoate
    —— 4-[(4-Methylphenyl)methylthio]pyridine-2-carbonitrile 225112-63-0 C14H12N2S
    4-[(4-Methylphenyl)methylthio]pyridine-2-carbonitrile
    —— 2-acetoxy-5-(ethylthio)furan 114583-66-3 C8H10O3S
    2-acetoxy-5-(ethylthio)furan
    —— 2-((ethoxycarbonyl)oxy)-5-(ethylthio)furan 114583-67-4 C9H12O4S
    2-((ethoxycarbonyl)oxy)-5-(ethylthio)furan
    —— 5-(ethylthio)-5-<2'-(methoxycarbonyl)ethyl>furan-2(5H)-one 114583-60-7 C10H14O4S
    5-(ethylthio)-5-<2'-(methoxycarbonyl)ethyl>furan-2(5H)-one
    —— 5-(ethylthio)-5-(3'-oxycyclohexyl)furan-2(5H)-one 114583-59-4 C12H16O3S
    5-(ethylthio)-5-(3'-oxycyclohexyl)furan-2(5H)-one
    —— 3,5-bis(1'-hydroxypropyl)-5-(ethylthio)furan-2(5H)-one 114583-64-1 C12H20O4S
    3,5-bis(1'-hydroxypropyl)-5-(ethylthio)furan-2(5H)-one
    —— 2-butylmercapto-5-hydroxymethyl-thiophene 100144-46-5 C9H14OS2
    2-butylmercapto-5-hydroxymethyl-thiophene
    —— 2-Butylsulphanylthiophene 3988-71-4 C8H12S2
    2-Butylsulphanylthiophene
    —— 2,3-dimethoxy-5-phenylthio-1,4-diacetyloxynaphthalene 91814-53-8 C22H20O6S
    2,3-dimethoxy-5-phenylthio-1,4-diacetyloxynaphthalene
    —— trans-6-<(4-methylphenyl)thiomethyl>-7-phenyl-5,6,7,8-tetrahydroindolizin-8-one 141402-02-0 C22H21NOS
    trans-6-<(4-methylphenyl)thiomethyl>-7-phenyl-5,6,7,8-tetrahydroindolizin-8-one
    —— N,N’-bis(5-((4-methylbenzyl)thio)-1,3,4-thiadiazol-2-yl)methane diamine 53151-31-8 C21H22N6S4
    N,N’-bis(5-((4-methylbenzyl)thio)-1,3,4-thiadiazol-2-yl)methane diamine
    —— 2-(methylthio)-6-(pyridin-4-yl)pyrimidin-4(3H)-one 55361-63-2 C10H9N3OS
    2-(methylthio)-6-(pyridin-4-yl)pyrimidin-4(3H)-one
    —— 2-pentylsulfanyl-thiophene 54798-87-7 C9H14S2
    2-pentylsulfanyl-thiophene
    —— 2-hydroxymethyl-5-pentylmercapto-thiophene 99180-86-6 C10H16OS2
    2-hydroxymethyl-5-pentylmercapto-thiophene
    —— bis-(2,2-bis-ethylsulfanyl-ethyl) ether 56999-22-5 C12H26OS4
    bis-(2,2-bis-ethylsulfanyl-ethyl) ether
    —— 2-(3-methyl-butylsulfanyl)-thiophene 7065-60-3 C9H14S2
    2-(3-methyl-butylsulfanyl)-thiophene
    —— 2-hydroxymethyl-5-isopentylmercapto-thiophene 99180-85-5 C10H16OS2
    2-hydroxymethyl-5-isopentylmercapto-thiophene
    —— 5-isopentylmercapto-thiophene-2-carbaldehyde 99172-38-0 C10H14OS2
    5-isopentylmercapto-thiophene-2-carbaldehyde
    —— 5-pentylmercapto-thiophene-2-carbaldehyde 99172-39-1 C10H14OS2
    5-pentylmercapto-thiophene-2-carbaldehyde