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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(benzylthio)-3-methyl-6-(p-ethylanilino)-4-pyrimidone 98421-10-4 C20H21N3OS
    2-(benzylthio)-3-methyl-6-(p-ethylanilino)-4-pyrimidone
    —— 2-(benzylthio)-6-(p-ethylanilino)-4-pyrimidone 98421-08-0 C19H19N3OS
    2-(benzylthio)-6-(p-ethylanilino)-4-pyrimidone
    —— 1,6-Bis-carbamimidoylmercapto-hexan 58479-97-3 C8H18N4S2
    1,6-Bis-carbamimidoylmercapto-hexan
    —— Raphanin 2404-46-8 C6H9NOS2
    Raphanin
    —— 1,6-bis[3-(pyrid-3-yl)-1,2,5-thiadiazol-4-ylthio]hexane 390799-95-8 C20H20N6S4
    1,6-bis[3-(pyrid-3-yl)-1,2,5-thiadiazol-4-ylthio]hexane
    —— 6-(hexylthio)-1-hexanethiol 906675-05-6 C12H26S2
    6-(hexylthio)-1-hexanethiol
    —— 3-{[4-amino-5-(2-thienylmethyl)-4H-1,2,4-triazol-3-yl]sulfanyl}-3-(4-chlorophenyl)-1-(2-thienyl)-1-propanone 869734-23-6 C20H17ClN4OS3
    3-{[4-amino-5-(2-thienylmethyl)-4H-1,2,4-triazol-3-yl]sulfanyl}-3-(4-chlorophenyl)-1-(2-thienyl)-1-propanone
    —— ethyl N-(5-amino-2,2-dimethyl-3-phenyl-pyrido[4,3-b][1,4]thiazin-7-yl)carbamate 91599-72-3 C18H20N4O2S
    ethyl N-(5-amino-2,2-dimethyl-3-phenyl-pyrido[4,3-b][1,4]thiazin-7-yl)carbamate
    —— 3-(3-chloropropyl)-1H-2,4,1-benzodithiazine 2,2-dioxide 1033629-43-4 C10H12ClNO2S2
    3-(3-chloropropyl)-1H-2,4,1-benzodithiazine 2,2-dioxide
    —— (<i>Z</i>)-1,2-dichloro-1-phenylsulfanyl-ethylene 877122-23-1 C8H6Cl2S
    (<i>Z</i>)-1,2-dichloro-1-phenylsulfanyl-ethylene
    —— (E)-1-(phenyl-2-phenylsulfanyl)hept-2-en-1-ol 1217367-32-2 C19H22OS
    (E)-1-(phenyl-2-phenylsulfanyl)hept-2-en-1-ol
    —— di(S)-pent-1-en-3-ylsulfane 1314185-28-8 C10H18S
    di(S)-pent-1-en-3-ylsulfane
    —— (E)-2-(4-hydroxyphenyl)sulfanylbut-2-enedioic acid —— C10H8O5S
    (E)-2-(4-hydroxyphenyl)sulfanylbut-2-enedioic acid
    —— 4,5-(1-tert-butyldiphenylsilyloxypropane-2,3-diyldithio)-1,3-dithiole-2-thione 307543-47-1 C22H24OS5Si
    4,5-(1-tert-butyldiphenylsilyloxypropane-2,3-diyldithio)-1,3-dithiole-2-thione
    —— 4,5-(1-tert-butyldiphenylsilyloxypropane-2,3-diyldithio)-1,3-dithiol-2-one 307543-49-3 C22H24O2S4Si
    4,5-(1-tert-butyldiphenylsilyloxypropane-2,3-diyldithio)-1,3-dithiol-2-one
    —— S-[[dichloro(methoxy)methyl]trisulfanyl] chloromethanethioate 88766-45-4 C3H3Cl3O2S4
    S-[[dichloro(methoxy)methyl]trisulfanyl] chloromethanethioate
    —— 3,5-dichloro-6-(methylthio)pyridin-2-ol 870971-34-9 C6H5Cl2NOS
    3,5-dichloro-6-(methylthio)pyridin-2-ol
    —— S-[[dichloro(ethoxy)methyl]trisulfanyl] chloromethanethioate 88766-46-5 C4H5Cl3O2S4
    S-[[dichloro(ethoxy)methyl]trisulfanyl] chloromethanethioate
    —— 5-chloro-N-(2,4-dimethoxybenzyl)-2-fluoro-N-1,3,4-thiadiazol-2-yl-4-{[3-(trifluoromethyl)phenyl]thio}benzenesulfonamide 1354917-51-3 C24H18ClF4N3O4S3
    5-chloro-N-(2,4-dimethoxybenzyl)-2-fluoro-N-1,3,4-thiadiazol-2-yl-4-{[3-(trifluoromethyl)phenyl]thio}benzenesulfonamide
    —— [Dichloro-[[dichloro(ethoxy)methyl]tetrasulfanyl]methoxy]ethane 88766-47-6 C6H10Cl4O2S4
    [Dichloro-[[dichloro(ethoxy)methyl]tetrasulfanyl]methoxy]ethane
    —— 5-chloro-2-fluoro-4-[(4-methoxyphenyl)thio]-N-1,3,4-thiadiazol-2-ylbenzenesulfonamide 1354917-03-5 C15H11ClFN3O3S3
    5-chloro-2-fluoro-4-[(4-methoxyphenyl)thio]-N-1,3,4-thiadiazol-2-ylbenzenesulfonamide
    —— 5-chloro-2-fluoro-N-1,3,4-thiadiazol-2-yl-4-{[3-(trifluoromethyl)phenyl]thio}benzenesulfonamide 1354917-01-3 C15H8ClF4N3O2S3
    5-chloro-2-fluoro-N-1,3,4-thiadiazol-2-yl-4-{[3-(trifluoromethyl)phenyl]thio}benzenesulfonamide
    —— Benzo[c]thiophen-4(5H)-one, 6,7-dihydro-6,6-dimethyl-3-(methylthio)-, oxime —— C11H15NOS2
    Benzo[c]thiophen-4(5H)-one, 6,7-dihydro-6,6-dimethyl-3-(methylthio)-, oxime
    —— 1-((4-chloro-3-fluorophenyl)(1-methyl-1H-pyrazol-4-yl)methyl)-4-(2-(methylthio)pyrimidin-4-yl)pyridin-2(1H)-one 1453853-55-8 C21H17ClFN5OS
    1-((4-chloro-3-fluorophenyl)(1-methyl-1H-pyrazol-4-yl)methyl)-4-(2-(methylthio)pyrimidin-4-yl)pyridin-2(1H)-one
    —— (E)-2-Phenylsulfanyl-but-2-enedioic acid 59790-40-8 C10H8O4S
    (E)-2-Phenylsulfanyl-but-2-enedioic acid
    —— N'-[2-[2-(6-aminohexylamino)ethyldisulfanyl]ethyl]hexane-1,6-diamine;hydrochloride 68535-75-1 C16H38N4S2*4ClH
    N'-[2-[2-(6-aminohexylamino)ethyldisulfanyl]ethyl]hexane-1,6-diamine;hydrochloride
    —— (S)-1-(2-(tert-butyldimethylsilyloxy)-1-(3-chloro-4-fluorophenyl)ethyl)-4-(2-(methylthio)pyrimidin-4-yl)pyridin-2(1H)-one 1453852-92-0 C24H29ClFN3O2SSi
    (S)-1-(2-(tert-butyldimethylsilyloxy)-1-(3-chloro-4-fluorophenyl)ethyl)-4-(2-(methylthio)pyrimidin-4-yl)pyridin-2(1H)-one
    —— 1-((4-chloro-3-fluorophenyl)(1H-pyrazol-4-yl)methyl)-4-(2-(methylthio)pyrimidin-4-yl)pyridin-2(1H)-one 1453853-53-6 C20H15ClFN5OS
    1-((4-chloro-3-fluorophenyl)(1H-pyrazol-4-yl)methyl)-4-(2-(methylthio)pyrimidin-4-yl)pyridin-2(1H)-one
    —— (S)-1-(2-(tert-butyldimethylsilyloxy)-1-(3-chlorophenyl)ethyl)-4-(2-(methylthio)pyrimidin-4-yl)pyridin-2(1H)-one 1453853-18-3 C24H30ClN3O2SSi
    (S)-1-(2-(tert-butyldimethylsilyloxy)-1-(3-chlorophenyl)ethyl)-4-(2-(methylthio)pyrimidin-4-yl)pyridin-2(1H)-one
    —— 1-((4-chloro-3-fluorophenyl)(oxazol-5-yl)methyl)-4-(2-(methylthio)pyrimidin-4-yl)pyridin-2(1H)-one 1453853-42-3 C20H14ClFN4O2S
    1-((4-chloro-3-fluorophenyl)(oxazol-5-yl)methyl)-4-(2-(methylthio)pyrimidin-4-yl)pyridin-2(1H)-one
    —— 2-(5'-Hexenyl)-2-<2"-(1,3-dioxolanyl)ethyl>-1,3-dithiane 146353-05-1 C15H26O2S2
    2-(5'-Hexenyl)-2-<2"-(1,3-dioxolanyl)ethyl>-1,3-dithiane
    —— (3-Bromo-1-phenylsulfanylpropyl)sulfanylbenzene 89593-90-8 C15H15BrS2
    (3-Bromo-1-phenylsulfanylpropyl)sulfanylbenzene
    —— 2-[2-(2-fluoromethylphenylsulfanyl)ethyl]-[1,3]dioxolane 758717-02-1 C12H15FO2S
    2-[2-(2-fluoromethylphenylsulfanyl)ethyl]-[1,3]dioxolane
    —— 2-Tert-butyl-1-[2-(1,3-dioxolan-2-yl)ethyl]-6-(2-fluoropyridin-4-yl)sulfanylbenzimidazole 1001077-27-5 C21H24FN3O2S
    2-Tert-butyl-1-[2-(1,3-dioxolan-2-yl)ethyl]-6-(2-fluoropyridin-4-yl)sulfanylbenzimidazole
    —— 2,6-dibromo-4-fluorothioanisole 38366-77-7 C7H5Br2FS
    2,6-dibromo-4-fluorothioanisole
    —— 3-(ethylsulfanyl)-5-methyl-1-phenyl-7-(tetrahydro-1H-1-pyrrolyl)-1H-pyrimido[4,5-e][1,3,4]thiadiazine 1161010-40-7 C18H21N5S2
    3-(ethylsulfanyl)-5-methyl-1-phenyl-7-(tetrahydro-1H-1-pyrrolyl)-1H-pyrimido[4,5-e][1,3,4]thiadiazine
    —— 5-fluoro-2-phenylsulfanyl-3-phenylsulfanylmethyl-1H-indole 1295558-78-9 C21H16FNS2
    5-fluoro-2-phenylsulfanyl-3-phenylsulfanylmethyl-1H-indole
    —— 4-amino-2-[(6-chloropyridin-3-yl)methylsulfanyl]-1H-pyrimidin-6-one 95016-54-9 C10H9ClN4OS
    4-amino-2-[(6-chloropyridin-3-yl)methylsulfanyl]-1H-pyrimidin-6-one
    —— 2-amino-3-nitro-6-(methylthio)pyridine 144435-17-6 C6H7N3O2S
    2-amino-3-nitro-6-(methylthio)pyridine
    —— 4,5-Bis(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylsulfanyl)-1,3-dithiole-2-thione 166545-02-4 C19H8F26S5
    4,5-Bis(3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctylsulfanyl)-1,3-dithiole-2-thione
    —— 1-(6-methoxy-2-pyridyl)-N-(2-methylsulfanylphenyl)-methanimine 1618679-78-9 C14H14N2OS
    1-(6-methoxy-2-pyridyl)-N-(2-methylsulfanylphenyl)-methanimine
    —— 2-nitro-5-[[3-(trifluoromethyl)phenyl]sulfanyl]pyridine 1609560-94-2 C12H7F3N2O2S
    2-nitro-5-[[3-(trifluoromethyl)phenyl]sulfanyl]pyridine
    —— 5-[(3,5-difluorophenyl)sulfanyl]-2-nitropyridine 1609560-89-5 C11H6F2N2O2S
    5-[(3,5-difluorophenyl)sulfanyl]-2-nitropyridine
    —— 1-Cyclopentyl-7-methylsulfanyl-1H-2-thia-1,6,8-triaza-naphthalene 2,2-dioxide 572915-36-7 C12H15N3O2S2
    1-Cyclopentyl-7-methylsulfanyl-1H-2-thia-1,6,8-triaza-naphthalene 2,2-dioxide
    —— 1-(4-cyclopentylamino-2-methylsulfanylpyrimidin-5-yl)propan-1-one 850628-74-9 C13H19N3OS
    1-(4-cyclopentylamino-2-methylsulfanylpyrimidin-5-yl)propan-1-one
    —— <i>tert</i>-Butylmercapto-acetylen 41463-35-8 C6H10S
    <i>tert</i>-Butylmercapto-acetylen
    —— 1-(4-cyclopentylamino-2-methylsulfanylpyrimidin-5-yl)-2,2,2-trifluoroethanone 850628-75-0 C12H14F3N3OS
    1-(4-cyclopentylamino-2-methylsulfanylpyrimidin-5-yl)-2,2,2-trifluoroethanone
    —— cis-Ethylen-1.2-di-tert.-butyl-sulfon 87137-89-1 C10H20O4S2
    cis-Ethylen-1.2-di-tert.-butyl-sulfon
    —— 1.2-Bis-tert.butylsulfonyl-aethan 5862-63-5 C10H22O4S2
    1.2-Bis-tert.butylsulfonyl-aethan
    —— 1-(4-cyclopentylamino-2-methylsulfanylpyrimidin-5-yl)-2,2,2-trifluoroethanol 850628-72-7 C12H16F3N3OS
    1-(4-cyclopentylamino-2-methylsulfanylpyrimidin-5-yl)-2,2,2-trifluoroethanol