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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-Chlor-4-hydrazino-10H-pyridazino<4,5-b><1,4>benzothiazin 37150-06-4 C10H8ClN5S
    1-Chlor-4-hydrazino-10H-pyridazino<4,5-b><1,4>benzothiazin
    —— 1,2-Ethanediamine, N,N-bis(1-methylethyl)-N'-(6-chloro-5-(methylthio)-2-(1-piperidinyl)-4-pyrimidinyl)-, monohydrobromide 55417-02-2 C18H33BrClN5S
    1,2-Ethanediamine, N,N-bis(1-methylethyl)-N'-(6-chloro-5-(methylthio)-2-(1-piperidinyl)-4-pyrimidinyl)-, monohydrobromide
    —— <i>N</i>'-(6-chloro-5-methylsulfanyl-2-morpholin-4-yl-pyrimidin-4-yl)-<i>N</i>,<i>N</i>-dimethyl-ethane-1,2-diamine 55416-98-3 C13H22ClN5OS
    <i>N</i>'-(6-chloro-5-methylsulfanyl-2-morpholin-4-yl-pyrimidin-4-yl)-<i>N</i>,<i>N</i>-dimethyl-ethane-1,2-diamine
    —— isothiocyanato-2 octene-1 87656-60-8 C9H15NS
    isothiocyanato-2 octene-1
    —— Methylglyoxylsaeure-N-isopropyl-thioamid 13621-41-5 C6H11NOS
    Methylglyoxylsaeure-N-isopropyl-thioamid
    —— <i>N</i><sup>4</sup>-methyl-7<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazine-4,6-diamine 55383-59-0 C7H9N5S
    <i>N</i><sup>4</sup>-methyl-7<i>H</i>-pyrimido[4,5-<i>b</i>][1,4]thiazine-4,6-diamine
    —— 6-chloro-<i>N</i><sup>4</sup>-(2-dimethylamino-ethyl)-<i>N</i><sup>2</sup>,<i>N</i><sup>2</sup>-dimethyl-5-methylsulfanyl-pyrimidine-2,4-diamine 55416-97-2 C11H20ClN5S
    6-chloro-<i>N</i><sup>4</sup>-(2-dimethylamino-ethyl)-<i>N</i><sup>2</sup>,<i>N</i><sup>2</sup>-dimethyl-5-methylsulfanyl-pyrimidine-2,4-diamine
    —— 2,4-Pyrimidinediamine, 6-chloro-N(sup 4)-(2-(diethylamino)ethyl)-N(sup 2),N(sup 2)-diethyl-5-(methylthio)-, dihydrobromide 55416-93-8 C15H30Br2ClN5S
    2,4-Pyrimidinediamine, 6-chloro-N(sup 4)-(2-(diethylamino)ethyl)-N(sup 2),N(sup 2)-diethyl-5-(methylthio)-, dihydrobromide
    —— 6-chloro-<i>N</i><sup>4</sup>-(2-diethylamino-ethyl)-<i>N</i><sup>2</sup>,<i>N</i><sup>2</sup>-dimethyl-5-methylsulfanyl-pyrimidine-2,4-diamine 55416-91-6 C13H24ClN5S
    6-chloro-<i>N</i><sup>4</sup>-(2-diethylamino-ethyl)-<i>N</i><sup>2</sup>,<i>N</i><sup>2</sup>-dimethyl-5-methylsulfanyl-pyrimidine-2,4-diamine
    —— 1,2-Ethanediamine, N,N-bis(1-methylethyl)-N'-(6-methoxy-5-(methylthio)-2-(1-piperidinyl)-4-pyrimidinyl)-, monohydrobromide 55417-16-8 C19H36BrN5OS
    1,2-Ethanediamine, N,N-bis(1-methylethyl)-N'-(6-methoxy-5-(methylthio)-2-(1-piperidinyl)-4-pyrimidinyl)-, monohydrobromide
    —— 1,14-Dioxa-4,6,9,11-tetraaza-cyclohexadecane-5,10-dithione 111039-13-5 C10H20N4O2S2
    1,14-Dioxa-4,6,9,11-tetraaza-cyclohexadecane-5,10-dithione
    —— 1-Oxa-4,6,9,11-tetraaza-cyclotridecane-5,10-dithione 111039-12-4 C8H16N4OS2
    1-Oxa-4,6,9,11-tetraaza-cyclotridecane-5,10-dithione
    —— 2,4-Pyrimidinediamine, N(sup 4)-(2-(bis(1-methylethyl)amino)ethyl)-6-chloro-N(sup 2),N(sup 2)-diethyl-5-(methylthio)-, monohydrobromide 55417-05-5 C17H33BrClN5S
    2,4-Pyrimidinediamine, N(sup 4)-(2-(bis(1-methylethyl)amino)ethyl)-6-chloro-N(sup 2),N(sup 2)-diethyl-5-(methylthio)-, monohydrobromide
    —— 2,4-Pyrimidinediamine, N(sup 4)-(2-(dimethylamino)ethyl)-N(sup 2),N(sup 2)-dimethyl-5-(methylthio)-6-(3-pyridinylmethoxy)-, dihydrobromide 55417-11-3 C17H28Br2N6OS
    2,4-Pyrimidinediamine, N(sup 4)-(2-(dimethylamino)ethyl)-N(sup 2),N(sup 2)-dimethyl-5-(methylthio)-6-(3-pyridinylmethoxy)-, dihydrobromide
    —— 2,4-Pyrimidinediamine, N(sup 4)-(2-(bis(1-methylethyl)amino)ethyl)-6-butoxy-N(sup 2)-methyl-5-(methylthio)-N(sup 2)-(phenylmethyl)-, monohydrobromide 55417-17-9 C25H42BrN5OS
    2,4-Pyrimidinediamine, N(sup 4)-(2-(bis(1-methylethyl)amino)ethyl)-6-butoxy-N(sup 2)-methyl-5-(methylthio)-N(sup 2)-(phenylmethyl)-, monohydrobromide
    —— 6-Chloro-N4-(2-(diethylamino)ethyl)-N2-methyl-N2-(phenylmethyl)-2,4-pyrimidinediamine HBr 55416-94-9 C19H29BrClN5S
    6-Chloro-N4-(2-(diethylamino)ethyl)-N2-methyl-N2-(phenylmethyl)-2,4-pyrimidinediamine HBr
    —— (4-Methylthiophenyl)guanidin-nitrat 71198-46-4 C8H11N3S*HNO3
    (4-Methylthiophenyl)guanidin-nitrat
    —— 4-[2-(diethylamino)ethyl]pyrazino[2,3-b][1,4]thiazin-3-one;hydron;chloride —— C12H19ClN4OS
    4-[2-(diethylamino)ethyl]pyrazino[2,3-b][1,4]thiazin-3-one;hydron;chloride
    —— (2-(2-(chloromethyl)allyl)-3,5-dimethylphenyl)(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)sulfide 1338723-54-8 C22H18ClF17S
    (2-(2-(chloromethyl)allyl)-3,5-dimethylphenyl)(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)sulfide
    —— (2-(2-bromoallyl)-3,5-dimethylphenyl)(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)sulfide 1338723-55-9 C21H16BrF17S
    (2-(2-bromoallyl)-3,5-dimethylphenyl)(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)sulfide
    —— <i>N</i>-pentyl-thioacetamide 98430-63-8 C7H15NS
    <i>N</i>-pentyl-thioacetamide
    —— Heptanethioic acid methylamide 80597-92-8 C8H17NS
    Heptanethioic acid methylamide
    —— (E)-2-(phenylthio)-1,3-pentadiene 110026-94-3 C11H12S
    (E)-2-(phenylthio)-1,3-pentadiene
    —— 2-Propanamine, N-(1-methylethyl)-N-(2-((6-((1-methyl-4-piperidinyl)oxy)-5-(methylthio)-2-(4-morpholinyl)-4-pyrimidinyl)oxy)ethyl)-, hydrobromide, hydrate (1:2:2) 57259-22-0 C23H43Br2N5O3S
    2-Propanamine, N-(1-methylethyl)-N-(2-((6-((1-methyl-4-piperidinyl)oxy)-5-(methylthio)-2-(4-morpholinyl)-4-pyrimidinyl)oxy)ethyl)-, hydrobromide, hydrate (1:2:2)
    —— 1-Butanesulfinic acid, 4,4'-trithiobis-, disodium salt 56527-86-7 C8H16Na2O4S5
    1-Butanesulfinic acid, 4,4'-trithiobis-, disodium salt
    —— 1-Phenylmercapto-2-butylmercapto-propan 6839-03-8 C13H20S2
    1-Phenylmercapto-2-butylmercapto-propan
    —— 2-Butylmercapto-2-phenylmercapto-propan 6839-01-6 C13H20S2
    2-Butylmercapto-2-phenylmercapto-propan
    —— (3-Methylthiophenyl)guanidin-nitrat 71198-44-2 C8H11N3S*HNO3
    (3-Methylthiophenyl)guanidin-nitrat
    —— 3,3-Dimethyl-2,4-dithiapentan-2-oxid 35493-34-6 C5H12OS2
    3,3-Dimethyl-2,4-dithiapentan-2-oxid
    —— methyl 2-methyl-2-methylsulfonylpropanoate 23550-42-7 C6H12O4S
    methyl 2-methyl-2-methylsulfonylpropanoate
    —— N-<Phenyl(phenylsulfanyl)methyl>formamide 177366-73-3 C14H13NOS
    N-<Phenyl(phenylsulfanyl)methyl>formamide
    —— 5-Methyl-4-(4-methylphenyl)thiomethyl-1,3-dioxol-2-one 111738-31-9 C12H12O3S
    5-Methyl-4-(4-methylphenyl)thiomethyl-1,3-dioxol-2-one
    —— 5-Methyl-4-phenylthiomethyl-1,3-dioxol-2-one 111738-33-1 C11H10O3S
    5-Methyl-4-phenylthiomethyl-1,3-dioxol-2-one
    —— 4-(4-Chlorophenyl)thiomethyl-5-methyl-1,3-dioxol-2-one 111738-34-2 C11H9ClO3S
    4-(4-Chlorophenyl)thiomethyl-5-methyl-1,3-dioxol-2-one
    —— 2H-Pyrazino(2,3-b)-1,4-thiazin-3(4H)-one, 4-(2-(dimethylamino)ethyl)-, monohydrochloride 55879-59-9 C10H15ClN4OS
    2H-Pyrazino(2,3-b)-1,4-thiazin-3(4H)-one, 4-(2-(dimethylamino)ethyl)-, monohydrochloride
    —— 1,5-dihydro-pyrimido[4,5-<i>b</i>][1,4]thiazine-2,4,6-trione 56223-56-4 C6H5N3O3S
    1,5-dihydro-pyrimido[4,5-<i>b</i>][1,4]thiazine-2,4,6-trione
    —— (E)-methoxycarbonyl methyl sulfine 247933-84-2 C4H6O3S
    (E)-methoxycarbonyl methyl sulfine
    —— 6-(phenylthio)-9-ethylpurine 83026-97-5 C13H12N4S
    6-(phenylthio)-9-ethylpurine
    —— 5-<4-Chlor-phenyl>-2-methylmercapto-1,3,4-oxadiazol 23767-37-5 C9H7ClN2OS
    5-<4-Chlor-phenyl>-2-methylmercapto-1,3,4-oxadiazol
    —— 2-[(4S,5S)-4,5-dimethyl-1,3-dioxolan-2-yl]-N-[(1S)-1-phenylethyl]-2-phenylsulfanylacetamide 1296255-08-7 C21H25NO3S
    2-[(4S,5S)-4,5-dimethyl-1,3-dioxolan-2-yl]-N-[(1S)-1-phenylethyl]-2-phenylsulfanylacetamide
    —— (-)-(R,R)-2,3-butanedithiol 68170-33-2 C4H10S2
    (-)-(R,R)-2,3-butanedithiol
    —— Dimethyl-(1-methylsulfanyl-allyl)-amine 89745-82-4 C6H13NS
    Dimethyl-(1-methylsulfanyl-allyl)-amine
    —— S-[[5-(2-hydroxyethoxy)-1,2,4-thiadiazol-3-yl]] N,N-dimethylcarbamothioate 1012073-48-1 C7H11N3O3S2
    S-[[5-(2-hydroxyethoxy)-1,2,4-thiadiazol-3-yl]] N,N-dimethylcarbamothioate
    —— ((Z)-N-Propenyl)-thioacetamide 56634-57-2 C5H9NS
    ((Z)-N-Propenyl)-thioacetamide
    —— 2-amino-3-methylthio-4-picoline 179554-97-3 C7H10N2S
    2-amino-3-methylthio-4-picoline
    —— (4-chlorophenyl)(2-nitro-1-p-tolylethyl)sulfide 110113-23-0 C15H14ClNO2S
    (4-chlorophenyl)(2-nitro-1-p-tolylethyl)sulfide
    —— (2-nitro-1-p-tolyl-ethyl)(phenyl)sulfide 110113-16-1 C15H15NO2S
    (2-nitro-1-p-tolyl-ethyl)(phenyl)sulfide
    —— (2-nitro-1-p-tolylethyl)(p-tolyl)sulfide 110129-93-6 C16H17NO2S
    (2-nitro-1-p-tolylethyl)(p-tolyl)sulfide
    —— 2-Methyl-N-phenyl-thiopropionimidic acid p-tolyl ester 120346-02-3 C17H19NS
    2-Methyl-N-phenyl-thiopropionimidic acid p-tolyl ester
    —— 2-Methyl-N-phenyl-thiopropionimidic acid phenyl ester 120346-01-2 C16H17NS
    2-Methyl-N-phenyl-thiopropionimidic acid phenyl ester